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21. 发明授权

US06875896B2 Method for producing high purity 1,1-bis(4-hydroxyphenyl)cyclohexanes 失效
标题翻译：高纯度1,1-双（4-羟苯基）环己烷的制备方法
公开(公告)号：US06875896B2
公开(公告)日：2005-04-05
申请号：US10879436
申请日：2004-06-29
申请人： Kazuhiko Yao , Tooru Nakaguchi , Kenji Ekawa
发明人： Kazuhiko Yao , Tooru Nakaguchi , Kenji Ekawa
IPC分类号： C07C37/70 , G02F1/13 , B08B3/02 , C07C37/20 , C07C37/68 , C07C37/82 , C07C37/84 , C07C39/12 , C07C39/16 , C07C39/17 , G02F1/1333 , H01L21/304 , H01L21/68 , H01L21/683
CPC分类号： C07C37/20 , C07C37/84 , C07C2601/14 , C07C39/17
摘要： A method for producing a high purity 1,1-bis(4-hydroxyphenyl)cyclohexane represented by the general formula (II), wherein R is a hydrogen atom or alkyl group, comprising the steps of: reacting cyclohexanone and a phenol represented by the general formula (I) in the presence of an acid catalyst; wherein R is the same as defined above, neutralizing the resultant reaction mixture with an alkali; primarily crystallizing and filtering a 1,1-bis(4-hydroxyphenyl)cyclohexane produced to obtain a primary crystallization filtrate; dissolving 100 parts by weight of the primary crystallization filtrate in a mixed solvent, which comprises 5 to 10 parts by weight of water and 100 to 200 parts by weight of a lower aliphatic ketone solvent, or 200 to 400 parts by weight of a lower aliphatic alcohol solvent; filtering the resulting solution through a zeta potential filter; and secondarily crystallizing and filtering the 1,1-bis(4-hydroxyphenyl)cyclohexane from the resulting filtrate in the presence of water.
摘要翻译：一种制备由通式（II）表示的高纯度1,1-双（4-羟基苯基）环己烷的方法，其中R是氢原子或烷基，包括以下步骤：使环己酮与由在通式（I）中，在酸催化剂存在下，其中R与上述定义相同，用碱中和得到的反应混合物; 主要结晶并过滤产生的1,1-双（4-羟基苯基）环己烷以获得一级结晶滤液; 将100重量份的一次结晶滤液溶解在混合溶剂中，该混合溶剂包含5至10重量份的水和100至200重量份的低级脂族酮溶剂，或200至400重量份的低级脂族酒精溶剂; 通过ζ电位过滤器过滤所得溶液; 并在水存在下，从所得滤液中二次结晶并过滤1,1-双（4-羟基苯基）环己烷。

22. 发明授权

US06858759B2 Process for manufacture of bisphenols 有权
标题翻译：双酚制造工艺
公开(公告)号：US06858759B2
公开(公告)日：2005-02-22
申请号：US10639929
申请日：2003-08-12
申请人： Martin Herke Oyevaar , Rudy Francois Alain Jos Peemans , Eduard Hendricus Schlarmann
发明人： Martin Herke Oyevaar , Rudy Francois Alain Jos Peemans , Eduard Hendricus Schlarmann
IPC分类号： C07C37/20 , C07C37/84 , C07C39/16
CPC分类号： C07C37/84 , C07C37/20 , C07C39/16
摘要： A method for the manufacture of bisphenols comprises introducing a combined feed stream comprising a feed stream and a recycle stream into a reactor system comprising at least one reactor containing a catalytic proportion of an acid catalyst and wherein the combined feed stream comprises a carbonyl compound and a stoichiometric excess of phenol; removing from the reactor system a reactor effluent; splitting the reactor effluent into a crystallization feed stream and an effluent recycle stream; extracting from said crystallization feed stream a bisphenol adduct, remainder comprising a mother liquor stream; dehydrating said mother liquor stream and said effluent recycle stream in a dehydrator wherein excess water and carbonyl compound are removed; and recycling the dehydrated mother liquor and the dehydrated effluent recycle stream back to the combined feed stream to effect improved production of p,p-bisphenol, along with increased reactor selectivity and reduced promoter quantities.
摘要翻译：制备双酚的方法包括将包含进料流和再循环料流的组合进料流引入包含至少一个含有催化剂比例的酸催化剂的反应器的反应器系统中，其中组合进料流包含羰基化合物和化学计量过量的苯酚; 从反应器系统中除去反应器流出物; 将反应器流出物分解成结晶进料流和流出物再循环流; 从所述结晶进料流中提取双酚加合物，其余包含母液流; 在脱水器中脱水所述母液流和所述废水再循环流，其中除去过量的水和羰基化合物; 并将脱水的母液和脱水的废液再循环物流再循环回到组合的进料流中，以改善p，p双酚的生产，同时增加反应器的选择性和减少的助催化剂量。

23. 发明授权

US6011184A Descaling of bisphenol-A reactor using water 失效
标题翻译：用双酚A反应器除水
公开(公告)号：US6011184A
公开(公告)日：2000-01-04
申请号：US55590
申请日：1998-04-06
申请人： Johan Adrianus Aarssen , Gerrit Op Den Dries , Ad Nieuwlaat , Marcel Vieveen , Rudy Francois Alain Joseph Peemans
发明人： Johan Adrianus Aarssen , Gerrit Op Den Dries , Ad Nieuwlaat , Marcel Vieveen , Rudy Francois Alain Joseph Peemans
IPC分类号： C07C37/20 , C07C37/84 , C07C39/16 , C07C39/12 , C07C37/68
CPC分类号： C07C37/84 , C07C37/20 , Y02P20/125
摘要： An integrated process for the preparation and recovery of BPA in pure form utilizes a series of steps to crystallize the 1:1 adduct of phenol and bisphenol-A, with periodic descaling of the crystallizer surfaces with a modified reactor/crystallizer containing 1 to 40 percent water.
摘要翻译：以纯形式制备和回收BPA的综合方法采用一系列步骤，使苯酚和双酚A的1:1加合物结晶，同时用改性反应器/结晶器定期除锈结晶器，该改性反应器/结晶器含有1〜40％水。

24. 发明授权

US5786522A Manufacture of bisphenol-A 失效
标题翻译：双酚A的制造
公开(公告)号：US5786522A
公开(公告)日：1998-07-28
申请号：US712929
申请日：1996-09-13
申请人： Michael J. Cipullo
发明人： Michael J. Cipullo
IPC分类号： C07C37/20 , C07B61/00 , C07C37/74 , C07C37/84 , C07C37/86 , C07C39/16
CPC分类号： C07C37/84 , C07C37/685 , C07C37/74 , Y02P20/125
摘要： An integrated process for the preparation and recovery of BPA in pure form utilizes a series of steps to crystallize pure BPA of improved color stability and recycle separated impurities to improve overall yields. The principal impurity recycled to the process is o,p-BPA which functions as a color stabilizer in the product and in polycarbonate resins prepared from the BPA.
摘要翻译：以纯形式制备和回收BPA的综合方法采用一系列步骤，使纯BPA结晶，改善颜色稳定性和回收分离的杂质，以提高总产率。再循环到该方法中的主要杂质是o，p-BPA，其作为产品中的颜色稳定剂和由BPA制备的聚碳酸酯树脂。

25. 发明授权

US5756860A Crystalline adduct of bisphenol A and bisphenol TMC 失效
标题翻译：双酚A和双酚TMC的结晶加合物
公开(公告)号：US5756860A
公开(公告)日：1998-05-26
申请号：US691390
申请日：1996-08-02
申请人： Kurt-Peter Meurer , Tony Van Osselaer , Claus Wulff , Jurgen Hinz
发明人： Kurt-Peter Meurer , Tony Van Osselaer , Claus Wulff , Jurgen Hinz
IPC分类号： C07C37/84 , C07C39/16 , C07C39/17 , C08G64/00 , C08G64/06
CPC分类号： C07C39/17 , C07C37/84 , C07C39/16 , C07C2101/14
摘要： The invention relates to the preparation of a transparent crystalline adduct consisting of bisphenol A (75 parts) and bisphenol TMC (25 parts), which has a melting point of 144.degree. C. which is below the melting points of the pure starting compounds bisphenol A (157.degree. C.) and bisphenol TMC (208.degree. C.).
摘要翻译：本发明涉及由双酚A（75份）和双酚TMC（25份）组成的透明结晶加合物的制备，其熔点为144℃，低于纯起始化合物双酚A的熔点（157℃）和双酚TMC（208℃）。

26. 发明授权

US5675044A Process for recovery of bisphenol-A from thermoplastic polymer containing dihydric phenol units 失效
标题翻译：从含二羟酚单元的热塑性聚合物中回收双酚A的方法
公开(公告)号：US5675044A
公开(公告)日：1997-10-07
申请号：US673990
申请日：1996-07-01
申请人： Paul Eijsbouts , Jos De Heer , Gabrie Hoogland , Srikanth Nanguneri , Gert De Wit
发明人： Paul Eijsbouts , Jos De Heer , Gabrie Hoogland , Srikanth Nanguneri , Gert De Wit
IPC分类号： C07C27/02 , C07C37/52 , C07C37/82 , C07C39/16 , C07C37/84
CPC分类号： C07C39/16 , C07C37/0555 , C08J11/16 , C08J2369/00 , Y02W30/705
摘要： A method of recovering dihydric phenol, particularly bisphenol-A, from compositions containing the reaction residue of bisphenol-A units which method comprises: a. granulating a bisphenol-A containing polymer; b. treating the particles with an alcohol, or any other organic swelling solvent miscible with water and easily distilled off from an aqueous solution, preferably a C.sub.1 -C.sub.10 alcohol for a time sufficient to swell the particles; c. contacting the swelled particles with a ammoniacal solution at a temperature of at least about 25.degree. C. depending on the swelling solvent employed in order to selectively sever the ester bonds of the bisphenol-A residue units; d. separating the liquid phase from the solid phase; e. distilling ammonia and swelling solvent from the liquid phase of d. above, thus obtaining an essentially aqueous solution with dissolved urea and partially precipitated bisphenol-A; f. adding sufficient water to the residue of e. above to precipitate bisphenol-A thereby forming a liquid and solid phase; g. recovering the solid phase of bisphenol-A; and h. drying the bisphenol-A. Since urea is soluble in water, urea goes into solution in step f. above. The urea is, therefore, recoverable, as well, which can be used as such or broken down into its component parts such as carbon dioxide and ammonia which ammonia can also be reused in this ammonical process.
摘要翻译：从含有双酚A单元的反应残基的组合物中回收二元酚，特别是双酚A的方法，该方法包括：a。造粒含双酚A的聚合物; b。用醇处理颗粒，或与水混溶的任何其它有机溶胀溶剂，并且容易从水溶液，优选C1-C10醇中蒸出足以溶胀颗粒的时间; C。根据所用的溶胀溶剂，使溶胀的颗粒与氨溶液在至少约25℃的温度下接触，以选择性地切断双酚A残基单元的酯键; d。将液相与固相分离; e。从d的液相中蒸馏氨和溶胀溶剂。从而获得具有溶解的尿素和部分沉淀的双酚A的基本水溶液; F。向e的残留物中加入足够的水。以沉淀双酚A，从而形成液相和固相; G。回收双酚A的固相; 和h。干燥双酚A。由于尿素可溶于水，所以在步骤f中尿素进入溶液。以上。因此，尿素也是可回收的，其可以原样使用或分解成其组分部分如二氧化碳和氨，氨也可以在该氨过程中再次使用。

27. 发明授权

US5648561A Process for the production of high purity and ultrapure bisphenol-A 失效
标题翻译：生产高纯度和超纯双酚A的方法
公开(公告)号：US5648561A
公开(公告)日：1997-07-15
申请号：US505309
申请日：1995-10-11
申请人： Qiu Tan , Minhua Zhang , Shenbo Yu , Zongzhang Liu , Shenghua Qian , Chuanzhao Li
发明人： Qiu Tan , Minhua Zhang , Shenbo Yu , Zongzhang Liu , Shenghua Qian , Chuanzhao Li
IPC分类号： B01J31/08 , B01J19/30 , B01J39/04 , C07C37/20 , C07C37/74 , C07C37/84 , C07C39/16 , C07C37/68 , C07C39/12
CPC分类号： C07C37/20 , C07C37/74 , C07C37/84 , Y02P20/52
摘要： High purity and ultrapure bisphenol A is prepared in a novel process.
摘要翻译： PCT No.PCT / CN94 / 00011 Sec。 371 1995年10月11日第 102（e）日期1995年10月11日PCT 1994年2月16日PCT PCT。 WO94 / 19302 PCT公开号日期1994年9月1日以新颖的方法制备高纯度和超纯双酚A。

28. 发明授权

US5589598A Process of purification of 2,6-diisopropylphenol 失效
标题翻译：纯化2,6-二异丙基苯酚的方法
公开(公告)号：US5589598A
公开(公告)日：1996-12-31
申请号：US457592
申请日：1995-06-01
申请人： Maurizio Paiocchi
发明人： Maurizio Paiocchi
IPC分类号： C07C37/84 , C07C37/86 , C07C39/06 , C07C67/14 , C07C69/78 , C07C69/92 , C07C201/12 , C07C205/57 , C07C303/24 , C07C303/28 , C07C303/44 , C07C309/31 , C07C37/68
CPC分类号： C07C303/24 , C07C37/0555 , C07C37/86 , C07C67/14
摘要： A process for the purification of 2,6-diisopropylphenol (Propofol) by transformation of the crude Propofol into its ester with a carboxylic or sulphonic acid, crystallization and hydrolysis, is described.
摘要翻译：描述了通过用羧酸或磺酸将粗异丙酚转化成其酯，结晶和水解来纯化2,6-二异丙基苯酚（异丙酚）的方法。

29. 发明授权

US5512700A Process for purifying a bisphenol 失效
标题翻译：纯化双酚的方法
公开(公告)号：US5512700A
公开(公告)日：1996-04-30
申请号：US401513
申请日：1995-03-10
申请人： Emil Patrascu , Karl Kraehling , Jochen Gressmann
发明人： Emil Patrascu , Karl Kraehling , Jochen Gressmann
IPC分类号： C07C37/84 , C07C39/16
CPC分类号： C07C37/84 , C07C37/685
摘要： A process for the purification of a crude bisphenol comprises the following steps:(1) preparing a mixture comprising from about 35 to about 70% of a crude bisphenol and from about 65 to about 30% of water, by the total weight of bisphenol and water, without addition of a substantial amount of an organic solvent or an alkaline compound, at a pressure above atmospheric and a temperature above about 100.degree. C.,(2) crystallizing bisphenol at a pressure below atmospheric,(3) separating crystalline bisphenol from the mother liquor,(4) dividing at least a portion of the mother liquor into a bisphenol-rich oil phase and a water-rich phase,(5) preparing a mixture comprising at least a portion of the bisphenol-rich oil phase, water and optionally an additional amount of crude bisphenol at a pressure above atmospheric and a temperature above about 100.degree. C.,(6) cooling the mixture and crystallizing bisphenol; and(7) separating crystalline bisphenol from the mother liquor.
摘要翻译：用于纯化粗双酚的方法包括以下步骤：（1）制备包含约35％至约70％粗双酚和约65至约30％水的混合物与双酚的总重量，水，不加大量的有机溶剂或碱性化合物，在高于大气压和高于约100℃的温度下，（2）在低于大气压的压力下结晶双酚，（3）将结晶双酚与母液，（4）将至少一部分母液分成富含双酚的油相和富水相，（5）制备包含至少一部分富含双酚的油相的混合物，水和任选的另外量的粗双酚在高于大气压和高于约100℃的温度下，（6）冷却混合物并结晶双酚; 和（7）从母液中分离出结晶双酚。

30. 发明授权

US5475152A Process and composition 失效
标题翻译：过程和组成
公开(公告)号：US5475152A
公开(公告)日：1995-12-12
申请号：US329746
申请日：1994-10-26
申请人： Gaylord M. Kissinger , Nicholas P. Wynn
发明人： Gaylord M. Kissinger , Nicholas P. Wynn
IPC分类号： C07C37/84 , C07C39/16 , C07C37/68
CPC分类号： C07C37/84
摘要： A method comprising purifying impure bisphenol-A by fractional melt crystallization in a falling film dynamic crystallizer.
摘要翻译：一种包括在降膜动态结晶器中通过分级熔融结晶纯化不纯双酚A的方法。

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