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21. 发明申请

US20050014957A1 Processes for producing oxide with higher oxidation than alcohol 失效
标题翻译：生产氧化比醇高的氧化物的方法
公开(公告)号：US20050014957A1
公开(公告)日：2005-01-20
申请号：US10915600
申请日：2004-08-11
申请人： Hideo Tanaka , Yutaka Kameyama
发明人： Hideo Tanaka , Yutaka Kameyama
IPC分类号： C07B41/00 , C07C45/29 , C07C45/30 , C07C67/40 , C25B3/02 , C07D307/02 , C07C51/16 , C07C51/235 , C07C51/245
CPC分类号： C25B3/02 , C07B41/00 , C07C45/29 , C07C45/294 , C07C45/30 , C07C67/40 , C07C69/716
摘要： The present invention provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound thereon and an oxidative catalyst thereon, and oxidizing the alcohol compound in the presence of an oxidizing agent, giving an oxide higher in oxidizing degree than the alcohol compound, and also provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound, and subjecting the alcohol compound to an electrolytic oxidation, giving an oxide higher in oxidizing degree than the alcohol compound.
摘要翻译：本发明提供一种由醇化合物制备氧化物的方法，该方法包括以下步骤：使硅胶在其上载有醇化合物及其上的氧化催化剂，并在氧化剂存在下氧化醇化合物，得到氧化度高于醇化合物的氧化物，还提供了由醇化合物制造氧化物的方法，该方法包括使硅胶携带醇化合物，并对醇化合物进行电解氧化，产生氧化度高于醇化合物的氧化物。

22. 发明授权

US06552220B1 Catalyst for production of acetic acid and ethyl acetate, process for its production and process for production of acetic acid and ethyl acetate using it 失效
标题翻译：用于生产乙酸和乙酸乙酯的催化剂，其生产方法和使用它生产乙酸和乙酸乙酯的方法
公开(公告)号：US06552220B1
公开(公告)日：2003-04-22
申请号：US09554752
申请日：2000-05-19
申请人： Yoshiaki Obana , Hiroshi Uchida , Ken-ichi Sano
发明人： Yoshiaki Obana , Hiroshi Uchida , Ken-ichi Sano
IPC分类号： C07C5116
CPC分类号： C07C51/235 , B01J21/08 , B01J23/56 , B01J23/644 , B01J27/057 , B01J27/0576 , B01J37/16 , C07C67/40 , C07C53/08 , C07C69/14
摘要： An acetic acid production catalyst that contains (b) at least one element selected from the group consisting of Group 14 elements, Group 15 elements and Group 16 elements of the Periodic Table and/or (c) at least one element selected from the group consisting of Group 6 elements, Group 7 elements, Group 8 elements, Group 9 elements, Group 10 elements, Group 11 elements and Group 12 elements of the Periodic Table, added to a palladium-loaded catalyst, as well as an acetic acid and ethyl acetate production catalyst that contains (b) at least one compound selected from the group consisting of inorganic acids and salts thereof and/or (c) at least one element selected from the group consisting of Group 14 elements, Group 15 elements and Group 16 elements of the Periodic Table and/or (d) at least one element selected from the group consisting of Group 6 elements, Group 7 elements, Group 8 elements, Group 9 elements, Group 10 elements, Group 11 elements and Group 12 elements of the Periodic Table, added to palladium.
摘要翻译：一种乙酸生产催化剂，其含有（b）选自元素周期表第14族元素，第15族元素和第16族元素中的至少一种元素和/或（c）至少一种选自以下的元素：的第6族元素，第7族元素，第8族元素，第9族元素，第10族元素，第11族元素和第12族元素加入到负载钯的催化剂中，以及乙酸和乙酸乙酯生产催化剂，其含有（b）至少一种选自无机酸及其盐的化合物和/或（c）至少一种选自第14族元素，第15族元素和第16族元素的元素周期表和/或（d）选自元素周期T的第6族元素，第7族元素，第8族元素，第9族元素，第10族元素，第11族元素和第12族元素中的至少一种元素能够加入钯。

23. 发明申请

US20030060655A1 Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters 失效
标题翻译：用于制备羧酸酯的催化剂和制备羧酸酯的方法
公开(公告)号：US20030060655A1
公开(公告)日：2003-03-27
申请号：US10162040
申请日：2002-06-03
发明人： Toshio Hayashi , Takahiro Inagaki
IPC分类号： B01J023/52 , C07C067/39
CPC分类号： B01J27/057 , B01J23/52 , B01J23/66 , B01J23/89 , B01J35/0013 , B01J35/002 , B01J35/006 , C07C67/39 , C07C67/40 , C07D313/04 , C07D319/12 , C07C69/78 , C07C69/54 , C07C69/716 , C07C69/593 , C07C69/675
摘要： It is an object of the present invention to provide a catalyst for manufacturing a carboxylic ester, which has superior catalytic activity. The present invention relates to a catalyst for preparing a carboxylic ester, used in a) a reaction for preparing a carboxylic ester by reacting oxygen, an aldehyde, and an alcohol, or b) a reaction for manufacturing a carboxylic ester by reacting oxygen and one or more types of alcohol, comprising a carrier and 1) ultrafine gold particles and/or 2) ultrafine metal particles containing gold and a second element other than gold, having an average particle diameter of not more than 6 nm, are supported on the carrier.
摘要翻译：本发明的目的是提供一种具有优异催化活性的羧酸酯的制造用催化剂。本发明涉及一种用于制备羧酸酯的催化剂，用于a）通过使氧，醛和醇反应制备羧酸酯的反应，或b）通过使氧和一氧化碳反应制备羧酸酯的反应或更多类型的醇，其包含载体和1）超细金颗粒和/或2）具有平均粒径不大于6nm的金和金以外的第二元素的超细金属颗粒负载在载体上。

24. 发明申请

US20020103397A1 Process for the preparation of acetic acid or methyl acetate 失效
标题翻译：乙酸或乙酸甲酯的制备方法
公开(公告)号：US20020103397A1
公开(公告)日：2002-08-01
申请号：US09774246
申请日：2001-01-30
申请人： Council of Scientific and Industrial Research
发明人： Ashutosh Anant Kelkar , Sunil Sopana Tonde , Sunil Sadashiv Divekar , Raghunath Vitthal Chaudhari
IPC分类号： C07C067/36 , C07C051/12
CPC分类号： C07C51/16 , C07C67/40 , C07C53/08 , C07C69/14
摘要： Methanol is reacted in presence of catalyst system comprising of an iron containing compound and a tin containing compound with or without an organic compound containing C, N, O, P, S, diamine, diketone, and or diphosphines as a ligand to produce acetic acid or methyl acetate. The reaction is effected in a solvent containing nitro or nitrile group.
摘要翻译：在包含含铁化合物和含锡化合物的催化剂体系的存在下，甲醇在含或不含含有C，N，O，P，S，二胺，二酮和/或二膦作为配体的有机化合物的存在下反应，生成乙酸或乙酸甲酯。反应在含有硝基或腈基的溶剂中进行。

25. 发明授权

US5877330A Vanadium-containing catalysts, process for manufacturing and use of the same 失效
标题翻译：含钒催化剂，其制造及使用方法
公开(公告)号：US5877330A
公开(公告)日：1999-03-02
申请号：US776543
申请日：1997-01-29
申请人： Nobuji Kishimoto , Etsushige Matsunami
发明人： Nobuji Kishimoto , Etsushige Matsunami
IPC分类号： B01J23/22 , C07C5/48 , C07C45/36 , C07C67/40 , C07C253/24 , C07D307/77
CPC分类号： C07C253/24 , B01J23/22 , C07C45/36 , C07C5/48 , C07C67/40 , Y02P20/52
摘要： Vanadium-containing catalysts are obtained by using polyvanadic acid as a source of vanadium. Vanadium-containing catalysts are obtained by mixing catalyst components other than vanadium, or their precursors, with a polyvanadic acid sol which is formed by ion-exchanging a metavanadic acid aqueous solution with a proton-type cation-exchange resin and performing polycondensation, and by drying and/or calcining the mixture. Such vanadium-containing catalysts can fully exhibit their catalytic activity under mild reaction conditions, and can be suitably used for various reactions, such as synthesis of phthalic anhydride by the partial oxidation of o-xylene, synthesis of benzaldehyde by the partial oxidation of toluene, synthesis of benzoic acid by the partial oxidation of toluene, synthesis of anisaldehyde by the partial oxidation of p-methoxy toluene, synthesis of propylene by the oxidative dehydrogenation of propane, synthesis of isobutene by the oxidative dehydrogenation of isobutane, synthesis of methyl formate by the oxidative dehydrogenation of methanol, and synthesis of acrylonitrile by the ammoxidation of propane.
摘要翻译： PCT No.PCT / JP96 / 01547 Sec。 371日期1997年1月29日 102（e）1997年1月29日PCT PCT 1996年6月7日PCT公布。公开号WO96 / 41678 日期：1996年12月27日使用聚钒酸作为钒源可得到含钒催化剂。含钒催化剂通过将除钒以外的催化剂组分或其前体与通过与质子型阳离子交换树脂离子交换偏钒酸水溶液并进行缩聚而形成的聚阴离子溶胶获得，并进行缩聚干燥和/或煅烧该混合物。这种含钒催化剂可以在温和的反应条件下充分发挥其催化活性，适用于各种反应，如通过邻二甲苯的部分氧化合成邻苯二甲酸酐，通过甲苯的部分氧化合成苯甲醛，通过甲苯的部分氧化合成苯甲酸，通过对甲氧基甲苯的部分氧化合成茴香醛，通过丙烷的氧化脱氢合成丙烯，通过异丁烷的氧化脱氢合成异丁烯，通过甲酸甲酯合成甲酸甲酯甲醇的氧化脱氢，丙烷的氨氧化合成丙烯腈。

26. 发明授权

US5144062A Process for producing methyl formate 失效
标题翻译：甲酸甲酯生产方法
公开(公告)号：US5144062A
公开(公告)日：1992-09-01
申请号：US578958
申请日：1990-09-07
申请人： Shien-Chang Chen , Wan-Jy Cheng , Fu-Shen Lin , Fu-Juh Huang
发明人： Shien-Chang Chen , Wan-Jy Cheng , Fu-Shen Lin , Fu-Juh Huang
IPC分类号： B01J23/86 , B01J37/03 , C07C67/40
CPC分类号： B01J23/868 , C07C67/40 , B01J37/03
摘要： A process for the preparation of methyl formate by the vapor phase dehydrogenation of methanol in the presence of a catalyst composed of copper oxide, a chromium oxide and a sodium compound is described.
摘要翻译：描述了在由氧化铜，氧化铬和钠化合物组成的催化剂存在下，通过甲醇气相脱氢来制备甲酸甲酯的方法。

27. 发明授权

US4996007A Process for the oxidation of alcohols to aldehydes/acids/esters 失效
标题翻译：将醇氧化成醛/酸/酯的方法
公开(公告)号：US4996007A
公开(公告)日：1991-02-26
申请号：US467118
申请日：1990-01-19
申请人： Kuo-Hua Chao , Tamal K. Dutta , Lynn H. Slaugh
发明人： Kuo-Hua Chao , Tamal K. Dutta , Lynn H. Slaugh
IPC分类号： B01J21/04 , B01J21/18 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/889 , B01J31/02 , B01J31/28 , C07C45/38 , C07C51/235 , C07C67/40
CPC分类号： B01J31/40 , B01J23/40 , B01J31/0239 , B01J31/28 , C07C45/38 , C07C51/235 , C07C67/40 , B01J21/04 , B01J21/18 , B01J2231/70 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/8896 , Y02P20/584
摘要： The instant invention relates to a process for the oxidation of primary alcohols to aldehydes, acids and esters, particularly to aldehydes. In this process and alcohol and oxygen are contacted and reacted with a dihydrodihydroxynaphthalene or a dihydrodihydroxyanthracene in the presence of a Group VIII metal oxidation catalyst and optionally in the presence of a quaternary ammonium halide cocatalyst, and subsequently product aldehyde/acid/ester and the corresponding napthoquinone or anthraquinone are separated from the reaction mixture. The by-product naphthoquinone or anthraquinone is suitably recycled to the alcohol oxidation step by hydrogenating the naphthoquinone or anthraquinone to the corresponding dihydrodihydroxynaphthalene or dihydrodihydroxyanthracene by contacting it with hydrogen in the presence of a hydrogenation catalyst.
摘要翻译：本发明涉及将伯醇氧化成醛，酸和酯，特别是醛的方法。在该方法中，在VIII族金属氧化催化剂存在下，任选地在季铵卤化物助催化剂存在下，使醇和氧与二羟基二羟基萘或二氢二羟基蒽反应，随后将产物醛/酸/酯和相应的萘酚或蒽醌与反应混合物分离。通过在氢化催化剂的存在下使萘醌或蒽醌与氢气接触，将萘醌或蒽醌氢化为相应的二氢二羟基萘或二氢二羟基蒽，将副产物萘醌或蒽醌适当地再循环至醇氧化步骤。

28. 发明授权

US4319037A Process for producing methyl formate 失效
标题翻译：甲酸甲酯生产方法
公开(公告)号：US4319037A
公开(公告)日：1982-03-09
申请号：US938344
申请日：1978-08-31
申请人： Mikio Yoneoka
发明人： Mikio Yoneoka
IPC分类号： B01J23/72 , B01J23/83 , C07C67/40 , C07C69/06
CPC分类号： C07C67/40 , C07C69/06 , B01J23/72 , B01J23/83
摘要： A process for producing methyl formate which comprises dehydrogenating methanol in vapor phase in the presence as a catalyst of copper and at least one element selected from the group consisting of elements of Group IIIA (including the rare earths) of the periodic table, of Group IVA and of the actinides is disclosed.
摘要翻译：一种生产甲酸甲酯的方法，其包括在作为铜的催化剂存在下气相脱氢甲醇和选自元素周期表IIIA族（包括稀土）元素中的至少一种元素的组IVA 和锕系元素。

29. 发明授权

US2160064A Manufacture of formic acid 失效
标题翻译：甲酸的制造
公开(公告)号：US2160064A
公开(公告)日：1939-05-30
申请号：US8566436
申请日：1936-06-17
申请人： CARBIDE & CARBON CHEM CORP
发明人： EVERSOLE JAMES F
IPC分类号： C07C29/09 , C07C51/09 , C07C67/40
CPC分类号： C07C51/09 , C07C29/095 , C07C67/40 , C07C53/02 , C07C69/04 , C07C31/04

30. 发明授权

US2136613A Process for the manufacture of esters, especially of ethyl acetate 失效
标题翻译：用于制造酯，特别是乙酸乙酯的方法
公开(公告)号：US2136613A
公开(公告)日：1938-11-15
申请号：US6478636
申请日：1936-02-19
申请人： MELLE USINES SA
发明人： MARTIN GUINOT HENRI
IPC分类号： C07C67/08 , C07C67/40 , C07C69/12 , C07C69/14
CPC分类号： C07C67/40 , C07C69/14

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