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21. 发明申请

US20050169823A1 Procedure to leach copper concentrates, under pressure and at ambient temperature, by forming a reactive gel in a sulfate-chloride medium 有权
标题翻译：在压力和环境温度下通过在硫酸盐 - 氯化物介质中形成反应性凝胶来浸出铜浓缩物的步骤
公开(公告)号：US20050169823A1
公开(公告)日：2005-08-04
申请号：US11018614
申请日：2004-12-21
申请人： Jamie Faine , Freddy Alfaro , Raul Jullian , Abraham Gutierrez
发明人： Jamie Faine , Freddy Alfaro , Raul Jullian , Abraham Gutierrez
IPC分类号： C22B3/04 , C22B3/08 , C22B3/10 , C22B15/00 , C22B15/14
CPC分类号： C22B15/0008 , C22B15/0067 , C22B15/0069 , C22B15/0071 , Y02P10/236
摘要： A chemical process to leach copper concentrates in the presence of a concentrated solution of sulfates and chlorides. The process includes forming a high reactivity chemical paste containing a high concentration of ions in the liquid phase of the paste which react with copper ores and forms a series of soluble salts. The salts are extracted by a simple wash. Mixing equipment for handling high viscosity liquids is used. The total mixing time is about 5 minutes, after which the paste is poured into a rectangular mold, of several hundred meters per side, and is left to settle and breathe During settling, water and sulfuric acid are added at intervals to replace that consumed by the reactions taking place during the aeration, until the reactions have virtually end. This treatment results in a dry, very resistant mass, containing the copper extracted in form of chlorine salts, and sulfate.
摘要翻译：在硫酸盐和氯化物的浓缩溶液存在下浸出铜精矿的化学方法。该方法包括在与铜矿反应的糊状物的液相中形成含有高浓度离子的高反应性化学糊剂并形成一系列可溶性盐。盐通过简单的洗涤来提取。使用用于处理高粘度液体的混合设备。总混合时间约为5分钟，然后将浆料倒入每边几百米的矩形模具中，并静置并呼吸。在沉降期间，每隔一段时间加入水和硫酸以代替由反应在曝气期间发生，直到反应实际结束。这种处理导致干燥，非常耐受的质量，含有以氯盐形式提取的铜和硫酸盐。

22. 发明申请

US20040250655A1 Method for purifying the solution in the hydrometallurgical processing of copper 有权
标题翻译：在铜的湿法冶金加工中纯化溶液的方法
公开(公告)号：US20040250655A1
公开(公告)日：2004-12-16
申请号：US10492893
申请日：2004-04-16
发明人： Matti Hamalainen
IPC分类号： C22B015/00
CPC分类号： C22B15/0089 , C22B15/0069 , Y02P10/236
摘要： The invention relates to the removal of bivalent copper from copper chloride solution in connection with the hydrometallurgical production of copper. In the copper production process, a copper-bearing raw material is leached with a chloride-bearing solution. The copper chloride solution formed in the leaching, which contains both mono- and bivalent copper, undergoes bivalent copper removal at least in part by precipitation, and the copper(I) chloride solution is conduced to further treatment. Precipitation of the bivalent copper occurs as alkaline copper chloride precipitation. The alkaline copper (II) chloride formed is leached as copper(II) chloride either separately or in connection with raw material leaching, and is used in copper raw material leaching.
摘要翻译：本发明涉及从铜的湿法冶金生产中除去氯化铜溶液中的二价铜。在铜生产过程中，含铜原料用含氯化合物溶液浸出。含有单价和二价铜的浸出中形成的氯化铜溶液至少部分通过沉淀进行二价铜去除，并且进一步处理氯化铜（I）溶液。二价铜的析出发生为碱性氯化铜沉淀。形成的碱性铜（II）氯化物分别或与原料浸出相连，作为氯化铜（II）浸出，用于铜原料浸出。

23. 发明申请

US20030192404A1 Process for the treatment or removal of impurities in a hydrometallurgical extraction process 有权
标题翻译：在湿法冶金提取过程中处理或除去杂质的方法
公开(公告)号：US20030192404A1
公开(公告)日：2003-10-16
申请号：US10122346
申请日：2002-04-16
申请人： COMINCO ENGINEERING SERVICES LTD.
发明人： David L. Jones
IPC分类号： C22B011/00
CPC分类号： C22B15/0008 , C22B3/0005 , C22B7/007 , C22B7/02 , C22B15/0069 , C22B15/0071 , C22B15/0089 , C22B30/00 , Y02P10/234 , Y02P10/236
摘要： A Process for the treatment or removal of impurities, such as arsenic, antimony or bismuth, generated as by-products during smelting and refining of copper concentrates, comprises subjecting the by-products to pressure oxidation along with a copper concentrate in a hydrometallurgical copper extraction process or the treatment of impurities when present in a concentrate by subjecting the concentrate to a hydrometallurgical extraction process.
摘要翻译：用于处理或除去在铜精矿冶炼和精炼期间作为副产物产生的杂质如砷，锑或铋的方法包括在铜精矿的浸出和铜精矿中对副产物进行压力氧化通过使浓缩物经受湿法冶金提取方法，当存在于浓缩物中时，处理或处理杂质。

24. 发明申请

US20030124040A1 Process for the treatment of molybdenum concentrate 有权
标题翻译：钼精矿的处理工艺
公开(公告)号：US20030124040A1
公开(公告)日：2003-07-03
申请号：US10307412
申请日：2002-12-02
申请人： COMINCO ENGINEERING SERVICES LTD.
发明人： David L. Jones
IPC分类号： C22B015/00
CPC分类号： C22B3/10 , C22B3/0005 , C22B3/06 , C22B15/0069 , C22B15/0071 , C22B15/0089 , C22B34/34 , Y02P10/234 , Y02P10/236
摘要： A method of treatment or purification of a molybdenum concentrate also containing copper, comprises the step of subjecting the molybdenum concentrate to pressure oxidation in the presence of oxygen and a feed solution containing copper (e.g. CuSO4) and halide (e.g. CuCl2) to produce a pressure oxidation solution containing copper and a solid residue containing molybdenum. The pressure oxidation solution may be combined with feed solution to a second pressure oxidation in which a copper concentrate is treated for the recovery of copper therefrom.
摘要翻译：处理或纯化还含有铜的钼精矿的方法包括在氧气和含铜（例如CuSO 4）和卤化物（例如CuCl 2）的进料溶液的存在下对钼浓缩物进行压力氧化以产生压力的步骤含有铜的氧化溶液和含钼的固体残余物。压力氧化溶液可以与进料溶液组合到第二压力氧化，其中处理铜精矿以从中回收铜。

25. 发明授权

US4578162A Method for dissolving copper in the presence of iron 失效
标题翻译：在铁存在下溶解铜的方法
公开(公告)号：US4578162A
公开(公告)日：1986-03-25
申请号：US614502
申请日：1984-05-29
申请人： James A. McIntyre , Robert F. Phillips , Max R. Oswald
发明人： James A. McIntyre , Robert F. Phillips , Max R. Oswald
IPC分类号： C01G3/00 , C22B3/16 , C22B15/00 , C23G1/00 , G21F9/00 , C25C1/12
CPC分类号： G21F9/004 , C01G3/003 , C22B15/0069 , C22B15/0071 , C22B15/0078 , C22B15/0082 , C22B3/165 , C23G1/00 , Y02P10/234 , Y02P10/236
摘要： The invention is a method for dissolving copper in the presence of iron comprising:(a) contacting the copper with an oxidant solution;(b) dissolving at least a portion of the copper into the solution;(c) controlling the copper ion concentration in the solution below that required to cause a runaway oxidant decomposition reaction;(d) removing at least a portion of the dissolved copper from the solution;(e) adding additional oxidant to the solution; and(f) at least repeating steps (a) and (b).
摘要翻译：本发明是一种在铁存在下溶解铜的方法，包括：（a）使铜与氧化剂溶液接触; （b）将至少一部分铜溶解到溶液中; （c）控制溶液中的铜离子浓度低于引起失控氧化剂分解反应所需的铜离子浓度; （d）从溶液中去除至少一部分溶解的铜; （e）向溶液中加入额外的氧化剂; 和（f）至少重复步骤（a）和（b）。

26. 发明授权

US4362607A Recovery of copper and zinc from complex chloride solutions 失效
标题翻译：从复合氯化物溶液中回收铜和锌
公开(公告)号：US4362607A
公开(公告)日：1982-12-07
申请号：US284580
申请日：1981-07-17
申请人： Gordon M. Ritcey , Kenneth T. Price , Bernard H. Lucas
发明人： Gordon M. Ritcey , Kenneth T. Price , Bernard H. Lucas
IPC分类号： C01G3/00 , C01G9/00 , C22B1/08 , C22B3/10 , C22B3/26 , C22B3/38 , C22B13/08 , C22B13/10 , C22B15/00 , C25C1/12 , C25C1/16 , C25C1/18
CPC分类号： C22B15/0084 , C01G3/003 , C01G9/003 , C22B1/08 , C22B13/04 , C22B13/08 , C22B13/10 , C22B15/0069 , C22B19/22 , C22B3/0032 , C22B3/0068 , C22B3/10 , Y02P10/234 , Y02P10/236
摘要： The solvent extraction separation and recovery of copper and zinc from complex chloride liquors; e.g. those resulting from the low temperature chlorination and leach of a copper-lead-zinc sulphide ore or concentrate; are described, including the selection of sequence, conditions, extractants, scrubbing and stripping media and adaptations for electrowinning and recycle. High purity copper sulphate and zinc chloride electrolytes are produced for subsequent direct electrowinning. Lead may also be recovered.
摘要翻译：从复合氯化物溶液萃取分离和回收铜和锌; 例如那些由铜 - 铅 - 硫化锌矿石或精矿的低温氯化和浸出产生的那些; 包括选择序列，条件，萃取剂，洗涤和汽提介质以及电解冶金和回收的适应性。生产高纯度硫酸铜和氯化锌电解质用于随后的直接电解沉积。铅也可能回收。

27. 发明授权

US4013457A Process for the recovery of cuprous chloride in the presence of metal impurities 失效
标题翻译：在金属杂质存在下回收氯化亚铜的方法
公开(公告)号：US4013457A
公开(公告)日：1977-03-22
申请号：US552694
申请日：1975-02-24
申请人： Duane N. Goens , Paul R. Kruesi
发明人： Duane N. Goens , Paul R. Kruesi
IPC分类号： C01G3/05 , C22B15/00 , C22B3/00 , C01G3/04
CPC分类号： C22B15/0093 , C01G3/05 , C22B15/0069 , C22B15/0086 , Y02P10/236
摘要： A process is disclosed for separating cuprous chloride from a solution comprising cuprous chloride and one or more of a number of metal impurities, the process comprising crystallizing the cuprous chloride from the solution in the presence of copper as cupric chloride in a concentration of at least about 20 grams per liter. In one embodiment, the process is employed for recovering substantially pure copper from copper sulfide concentrates containing one or more metal impurities, the basic process comprising leaching the copper sulfide concentrates with ferric chloride to produce a leach solution comprising cuprous chloride, cupric chloride, ferrous chloride and the metal impurities, crystallizing a substantial portion of the cuprous chloride from the leach solution in the presence of cupric ion in a concentration of at least about 20 grams per liter in order to produce substantially pure cuprous chloride and a mother liquor, separating the crystallized cuprous chloride from the mother liquor, reducing the crystallized cuprous chloride to substantially pure elemental copper, treating a substantial portion of the mother liquor with oxygen and hydrochloric acid to produce iron oxide, cupric chloride and ferric chloride, and treating the remainder of the mother liquor in order to remove the impurities.
摘要翻译：公开了一种从包含氯化亚铜和一种或多种多种金属杂质的溶液中分离氯化亚铜的方法，该方法包括在铜的存在下，将铜氯化亚铜从浓度为至少约为每升20克在一个实施方案中，该方法用于从含有一种或多种金属杂质的硫化铜浓缩物中回收基本上纯的铜，其基本方法包括将硫化铜浓缩物与氯化铁浸出以产生包含氯化亚铜，氯化铜，氯化亚铁和金属杂质，在铜离子存在下，以至少约20克/升的浓度从浸出溶液中结晶大部分氯化亚铜以产生基本上纯的氯化亚铜和母液，将结晶的将氯化亚铜从母液中还原，将结晶的氯化亚铜还原为基本上纯的元素铜，用氧和盐酸处理大部分母液以产生氧化铁，氯化铜和氯化铁，并处理剩余的母液以去除杂质。

28. 发明授权

US3950486A Method for separating metal constituents from ocean floor nodules 失效
标题翻译：从海底结节分离金属成分的方法
公开(公告)号：US3950486A
公开(公告)日：1976-04-13
申请号：US247554
申请日：1972-04-26
申请人： Paul H. Cardwell , William S. Kane
发明人： Paul H. Cardwell , William S. Kane
IPC分类号： C01G3/00 , C01G45/00 , C01G49/00 , C01G53/00 , C22B1/08 , C22B3/10 , C22B3/28 , C22B3/30 , C22B3/32 , C22B3/36 , C22B3/38 , C22B15/00 , C22B47/00 , C01G3/04 , C01G45/06 , C01G49/10
CPC分类号： C01G3/003 , C01G49/0009 , C01G53/003 , C22B1/08 , C22B15/0006 , C22B15/0019 , C22B15/0069 , C22B15/0082 , C22B23/04 , C22B3/001 , C22B3/0017 , C22B3/0027 , C22B3/0037 , C22B3/0068 , C22B3/0077 , C22B3/10 , C22B47/0063 , C22B47/0081 , Y02P10/234 , Y02P10/236 , Y10S423/04
摘要： Ocean floor nodules are treated with aqueous hydrogen halide to produce a pregnant leach solution which is subjected to selective solvent extraction to isolate metal values contained in the ore.
摘要翻译：海底结节用卤化氢水溶液处理以产生一个怀孕的浸出溶液，该溶液经过选择性溶剂萃取以分离矿石中所含的金属值。

29. 发明授权

US3918962A Process for winning copper using carbon monoxide 失效
标题翻译：使用一氧化碳获得铜的工艺
公开(公告)号：US3918962A
公开(公告)日：1975-11-11
申请号：US51233174
申请日：1974-10-04
申请人： ETHYL CORP
发明人： DUBECK MICHAEL , IM SUK JOONG
IPC分类号： C22B15/00 , C22B15/12
CPC分类号： C22B15/0021 , C22B15/0006 , C22B15/0069 , C22B15/0093 , Y02P10/236
摘要： Process of winning copper from chloride containing solutions by treating with carbon monoxide. Process makes copper separable from iron, and can be applied to leach solutions prepared by treating sulfide ores with HCl in the presence of air or oxygen.
摘要翻译：通过用一氧化碳处理从含氯化物溶液中获得铜的工艺。工艺使铜与铁分离，并可应用于在空气或氧气存在下用HCl处理硫化矿石制备的浸出溶液。

30. 发明授权

US3901776A Process for the recovery of copper from its sulfide ores 失效
标题翻译：从其硫酸盐还原铜的方法
公开(公告)号：US3901776A
公开(公告)日：1975-08-26
申请号：US52358874
申请日：1974-11-14
申请人： CYPRUS METALLURG PROCESS
发明人： KRUESI PAUL R , GOENS DUANE N
IPC分类号： C22B15/00 , C25C1/12 , C22D1/16
CPC分类号： C22B15/0069 , C25C1/12 , Y02P10/236
摘要： An improvement in the process for recovering copper from its sulfide ores or concentrates thereof which comprises treating the ore with cupric chloride and/or ferric chloride to form a copper chloride electrolyte and a residue, electrolytically recovering copper from the electrolyte and further treating the residue with ferric chloride to solubilize substantially all of the copper remaining therein for conversion to copper chloride electrolyte, with ferrous chloride from the electrolyte being regenerated to ferric chloride for leaching the residue, the improvement which comprises conducting the electrolysis without the conversion of any cuprous copper to cupric copper, using a separator between the anolyte and catholyte compartments of the electrolytic cell to prevent passage of ions of copper and iron between the catholyte and anolyte, continuously further treating the residue with regenerated ferric chloride of a concentration to insure there is no cuprous copper in the resulting solution and regenerating ferric chloride from ferrous chloride in the solution free of cuprous chloride by passing the solution through the anolyte compartment of the electrolytic cell as copper is continuously being recovered at the cathode of the cell.

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