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31. 发明授权

US08461232B2 Dispersing agent containing copolymer mixture 有权
标题翻译：分散剂含共聚物混合物
公开(公告)号：US08461232B2
公开(公告)日：2013-06-11
申请号：US13132971
申请日：2009-11-25
申请人： Mario Vierle , Klaus Lorenz , Silke Flakus , Petra Wagner , Christian Scholz , Barbara Wimmer , Manfred Bichler , Angelika Hartl , Martin Winklbauer
发明人： Mario Vierle , Klaus Lorenz , Silke Flakus , Petra Wagner , Christian Scholz , Barbara Wimmer , Manfred Bichler , Angelika Hartl , Martin Winklbauer
IPC分类号： C04B28/02 , C08J3/02 , C08K3/20 , C08L39/04 , C08L33/14
CPC分类号： C04B24/2694 , C04B24/2647 , C04B24/267 , C04B2103/30 , C04B2103/40 , C04B2103/52 , C08L29/10 , C08L33/02 , C08L35/08 , C08L2205/02 , C08L2666/04
摘要： The invention relates to a polymer composition containing 3 to 90% by weight of a copolymer H and 3 to 90% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, at least 60 mol % of the polyether macromonomer structural units of the copolymer H being represented by the isoprenol polyether derivative structural units and at least 60 mol % of the polyether macromonomer structural units of the copolymer K being represented by the vinyloxy polyether derivative structural units.
摘要翻译：本发明涉及含有3〜90重量％共聚物H和3〜90重量％共聚物K的聚合物组合物，共聚物H和K各自具有聚醚大分子单体结构单元和酸单体结构单元，其存在在共聚物H和K中的摩尔比为1:20至1:1的共聚物中，和共聚物H的所有结构单元的至少20摩尔％和共聚物K的所有结构单元的至少25摩尔％在各种情况下以酸性单体结构单元的形式存在，共聚物H的至少60摩尔％的聚醚大分子单体结构单元由异戊二烯醇聚醚衍生物结构单元表示，并且至少60摩尔％的聚醚大分子单体结构单元的共聚物K由乙烯基氧基聚醚衍生物结构单元表示。

32. 发明申请

US20090312504A1 Copolymer Synthesis Process 有权
标题翻译：共聚物合成工艺
公开(公告)号：US20090312504A1
公开(公告)日：2009-12-17
申请号：US12477565
申请日：2009-06-03
申请人： Klaus K. Lorenz , Alexander Kraus , Barbara Wimmer , Petra Wagner , Christian Scholz , Manfred Bichler
发明人： Klaus K. Lorenz , Alexander Kraus , Barbara Wimmer , Petra Wagner , Christian Scholz , Manfred Bichler
IPC分类号： C08F2/04
CPC分类号： C04B28/02 , C04B24/2647 , C04B24/2694 , C04B2103/308 , C08F216/1416 , C08F220/26 , Y10S526/915 , C04B2103/302
摘要： Preparing a non-ionic copolymer having a hydrolysable monomer residue and a polyether macromonomer residue in a semicontinuous mode in a polymerization reactor associated with a metering device, including introducing polyether macromonomer and water into the reactor, wherein hydrolysable monomer which is added thereto forms a polymerization reaction mixture; introducing hydrolysable monomer into the metering device; adding hydrolysable monomer into the reactor from the metering device; passing a free radical polymerization initiator into the reactor before and/or during the addition of the hydrolysable monomer, the hydrolysable monomer and the polyether macromonomer reacting by free radical polymerization to form the non-ionic copolymer; and, subjecting the reaction mixture to polymerization while an addition rate of the hydrolysable monomer and/or at least a component of the polymerization initiator is varied stepwise or continuously. No monomer is introduced to incorporate ionic cement binding sites into the non-ionic copolymer.
摘要翻译：在与计量装置相关联的聚合反应器中制备具有可水解单体残基和聚醚大分子单体残基的非离子共聚物，其包括将聚醚大分子单体和水引入反应器，其中加入的可水解单体形成聚合反应混合物; 将可水解单体引入计量装置; 从计量装置将可水解单体加入到反应器中; 在可水解单体加入之前和/或期间将自由基聚合引发剂通入自由基聚合引发剂，可水解单体和聚醚大分子单体通过自由基聚合反应形成非离子共聚物; 并且使反应混合物进行聚合，同时可水解单体和/或至少一种聚合引发剂组分的添加速率逐步或连续地改变。没有引入单体以将离子水泥结合位点引入非离子共聚物。

33. 发明申请

US20090163622A1 Copolymers Based On Unsaturated Monocarboxylic or Dicarboxylic Acid Derivatives and Oxyalkylene Glycol Alkenyl Ethers, Process for Preparing Them and Their Use 审中-公开
标题翻译：基于不饱和单羧酸或二羧酸衍生物和氧亚烷基二醇乙烯基醚的共聚物，其制备方法及其应用
公开(公告)号：US20090163622A1
公开(公告)日：2009-06-25
申请号：US12084665
申请日：2006-12-20
申请人： Gerhard Albrecht , Klaus Lorenz , Christian Scholz , Petra Wagner
发明人： Gerhard Albrecht , Klaus Lorenz , Christian Scholz , Petra Wagner
IPC分类号： C08F220/00 , C08F222/04 , C08F216/12 , C08K3/00 , C08K3/30
CPC分类号： C04B24/2605 , C04B24/2647 , C04B24/267 , C04B24/2694 , C04B2103/30 , C04B2103/408 , C08F216/1416 , C08F220/06 , C08F222/06
摘要： Copolymers based on unsaturated mono- or dicarboxylic acid derivatives, oxyalkylene glycol alkenyl ethers and optionally vinylic polyalkylene glycol or ester compounds are described and also their use as additives for aqueous suspensions based on mineral or bituminous binders, in particular cement, gypsum, lime, anhydrite, or other calcium sulphate-based binders, and based on pulverulent dispersion binders. The copolymers according to the invention impart to the aqueous binder suspensions a very good dispersing and liquefying action with, at the same time, simultaneous excellent processing properties. Moreover, the oxyalkylene glycol alkenyl ethers according to the invention are industrially relatively simple and inexpensive to prepare and need comparatively low initiator concentrations in the copolymerization.
摘要翻译：描述了基于不饱和单羧酸或二羧酸衍生物，氧亚烷基二醇烯基醚和任选的乙烯基聚亚烷基二醇或酯化合物的共聚物，也用作基于矿物或沥青粘合剂，特别是水泥，石膏，石灰，无水石膏，或其它基于硫酸钙的粘合剂，并且基于粉末分散粘合剂。根据本发明的共聚物赋予水性粘合剂悬浮液非常好的分散和液化作用，同时具有同时优异的加工性能。此外，根据本发明的氧亚烷基二醇烯基醚在工业上相对简单且制备成本低，并且在共聚中需要相对较低的引发剂浓度。

34. 发明申请

US20090077975A1 Heat shield element for lining a combustion chamber wall, combustion chamber and gas turbine 有权
标题翻译：用于衬里燃烧室壁，燃烧室和燃气轮机的隔热元件
公开(公告)号：US20090077975A1
公开(公告)日：2009-03-26
申请号：US11918608
申请日：2006-04-18
申请人： Christian Scholz , Andreas Heilos , Stefan Hoffmann
发明人： Christian Scholz , Andreas Heilos , Stefan Hoffmann
IPC分类号： F23M5/00
CPC分类号： F27D1/04 , F23R3/005 , F23R2900/00005 , F27D1/0006 , F27D1/14
摘要： The invention relates to a heat shield element for lining a combustion chamber wall, to a combustion chamber and to a gas turbine. The heat shield element comprises a hot side that can be exposed to a hot medium, a wall side opposite said hot side, and a peripheral side adjoining the hot side and the wall side and having a peripheral side surface. Relief slots are introduced into the material in an area of the heat shield element that is susceptible to material cracks induced by thermal stress, thereby limiting crack propagation.
摘要翻译：本发明涉及一种用于将燃烧室壁，燃烧室和燃气轮机衬套的隔热元件。隔热元件包括可以暴露于热介质的热侧，与热侧相对的壁面和与热侧和壁侧相邻并具有周边侧表面的周边。在隔热元件的易受热应力引起的材料裂纹敏感的区域中的材料中引入浮雕槽，从而限制裂纹扩展。

35. 发明授权

US08754150B2 Copolymer having polyether side chains and dicarboxylic acid derivative components 有权
标题翻译：具有聚醚侧链和二羧酸衍生物成分的共聚物
公开(公告)号：US08754150B2
公开(公告)日：2014-06-17
申请号：US12867028
申请日：2009-01-12
申请人： Silke Flakus , Klaus Lorenz , Gerhard Albrecht , Helmut Mack , Angelika Hartl , Martin Winklbauer , Petra Wagner , Barbara Wimmer , Christian Scholz
发明人： Silke Flakus , Klaus Lorenz , Gerhard Albrecht , Helmut Mack , Angelika Hartl , Martin Winklbauer , Petra Wagner , Barbara Wimmer , Christian Scholz
IPC分类号： C04B24/26 , C08F222/40 , C08F222/06 , C08L39/06 , C08L39/08
CPC分类号： C08F222/06 , C04B24/267 , C04B2103/32
摘要： The invention relates to a copolymer which can be used as a superplasticizer for hydraulic binders and comprises 30 to 47 mol % of a (meth)allyl alcohol polyether derivative structural unit and 53 to 70 mol % of a maleic acid derivative structural unit.
摘要翻译：本发明涉及可用作水硬性粘合剂的超增塑剂的共聚物，其包含30〜47摩尔％的（甲基）烯丙醇聚醚衍生物结构单元和53〜70摩尔％的马来酸衍生物结构单元。

36. 发明授权

US08536285B2 Semi-continuous method for producing copolymers 有权
标题翻译：半连续共聚物的制备方法
公开(公告)号：US08536285B2
公开(公告)日：2013-09-17
申请号：US13133026
申请日：2009-11-25
申请人： Reinhard Dorfner , Klaus Lorenz , Petra Wagner , Christian Scholz
发明人： Reinhard Dorfner , Klaus Lorenz , Petra Wagner , Christian Scholz
IPC分类号： C08F216/14 , C08F2/10 , C08F224/00 , C04B16/04
CPC分类号： C08F290/00 , C08F265/00 , C08F267/00 , C08F283/06 , C08F290/062 , C08F290/142 , C08L51/003 , C08L2666/02
摘要： A process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus including a polymerization reactor connected to a metering device, acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device via an acid monomer metering line into the polymerization reactor, a portion of the copolymer-containing aqueous medium being passed continuously during the free radical polymerization from the polymerization reactor via a reaction mixture line which is connected via a mixing device to the acid monomer metering line, the discharged copolymer-containing aqueous medium being mixed with the acid monomer in the mixing device during the metering of the acid monomer and being recycled to the polymerization reactor after the mixing via the acid monomer metering line.
摘要翻译：一种在包括连接到计量装置的聚合反应器的聚合装置中的半连续操作中制备共聚物的方法，初始计量装置中的酸单体和聚合反应器中的聚醚大分子单体和水，酸单体从计量装置通过酸性单体计量管线进入聚合反应器，一部分含共聚物的水性介质在自由基聚合期间通过经由混合装置连接到酸单体的反应混合物线从聚合反应器中连续通过计量管线，在计量酸性单体期间将含有共聚物的含水介质与酸性单体混合在混合装置中，并通过酸性单体计量管道在混合后再循环到聚合反应器中。

37. 发明授权

US08536252B2 Semi continuously operated method for producing copolymers 有权
标题翻译：半连续生产共聚物的方法
公开(公告)号：US08536252B2
公开(公告)日：2013-09-17
申请号：US13133004
申请日：2009-11-25
申请人： Gerhard Albrecht , Helmut Mack , Klaus Lorenz , Mario Vierle , Silke Flakus , Petra Wagner , Christian Scholz , Harald Grassl , Barbara Wimmer
发明人： Gerhard Albrecht , Helmut Mack , Klaus Lorenz , Mario Vierle , Silke Flakus , Petra Wagner , Christian Scholz , Harald Grassl , Barbara Wimmer
IPC分类号： C08F224/00 , C08F2/10 , C04B28/28
CPC分类号： C08F2/01 , C04B24/267 , C04B24/2694 , C04B2103/408 , C08F216/1416 , C08F220/06 , C08F222/06
摘要： A process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, acid monomer being initially taken in the metering device and polyether macromonomer, acid monomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, the metering of the acid monomer being effected with the proviso that at least 70 mol % of the acid monomer metered in altogether are metered in the course of 5 to 19 minutes at a metering rate that is constant or varies to a limited extent.
摘要翻译：一种在聚合装置中半连续操作中制备共聚物的方法，包括连接到计量装置的聚合反应器，初始计量装置中的酸单体和聚合反应器中的聚合物大分子单体，酸单体和水，酸单体从计量装置计量到聚合反应器中，酸性单体的计量是在条件下进行的，条件是至少70mol％的酸单体一次计量在5至19分钟的过程中以计量速率计量，是恒定的或在有限的程度上变化。

38. 发明授权

US07973110B2 Copolymer synthesis process 有权
标题翻译：共聚物合成工艺
公开(公告)号：US07973110B2
公开(公告)日：2011-07-05
申请号：US12477565
申请日：2009-06-03
申请人： Klaus K. Lorenz , Alexander Kraus , Barbara Wimmer , Petra Wagner , Christian Scholz , Manfred Bichler
发明人： Klaus K. Lorenz , Alexander Kraus , Barbara Wimmer , Petra Wagner , Christian Scholz , Manfred Bichler
IPC分类号： C08F2/10 , C08F2/16 , C08F216/14
CPC分类号： C04B28/02 , C04B24/2647 , C04B24/2694 , C04B2103/308 , C08F216/1416 , C08F220/26 , Y10S526/915 , C04B2103/302
摘要： Preparing a non-ionic copolymer having a hydrolysable monomer residue and a polyether macromonomer residue in a semicontinuous mode in a polymerization reactor associated with a metering device, including introducing polyether macromonomer and water into the reactor, wherein hydrolysable monomer which is added thereto forms a polymerization reaction mixture; introducing hydrolysable monomer into the metering device; adding hydrolysable monomer into the reactor from the metering device; passing a free radical polymerization initiator into the reactor before and/or during the addition of the hydrolysable monomer, the hydrolysable monomer and the polyether macromonomer reacting by free radical polymerization to form the non-ionic copolymer; and, subjecting the reaction mixture to polymerization while an addition rate of the hydrolysable monomer and/or at least a component of the polymerization initiator is varied stepwise or continuously. No monomer is introduced to incorporate ionic cement binding sites into the non-ionic copolymer.
摘要翻译：在与计量装置相关联的聚合反应器中制备具有可水解单体残基和聚醚大分子单体残基的非离子共聚物，其包括将聚醚大分子单体和水引入反应器，其中加入的可水解单体形成聚合反应混合物; 将可水解单体引入计量装置; 从计量装置将可水解单体加入到反应器中; 在可水解单体加入之前和/或期间将自由基聚合引发剂通入自由基聚合引发剂，可水解单体和聚醚大分子单体通过自由基聚合反应形成非离子共聚物; 并且使反应混合物进行聚合，同时可水解单体和/或至少一种聚合引发剂组分的添加速率逐步或连续地改变。没有引入单体以将离子水泥结合位点引入非离子共聚物。

39. 发明申请

US20110054083A1 Copolymer Comprising Polyether Side Chains and Hydroxyalkyl and Acid Structural Units 有权
标题翻译：包含聚醚侧链和羟烷基和酸结构单元的共聚物
公开(公告)号：US20110054083A1
公开(公告)日：2011-03-03
申请号：US12866998
申请日：2009-01-12
申请人： Klaus Lorenz , Gerhard Albrecht , Silke Flakus , Alexander Kraus , Helmut Mack , Petra Wagner , Christian Scholz , Barbara Wimmer , Angelika Hartl , Martin Winklbauer
发明人： Klaus Lorenz , Gerhard Albrecht , Silke Flakus , Alexander Kraus , Helmut Mack , Petra Wagner , Christian Scholz , Barbara Wimmer , Angelika Hartl , Martin Winklbauer
IPC分类号： C08F220/06 , C08L31/02 , C04B16/04
CPC分类号： C08F290/062 , C04B24/2647 , C04B2103/408
摘要： The invention relates to a copolymer which is suitable as a superplasticizer for hydraulic binders and comprises 5 to 55 mol % of an isoprenol polyether derivative structural unit, 2 to 90 mol % of an acrylic acid derivative structural unit and 2 to 90 mol % of a hydroxyalkyl acrylate structural unit.
摘要翻译：本发明涉及一种适用作水硬性粘合剂的超增塑剂的共聚物，它包括5至55摩尔％的异戊二烯醇聚醚衍生物结构单元，2至90摩尔％的丙烯酸衍生物结构单元和2至90摩尔％的丙烯酸羟烷基酯结构单元。

40. 发明申请

US20110009529A1 Copolymer Having Polyether Side Chains And Dicarboxylic Acid Derivative Components 有权
标题翻译：具有聚醚侧链和二羧酸衍生物组分的共聚物
公开(公告)号：US20110009529A1
公开(公告)日：2011-01-13
申请号：US12867028
申请日：2009-01-12
申请人： Silke Flakus , Klaus Lorenz , Gerhard Albrecht , Helmut Mack , Angelika Hartl , Martin Winklbauer , Petra Wagner , Barbara Wimmer , Christian Scholz
发明人： Silke Flakus , Klaus Lorenz , Gerhard Albrecht , Helmut Mack , Angelika Hartl , Martin Winklbauer , Petra Wagner , Barbara Wimmer , Christian Scholz
IPC分类号： C04B24/26 , C08F222/40 , C08F222/06 , C08F220/68 , C08L39/06 , C08L37/00 , C08L31/06
CPC分类号： C08F222/06 , C04B24/267 , C04B2103/32
摘要： The invention relates to a copolymer which can be used as a superplasticizer for hydraulic binders and comprises 30 to 47 mol % of a (meth)allyl alcohol polyether derivative structural unit and 53 to 70 mol % of a maleic acid derivative structural unit.
摘要翻译：本发明涉及可用作水硬性粘合剂的超增塑剂的共聚物，其包含30〜47摩尔％的（甲基）烯丙醇聚醚衍生物结构单元和53〜70摩尔％的马来酸衍生物结构单元。

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