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    • 33. 发明授权
    • Nitrogen-containing derivatives of carboxymethylcellulose, their
synthesis and their use in cosmetic preparations
    • 羧甲基纤维素的含氮衍生物,其合成及其在化妆品制剂中的应用
    • US4988806A
    • 1991-01-29
    • US365612
    • 1989-06-13
    • Burghard GruningKlaus HoffmannGotz KoernerHans-Joachim Kollmeier
    • Burghard GruningKlaus HoffmannGotz KoernerHans-Joachim Kollmeier
    • A61K8/73A61Q5/00A61Q5/02C08B11/14C08B11/20D21H17/26
    • A61Q5/00A61K8/731A61Q5/02C08B11/14C08B11/20D21H17/26A61K2800/5426Y10S514/88
    • Derivatives of carboxymethylcellulose are disclosed in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR1## in which R.sup.1 is a hydrogen or methyl group,R.sup.2 is a divalent aliphatic hydrocarbon group with 2 to 5 carbon atoms,R.sup.3, R.sup.4 are alkyl groups with 1 to 4 carbon atoms,R.sup.5 is an alkyl group with 1 to 4 carbon atoms or a benzyl group,X is a halogen or sulfate group or a sulfonic acid group,with the proviso that, on the average, at least 0.1 quaternary ammonium groups are contained per anhydroglucose unit of the polymeric molecule.The invention furthermore relates to derivatives of carboxymethylcellulose, in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR2## in which the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meaning, with the proviso that, on the average, at least 0.1 tertiary amino groups are contained per anhydroglucose unit of the polymeric molecule, as intermediates for the synthesis of the aforementioned derivatives.The invention furthermore is directed to a method for the synthesis of the derivatives of carboxymethylcellulose and their use in cosmetic preparations, especially for the care of hair.
    • 公开了羧甲基纤维素的衍生物,其中全部或部分羧甲基被R 1为氢或甲基的通式为“IMAGE”的基团取代,R 2为具有2至5个碳原子的二价脂族烃基, R3,R4是具有1至4个碳原子的烷基,R5是具有1至4个碳原子的烷基或苄基,X是卤素或硫酸根或磺酸基,条件是平均 ,聚合物分子中每个脱水葡萄糖单元含有至少0.1个季铵基团。 本发明还涉及羧甲基纤维素的衍生物,其中全部或部分羧甲基被由通式“IMAGE”的基团取代,其中取代基R 1,R 2,R 3和R 4具有上述含义,条件是 平均来说,作为合成上述衍生物的中间体,聚合物分子中每个脱水葡萄糖单元含有至少0.1个叔氨基。 此外,本发明涉及一种合成羧甲基纤维素衍生物的方法及其在化妆品制剂中的用途,特别是用于护理头发。