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    • 32. 发明授权
    • Method for liquid feed dispersion in fluid catalytic cracking systems
    • 流体催化裂化系统中液体进料分散的方法
    • US4793913A
    • 1988-12-27
    • US813152
    • 1985-12-24
    • Donald O. ChessmoreFrederick A. Pettersen
    • Donald O. ChessmoreFrederick A. Pettersen
    • B01J8/08C10G11/18C10G11/00C10G35/00
    • C10G11/18B01J8/085
    • An improved liquid hydrocarbon feed method is disclosed wherein substantially all of the liquid is converted to mist sized particles over a wide angled dispersion pattern without a concurrent shroud of steam or water. Such dispersion promotes vapor phase catalytic reaction between hydrocarbon vapors and fluidized catalyst in a reaction time of 1 to 3 seconds. The misting nozzle is characterized by a swirl chamber to which the full hydrocarbon feed, with or without steam included in the feed, is supplied for centrifugal rotation by vane members to form a free vortex. The flow is then released through a reduced area square-edge orifice having a short throat to form and maintain a characteristic "vena contrata" from such an orifice during flow into the catalyst stream in the riser reactor for dispersion over a wide angled conical dispersion pattern. Such flow from the orifice allows the nozzle to be recessed out of the flowing catalyst stream. This keeps the nozzle cooler and minimizes mechanical erosion of the nozzle by the flowing, heated catalyst, without use of two phase nozzles to separately add steam or water. However, if desired steam may be used as a portion of the single fluid flow from the nozzle to reduce partial pressure of the vaporizing hydrocarbon feed. In a preferred form, the liquid feed is introduced into the transition section of a riser reactor.
    • 公开了一种改进的液体烃进料方法,其中基本上所有的液体在宽角度的分散图案上转化成雾化尺寸的颗粒,而没有蒸汽或水的同时的罩。 这种分散促进烃蒸气和流化催化剂之间的气相催化反应,反应时间为1至3秒。 雾化喷嘴的特征在于一个涡流室,进料中包含或不含有蒸汽的全烃进料被供应用于叶片构件的离心旋转以形成自由涡流。 然后通过具有短喉部的减小面积的方形边缘孔释放流动,以在流入提升管反应器中的催化剂流中时从这种孔口形成并保持特征性“再生”,以在宽角锥形分散图案上分散 。 来自孔口的这种流动允许喷嘴从流动的催化剂流中凹入。 这样可以使喷嘴更冷却,并且通过流动的加热催化剂使喷嘴的机械腐蚀最小化,而不使用两相喷嘴分别加入蒸汽或水。 然而,如果需要,蒸汽可以用作来自喷嘴的单一流体流的一部分,以减少汽化烃进料的分压。 在优选的形式中,液体进料被引入提升管反应器的过渡部分。
    • 33. 发明授权
    • Steam injection profiling
    • 蒸汽喷射分析
    • US4793414A
    • 1988-12-27
    • US88465
    • 1987-08-19
    • Tanh V. NguyenC. Brent Davenport
    • Tanh V. NguyenC. Brent Davenport
    • E21B43/24E21B47/10E21B49/08
    • E21B47/1015E21B43/24
    • An improved method and apparatus for determining injection profiles in a steam injection well is disclosed. The mass flow rate and quality of steam entering the well is measured. A well logging tool is then used to measure temperature and/or pressure profiles within the perforated zone of the well. A liquid phase tracer is then injected for a short time into the well with the steam. The well logging tool contains dual gamma ray detectors and is used to measure the transit time of the tracer slug. In the preferred embodiment, the liquid tracer is radioactive elemental iodine or sodium iodide. The procedure is repeated with a vapor phase tracer which is radioactive Krypton, Argon, or Xenon in the preferred embodiment. A vapor and liquid profile can then be calculated with simple mass balance equations. In a second approach, a spinner survey and a single tracer survey are conducted. By combining the spinner and tracer survey results, vapor and liquid rates can be determined and steam injection profiles can be calculated.
    • 公开了一种用于确定蒸汽注入井中的注入分布的改进方法和装置。 测量进入井的蒸汽的质量流量和质量。 然后使用测井工具测量井的穿孔区域内的温度和/或压力分布。 然后用蒸汽将液相示踪剂短时间注入井中。 测井工具包含双伽马射线探测器,用于测量示踪器塞的通行时间。 在优选的实施方案中,液体示踪剂是放射性元素碘或碘化钠。 在优选实施方案中,用放射性氪,氩或氙的气相示踪剂重复该过程。 然后可以用简单的质量平衡方程计算蒸气和液体分布。 在第二种方法中,进行了微调测量和单次跟踪测量。 通过组合旋转器和示踪器测量结果,可以确定蒸汽和液体速率,并计算蒸汽喷射曲线。
    • 34. 发明授权
    • Method of avoiding stuck drilling equipment
    • 避免卡住钻井设备的方法
    • US4791998A
    • 1988-12-20
    • US935510
    • 1986-11-26
    • W. Brent HempkinsRoger H. KingsboroughWesley E. LohecConroy J. Nini
    • W. Brent HempkinsRoger H. KingsboroughWesley E. LohecConroy J. Nini
    • E21B21/00E21B31/03E21B43/30E21B44/00E21B7/00E21B7/04
    • E21B21/00E21B31/03E21B43/30E21B44/00
    • A method of avoiding stuck drilling equipment during drilling of a well over depth intervals where such equipment has stuck in similar wells in a geological province. A multiplicity of well drilling variable quantities are measured substantially simultaneously at a known depth in each of a multiplicity of wells. Such multiplicity of wells includes those in which drilling equipment has stuck due to mechanical problems or differential pressure between the drill string and an earth formation penetrated by the well bore, or both, and a multiplicity of similar wells where the drill string did not stick. By multivariate statistical analysis of all variables in all wells of each class, together with maximum separation of said classes from each other, a plotting plane for a currently drilling well relative to said classes is established. The location of the relative position of all variables in such a drilling well with respect to the well classes is determined by summing the products of the coefficient of each variable for the complete group of wells times the current value of the variables in the drilling well. The variables are then modified within allowable values to change the plotted location of the drilling well toward the mean of the wells that did not stick the drill string.
    • 一种避免在钻井过程中卡住钻井设备的方法,其深度间隔较深,其中这种设备已经卡在地质省的类似井中。 在多个孔中的每一个井中的已知深度基本上同时测量多个钻井可变量。 井的这种多重性包括钻井设备已经由于机械问题或井筒之间的钻井平台渗透的地层构造或两者之间的机械问题或压差以及钻柱未粘住的多个类似的井而被卡住的井。 通过对每个类别的所有井中所有变量的多变量统计分析,以及所述类别彼此的最大分离,建立了相对于所述类别的当前钻井的绘图平面。 通过将完整组井的每个变量的系数乘以钻井中的变量的当前值的乘积求和来确定相对于井类的这种钻井中所有变量的相对位置的位置。 然后将变量修改为允许值,以将钻井的绘制位置改变为不粘钻钻柱的孔的平均值。
    • 35. 发明授权
    • N-cyanoalkyl-N-haloalkylthio carboxamides as fungicides
    • N-氰基烷基-N-卤代烷基硫代甲酰胺作为杀真菌剂
    • US4785019A
    • 1988-11-15
    • US833948
    • 1986-02-27
    • Joseph E. Moore
    • Joseph E. Moore
    • A01N37/46A01N37/48A01N37/28C07C121/417C07C121/52
    • A01N37/48A01N37/46
    • N-cyanoalkyl-N-haloalkylthio alkyl-, aryl- and aralkyl-carboxamides of the general formula: ##STR1## wherein R is alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 10 carbon atoms, lower alkenyl of 2 to 6 carbon atoms or lower alkynyl of 2 to 6 carbon atoms, all optionally substituted with 1 to 4 halogen atoms; lower alkoxyalkylene; aryl of 6 to 12 carbon atoms; aralkyl of 7 to 16 carbon atoms; or substituted aryl or substituted aralkyl both substituted with 1 to 3 substituents independently selected from phenyl, lower alkyl of 1 to 6 carbon atoms, lower alkoxy of 1 to 6 carbon atoms, lower alkylthio of 1 to 6 carbon atoms, halogen, nitro, cyano, ##STR2## wherein R.sup.4 is hydrogen or lower alkyl of 1 to 6 carbon atoms, ##STR3## wherein R.sup.5 and R.sup.6 are independently hydrogen or lower alkyl of 1 to 6 carbon atoms; R.sup.1 and R.sup.2 are independently hydrogen, or lower alkyl of 1 to 6 carbon atoms; and R.sup.3 is alkyl of 1 to 3 carbon atoms substituted with 3 to 6 halogen atoms or trihalovinyl are fungicidal.
    • 具有以下通式的N-氰基烷基-N-卤代烷硫基烷基 - ,芳基 - 和芳烷基 - 甲酰胺:其中R是1至10个碳原子的烷基,3至10个碳原子的环烷基,2个低级链烯基 至6个碳原子或2至6个碳原子的低级炔基,全部任选被1至4个卤素原子取代; 低级烷氧基亚烷基; 6至12个碳原子的芳基; 7-16个碳原子的芳烷基; 或取代的芳烷基或取代的芳烷基均被1至3个独立地选自苯基,1至6个碳原子的低级烷基,1至6个碳原子的低级烷氧基,1至6个碳原子的低级烷硫基,卤素,硝基,氰基 ,其中R 4是氢或1至6个碳原子的低级烷基,其中R 5和R 6独立地是氢或1至6个碳原子的低级烷基; R1和R2独立地是氢或1-6个碳原子的低级烷基; R3为被3〜6个卤素原子取代的1〜3个碳原子的烷基或三卤乙烯基是杀真菌剂。
    • 40. 发明授权
    • Method of reducing sulfur deposition in hydrogen sulfide equipment
    • 减少硫化氢设备硫沉积的方法
    • US4769228A
    • 1988-09-06
    • US733345
    • 1985-05-13
    • Iren RomodaRobert V. HomsyRobert M. Ormiston
    • Iren RomodaRobert V. HomsyRobert M. Ormiston
    • C01B17/05
    • C01B17/05
    • A method is disclosed for reducing the sulfur deposition in the absorber of a Stretford process. In the Stretford process, hydrogen sulfide is removed from a gas stream by contacting the gas stream in an absorber with a circulating aqueous solution to convert the hydrogen sulfide to elemental sulfur particles, passing the solution containing the sulfur particles to a reaction vessel where the conversion of hydrogen sulfide to sulfur is completed, passing the solution containing the sulfur particles to an oxidizer, oxidizing the solution containing the sulfur particles in the oxidizer to form a regenerated solution, separating the sulfur particles from the regenerated solution, and recirculating the solution to the absorber. The sulfur deposition in the absorber is reduced by adding about 300 ppm of a hydroxyquinone compound, such as 1-hydroxyanthraquinone (1-HAQ); 1,2-dihydroxyanthraquinone (1,2-DHAQ); 1,8-dihydroxyanthraquinone (1,8-DHAQ); 1,2-dihydroxyanthraquinone 3-monosulfonic acid (1,2-DHAMA); 1,2,5,8-tetrahydroxyanthraquinone (1,2,5,8-THAQ); 1,4,5,8-tetrahydroxyanthraquinone (1,4,5,8-THAQ); 5- hydroxy 1,4-naphthoquinone (5-HNQ); or a mixture thereof, to the absorber.
    • 公开了一种减少Stretford工艺吸收器中硫沉积的方法。 在Stretford方法中,通过使吸收器中的气流与循环水溶液接触将气态流除去硫化氢,以将硫化氢转化为元素硫颗粒,将含有硫颗粒的溶液通过反应容器, 的硫化氢完全硫化,将含有硫粒子的溶液通入氧化剂,氧化含氧硫化物的溶液,形成再生溶液,从再生溶液中分离出硫粒子,再将溶液再循环到 吸收器。 通过加入约300ppm的羟基醌化合物如1-羟基蒽醌(1-HAQ),减少吸收剂中的硫沉积。 1,2-二羟基蒽醌(1,2-DHAQ); 1,8-二羟基蒽醌(1,8-DHAQ); 1,2-二羟基蒽醌3-单磺酸(1,2-DHAMA); 1,2,5,8-四羟基蒽醌(1,2,5,8-THAQ); 1,4,5,8-四羟基蒽醌(1,4,5,8-THAQ); 5-羟基1,4-萘醌(5-HNQ); 或其混合物。