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    • 30. 发明授权
    • Blends of poly(propylene carbonate) and poly(methyl methacrylate) and
their use in decomposition molding
    • 聚(碳酸丙烯酯)和聚(甲基丙烯酸甲酯)的共混物及其在分解成型中的应用
    • US4874030A
    • 1989-10-17
    • US326938
    • 1989-03-22
    • Jeffrey A. KuphalLloyd M. RobesonJames J. Weber
    • Jeffrey A. KuphalLloyd M. RobesonJames J. Weber
    • B22C7/02C08J9/00
    • C08J9/0061B22C7/023C08J2333/12C08J2369/00C08J2433/00C08J2469/00
    • Compositions useful in decomposition molding procedures such as destructive foam casting or ceramic or metallic powder sintering are provided by blends of polymers having greater than 50 weight percent propylene carbonate units and polymers having greater than 50 weight percent methyl methacrylate units. Such blends exhibit an unexpectedly even decomposition profile over the range of temperatures at which their constituent polymers each decompose relatively rapidly. The controlled decomposition rate reduces problems in destructive foam casting and ceramic or metallic powder molding caused by sudden release of gases by the foam pattern or the polymer binder. Preferred blends contain 35 to 65 weight percent poly(methyl methacrylate) and 65 to 35 weight percent poly(propylene carbonate), and very even decomposition behavior is exhibited by blends of 35 to 45 weight percent poly(methyl methacrylate) and 65 to 55 weight percent poly(propylene carbonate).
    • 通过具有大于50重量%的碳酸丙烯酯单元的聚合物和具有大于50重量%的甲基丙烯酸甲酯单元的聚合物的共混物来提供可用于分解模塑程序如破坏性泡沫浇铸或陶瓷或金属粉末烧结的组合物。 这些共混物在它们的组成聚合物各自相对快速分解的温度范围内显示出意想不到的均匀分解曲线。 受控的分解速率降低了由泡沫图案或聚合物粘合剂突然释放出来的破坏性泡沫铸造和陶瓷或金属粉末成型中的问题。 优选的共混物包含35至65重量%的聚(甲基丙烯酸甲酯)和65至35重量%的聚(碳酸亚丙酯),并且通过35至45重量%的聚(甲基丙烯酸甲酯)和65至55重量份的共混物显示非常均匀的分解行为 百分比聚(碳酸亚丙酯)。