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    • 31. 发明授权
    • Continuous loop flow process for polyether polyol production
    • 聚醚多元醇生产的连续循环流程
    • US08912364B2
    • 2014-12-16
    • US12992025
    • 2009-05-19
    • Carlos M. VillaJohn W. WestonPradeep JainLeigh H. ThompsonJean-Paul Masy
    • Carlos M. VillaJohn W. WestonPradeep JainLeigh H. ThompsonJean-Paul Masy
    • C08G65/00C08G65/26
    • C08G65/2663C08G65/2609C08G65/2696Y02P20/124
    • The present disclosure relates, according to some embodiments, to compositions, apparatus, methods, and systems that may be used to produce polyols, for example, polyether polyols with a narrow range of molecular weights, with little if any unsaturated byproducts, in a sustained and/or continuous reaction, with efficient heat transfer, and/or at high production rates. For example, in some embodiments, teachings of the disclosure may be used to produce polyether polyols in a continuous loop flow process. A continuous loop flow process may be practiced such that heat is effectively transferred and/or product properties (e.g., range of molecular weights) are controllable. For example, a continuous loop flow process may use one or more continuous flow loops comprising a heat exchanger, a means to move material around each loop, inlets for catalyst, monomer, initiator or starter, and an outlet for polyol product.
    • 根据一些实施方案,本公开涉及可用于制备多元醇的组合物,装置,方法和系统,例如具有窄范围分子量的聚醚多元醇,几乎没有不饱和副产物,在持续的 和/或连续反应,有效的热传递和/或以高生产率。 例如,在一些实施方案中,本公开的教导可用于在连续环流过程中制备聚醚多元醇。 可以实践连续环流过程,使得有效地转移热量和/或产物性质(例如,分子量范围)是可控的。 例如,连续环流过程可以使用一个或多个连续流动回路,其包括热交换器,用于在每个回路周围移动材料的装置,用于催化剂,单体,引发剂或起动器的入口以及多元醇产物的出口。
    • 39. 发明授权
    • Narrow MWD, compositionally optimized ethylene interpolymer composition, process for making the same and article made therefrom
    • 窄MWD,组分优化的乙烯互聚物组合物,其制备方法和由其制备的制品
    • US06469103B1
    • 2002-10-22
    • US09156948
    • 1998-09-18
    • Pradeep JainLonnie G. HazlittJacquelyn A. deGrootKenneth W. Anderson
    • Pradeep JainLonnie G. HazlittJacquelyn A. deGrootKenneth W. Anderson
    • C08L2306
    • C08L23/0815C08F210/16C08L2205/02C08L2308/00C08L2314/06C08L2666/04C08F210/14C08F2500/03C08F2500/12C08F2500/26C08F2/001
    • The present invention pertains to an ethylene interpolymer composition characterized as having a narrow molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having at least two polymer components, the first component having an ATREF peak temperature, Tpeak1 and a viscosity average molecular weight, Mv1, and the second component having an ATREF peak temperature, Tpeak2, and a viscosity average molecular, Mv2, wherein the temperature differential between Tpeak2 and Tpeak1 decreases with increased composition density and Mv1/Mv2 is less than or equal to 1.2. The novel composition is further characterized as having a Mw/Mn of less than or equal to 3.3 as determined by gel permeation chromatography, an I10/I2>6.6, and a composition density less than 0.945 gram/cubic centimeter. The novel composition exhibits high, balanced toughness properties, good processibility and surprisingly improved optical properties and is particularly well-suited for use in applications such as lamination films trash can liners and heavy duty shipping bags, especially as a blown film.
    • 本发明涉及具有窄分子量分布(MWD)和优化组合均匀性的乙烯互聚物组合物,制备这种组合物的方法和由这种组合物制成的制造制品。 该新型组合物的特征在于具有至少两种聚合物组分,第一组分具有ATREF峰温度,Tpeak1和粘均分子量Mv1,第二组分具有ATREF峰温度Tpeak2和粘均分子, Mv2,其中Tpeak2和Tpeak1之间的温差随着组成密度的增加而降低,Mv1 / Mv2小于或等于1.2。 该新型组合物的特征还在于通过凝胶渗透色谱法测定的Mw / Mn小于或等于3.3,I10 / I2> 6.6,组成密度小于0.945克/立方厘米。 该新型组合物显示出高的平衡的韧性,良好的加工性和令人惊奇的改进的光学性能,特别适用于诸如层压膜垃圾桶衬里和重型运输袋,特别是作为吹塑薄膜的应用。