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21. 发明授权

US4894394A Process for the manufacture of methanol in combination with steam reforming of light hydrocarbons 失效
标题翻译：与轻烃的蒸汽重整相结合制造甲醇的方法
公开(公告)号：US4894394A
公开(公告)日：1990-01-16
申请号：US256522
申请日：1988-10-12
申请人： Arjan Van Dijk , Swan T. Sie
发明人： Arjan Van Dijk , Swan T. Sie
IPC分类号： C07C29/156 , C07C29/157
CPC分类号： C07C29/156 , C07C29/157
摘要： Process for the manufacture of methanol by the reaction of a carbon monoxide and hydrogen mixture obtained by steam reforming of light hydrocarbons in the liquid phase in the presence of the catalyst system obtainable by combination of at least:(a) the salt containing a cation of a metal of group VIII of the Periodic Table of the Elements,(b) an alcoholate from an alkaline metal or alkaline earth metal, in a single pass through reactor, by conversion of the hydrogen-carbon monoxide gas mixture, which has been treated after steam treatment of natural gas by scrubbing carbon dioxide from the obtained gas mixture, and which has a hydrogen-carbon monoxide molar ratio in the range of from 2.8-4.5, and using the off-gas from the reaction after recovery of methanol as fuel to the reformer furnace.
摘要翻译：在通过在催化剂体系的存在下在液相中通过轻烃的蒸汽重整获得的一氧化碳和氢气混合物的反应来制造甲醇的方法，所述催化剂体系可以通过以下方式组合获得：（a）含有阳离子的盐元素周期表第Ⅷ族金属，（b）来自碱金属或碱土金属的醇化物，在单次通过反应器中，通过转化已经经过处理的氢 - 一氧化碳气体混合物通过从所获得的气体混合物中洗涤二氧化碳来蒸汽处理天然气，其氢 - 一氧化碳摩尔比在2.8-4.5范围内，并且在甲醇作为燃料回收之后使用来自反应的废气重整炉。

22. 发明授权

US4876286A Process for the production of methanol and a composition suitable for use as a catalyst in said process 失效
公开(公告)号：US4876286A
公开(公告)日：1989-10-24
申请号：US270599
申请日：1988-11-14
申请人： Swan T. Sie , Eit Drent , Willem W. Jager
发明人： Swan T. Sie , Eit Drent , Willem W. Jager
IPC分类号： B01J31/04 , C07C27/00 , C07C29/149 , C07C29/156 , C07C31/04 , C07C67/00
CPC分类号： C07C29/149 , C07C29/156 , Y02P20/52
摘要： A process for producing methanol which comprises the following consecutive steps:Step 1: Preparing a novel catalytic system by combining (a) a nickel (b) a hydride of an alkali metal or of an alkaline earth metal, and (c) an ester of formic acid which originates from an external source, and allowing the combined components (a), (b) and (c) to react; andStep 2: Contacting a gaseous mixture of CO and H.sub.2 with the catalytic system prepared in step 1.

23. 发明授权

US4766155A Process for producing alcohols 失效
标题翻译：醇的制备方法
公开(公告)号：US4766155A
公开(公告)日：1988-08-23
申请号：US805395
申请日：1985-12-04
申请人： Jui-Yuan Sun , Erek J. Erekson
发明人： Jui-Yuan Sun , Erek J. Erekson
IPC分类号： C07C29/156 , C07C29/157 , C07C27/06
CPC分类号： C07C29/156 , C07C29/157
摘要： A process for producing alcohols by reacting carbon monoxide with hydrogen in the presence of a catalyst comprising (a) copper; (b) zinc; (c) at least one element selected from the group consisting of iron, cobalt, nickel, ruthenium, thorium and mixtures thereof; and (d) at least one element selected from the group consisting of alkali metals, alkaline earth metals and mixtures thereof.
摘要翻译：一种在催化剂存在下使一氧化碳与氢气反应生产醇的方法，包括：（a）铜; （b）锌; （c）选自铁，钴，镍，钌，钍及其混合物中的至少一种元素; 和（d）选自碱金属，碱土金属及其混合物中的至少一种元素。

24. 发明授权

US4748144A Delafossite mixed metal oxide catalysts and method for their preparation 失效
标题翻译： Delafossite复合金属氧化物催化剂及其制备方法
公开(公告)号：US4748144A
公开(公告)日：1988-05-31
申请号：US896044
申请日：1986-08-13
申请人： John R. Monnier , Gustav R. Apai, II , Michael J. Hanrahan
发明人： John R. Monnier , Gustav R. Apai, II , Michael J. Hanrahan
IPC分类号： B01J23/745 , B01J23/86 , B01J23/88 , C07C29/156 , C07C45/49 , B01J21/04 , B01J23/72
CPC分类号： B01J23/8872 , B01J23/002 , B01J23/745 , B01J23/868 , B01J23/8878 , C07C29/156 , C07C45/49 , B01J2523/00 , Y02P20/52
摘要： Catalysts for the conversion of synthesis gas to linear alcohols and aldehydes are disclosed. The catalysts are mixed oxides of copper, iron and either chromium or aluminum and wherein said mixed oxide has a delafossite type of crystal lattice structure.
摘要翻译：公开了将合成气转化为直链醇和醛的催化剂。催化剂是铜，铁和铬或铝的混合氧化物，其中所述混合氧化物具有delafossite型晶格结构。

25. 发明授权

US4670474A Synthetic crystalline metallosilicate compositions, the preparation thereof and their use in the conversion of synthesis gas to low molecular weight hydrocarbons 失效
标题翻译：合成结晶金属硅酸盐组合物，其制备方法及其在将合成气转化为低分子量烃的用途
公开(公告)号：US4670474A
公开(公告)日：1987-06-02
申请号：US750219
申请日：1985-07-01
申请人： James A. Hinnenkamp , Vernon V. Walatka
发明人： James A. Hinnenkamp , Vernon V. Walatka
IPC分类号： B01J29/04 , C07C1/04 , C07C1/20 , C07C29/156 , C07C29/157 , C07C29/158 , C07C45/68 , C08F10/02 , C10G3/00
CPC分类号： C07C29/156 , B01J29/04 , C01B35/1009 , C07C1/0435 , C07C1/20 , C07C29/157 , C07C29/158 , C07C45/68 , C08F10/02 , C10G3/45 , C10G3/47 , C10G3/49 , C07C2529/068 , C07C2529/072 , C07C2529/86 , C10G2300/1022 , Y02P20/52 , Y02P30/20
摘要： Crystalline palladium or platinum ferrometallosilicate compositions are prepared from a silica-containing mixture by digesting a reaction mixture comprising (a) a tetraalkylammonium compound, (b) a sodium hydroxide, (c) a titanium compound, an aluminum compound, or a manganese compound, (d) an oxide of silicon, (e) an iron ion source, (f) optionally, a chelating agent and (g) water to provide a crystalline ferrometallosilicate which is then palladium or platinum ion-exchanged. Conversion of synthesis gas to low molecular hydrocarbons with high C.sub.2 -C.sub.3 alkanes selectivity employing these new ferrometallosilicates as catalysts is also disclosed.
摘要翻译：通过消化含有（a）四烷基铵化合物，（b）氢氧化钠，（c）钛化合物，铝化合物或锰化合物的反应混合物的反应混合物，由含二氧化硅的混合物制备结晶钯或铂硅酸钼酸盐组合物，（d）硅的氧化物，（e）铁离子源，（f）任选的螯合剂和（g）水以提供结晶的硅酸铝硅酸盐，然后进行钯或铂离子交换。还公开了使用这些新的硫酸铁酸盐作为催化剂将合成气转化为具有高C2-C3烷烃选择性的低分子烃。

26. 发明授权

US4521540A Process for producing dimethyl ether form synthesis gas 失效
标题翻译：生产二甲醚形成合成气的方法
公开(公告)号：US4521540A
公开(公告)日：1985-06-04
申请号：US592324
申请日：1984-03-22
申请人： Ronald Pierantozzi
发明人： Ronald Pierantozzi
IPC分类号： C07C29/156 , C07C41/01 , C07C27/06
CPC分类号： C07C29/156 , C07C41/01 , C12C11/02
摘要： This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.
摘要翻译：本发明涉及将合成气转化为含氧烃的费 - 托法，特别强调二甲醚。包含一氧化碳和氢气的合成气体通过在掺入到氧化锆 - 氧化铝载体上的碱金属 - 锰 - 铁 - 羰基簇的存在下进行反应而转化为二甲醚。

27. 发明授权

US4177203A Process for the production of hydrocarbons and oxygen-containing compounds and catalysts therefor 失效
标题翻译：用于生产烃和含氧化合物及其催化剂的方法
公开(公告)号：US4177203A
公开(公告)日：1979-12-04
申请号：US840059
申请日：1977-10-06
申请人： Herbert Kolbel , Klaus D. Tillmetz
发明人： Herbert Kolbel , Klaus D. Tillmetz
IPC分类号： B01J23/889 , B01J37/16 , B01J37/18 , C07C1/04 , C07C29/156 , C07C45/49 , C07C27/06
CPC分类号： B01J23/8892 , C07C1/0445 , C07C29/156 , C07C45/49 , B01J37/16 , B01J37/18 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/34 , C07C2523/745 , C07C2523/889
摘要： Processes for synthesizing unsaturated and saturated hydrocarbons and oxygen-containing compounds by catalytic hydrogenation of carbon monoxide at temperatures of 220 to 375 degrees C. and pressures from 1 to 60 bars. Specially activated catalysts for this purpose contain at least 50% manganese and less than 50% iron, by weight. The product distribution spectrum is shifted in the direction of C.sub.2 to C.sub.4 hydrocarbons, the chain length of the products extending only to about C.sub.6 and methane being formed only in traces.
摘要翻译：通过一氧化碳在220至375℃的温度和1至60巴的压力下催化氢化合成不饱和烃和饱和烃和含氧化合物的方法。用于此目的的特殊活化催化剂含有至少50％的锰和小于50重量％的铁。产物分布谱在C2至C4烃的方向上移动，产物的链长仅延伸至约C6，甲烷仅形成痕迹。

28. 发明授权

US4133776A Manufacture of polyfunctional compounds 失效
标题翻译：多官能化合物的制造
公开(公告)号：US4133776A
公开(公告)日：1979-01-09
申请号：US842366
申请日：1977-10-14
申请人： Roy L. Pruett , Wellington E. Walker
发明人： Roy L. Pruett , Wellington E. Walker
IPC分类号： B01J31/20 , C07C29/153 , C07C29/156 , C07C29/157 , C07C29/158 , B01J31/22 , B01J31/24
CPC分类号： B01J31/2243 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/20 , C07C29/153 , C07C29/156 , C07C29/157 , C07C29/158 , B01J2231/648 , B01J2531/822 , B01J31/2234 , Y02P20/52
摘要： A catalyst composition useful in the process for the preparation of polyfunctional oxygen-containing compounds such as ethylene glycol and/or derivatives thereof which comprise reacting an oxide of carbon with hydrogen using a rhodium complex catalyst.
摘要翻译：用于制备多官能含氧化合物如乙二醇和/或其衍生物的方法中的催化剂组合物，其包括使用铑配合物催化剂使碳氧化物与氢气反应。

29. 发明授权

US4122110A Process for manufacturing alcohols, particularly linear saturated primary alcohols, from synthesis gas 失效
标题翻译：从合成气制造醇，特别是线性饱和伯醇的方法
公开(公告)号：US4122110A
公开(公告)日：1978-10-24
申请号：US846486
申请日：1977-10-28
申请人： Andre Sugier , Edouard Freund
发明人： Andre Sugier , Edouard Freund
IPC分类号： B01J23/78 , B01J23/84 , C07C29/151 , C07C29/156 , C07C29/00 , C07C31/06 , C07C31/08
CPC分类号： B01J23/868 , B01J23/78 , B01J23/84 , B01J23/8472 , B01J23/8892 , C07C29/1512 , C07C29/156 , Y02P20/52
摘要： Alcohols, particularly linear saturated primary alcohols, are manufactured from CO and H.sub.2 in the presence of a catalyst comprising at least 4 essential elements, copper, cobalt, a third metal selected from chromium, iron, vanadium and manganese, and at least one alkali metal. A preferred method for manufacturing the catalyst is also described; it comprises the use of a complexant, such as citric acid.
摘要翻译：醇，特别是直链饱和伯醇由CO和H 2在催化剂存在下制备，催化剂包含至少4种必需元素，铜，钴，选自铬，铁，钒和锰的第三种金属，以及至少一种碱金属。还描述了制造催化剂的优选方法; 它包括使用络合剂，例如柠檬酸。

30. 发明授权

US2786817A Iron catalysts for carbon monoxide hydrogenation precipitated from ferrous sulfate solutions 失效
标题翻译：用于一氧化碳氢化的铁催化剂从硫酸亚铁溶液中沉淀出来
公开(公告)号：US2786817A
公开(公告)日：1957-03-26
申请号：US28017352
申请日：1952-04-02
申请人： RUHRCHEMIE AG , LURGI GES FUER WAERMETECHNIK
发明人： WALTER ROTTIG
IPC分类号： B01J21/00 , B01J23/74 , B01J23/745 , B01J23/76 , C07C1/04 , C07C29/156
CPC分类号： C07C29/156 , B01J21/00 , B01J23/74 , B01J23/745 , B01J23/76 , C07C1/044 , C07C1/0445 , C07C2523/04 , C07C2523/745 , C07C2523/78 , Y02P20/52 , C07C31/04

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