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    • 21. 发明授权
    • Process for removing oxygenate from an olefin stream
    • 从烯烃流中除去含氧化合物的方法
    • US09115103B2
    • 2015-08-25
    • US14136222
    • 2013-12-20
    • Shell Oil Company
    • Jeroen Van Westrenen
    • C07C1/00C07D301/02C07C7/08C07C41/42C07C1/20
    • C07D301/02C07C1/20C07C7/08C07C41/42C07C2529/70Y02P30/42C07C11/06C07C43/043
    • The present invention relates to a process for producing an olefinic product, comprising (a) preparing a reaction product by converting an oxygenate-comprising feedstock in an oxygenate to olefin process, the reaction product comprising at least C2+ olefins and DME, (b) separating at least part of the reaction product by means of extractive distillation using a butanol solvent into: (i) a first fraction comprising C3− olefins and butanol; and (ii) a second fraction comprising C4+ olefins, DME and butanol; (c) separating the first fraction into: (iii)a C3− olefinic product; and (iv) a third fraction comprising butanol; (d) separating the second fraction into: (v) a DME-comprising C4-C5 olefinic product; and (vi) a fourth fraction comprising butanol and C6+ olefins, wherein at least part of the third and/or fourth fraction are recycled to step (b) together with or as part of the butanol solvent.
    • 本发明涉及一种制备烯烃产品的方法,包括(a)通过将含氧化合物的原料在含氧化合物转化为烯烃方法来制备反应产物,所述反应产物至少包含C2 +烯烃和DME,(b)分离 至少部分反应产物通过使用丁醇溶剂的萃取蒸馏进入:(i)包含C 3 - 烯烃和丁醇的第一级分; 和(ii)包含C4 +烯烃,DME和丁醇的第二级分; (c)将第一部分分离成:(iii)C3-烯烃产物; 和(iv)包含丁醇的第三级分; (d)将第二部分分离成:(v)包含DME的C 4 -C 5烯烃产物; 和(vi)包含丁醇和C 6 +烯烃的第四馏分,其中第三和/或第四馏分的至少一部分与丁醇溶剂一起或作为丁醇溶剂的一部分再循环到步骤(b)。
    • 22. 发明授权
    • Process for removing oxygenate from an olefin stream
    • 从烯烃流中除去含氧化合物的方法
    • US09115037B2
    • 2015-08-25
    • US14136189
    • 2013-12-20
    • Shell Oil Company
    • Jeroen Van Westrenen
    • C07D301/03C07C1/00C07C2/00C07C7/10C07C1/20C07C7/08C07C11/04C07C11/06
    • C07C7/10C07C1/20C07C7/08C07C11/04C07C11/06C07D301/03Y02P30/42
    • The present invention relates to a process for removing dimethylether from an olefin stream comprising dimethylether, comprising: (a) providing to an oxygenate recovery zone the olefin stream comprising dimethylether and a methanol-comprising solvent, treating the olefin stream comprising dimethylether with the methanol comprising solvent, and retrieving at least a dimethylether-depleted, methanol-comprising olefin stream; and (b) providing to the oxygenate recovery zone a non-aqueous C2 to C4 alcohol solvent and treating the dimethylether-depleted, methanol-comprising olefin stream with the non-aqueous C2 to C4 alcohol solvent, and retrieving from the oxygenate recovery zone at least an olefinic product that is depleted in dimethylether and methanol and a spent solvent comprising at least one C2 to C4 alcohol and methanol.
    • 本发明涉及从包含二甲醚的烯烃流中除去二甲醚的方法,包括:(a)向含氧物回收区提供包含二甲醚和含甲醇溶剂的烯烃流,用包含二甲醚的甲醇处理包含 溶剂,并回收至少二甲醚耗尽的含甲醇的烯烃流; 和(b)向含氧物回收区提供非水性C2至C4醇溶剂,并用非水性C2至C4醇溶剂处理二甲醚耗尽的含甲醇的烯烃流,并从含氧化合物回收区 至少一种贫二甲醚和甲醇的烯烃产物和包含至少一种C 2至C 4醇和甲醇的废溶剂。
    • 25. 发明授权
    • Extractive distillation process for benzene recovery
    • 萃取蒸馏法回收苯
    • US09005405B2
    • 2015-04-14
    • US13410286
    • 2012-03-01
    • Kuang-Yeu WuTzong-Bin LinFu-Ming LeeTsung-Min ChiuJeng-Cheng Lee
    • Kuang-Yeu WuTzong-Bin LinFu-Ming LeeTsung-Min ChiuJeng-Cheng Lee
    • B01D3/40C07C7/08C07C15/04
    • B01D3/40C07C7/08C07C15/04
    • Recovering high purity benzene from hydrocarbon feedstock containing aromatics and non-aromatics is implemented by simple and low-cost modifications to conventional extractive distillation columns (EDCs). Methyl cyclohexane (MCH) that is generated through non-selective hydrogenation of toluene in hydrodesulfurization (HDS) units is a major contaminant in benzene production. To meet MCH specifications, often times the extractive distillation (ED) process for recovering purified benzene is operated with excessive benzene loss to the overhead raffinate stream, producing a lower quality non-aromatic product. Novel techniques (1) remove operational constrictions of the HDS unit on MCH production, thus lengthening the catalyst life and (2) allow the EDC to drive essentially any amount of MCH away from the bottom benzene product without concerns with benzene loss to the overhead raffinate stream and (3) recover benzene from the overhead raffinate stream to upgrade the quality of non-aromatic product and increase the benzene product recovery.
    • 通过对常规萃取蒸馏塔(EDC)的简单且低成本的改进来实现从芳族化合物和非芳族化合物的烃原料中回收高纯度苯。 通过在加氢脱硫(HDS)单位中甲苯的非选择性氢化产生的甲基环己烷(MCH)是苯生产中的主要污染物。 为了满足MCH规范,通常多次用于回收纯化苯的萃取蒸馏(ED)方法对顶部萃余液流具有过量的苯损失,产生较低质量的非芳族产物。 新技术(1)消除了HDS单元在MCH生产中的操作限制,从而延长了催化剂寿命,(2)允许EDC将基本上任意数量的MCH从底部苯产品中驱出,而不考虑苯残留到塔顶残液 流和(3)从塔顶残液流回收苯,提高非芳香族产品的质量,提高苯产品回收率。
    • 28. 发明申请
    • Process for Preparing 1,3-Butadiene from N-Butenes by Oxidative Dehydrogenation
    • 通过氧化脱氢从N-丁烯制备1,3-丁二烯的方法
    • US20140200380A1
    • 2014-07-17
    • US14154558
    • 2014-01-14
    • BASF SE
    • Jan Pablo JoschPhilipp GrüneChristian WalsdorffOliver HammenRagavendra Prasad Balegedde Ramachandran
    • C07C7/05C07C5/48
    • C07C7/05C07C5/48C07C7/08C07C7/11C07C11/167
    • The invention relates to a process for preparing butadiene from n-butenes, which comprises the steps: A) provision of a feed gas stream a comprising n-butenes; B) introduction of the feed gas stream a comprising n-butenes and an oxygen-comprising gas into at least one oxidative dehydrogenation zone and oxidative dehydrogenation of n-butenes to butadiene, giving a product gas stream b comprising butadiene, unreacted n-butenes, water vapor, oxygen, low-boiling hydrocarbons, high-boiling secondary components, possibly carbon oxides and possibly inert gases; Ca) cooling of the product gas stream b by contacting with an organic solvent as coolant, Cb) compression of the product gas stream b in at least one compression stage, giving at least one aqueous condensate stream c1 and a gas stream c2 comprising butadiene, n-butenes, water vapor, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases; D) separation of incondensable and low-boiling gas constituents comprising oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases as gas stream d2 from the gas stream c2 by absorption of the C4-hydrocarbons comprising butadiene and n-butenes in an absorption medium, giving an absorption medium stream loaded with C4 -hydrocarbons and the gas stream d2, and subsequent desorption of the C4-hydrocarbons from the loaded absorption medium stream to give a C4-product gas stream d1, E) separation of the C4 product stream d1 by extractive distillation using a solvent selective for butadiene into a stream e1 comprising butadiene and the selective solvent and a stream e2 comprising n-butenes; F) distillation of the stream f2 comprising butadiene and the selective solvent to give a stream g1 consisting essentially of the selective solvent and a stream g2 comprising butadiene.
    • 本发明涉及从正丁烯制备丁二烯的方法,其包括以下步骤:A)提供包含正丁烯的进料气流a; B)将包含正丁烯和含氧气体的进料气流a引入至少一个氧化脱氢区和将正丁烯氧化脱氢成丁二烯,得到包含丁二烯,未反应的正丁烯, 水蒸气,氧气,低沸点烃,高沸点次级组分,可能的碳氧化物和可能的惰性气体; Ca)通过与有机溶剂作为冷却剂接触来冷却产物气流b,Cb)在至少一个压缩级中压缩产物气流b,得到至少一种含水冷凝物流c1和包含丁二烯的气流c2, 正丁烯,水蒸气,氧气,低沸点烃,可能的碳氧化物和可能的惰性气体; D)通过吸收包含丁二烯和正丁烯的C 4烃在内,从气体流c2分离包含氧,低沸点烃,可能的碳氧化物和可能的惰性气体的不可冷凝和低沸点气体成分 吸收介质,得到负载有C4-烃和气流d2的吸收介质流,随后将C4-烃从负载的吸收介质流中解吸,得到C4-产物气流d1,E)C4产物的分离 通过使用对丁二烯选择性的溶剂进行萃取蒸馏,将其流入包含丁二烯和选择性溶剂的流e1和包含正丁烯的流e2; F)蒸馏包含丁二烯和选择性溶剂的料流f2,得到基本上由选择性溶剂组成的料流g1和包含丁二烯的料流g2。
    • 29. 发明申请
    • Process for the Oxidative Dehydrogenation of N-Butenes to Butadiene
    • US20140200379A1
    • 2014-07-17
    • US14150239
    • 2014-01-08
    • BASF SE
    • Jan Pablo JoschAlexander WeckSonja GiesaSteffen BütebornRagavendra Prasad Balegedde RamachandranRegina BenferMarkus Weber
    • C07C5/48
    • C07C5/48C07C7/08C07C7/11C07C11/167
    • The invention relates to a process for preparing butadiene from n-butenes, which comprises the following steps: A) provision of a feed gas stream a comprising n-butenes; B) introduction of the feed gas stream a comprising n-butenes and an oxygen-comprising gas into at least one dehydrogenation zone and oxidative dehydrogenation of n-butenes to butadiene, giving a product gas stream b comprising butadiene, unreacted n-butenes, water vapor, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases; C) cooling and compression of the product gas stream b in at least one compression stage, giving at least one condensate stream c1 comprising water and a gas stream c2 comprising butadiene, n-butenes, water vapor, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases; D) separation of incondensable and low-boiling gas constituents comprising oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases as gas stream d2 from the gas stream c2 by Da) absorption of the C4-hydrocarbons comprising butadiene and n-butenes in a high-boiling absorption medium, giving an absorption medium stream loaded with C4-hydrocarbons and the gas stream d2, Db) removal of oxygen from the absorption medium stream loaded with C4-hydrocarbons by stripping with an inert gas and Dc) desorption of the C4-hydrocarbons from the loaded absorption medium stream to give a C4 product gas stream d1 which consists essentially of C4-hydrocarbons and comprises less than 100 ppm of oxygen; E) separation of the C4 product stream d1 by extractive distillation with a solvent which is selective for butadiene into a stream e1 comprising butadiene and the selective solvent and a stream e2 comprising n-butenes; F) distillation of the stream e1 comprising butadiene and the selective solvent to give a stream f1 consisting essentially of the selective solvent and a butadiene-comprising stream f2.
    • 30. 发明申请
    • PROCESS FOR REMOVING OXYGENATE FROM AN OLEFIN STREAM
    • 从OLEFIN STREAM去除氧气的方法
    • US20140187805A1
    • 2014-07-03
    • US14136189
    • 2013-12-20
    • Shell Oil Company
    • Jeroen VAN WESTRENEN
    • C07C7/10C07D301/03
    • C07C7/10C07C1/20C07C7/08C07C11/04C07C11/06C07D301/03Y02P30/42
    • The present invention relates to a process for removing dimethylether from an olefin stream comprising dimethylether, comprising: (a) providing to an oxygenate recovery zone the olefin stream comprising dimethylether and a methanol-comprising solvent, treating the olefin stream comprising dimethylether with the methanol comprising solvent, and retrieving at least a dimethylether-depleted, methanol-comprising olefin stream; and (b) providing to the oxygenate recovery zone a non-aqueous C2 to C4 alcohol solvent and treating the dimethylether-depleted, methanol-comprising olefin stream with the non-aqueous C2 to C4 alcohol solvent, and retrieving from the oxygenate recovery zone at least an olefinic product that is depleted in dimethylether and methanol and a spent solvent comprising at least one C2 to C4 alcohol and methanol.
    • 本发明涉及从包含二甲醚的烯烃流中除去二甲醚的方法,包括:(a)向含氧物回收区提供包含二甲醚和含甲醇溶剂的烯烃流,用包含二甲醚的甲醇处理包含 溶剂,并回收至少二甲醚耗尽的含甲醇的烯烃流; 和(b)向含氧物回收区提供非水性C2至C4醇溶剂,并用非水性C2至C4醇溶剂处理二甲醚耗尽的含甲醇的烯烃流,并从含氧化合物回收区 至少一种贫二甲醚和甲醇的烯烃产物和包含至少一种C 2至C 4醇和甲醇的废溶剂。