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    • 32. 发明授权
    • Yellow dye mixture for thermal color proofing
    • 黄色染料混合物用于热色印
    • US5081101A
    • 1992-01-14
    • US676922
    • 1991-03-28
    • Steven EvansDerek D. Chapman
    • Steven EvansDerek D. Chapman
    • B41M5/382B41M5/26B41M5/385B41M5/388B41M5/39B41M5/50B41M5/52G03F3/10
    • B41M5/3854G03F3/108Y10S428/913Y10S428/914Y10S430/146
    • A yellow dye-donor element for thermal dye transfer comprises a support having thereon a dye layer comprising a mixture of yellow dyes dispersed in a polymeric binder, at least one of the yellow dyes having the formula: ##STR1## wherein: R.sup.1 is a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; or a substituted or unsubstituted allyl group;R.sup.2 is any of the groups for R.sup.1 or represents the atoms which when taken together with Z form a 5- or 6-membered ring;Z is hydrogen; any of the groups for R.sup.1 ; alkoxy; halogen; aryloxy; or represents the atoms which when taken together with R.sup.2 forms a 5- or 6-membered ring;Y is any of the groups for R.sup.1 ; alkoxy of from 1 to about 10 carbon atoms; halogen; or represents the atoms necessary to complete a 5- or 6-membered ring, thus forming a fused ring system; andn is a positive integer from 1 to 3; and at least one of the other of the dyes having the formula: ##STR2## wherein: R.sup.6 represents a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; or an aryl group having from about 6 to about 10 carbon atoms;R.sup.7 represents a substituted or unsubstituted alkoxy group having from 1 to about 10 carbon atoms; a substituted or unsubstituted aryloxy group having from about 6 to about 10 carbon atoms; NHR.sup.8 ; NR.sup.8 R.sup.9 or the atoms necessary to complete a 6-membered ring fused to the benzene ring;R.sup.3 and R.sup.4 each represents any of the groups for R.sup.6 ; or R.sup.3 and R.sup.4 can be joined together to form, along with the nitrogen to which they are attached, a 5- or 6-membered heterocyclic ring; or either or both of R.sup.3 and R.sup.4 can be joined to the carbon atom of the benzene ring at a position ortho to the position of attachment of the anilino nitrogen to form a 5- or 6-membered ring, thus forming a polycyclic system;R.sup.5 represents hydrogen; a substituted or unsubstituted alkyl group of from 1 to about 10 carbon atoms; a cycloalkyl group of from about 5 to about 7 carbon atoms; a substituted or unsubstituted allyl group; carbamoyl; or alkoxycarbonyl;R.sup.8 and R.sup.9 each independently represents any of the groups for R.sup.6 ; or R.sup.8 and R.sup.9 may be joined together to form, along with the nitrogen to which they are attached, a 5- or 6-membered heterocyclic ring;m is a positive integer from 1 to 3; andG represents a substituted or unsubstituted alkyl or alkoxy group of from 1 to about 10 carbon atoms; halogen; aryloxy; or represents the atoms necessary to complete a 5- or 6-membered ring, thus forming a fused ring system.In a preferred embodiment of the invention, a third yellow dye is employed having the formula: ##STR3## wherein: R.sup.10 represents OR.sup.13 or NHR.sup.13 ;R.sup.11 represents any of the groups for R.sup.4 ;R.sup.12 represents any of the groups for R.sup.4 ;R.sup.13 represents any of the groups for R.sup.6 ;J represents any of the groups for G; andp is a positive integer from 1 to 3.
    • 38. 发明授权
    • Photographic products and processes employing metal complexable
nondiffusible azo dye-releasing compounds
    • 使用金属可络合的非扩散偶氮染料释放化合物的摄影产品和方法
    • US4183755A
    • 1980-01-15
    • US950193
    • 1978-10-10
    • Derek D. ChapmanE-Ming Wu
    • Derek D. ChapmanE-Ming Wu
    • C09B45/04G03C8/10G03C1/40C09B45/14
    • C09B45/04G03C8/10
    • Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable azo dye moiety. The compound has the formula: ##STR1## wherein: G is a metal chelating group (or a salt or hydrolyzable precursor thereof) or a group which together with a ##STR2## is CAR (bonded through the oxygen); G.sup.1 is a hydroxy group (or a salt or hydrolyzable precursor thereof);Z is an electron withdrawing group;Z' is alkyl, aryl or N(R).sub.2 (R being H, alkyl or aryl);CAR is a ballasted carrier moiety; andt is 0 or 1.The dye can be transferred imagewise to an image-receiving layer where it can be contacted with metal ions to form a metal-complexed azo dye transfer image of excellent stability. The retained dye image in the photographic element can also be bleached, fixed and metallized to form a color transparency or a motion picture film.
    • 描述了摄影元件,扩散转移组合和方法,其使用具有可释放的偶氮染料部分的新型不可扩散化合物。 该化合物具有下式:其中:G是金属螯合基团(或其盐或可水解的前体)或与“IMA”键合的基团(通过氧键合); G1是羟基(或其盐或可水解的前体); Z是吸电子基团; Z'是烷基,芳基或N(R)2(R是H,烷基或芳基); CAR是压载载体部分; 并且t为0或1.染料可以成像转移到图像接收层,其中它可以与金属离子接触以形成具有优异稳定性的金属络合的偶氮染料转移图像。 摄影元件中保留的染料图像也可以被漂白,固定和金属化以形成彩色透明或电影胶片。