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    • 21. 发明授权
    • Crosslinkable biopolymer
    • 可交联的生物聚合物
    • US08563664B2
    • 2013-10-22
    • US11667929
    • 2005-11-03
    • Jukka Seppälä
    • Jukka Seppälä
    • C08G63/08
    • C09J167/07C08F283/00C08F283/01C08F289/00C08F290/06C08F290/14C08G4/00C08G63/912C08L67/07C08L2666/02C09D151/003C09D151/08C09D167/07C09J151/003C09J151/08
    • A composition, prepolymer and method to produce a polymer based on biodegradable or essentially renewable crude materials, which can be crosslinked by free radicals. The composition is based on polyesters that are functionalized with unsaturated monomer units, in a way that unsaturated groups can be located along the polymer main chain as well as at the ends of the prepolymer. In connection to the product production, the prepolymer is exposed to free radicals that leads to network formation. The composition of the crosslinked biopolymer can be adjusted from a stiff engineering material to an elastic rubbery material. The new biopolymer can be used in composite materials, dispersions, barrier materials, rubbery materials, biomedical applications, and the like.
    • 基于可生物降解的或基本上可再生的粗制材料生产聚合物的组合物,预聚物和方法,其可以通过自由基交联。 该组合物基于用不饱和单体单元官能化的聚酯,其方式是不饱和基团可以沿聚合物主链以及预聚物的末端位置。 关于产品生产,预聚物暴露于导致网络形成的自由基。 交联的生物聚合物的组成可以从刚性工程材料调整到弹性橡胶材料。 新的生物聚合物可用于复合材料,分散体,阻隔材料,橡胶材料,生物医学应用等。
    • 26. 发明申请
    • AQUEOUS HYBRID DISPERSIONS
    • 水性混合分散剂
    • US20120088878A1
    • 2012-04-12
    • US13083622
    • 2011-04-11
    • Dirk Emiel Paula MESTACHWincenty Lambertus Stanislaw PILASZEK
    • Dirk Emiel Paula MESTACHWincenty Lambertus Stanislaw PILASZEK
    • C08L33/12C09D11/00C09D133/12C09J133/12
    • C09D153/00C08F283/00C08F289/00C08F290/06C08F290/14C08L51/003C08L51/08C08L2666/02C09D151/003C09D151/08C09J151/003C09J151/08
    • The invention relates to a process for the preparation of an aqueous hybrid polymer dispersion comprising an auto-oxidatively crosslinkable polymer and an addition polymer. The invention further relates to the aqueous hybrid polymer dispersion obtainable by said process, the use thereof for the manufacture of coating compositions, ink compositions or adhesives and to coating compositions includes the hybrid polymer dispersion as a binder. The process includes a first polymerization step wherein a first hybrid polymer dispersion is formed by addition polymerization of vinyl monomers in the presence of dispersed auto-oxidatively crosslinkable polymer and a second polymerization step wherein secondary polymerization loci are provided in the first hybrid polymer dispersion to polymerise residual vinyl monomer of the first polymerisation step. The aqueous hybrid polymer dispersions have very low residual vinyl monomer content by achieving a high if not full conversion of the vinyl monomers at the end of the polymerization.
    • 本发明涉及一种制备含有自氧化可交联聚合物和加成聚合物的水性杂化聚合物分散体的方法。 本发明还涉及通过所述方法获得的水性混合聚合物分散体,其用于制备涂料组合物,油墨组合物或粘合剂的用途以及涂料组合物,包括作为粘合剂的杂化聚合物分散体。 该方法包括第一聚合步骤,其中通过在分散的自氧化可交联聚合物的存在下乙烯基单体的加成聚合形成第一杂化聚合物分散体,以及第二聚合步骤,其中在第一混合聚合物分散体中提供二聚合位点以进行聚合 第一聚合步骤的残余乙烯基单体。 水性杂化聚合物分散体通过在聚合结束时实现高乙烯基单体的高转化率而具有非常低的残余乙烯基单体含量。