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    • 33. 发明申请
    • Sulfonium Initiators, Process For Production And Use In Cationic Polymerizable Compositions
    • 锍引发剂,阳离子可聚合组合物的生产和使用方法
    • US20080200585A1
    • 2008-08-21
    • US11997192
    • 2006-07-27
    • Thomas KlettkeCornelia B. FuehrerAndrea HailandMarkus Mikulla
    • Thomas KlettkeCornelia B. FuehrerAndrea HailandMarkus Mikulla
    • C07C323/03C08G73/06A61K6/10
    • C08K5/372C08G59/687
    • The invention relates to an initiator comprising at least one structural element characterized by the following formula (I) wherein X− is a non or low coordinating anion, R1, R2, R3, R4 are independently linear, cyclic or branched C1-C20 alkyl or alkylene groups, wherein one or more of the methylene groups contained in the alkyl or alkylene group can be substituted by —CO—, —CONH—, —CON(CH3)—, —S— and/or —O—, and wherein R1, R2, R3 and/or R4 can act as a bridging element connecting two or more structural elements. The invention is also related to a process of producing the initiator and to a curable composition comprising the initiator, a process for producing the curable composition a kit comprising a cationically curable composition and the inventive initiator and the use of the initiator or the curable composition comprising the initiator for various applications, especially in the dental field.
    • 本发明涉及包含至少一种结构元件的引发剂,其特征在于以下式(I),其中X为 - 非配位阴离子或低配位阴离子,R1,R2,R3,R4独立地为直链,环状 或支链C 1 -C 20烷基或亚烷基,其中烷基或亚烷基中所含的一个或多个亚甲基可以被-CO - , - CONH-,-CON(CH 3) - , - S-和/或-O-,并且其中R 1,R 2,R 3和/或R 4可以作为连接两个或多个结构 元素。 本发明还涉及制备引发剂的方法和包含引发剂的可固化组合物的方法,制备可固化组合物的方法,包括阳离子可固化组合物和本发明引发剂的试剂盒以及引发剂或可固化组合物的用途,所述引发剂或可固化组合物包含 用于各种应用的引发剂,特别是在牙科领域。
    • 37. 发明申请
    • CURABLE COMPOSITION, PROCESS OF PRODUCTION AND USE THEREOF
    • 可固化组合物,生产方法及其用途
    • US20130157226A1
    • 2013-06-20
    • US13819002
    • 2011-08-23
    • Joachim W. ZechHendrik GruppThomas Klettke
    • Joachim W. ZechHendrik GruppThomas Klettke
    • A61K6/10A61C9/00A61K6/087
    • A61K6/10A61C9/00A61K6/087
    • The present disclosure relates to a curable composition to be prepared by mixing a base paste and a catalyst paste, the base paste comprising (A) a hardenable compound comprising at least two aziridine moieties, and (B) a metal containing component containing anions and/or ligands, the metal containing component being present in an amount of about 0.1 to about 5 wt.-%, the metal being selected from Zn, Cu, Co, Ni, Ag and combinations thereof, the anions or ligands being selected from oxide, hydroxyl, (hydro)carbonate, sulphate, nitrate, halide, lactate, benzoate, wolframate, linear or branched aliphatic carboxylic acid anions, ligands having not more than two coordinating moieties and combinations thereof, the catalyst paste comprising (C) a Lewis acid, the composition optionally further comprising (D) a retarder, (E) filler and (F) additive(s).The present disclosure also relates to a kit of parts, the use of a metal containing component as a means for reducing the curing time of a cationically curable composition and a method of taking a dental impression.
    • 本公开内容涉及通过将基础浆料和催化剂浆料混合而制备的可固化组合物,所述基料糊料包含(A)包含至少两个氮丙啶部分的可硬化化合物,和(B)含有金属的组分含有阴离子和/ 或配体,所述含金属组分以约0.1至约5重量%的量存在,所述金属选自Zn,Cu,Co,Ni,Ag及其组合,所述阴离子或配体选自氧化物, 羟基,碳酸氢盐,硫酸盐,硝酸盐,卤化物,乳酸盐,苯甲酸盐,钨酸盐,直链或支链脂族羧酸阴离子,具有不超过两个配位部分的配体及其组合,所述催化剂浆料包含(C)路易斯酸, 组合物任选地还包含(D)缓凝剂,(E)填料和(F)添加剂。 本公开还涉及一种试剂盒,使用含金属成分作为降低阳离子可固化组合物的固化时间的手段和采用牙印的方法。