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21. 发明授权

US06919487B2 Bis(4-hydroxyaryl)alkanes 有权
标题翻译：双（4-羟基芳基）烷烃
公开(公告)号：US06919487B2
公开(公告)日：2005-07-19
申请号：US10149906
申请日：2000-12-07
申请人： Rainer Neumann , Rolf Lanze , Frieder Heydenreich , Michael Bödiger , Michael Prein
发明人： Rainer Neumann , Rolf Lanze , Frieder Heydenreich , Michael Bödiger , Michael Prein
IPC分类号： F28F21/04 , B01D9/02 , B01J8/02 , C07C37/68 , C07C37/70 , C07C37/74 , C07C37/84 , C07C39/04 , C07C39/16
CPC分类号： C07C37/70 , C07C37/685 , C07C39/16
摘要： The present application relates to a process for producing high-purity bis(4-hydroxyaryl)alkanes from adducts of bis(4-hydroxyaryl)alkanes and aromatic hydroxy compounds, which are obtained by acid-catalysed reaction of the aromatic hydroxy compounds with ketones.
摘要翻译：本申请涉及通过芳族羟基化合物与酮的酸催化反应获得的由双（4-羟基芳基）烷烃和芳族羟基化合物的加合物生产高纯度双（4-羟基芳基）烷烃的方法。

22. 发明授权

US5679312A Multiple stage suspended reactive stripping process and apparatus 失效
标题翻译：多级悬浮反应脱除工艺及装置
公开(公告)号：US5679312A
公开(公告)日：1997-10-21
申请号：US505311
申请日：1995-10-30
申请人： Shiyi Jin , Jitang Yuan , Zongli Zhang , Huisheng Lu , Lianshun Wang , Jinzhu Yin
发明人： Shiyi Jin , Jitang Yuan , Zongli Zhang , Huisheng Lu , Lianshun Wang , Jinzhu Yin
IPC分类号： B01D3/22 , B01D3/00 , B01J8/04 , B01J8/18 , B01J19/00 , C07C37/20 , C07C37/84 , C07C39/16 , B01D3/38 , B01D3/40 , C07C37/00
CPC分类号： C07C37/20 , B01D3/009 , B01J8/048 , Y02P20/127 , Y02P20/582 , Y10S203/06
摘要： A reactive stripping process for continuously carrying out chemical reactions while separating the reactants from the reaction products is provided. The process comprises passing liquid reactants and an inert stripping gaseous stream in a reactor column (1) having a plurality of perforated trays (2) provided therein and interconnected by a plurality of downcomers (3), screens (4 and 5) provided on the trays (2) and the top openings of the downcomers (3). The trays (2) and downcomers (3) are associated with the screens (4 and 5) to form a chamber optionally provided with a solid particulate or liquid catalyst (6) therein. A reactive stripping apparatus for performing such a process is also provided. According to the invention, at least one reaction product and the reaction mixture having different boiling points can be separated in order that chemical reactions proceed continuously as desired.
摘要翻译： PCT No.PCT / CN94 / 00012 Sec。 371 1995年10月30日第 102（e）日期1995年10月30日PCT 1994年2月16日PCT PCT。公开号WO94 / 19079 日期1994年9月1日提供了在将反应物与反应产物分离的同时连续进行化学反应的反应性汽提方法。该方法包括将液体反应物和惰性汽提气流送入反应器塔（1），反应器塔（1）中具有多个设置在其中的多孔塔板（2），并由多个降液管（3），设置在其上的筛网（4和5）托盘（2）和降液管（3）的顶部开口。托盘（2）和降液管（3）与筛网（4和5）相关联，以形成任选设有固体颗粒或液体催化剂（6）的室。还提供了用于执行这种处理的反应性剥离装置。根据本发明，至少一种反应产物和具有不同沸点的反应混合物可以分离，以使化学反应根据需要连续进行。

23. 发明授权

US5434316A Purification of bisphenol-A 失效
标题翻译：双酚A的纯化
公开(公告)号：US5434316A
公开(公告)日：1995-07-18
申请号：US281970
申请日：1994-07-28
申请人： Gaylord M. Kissinger
发明人： Gaylord M. Kissinger
IPC分类号： C07B63/00 , B01D9/00 , C07B61/00 , C07C37/20 , C07C37/84 , C07C39/16
CPC分类号： C07C37/84 , B01D9/0013
摘要： Bisphenol-A produced by the condensation of acetone and phenol is freed of contaminant co-products by melting and crystallization in and from water. The final washing, in hot water, cleanses the crystal surfaces of remaining contaminants without the need for organic solvents.
摘要翻译：通过丙酮和苯酚的缩合产生的双酚A通过在水中和从水中熔化和结晶而消除污染物的副产物。在热水中进行最后一次洗涤，清洁剩余污染物的晶体表面，无需有机溶剂。

24. 发明授权

US5399783A Preparation of 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane 失效
标题翻译： 6,6'-二羟基-3,3,3'，3'-四甲基-1,1'-螺二茚满的制备
公开(公告)号：US5399783A
公开(公告)日：1995-03-21
申请号：US225559
申请日：1994-04-11
申请人： Mizuo Ito , Shigeru Iimuro
发明人： Mizuo Ito , Shigeru Iimuro
IPC分类号： C07C37/84 , C07C39/12
CPC分类号： C07C37/84 , C07C2103/84
摘要： Crystals of 6,6'-dihydroxy-3,3,3',3'-tetramethyl -1,1'-spirobiindane (hereinafter referred to as SPI) are obtained by cooling a phenol solution containing 6,6'-dihydroxy-3,3,3',3'-tetramethyl-1,1'-spirobiindane when crystallization is started at a temperature higher than a transition temperature between SPI and an adduct of SPI with phenol. The crystals are washed with an organic solvent or contacted with water and further washed with an organic solvent. When crystallization is started at a temperature less than the transition temperature, adduct crystals of SPI with phenol are obtained from the phenol solution. Phenol is removed from the adduct crystals and the adduct crystals are contacted with water to obtain a hydrate and further the hydrate is washed with an organic solvent.
摘要翻译：通过将含有6,6'-二羟基-3,3,3'，3'-四甲基-1,1'-螺二茚满的酚溶液（以下称为SPI），3,3'，3'-四甲基-1,1'-螺二茚满当结晶在高于SPI与SPI与苯酚的加合物之间的转变温度的温度下开始时。晶体用有机溶剂洗涤或与水接触，并进一步用有机溶剂洗涤。当在低于转变温度的温度下开始结晶时，从苯酚溶液中获得SPI与苯酚的加合物晶体。从加合物晶体中除去苯酚，并将加合物晶体与水接触，得到水合物，再用有机溶剂洗涤水合物。

25. 发明授权

US5324492A Method of reducing nitrogen oxide content in gas 失效
标题翻译：减少气体中氮氧化物含量的方法
公开(公告)号：US5324492A
公开(公告)日：1994-06-28
申请号：US918277
申请日：1992-07-22
申请人： Senichi Masuda , Kaichi Sakakibara , Shigehiro Kitoh , Shigeo Saiki
发明人： Senichi Masuda , Kaichi Sakakibara , Shigehiro Kitoh , Shigeo Saiki
IPC分类号： C07B63/00 , B01D9/00 , B01D53/32 , B01D53/56 , B01D53/74 , B01J19/08 , C07C37/70 , C07C37/84 , C07C39/16 , C07C201/16 , C07C205/06 , C01B21/00 , C08F2/46
CPC分类号： B01J19/088 , B01D53/326 , B01D53/56 , B01D9/0004 , F23J2215/10 , F23J2219/201 , Y10T117/10
摘要： A method of reducing a nitrogen oxide content in gas is disclosed. In this method, subject gas containing nitrogen oxide is supplied to a gas passage of a surface discharger to decompose the nitrogen oxide content in the gas into nitrogen gas.
摘要翻译：公开了一种降低气体中氮氧化物含量的方法。在该方法中，将含有氮氧化物的对象气体供给到表面放电器的气体通道，以将气体中的氮氧化物含量分解成氮气。

26. 发明授权

US5245088A Process for crystallizing adduct of bisphenol A with phenol 失效
标题翻译：双酚A与苯酚的结晶过程
公开(公告)号：US5245088A
公开(公告)日：1993-09-14
申请号：US846996
申请日：1992-04-07
申请人： Shigeru Fimuro , Akira Yamada , Kenichi Ohmura
发明人： Shigeru Fimuro , Akira Yamada , Kenichi Ohmura
IPC分类号： C07C37/84
CPC分类号： C07C37/84
摘要： A process for preparing high-purity bisphenol A by estimating on line slurry concentration of a bisphenol A-phenol adduct in a crystallizer on the basis of a material balance and a heat balance around the crystallizer and thereby maintaining said slurry concentration at a prescribed level to precipitate the crystals of said adduct. The slurry having a constant concentration can be always fed to a slurry separating step, thereby enabling steady operation of the slurry separating step. Thus, the process is useful for enhancing productivity. As a result, extraordinary adhesion of the impurity-containing filtrate to the crystals of the bisphenol A-phenol adduct can be inhibited in the slurry separating step, and hence high-purity bisphenol A can be obtained.

27. 发明授权

US5169990A Preparation of 9,9-bis-(4-hydroxyphenyl)-fluorene 失效
标题翻译： 9,9-双（4-羟基苯基） - 荧光素的制备
公开(公告)号：US5169990A
公开(公告)日：1992-12-08
申请号：US833769
申请日：1992-02-11
申请人： Winfried Orth , Emmerich Pastorek , Wolfgang Weiss , Hans W. Kleffner
发明人： Winfried Orth , Emmerich Pastorek , Wolfgang Weiss , Hans W. Kleffner
IPC分类号： B01J31/02 , C07B61/00 , C07C37/20 , C07C37/84 , C07C39/15 , C07C39/17
CPC分类号： C07C39/17 , C07C37/20 , C07C2103/18
摘要： In the production of 9,9-bis-(4-hydroxphenyl)-fluorene by condensation by fluorenone and phenol in a molar ratio of 1:4 to 1:8 at 30.degree. to 90.degree. C. in the presence of gaseous hydrogen chloride and .beta.-mercapto-propionic acid as catalyst, the improvement comprising mixing the completed reaction mixture with a polyalkylene glycol, distilling excess phenol from the mixture, and mixing the distillation residue with a solvent miscible with the polyalkylene glycol, recovering the crystallized product, suspending the crystallized product in water and heating the suspension to obtain highly pure 9,9-bis-(4-hydroxyphenyl)-fluorene as white crystals.
摘要翻译：在通过芴酮和苯酚在摩尔比为1:4至1:8的温度下在30-90℃下在气态氯化氢存在下缩合制备9,9-双 - （4-羟基苯基） - 芴和β-巯基 - 丙酸作为催化剂，其改进包括将完成的反应混合物与聚亚烷基二醇混合，从混合物中蒸馏出过量的苯酚，并将蒸馏残余物与可与聚亚烷基二醇混溶的溶剂混合，回收结晶产物，悬浮结晶产物在水中并加热悬浮液，得到高纯度的9,9-双（4-羟基苯基） - 芴，为白色结晶。

28. 发明授权

US5110994A Process for synthesizing 9,9-bis-(hydroxyphenyl)fluorene 失效
标题翻译：合成9,9-双（羟基苯基）氟的方法
公开(公告)号：US5110994A
公开(公告)日：1992-05-05
申请号：US613668
申请日：1990-12-10
申请人： Peter Fialla
发明人： Peter Fialla
IPC分类号： B01J27/125 , C07B61/00 , C07C37/20 , C07C37/84 , C07C39/17
CPC分类号： C07C39/17 , C07C37/20 , C07C2103/18
摘要： The invention concerns a process for synthesizing 9,9-bis(hydroxyphenyl)fluorene by reacting fluorene with excess phenol using a liquid catalyst prepared by dissolving aluminum trichloride in an anhydrous organic solvent such as toluene evincing the property of an electron donor while hydrochloric-acid gas is being supplied. For the purpose of the synthesis, the fluorenone is dissolved for instance at 60.degree. C. in the liquid phenol and then the liquid catalyst is dripped into the agitated reaction mixture at such a rate that the temperature of the reaction mixture is kept below 60.degree. C. Following catalyst addition and subsequent after-reaction interval of several hours, the raw product is mixed with hot water and the excess phenol is removed by steam distillation. After signle-washing with water, the raw product is dissolved in hot acetone, allowed to crystallize, is filtered out and dried in vacuum. Lastly the raw product is recrystallized from 1,2-dichloroethane to form the pure product.
摘要翻译： PCT No.PCT / AT90 / 00031 Sec。 371 1990年12月10日第 102（e）1990年12月10日日期PCT提交1990年4月17日PCT公布。 WO90 / 12776 PCT出版物日本1990年11月1日。本发明涉及通过使用通过将三氯化铝溶解在无水有机溶剂如甲苯中制备的液体催化剂使芴与过量苯酚反应来合成9,9-双（羟基苯基）芴的方法，电子给体，同时供应盐酸气体。为了合成的目的，将芴酮例如在60℃下溶解在液体苯酚中，然后将液体催化剂滴入搅拌的反应混合物中，使反应混合物的温度保持在60℃以下 C.催化剂加入和随后的反应间隔数小时后，将原料与热水混合，通过蒸汽蒸馏除去过量的苯酚。用水标志洗涤后，将粗产物溶于热丙酮中，使其结晶，过滤并真空干燥。最后，将原料从1,2-二氯乙烷中重结晶形成纯产物。

29. 发明授权

US5003113A Process of producing isopropylnaphthols 失效
标题翻译：生产异丙基萘酚的方法
公开(公告)号：US5003113A
公开(公告)日：1991-03-26
申请号：US440212
申请日：1989-11-22
申请人： Michio Tanaka , Masayasu Ishibashi , Katsuo Taniguchi
发明人： Michio Tanaka , Masayasu Ishibashi , Katsuo Taniguchi
IPC分类号： C07C37/08 , C07C37/84 , C07C39/14 , C07C409/12
CPC分类号： C07C409/12 , C07C37/08 , C07C37/84 , C07C407/00
摘要： In a process of producing isopropylnaphthols by oxidizing diisopropylnaphthalenes with molecular oxygen in a liquid phase to provide a reaction mixture which contains therein diisopropylnaphthalene monohydroperoxides and then acid decomposing the monohydroperoxides to isopropylnaphthols, the improvement comprising separating an organic layer from the reaction mixture, adding lower aliphatic alcohols of 1-4 carbons to the organic layer, crystallizing the diisopropylnaphthalenes while allowing the diisopropylnaphthalene monohydroperoxides to remain dissolved in the lower aliphatic alcohols, thereby to separate the monohydroperoxides from the diisopropylnaphthalenes.A further improvement in the process comprises crystallizing the isopropylnaphthols from aromatic hydrocarbons of 6-12 carbons.

30. 发明授权

US4927978A Method of purifying bisphenols 失效
标题翻译：双酚纯化方法
公开(公告)号：US4927978A
公开(公告)日：1990-05-22
申请号：US285253
申请日：1988-12-16
申请人： James L. Buechele , Edward L. Nielsen , Walter Dong , Paul V. Shaw
发明人： James L. Buechele , Edward L. Nielsen , Walter Dong , Paul V. Shaw
IPC分类号： C07C37/84 , C07C39/04 , C07C39/16
CPC分类号： C07C37/84
摘要： A process for the preparation of crystals of an adduct of a bisphenol with a phenol which comprises:(a) adding an inert volatile liquid hydrocarbon diluent and 0-1.5% weight water to a crude mixture of the bisphenol and the phenol at a temperature above the boiling temperature of the added volatile liquid diluent; and(b) allowing the volatile liquid diluent to boil in the process, thereby cooling the resulting mixture of bisphenol and phenol to a temperature at which adduct crystals form.

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