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    • 29. 发明授权
    • Method for preparing high shrinkage rate polytrimethylene terephthalate
    • 制备高收缩率聚对苯二甲酸丙二醇酯的方法
    • US09045594B2
    • 2015-06-02
    • US13579938
    • 2011-02-23
    • Shuchang Bian
    • Shuchang Bian
    • C08G63/18C08G63/00C08G63/02C08G61/10C08G63/78C08G63/183C08G63/82D01F6/84
    • C08G63/78C08G63/183C08G63/82D01F6/84
    • A method for preparing high shrinkage PTT copolyester, includes adding starting raw materials into a reaction kettle and adding an esterification catalyst to carry out esterification reaction at 220° C.-260° C. under 0.05-0.30 MPa and completing the reaction when there being no water produced; and adding polymerization catalyst into the reaction system and carrying out the polymerization reaction at 240° C.-280° C. to get polytrimethylene terephthalate. The starting raw materials consists of 1,3-propylene glycol, terephtalic acid, a third monomer, a forth monomer and a fifth monomer. Polytrimethylene terephthalate prepared by the invention shows good spinning behaviour, of which the crystallization speed is noticeably lower than that of conventional polytrimethylene terephthalate, thus, fibers made of them has high boiling water shrinkage rate and ideal shrink property.
    • 一种制备高收缩率PTT共聚酯的方法,包括将起始原料加入到反应釜中,并加入酯化催化剂,在220℃-260℃,0.05-0.30MPa下进行酯化反应,并在存在时完成反应 没有水生产; 并在反应体系中加入聚合催化剂,并在240℃-280℃进行聚合反应,得到聚对苯二甲酸丙二醇酯。 起始原料由1,3-丙二醇,对苯二酸,第三单体,第四单体和第五单体组成。 通过本发明制备的聚对苯二甲酸丙二醇酯显示出良好的纺丝行为,其结晶速度明显低于常规聚对苯二甲酸丙二醇酯,因此,由它们制成的纤维具有高沸水收缩率和理想的收缩性能。