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21. 发明授权

US4290768A Process for dyeing and printing cellulose fibres 失效
标题翻译：染色和印花纤维素纤维的方法
公开(公告)号：US4290768A
公开(公告)日：1981-09-22
申请号：US110033
申请日：1980-01-07
申请人： Rutger Neeff , Robert Kuth , Werner Kuhnel , Wilhelm Gohrbandt
发明人： Rutger Neeff , Robert Kuth , Werner Kuhnel , Wilhelm Gohrbandt
IPC分类号： C09B1/46 , C09B1/516 , C09B1/58 , C09B5/02 , D06P3/60 , D06P3/82 , D06P3/852 , D06P1/24 , C09B1/26
CPC分类号： D06P3/8233 , C09B1/46 , C09B1/516 , C09B1/585 , C09B5/02 , D06P3/6041 , Y10S8/918
摘要： In order to dye and print cellulose fibres, which have been swollen with water-miscible swelling agents, or fibre mixtures containing such cellulose fibres, the fibres are treated with a dyestuff of the general formula ##STR1## wherein A denotes an optionally substituted anthraquinone radical, which can contain a further fused ring,X denotes oxygen or sulphur,Z denotes a mononuclear or binuclear aryl radical andn denotes 1 or 2,and the dyestuff is fixed by means of a heat treatment.
摘要翻译：为了染色和印刷已经与水混溶性溶胀剂溶胀的纤维素纤维或含有这种纤维素纤维的纤维混合物，纤维用通式为“IMAGE”的染料处理，其中A表示任选取代的蒽醌基可以含有另外的稠环，X表示氧或硫，Z表示单核或双核芳基，n表示1或2，染料用热处理固定。

22. 发明授权

US4098793A Anthraquinone compounds and process for preparing same 失效
标题翻译：蒽醌化合物及其制备方法
公开(公告)号：US4098793A
公开(公告)日：1978-07-04
申请号：US836087
申请日：1977-09-23
申请人： Giuseppe Ribaldone , Renato Grecu , Camillo Paffoni , Giuseppe Sironi
发明人： Giuseppe Ribaldone , Renato Grecu , Camillo Paffoni , Giuseppe Sironi
IPC分类号： C09B1/44 , C09B1/516 , C09B1/54 , D06P1/24 , C07D285/10
CPC分类号： D06P1/24 , C09B1/44 , C09B1/516 , C09B1/542
摘要： The present invention relates to a new class of compounds belonging to the anthraquinone series, having the general formula: ##STR1## wherein R, R', R", R'", R' are indifferently H or Chlorine, ##STR2## Such compounds exhibit a color varying from yellow to violet depending on the nature and position of substituents R, R', R", R'", R'.sup.v and, in virtue of their excellent stability characteristics, they are particularly useful as pigments and vat dyes.This invention relates furthermore to the preparation of compounds having general formula (I) and to the utilization thereof, particularly in the following applications:Pigmentation of plastic materials, such as polyvinyl chloride, polystyrene, polyolefins, polymethylmethacrylate, polycarbonates and ABS copolymers (acrylonitrile-butadiene-styrene);Pigmentation of varnishes, stoving enamels, inks and pastes for the printing of textiles;Vat dyeing of cellulose fibres such as cotton, flax, rayon.BACKGROUND OF THE INVENTIONAs far as it is known, the anthraquinone derivatives of 1,2,5-thiadiazole-3,4-dicarboxylic acid of formula (I), which are the object of the present invention, are not described in the Art.The prior Art, however not directly pertinent, generically describes dyestuffs of the anthraquinone series deriving from dicarboxylic acids, for example benzenic, pyridinic, aliphatic acids etc.OBJECTS OF THE INVENTIONIt is an object of this invention to provide a new class of anthraquinone compounds of general formula (I), having useful applications in the field of the pigments and of the vat dyes. Another object is to provide a process for preparing same.GENERAL DESCRIPTION OF THE INVENTIONThese and still other objects, that will more clearly appear to those skilled in the Art from the following description, are achieved by compounds having general formula (I), prepared by means of a process characterized in that the dichloride of 1,2,5-thiadiazole-3,4-dicarboxylic acid (II) is reacted with 1-aminoanthraquinone or substituted derivatives (III) thereof according to a substantially stoichiometric molar ratio, in the presence of an inert solvent, at a temperature ranging from 100.degree. to about 170.degree. C.The reaction can be schematically represented by the following equation (1): ##STR3## wherein R', R", R'", R'.sup.v have the meaning already specified; HCl forms and liberates as a gas from the reacting mixture. It is not necessary, therefore, to employ basic substances to neutralize hydrochloric acid. As mentioned hereinbefore, the reaction is conducted in an inert solvent and at a temperature comprised between 100.degree. and about 170.degree. C, preferably between 120.degree. and about 150.degree. C.1-aminoanthraquinones (III) employable in the present invention are in particular:1-aminoanthraquinone, 1-amino-4-hydroxyanthraquinone, 1-amino-4-benzamidoanthraquinone, 1-amino-5-benzamidoanthraquinone, 1-amino-4-(p-acetamidoanilino)-anthraquinone, 1-amino-4-(p-toluidino)-anthraquinone, 1-amino-5-methoxyanthraquinone, 1-amino-2-phenoxy-4-hydroxyanthraquinone, 1-amino-2,4-dibromoanthraquinone, 1-amino-2-bromo-4-hydroxyanthraquinone, 1-amino-6,7-dichloroanthraquinone etc.As inert solvent it is possible to use chlorobenzene, the various dichlorobenzenes and trichlorobenzenes, and nitrobenzenes.The time required for the reaction varies from 2 to 8 hours, depending on the reaction temperature and on the type of 1-aminoanthraquinones utilized. The molar ratio is practically stoichiometric, that is: 2 moles of anthraquinone compound (III) for 1 mole of dichloride (II).The raw materials necessary for the process according to this invention are easily available, as 1-aminoanthraquinone and the substituted derivatives (III) thereof are commercial products usually employed as intermediates for dyestuffs and pigments.As to the dichloride of 1,2,5-thiadiazole-3,4-dicarboxylic acid (II), such product is known since long and is obtained, according to known techniques, by chlorination with SOCl.sub.2 of the monopotassium salt of 1,2,5-thiadiazole-3,4-dicarboxylic acid, that is, in its turn, a known compound.According to an effective embodiment, the present invention is conducted by operating in practice as follows: the dichloride of 1,2,5-thiadiazole-3,4-dicarboxylic acid (II) and the 1-aminoanthraquinone or its substituted derivatives (III) are heated, after mixing in the inert solvent, to 100.degree.-170.degree. C, preferably to 120.degree.-150.degree. C, until the anthraquinone compound (III) has thoroughly disappeared.The thin layer chromatography is useful for this check.At the end of the reaction the reaction mixture is filtered, preferably in hot conditions, and the pigment cake is then washed with the reaction solvent and successively with methanol until the washings result colourless.The pigments obtained according to this invention are substances exhibiting a colour varying from yellow to violet and characterized by a high insolubility in the common organic solvents and by a high melting point, generally higher than 300.degree. C.To impart the particular desired applicative characteristics to the products so obtained it is impossible to utilize the grinding, for example in a ball mill, or the precipitation from sulphuric acid and in general the techniques already known.Also for the dyeing of plastic materials, of varnishing products and for the vat dyeing the pigments of the present invention are consistent with the conventional techniques.Due to the simple preparation conditions and applicative characteristics of the obtained pigments, the present invention appears particularly advantageous.Preparation and application of the present invention will be now described more in detail in the following examples, which are given, however, by way of example only.
摘要翻译：本发明涉及一类属于蒽醌系列的化合物，具有以下通式：其中R，R'，R“，R”'，R'为无差异的H或氯，

23. 发明授权

US3720693A Anthraquinone dyestuffs 失效
标题翻译： ANTHRAQUINONE DYESTUFFS
公开(公告)号：US3720693A
公开(公告)日：1973-03-13
申请号：US3720693D
申请日：1970-02-06
申请人： BAYER AG
发明人： PETERS K , NEEFF R
IPC分类号： C09B1/36 , C09B1/42 , C09B1/50 , C09B1/516 , C09B1/54 , C09B1/58 , C09B1/60
CPC分类号： C09B1/50 , C09B1/36 , C09B1/42 , C09B1/58
摘要： IN WHICH R is a substituent; p is a number 0-6; and n is 1 or 2; their production and use as pigments are disclosed.

Anthraquinone dyestuffs of the formula
摘要翻译：蒽醌染料，其中R为取代基; p是0-6; n为1或2; 公开了其作为颜料的生产和用途。

24. 发明授权

US3470178A Anthraquinone dyestuffs 失效
标题翻译： ANTHRAQUINONE DYESTUFFS
公开(公告)号：US3470178A
公开(公告)日：1969-09-30
申请号：US51069365
申请日：1965-11-30
申请人： BAYER AG
发明人： NEEFF RUTGER , GOHRBANDT WILHELM , KUTH ROBERT
IPC分类号： C09B1/46 , C09B1/467 , C09B1/516 , D06P1/20 , C07D55/44 , C09B5/44 , D06P1/00
CPC分类号： C09B1/46 , C09B1/467 , C09B1/516 , D06P1/20 , Y10S8/922

25. 发明授权

US2819274A Monohydroxy-beta-acylaminoanthraquinones 失效
标题翻译：单羟基-β-酰基氨基蒽醌
公开(公告)号：US2819274A
公开(公告)日：1958-01-07
申请号：US57222656
申请日：1956-03-19
申请人： CIBA LTD
发明人： PAUL GROSSMANN
IPC分类号： C09B1/516
CPC分类号： C09B1/5165 , Y10S8/931

26. 发明授权

US1602695A Dyeing and printing cellulose esters 失效
标题翻译：染色和印花纤维素酯
公开(公告)号：US1602695A
公开(公告)日：1926-10-12
申请号：US9234526
申请日：1926-03-04
申请人： IG FARBENINDUSTRIE AG
发明人： RICHARD METZGER
IPC分类号： C09B1/473 , C09B1/516 , C09B1/54 , C09B69/00 , D06P3/40
CPC分类号： C09B69/00 , C09B1/36 , C09B1/473 , C09B1/5165 , C09B1/545 , D06P1/0048 , D06P3/40 , Y10S8/921

27. 发明授权

US4609404A Organic dyes containing silane groups and process for preparing same 失效
标题翻译：含有硅烷基团的有机染料及其制备方法
公开(公告)号：US4609404A
公开(公告)日：1986-09-02
申请号：US524083
申请日：1983-08-17
申请人： Antonio Marraccini , Filippo M. Carlini , Antonio Pasquale , Giorgio Maranzana
发明人： Antonio Marraccini , Filippo M. Carlini , Antonio Pasquale , Giorgio Maranzana
IPC分类号： C09B1/467 , C09B1/516 , C09B1/54 , C09B1/58 , C09B69/00 , C09C1/28 , C09C1/36
CPC分类号： C09B69/008 , C09B1/467 , C09B1/516 , C09B1/547 , C09B1/585
摘要： This invention relates to organic dyes containing silane groups; composite pigments obtainable by grafting said dyes onto an inorganic substrate; and, the respective processes for preparing said dyes and composite pigments.The dyes have general formula: ##STR1## wherein R.sub.1 and R.sub.2, which may be equal or different, are selected from the group consisting of H, --NH.sub.2, --NHR wherein R is an alkyl group having from 1 to 4 carbon atoms or a phenyl group, --NHCOCH.sub.3, --NHCOC.sub.6 H.sub.5, --NO.sub.2, a halogen, --OH, --O--C.sub.6 H.sub.5 and --S--C.sub.6 H.sub.5 ; n is a number selected from 3, 4 and 5; W is selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms and a phenyl group; Y is an alkoxy group having from 1 to 4 carbon atoms; q is a number selected from 0 and 1; X is 3 and m is a number selected from 0, 1, 2 and 3 when q is 0; x is 2 and m is a number selected from 0, 1 and 2 when q is 1. The composite pigments obtained from said dyes are employed in the painting products, air enamels and stoving enamels, in the pigmentation of plastic materials, in the inks and in the printing of fabrics.
摘要翻译：本发明涉及含有硅烷基团的有机染料; 通过将所述染料接枝到无机基材上可获得的复合颜料; 以及制备所述染料和复合颜料的各个方法。染料具有以下通式：其中R 1和R 2可以相同或不同，选自H，-NH 2，-NHR，其中R是具有1至4个碳原子的烷基原子或苯基，-NHCOCH 3，-NHCOC 6 H 5，-NO 2，卤素，-OH，-O-C 6 H 5和-S-C 6 H 5; n是选自3,4和5的数字; W选自具有1至4个碳原子的烷基和苯基; Y是具有1至4个碳原子的烷氧基; q是选自0和1的数字; 当q为0时，X为3，m为选自0,1,2和3的数; x为2，当q为1时，m为选自0,1和2的数字。由所述染料得到的复合颜料用于油墨，空气搪瓷和烘烤搪瓷，在油墨着色中，在油墨中和织物的印花。

28. 发明授权

US4334068A Process for the preparation of triazinylamino-anthraquinones 失效
标题翻译：三嗪基氨基 - 蒽醌的制备方法
公开(公告)号：US4334068A
公开(公告)日：1982-06-08
申请号：US213242
申请日：1980-12-04
申请人： Rutger Neeff
发明人： Rutger Neeff
IPC分类号： C07D251/46 , C09B1/46 , C09B1/51 , C09B1/516 , C09B1/54 , C09B1/58 , C09B5/02 , C09B5/04 , C09B5/10 , C07D403/12 , C07D417/12
CPC分类号： C09B1/58 , C09B1/46 , C09B1/516 , C09B1/54 , C09B5/04 , C09B5/10
摘要： Anthraquinone dyestuffs of the formula ##STR1## wherein A is an optionally substituted anthraquinone radical andR is an optionally substituted aryl radical, are obtained in outstanding yields, and without pollution of the effluent, by reacting 1 mol each of amino-anthraquinone and cyanuric chloride in excess phenol in a one-pot process and at 50.degree.-200.degree. C. in the absence of acid acceptors and organic solvents.
摘要翻译：其中A是任选取代的蒽醌基，R是任选取代的芳基的蒽醌染料以突出的产率获得，并且不污染流出物，通过使1mol的氨基蒽醌和氰尿酰氯反应在一锅法中在过量的苯酚中，在50℃-200℃下，不存在酸受体和有机溶剂。

29. 发明授权

US4309221A Anthraquinone derivatives 失效
标题翻译：蒽醌衍生物
公开(公告)号：US4309221A
公开(公告)日：1982-01-05
申请号：US39852
申请日：1979-05-17
申请人： Rutger Neeff , Meinhard Rolf , Walter Muller
发明人： Rutger Neeff , Meinhard Rolf , Walter Muller
IPC分类号： C09B1/28 , C08K5/16 , C08K5/17 , C09B1/20 , C09B1/42 , C09B1/48 , C09B1/50 , C09B1/515 , C09B1/516 , C09B1/58 , C09B5/02 , C09B5/24 , C09B55/00 , D06P1/20 , C08L1/24 , C07C123/00 , C07C143/665
CPC分类号： C09B1/58 , C08K5/17 , C09B1/205 , C09B1/48 , C09B1/50 , C09B5/02 , C09B5/24 , D06P1/20
摘要： Anthraquinone derivatives of the formula ##STR1## or of the tautomeric formula ##STR2## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and is optionally further substituted and which preferably consists of at most 5 fused rings,m denotes an integer, preferably 1 or 2, andR.sub.1 denotes a hydroxyl group or a radical of the formula ##STR3## wherein R.sub.2 represents a substituent andn represents 0, 1, 2, 3 or 4,processes for their preparation, their use for pigmenting organic macromolecular substances and the material pigmented in this manner.
摘要翻译：式（I）的蒽醌衍生物或互变异构体式（Ia）的蒽醌衍生物，其中A表示不含磺酸基并且任选进一步取代的蒽醌基团，并且其优选由至多5个稠合环，m表示整数，优选1或2，并且R 1表示羟基或下式的基团其中R 2表示取代基，n表示0,1,2,3或4，其制备方法，它们用于着色有机高分子物质和以这种方式着色的材料。

30. 发明授权

US4256460A Process for dyeing and printing cellulose fibres 失效
标题翻译：染色和印花纤维素纤维的方法
公开(公告)号：US4256460A
公开(公告)日：1981-03-17
申请号：US81991
申请日：1979-10-04
申请人： Gunter Gehrke , Werner Kuhnel , Robert Kuth
发明人： Gunter Gehrke , Werner Kuhnel , Robert Kuth
IPC分类号： C09B1/514 , C09B1/516 , D06P3/60 , D06P5/28 , D06P3/82
CPC分类号： C09B1/514 , C09B1/516 , D06P3/6041 , D06P5/006 , Y10S8/918
摘要： For dyeing and printing cellulose fibres which have been swollen with water-miscible swelling agents or mixed fibres containing these fibres, the fibres are treated with dyestuffs which are free from sulphonic acid groups and carboxylic acid groups, of the general formula ##STR1## wherein R represents optionally substituted C.sub.1 -C.sub.6 -alkyl, cyclohexyl, C.sub.1 -C.sub.4 -alkoxy, phenyl, benzyl, phenylethyl, phenylpropyl or phenoxy, or chlorine or bromine,n represents 0, 1 or 2,one X represents OH and the other X represents NO.sub.2, NH.sub.2 or R'-CONH and R' represents optionally substituted C.sub.1 -C.sub.4 -alkyl or phenyl,and the dyestuffs are fixed by heat treatment.
摘要翻译：对于已经与水混溶性溶胀剂或含有这些纤维的混合纤维溶胀的纤维素纤维进行染色和印花，用不含磺酸基团和羧酸基团的染料处理纤维，其通式为“IMAGE”，其中R 表示任选取代的C 1 -C 6 - 烷基，环己基，C 1 -C 4 - 烷氧基，苯基，苄基，苯乙基，苯丙基或苯氧基或氯或溴，n表示0,1或2，一个X表示OH，另一个X表示NO 2 ，NH2或R'-CONH，R'表示任选取代的C 1 -C 4 - 烷基或苯基，染料通过热处理固定。

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