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31. 发明申请

US20050192413A1 Perioxidic perfluoropolyethers 有权
标题翻译：过氧化全氟聚醚
公开(公告)号：US20050192413A1
公开(公告)日：2005-09-01
申请号：US11063996
申请日：2005-02-24
申请人： Giuseppe Marchionni , Pier Guarda
发明人： Giuseppe Marchionni , Pier Guarda
IPC分类号： C07C69/708 , C08G65/00 , C08G65/32 , C08G65/48 , C08J3/09 , C08G59/14 , C07C409/24 , C07C409/44
CPC分类号： C08G65/32 , C08G65/007
摘要： Peroxidic perfluoropolyethers having formula: X1—O(CF2O)n1(CF2CF2O)m1(CF2(CF2)zCF2O)p1(O)h—X2 (I) wherein: X1 and X2, equal to or different from each other, are chain end groups selected between —CF2COF and —COF; n1, m1, p1 and h are integers such that the number average molecular weight is in the range 700-100,000; z=1 or 2; with the proviso that: the m1/n1 ratio is between 0.2 and 10; the p1/(n1+m1) ratio is lower than 0.05; the h/(n1+m1+p1) ratio is such that the PO content, defined as grams of active oxygen/100 g of compound, is in the range 0.8-4.5, preferably 1.4-3.8; the perfluorooxyalkylene units being statistically distributed along the polymeric chain.
摘要翻译：具有下式的过氧化全氟聚醚：<？in-line-formula description =“In-line Formulas”end =“lead”？> X 1 -O（CF 2 O）（CF 2）2（CF 2）2（CF 2）（CF 2）（CF 2）（O） > 2 <？in-line-formula description =“In-line Formulas”end =“tail”？>其中：X 1和X 2 < SUB>，彼此相同或不同，是在-CF 2 COF和-COF之间选择的链端基; n1，m1，p1和h是数均分子量在700-100,000范围内的整数; z = 1或2; 条件是：m1 / n1比在0.2和10之间; p1 /（n1 + m1）比低于0.05; h /（n1 + m1 + p1）的比例使得定义为活性氧克数/ 100g化合物的PO含量在0.8-4.5，优选1.4-3.8的范围内; 全氟氧化烯单元沿着聚合物链统计分布。

32. 发明授权

US5780414A Method of removing oily substances with hydrogen-terminated fluoropolyethers 失效
标题翻译：用氢封端的氟聚醚去除油状物质的方法
公开(公告)号：US5780414A
公开(公告)日：1998-07-14
申请号：US810771
申请日：1997-03-05
申请人： Rossella Silvani , Gianfranco Spataro , Giuseppe Marchionni
发明人： Rossella Silvani , Gianfranco Spataro , Giuseppe Marchionni
IPC分类号： C11D7/30 , C07C43/12 , C07C43/313 , C11D7/50 , C23G5/032 , B08B3/04 , C11D7/26
CPC分类号： C23G5/032 , C11D7/5018
摘要： Use of solvents capable of removing oily substances without solubilizing them, consisting of hydrofluoropolyethers having the general formula HF.sub.2 CO (CF.sub.2 O).sub.n (CF.sub.2 CF.sub.2 O).sub.m CF.sub.2 H wherein n and m are integers comprised between 0 and 20, excluding when m and n are contemporaneously 0, and having boiling point from 30.degree. to 200.degree. C. and having a molar ratio 0/C comprised between 0.5-1.
摘要翻译：使用能够除去油性物质而不溶解的溶剂，由具有通式为HF 2 CO（CF 2 O）n（CF 2 CF 2 O）m CF 2 H的氢氟聚醚组成，其中n和m为0和20之间的整数，不包括当m和n同时为0时，具有沸腾点在30℃至200℃之间，摩尔比0 / C为0.5-1。

33. 发明授权

US5744651A Process for preparing peroxidic perfluoropolyoxyalkylenes 失效
标题翻译：制备过氧化全氟聚氧化烯的方法
公开(公告)号：US5744651A
公开(公告)日：1998-04-28
申请号：US800022
申请日：1997-02-13
申请人： Giuseppe Marchionni , Pier Antonio Guarda
发明人： Giuseppe Marchionni , Pier Antonio Guarda
IPC分类号： C07C409/16 , C08F114/26 , C08G65/00 , C07C409/20
CPC分类号： C08G65/007
摘要： Tetrafluoroethylene oxidation process at temperatures comprised between -100.degree. C. and -40.degree. C., in absence of Uv radiations, and by operating in the presence of a chemical initiator containing at least one F--X bond, wherein X is oxygen or halogen, in the presence of a solvent comprising an amount of COF.sub.2 higher than 8% by moles.
摘要翻译：四氟乙烯氧化过程在-100℃至-40℃的温度下，在不存在Uv辐射的情况下，并且在含有至少一个FX键的化学引发剂存在下操作，其中X是氧或卤素，含有大于8摩尔％的COF的量的溶剂的存在。

34. 发明授权

US5488181A Process for preparing perfluoropolyethers 失效
标题翻译：制备全氟聚醚的方法
公开(公告)号：US5488181A
公开(公告)日：1996-01-30
申请号：US341150
申请日：1994-11-16
申请人： Giuseppe Marchionni , Pier A. Guarda , Maurizio Paganin
发明人： Giuseppe Marchionni , Pier A. Guarda , Maurizio Paganin
IPC分类号： C07C409/20 , C07C407/00 , C08G65/00 , C07C43/30
CPC分类号： C08G65/007
摘要： Process for preparing peroxidic perfluoropolyethers by oxidation of tetrafluoroethylene with oxygen, in liquid phase comprising a solvent and in the presence of a chemical initiator, at a pressure between 2 and 15 absolute atm and operating with a molar ratio of the tetrafluoroethylene to the chemical initiator higher than 35. The process allows to increase the molecular weight of the perfluoropolyethers at the same content of peroxidic oxygen.
摘要翻译：通过用氧气在包含溶剂的液相中并且在化学引发剂存在下，在2至15绝对大气压的压力下氧化四氟乙烯并以四氟乙烯与化学引发剂的摩尔比更高的方式制备过氧化全氟聚醚的方法该方法允许以相同的过氧化氧含量增加全氟聚醚的分子量。

35. 发明授权

US5258110A Process for preparing peroxidic perfluoropolyethers 失效
标题翻译：制备过氧化全氟聚醚的方法
公开(公告)号：US5258110A
公开(公告)日：1993-11-02
申请号：US613495
申请日：1990-10-31
申请人： Dario Sianesi , Antonio Marraccini , Giuseppe Marchionni
发明人： Dario Sianesi , Antonio Marraccini , Giuseppe Marchionni
IPC分类号： C08G65/00 , C07C41/00
CPC分类号： C08G65/007
摘要： A process is disclosed for preparing peroxidic perfluoropolyethers containing perfluoroalkylenoxy units (CF.sub.2 --CF.sub.2 O) and (CF.sub.2 O), which is characterized in that tetrafluoroethylene and oxygen are reacted in a solvent at a temperature not exceeding 50.degree. C. and in the presence of one or more compounds having one or more F--X bonds, in which X is selected from the group consisting of F, O and Cl.

36. 发明授权

US5220076A Perfluoropolyethers and processes for their preparation 失效
标题翻译：全氟聚醚及其制备方法
公开(公告)号：US5220076A
公开(公告)日：1993-06-15
申请号：US890087
申请日：1992-05-29
申请人： Antonio Marraccini , Antonio Pasquale , Anna M. Staccione , Giuseppe Marchionni
发明人： Antonio Marraccini , Antonio Pasquale , Anna M. Staccione , Giuseppe Marchionni
IPC分类号： C08G65/00 , C08G65/321 , C08G65/329
CPC分类号： C08G65/007 , C08G65/321 , C08G65/329
摘要： The invention relates to new peroxide perfluoropolyethers having formula: ##STR1## wherein: A and B are end groups,X represents a (R'O).sub.m R" group where R' is selected from the class consisting of --CF.sub.2 --, --CF.sub.2 --CF.sub.2 -- and ##STR2## and R" is a perfluoroalkyl group; the value of "m" ranging from 0 to 6. The invention relates also to processes for preparing said perfluoropolyethers and other classes of non peroxide perfluoropolyethers derived therefrom.
摘要翻译：本发明涉及具有下式的新型过氧化物全氟聚醚：其中：A和B是端基，X代表（R'O）mR“基团，其中R'选自-CF2- ，-CF 2 -CF2-和，R“为全氟烷基; “m”的值在0至6之间。本发明还涉及制备所述全氟聚醚和由其衍生的其它类型的非过氧化物全氟聚醚的方法。

37. 发明授权

US5059700A Perfluoropolyethers free from peroxidic oxygen and containing perfluoroepoxy groups positioned along the perfluoropolyether chain, and their derivatives 失效
标题翻译：全氟聚醚不含过氧氧化物和含有全氟代醇链的全氟醚基团及其衍生物
公开(公告)号：US5059700A
公开(公告)日：1991-10-22
申请号：US561251
申请日：1990-07-30
申请人： Giuseppe Marchionni , Ugo De Patto , Ezio Strepparola , Gian Tommaso Viola
发明人： Giuseppe Marchionni , Ugo De Patto , Ezio Strepparola , Gian Tommaso Viola
IPC分类号： C08G67/00 , C08G59/14 , C08G59/34 , C08G65/00 , C08G65/22
CPC分类号： C08G59/027 , C08G59/14 , C08G65/007
摘要： Perfluoropolyethers having fluorinated epoxy groups positioned along their perfluoropolyether chain, and free from peroxidic oxygen, are obtained using a low-temperture oxidation process, in the liquid phase, with molecular oxygen and in the presence of U.V. light, of a mixture of a perfluorinated monoolefin and a perfluorinated conjugated diene, and of the subsequent photochemical decomposition of the peroxy groups contained in the photoxidation product, carried out by treating the peroxy-groups-containing product with U.V. light at a temperature within the range of from 0.degree. C. to 160.degree. C. Derivatives of said epoxy containing perfluoropolyethers in which the epoxy groups have been turned into functional groups.

38. 发明授权

US4853097A Perfluoropolyethers free from peroxidic oxygen and containing perfluoroepoxy groups positioned along the perfluoropolyether chain, and their derivatives 失效
标题翻译：不含过氧氧并含有沿全氟聚醚链定位的全氟环氧基的全氟聚醚及其衍生物
公开(公告)号：US4853097A
公开(公告)日：1989-08-01
申请号：US45541
申请日：1987-05-04
申请人： Giuseppe Marchionni , Ugo De Patto , Ezio Strepparola , Gian T. Viola
发明人： Giuseppe Marchionni , Ugo De Patto , Ezio Strepparola , Gian T. Viola
IPC分类号： C08G67/00 , C08G59/14 , C08G59/34 , C08G65/00 , C08G65/22
CPC分类号： C08G59/027 , C08G59/14 , C08G65/007
摘要： Perfluoropolyethers having fluorinated epoxy groups positioned along their perfluoropolyether chain, and free from peroxidic oxygen, are obtained by means of a low-temperature oxidation process, in the liquid phase, with molecular oxygen and in the presence of U.V. light, of a mixture of a perfluorinated monoolefin and a perfluorinated conjugated diene, and of the subsequent photochemical decomposition of the peroxy groups contained in the photooxidation product, carried out by treating the peroxy-groups-containing product with U.V. light at a temperature comprised within the range of from 0.degree. C. to 160.degree. C. Derivatives of said epoxy containing perfluoropolyethers in which the epoxy groups have been turned into functional groups.
摘要翻译：具有位于其全氟聚醚链上且不含过氧氧的氟化环氧基的全氟聚醚通过在液相中与分子氧的低温氧化反应获得。光，全氟化单烯烃和全氟化共轭二烯的混合物，以及通过用紫外线处理含过氧基的产物进行的光氧化产物中所含的过氧基的随后的光化学分解。在0℃至160℃范围内的温度下进行光照。所述含环氧基的全氟聚醚的衍生物已经变成官能团。

39. 发明授权

US4788257A Process for preparing regulated molecular weight perfluoro-polyethers having neutral and functional end groups 失效
标题翻译：制备具有中性和功能性端基的调节分子量全氟聚醚的方法
公开(公告)号：US4788257A
公开(公告)日：1988-11-29
申请号：US929832
申请日：1986-11-13
申请人： Gerardo Caporiccio , Gian T. Viola , Giuseppe Marchionni , Pio De Iorio , Adriana Tasca
发明人： Gerardo Caporiccio , Gian T. Viola , Giuseppe Marchionni , Pio De Iorio , Adriana Tasca
IPC分类号： C08G65/32 , C08G65/00 , C08G65/323 , C07C51/58 , C07C49/04
CPC分类号： C08G65/3236 , C08G65/007 , C08G65/323
摘要： A process for the dissociation of high molecular weight perfluoropolyethers to obtain low molecular weight perfluoropolyethers which comprises treating a perfluoropolyether with 0.1-10% by weight of a catalyst consisting of Ti, Cr, Mn, Fe, Co, Ni, V, Cu, Mo, Sn, Sb, Zr, Zn oxides at temperatures comprised between 150.degree. and 380.degree. C.
摘要翻译：用于解离高分子量全氟聚醚以获得低分子量全氟聚醚的方法，其包括用0.1-10重量％的由Ti，Cr，Mn，Fe，Co，Ni，V，Cu，Mo组成的催化剂处理全氟聚醚，Sn，Sb，Zr，Zn氧化物，温度在150〜380℃之间。

40. 发明授权

US09249260B2 Method for preparing carbonylic perfluoropolyethers 有权
标题翻译：制备羰基全氟聚醚的方法
公开(公告)号：US09249260B2
公开(公告)日：2016-02-02
申请号：US12595037
申请日：2008-04-08
申请人： Ugo De Patto , Giuseppe Marchionni , Pier Antonio Guarda
发明人： Ugo De Patto , Giuseppe Marchionni , Pier Antonio Guarda
IPC分类号： C07C43/30 , C07C53/46 , C08G65/00 , C08G65/322
CPC分类号： C08G65/007 , C08G65/322
摘要： A process for preparing perfluoropolyethers of formula T-O—(RF)z-T′ (I) wherein: T, T' are end groups, z=0 or 1; RF is a perfluoro(poly)oxyalkylene chain containing one or more fluorooxyalkylene repeating units selected from the group consisting of (CF2O), —(CF(CF3)O)—, —(CF2CF2O)—, —(CF2CF(CF3)O)—, —(CF(CF3)CF2O)—, —(CF2CF2CF2O)—, —(CF2CF2CF2CF2O)—, and —(CF2)j—CFZ—O— wherein j is an integer from 0 to 3, and Z is a fluorooxyalkylene chain comprising from 1 to 20 repeating units selected from the above reported fluorooxyalkylene units; comprising the reduction of peroxidic perfluoropolyethers comprising one or more of the above defined repeating units by using gaseous hydrogen in the presence of a catalyst comprising one or more metals of the VIII group supported on graphitic materials.
摘要翻译：制备式T-O-（RF）z-T'（I）的全氟聚醚的方法，其中：T，T'是端基，z = 0或1; RF是包含选自（CF 2 O）， - （CF（CF 3）O） - ， - （CF 2 CF 2 O） - ， - （CF 2 CF（CF 3）O）中的一种或多种氧代烯烃重复单元的全氟（聚）氧化烯链， - （CF（CF 3）CF 2 O） - ， - （CF 2 CF 2 CF 2 O） - ， - （CF 2 CF 2 CF 2 CF 2 O） - 和 - （CF 2）j-CFZ-O-其中j为0至3的整数，Z为氟氧化烯链，其包含1至20个选自上述氟氧化烯单元的重复单元; 包括通过在包含一种或多种负载在石墨材料上的VIII族的金属的催化剂存在下使用气态氢来还原包含一个或多个上述定义的重复单元的过氧化全氟聚醚。

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