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21. 发明申请

US20140057185A1 HYDROGEN GENERATOR, OPERATING METHOD OF HYDROGEN GENERATOR, AND FUEL CELL SYSTEM 有权
标题翻译：氢发生器，氢发生器的操作方法和燃料电池系统
公开(公告)号：US20140057185A1
公开(公告)日：2014-02-27
申请号：US13989325
申请日：2012-10-03
申请人： PANASONIC CORPORATION
发明人： Yoshio Tamura , Koichi Kusumura
IPC分类号： H01M8/04
CPC分类号： H01M8/04664 , C01B3/38 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/066 , C01B2203/127 , C01B2203/148 , C01B2203/169 , H01M8/04425 , H01M8/04686 , H01M8/04955 , H01M8/0612 , H01M8/0675 , Y02E60/50
摘要： A hydrogen generator associated with the invention comprises a hydro-desulfurizer (1) configured to remove sulfur compounds from a raw material; a reformer (2) configured to generate hydrogen-containing gas with use of the raw material that has passed through the hydro-desulfurizer (1); a raw material supply device (3) configured to supply the raw material to the reformer (2); a recycle flow passage (4) configured to supply a portion of the hydrogen-containing gas, discharged from the reformer (2), to the raw material before the raw material flows into the hydro-desulfurizer (1); an on-off valve (5) provided in the recycle flow passage (4); a pressure detector (6) located at a position upstream of the on-off valve (5) in the recycle flow passage (4); and an abnormality detector (7) configured to detect an abnormal clogging in the recycle flow passage (4) based on a pressure detected by the pressure detector (6), in a state in which the raw material supply device (3) is supplying the raw material to the reformer (2) with the on-off valve (5) closed.
摘要翻译：与本发明相关的氢发生器包括：配置成从原料中除去硫化合物的加氢脱硫剂（1）; 重构器（2），其被配置为使用通过所述加氢脱硫器（1）的原料产生含氢气体; 原料供给装置（3），其将原料供给到重整器（2）中; 再循环流路（4），其构造成在原料流入加氢脱硫装置（1）之前将从重整器（2）排出的含氢气体的一部分供给原料; 设置在再循环流路（4）内的开闭阀（5）。压力检测器（6），其位于再循环流路（4）的开关阀（5）的上游位置。以及异常检测器（7），其被配置为在所述原料供给装置（3）供给所述再生流路（4）的状态下，基于由所述压力检测器（6）检测到的压力来检测所述再循环流路（4）重新开关阀（2）的原料与开关阀（5）关闭。

22. 发明授权

US08557463B2 Fuel cell system and method for load following operation of the same 失效
标题翻译：燃料电池系统及其负载跟随运行方法
公开(公告)号：US08557463B2
公开(公告)日：2013-10-15
申请号：US12934981
申请日：2009-02-18
申请人： Susumu Hatada
发明人： Susumu Hatada
IPC分类号： H01M8/04
CPC分类号： H01M8/04992 , C01B3/384 , C01B2203/0233 , C01B2203/066 , C01B2203/085 , C01B2203/1288 , C01B2203/1619 , C01B2203/1685 , C01B2203/169 , H01M8/04373 , H01M8/04425 , H01M8/04589 , H01M8/04753 , H01M8/04776 , H01M8/0491 , H01M8/0494 , H01M8/04955 , H01M8/0618 , H01M2008/1293
摘要： A method of load following operation of a fuel cell system may include measuring a temperature of the reforming catalyst layer, obtaining a reformable flow rate of the hydrocarbon-based fuel capable of being reformed in the reforming catalyst layer at the temperature, and controlling electric power generation based on the relationship between the reformable flow rate and a minimum value.
摘要翻译：燃料电池系统的负载跟随操作的方法可以包括测量重整催化剂层的温度，获得能够在重整催化剂层中在该温度下重整的烃系燃料的可重整流量，并控制电力基于可重整流量与最小值之间的关系。

23. 发明授权

US08557452B2 Hydrodesulfurizer recycle applied upstream of processor feedstock pressurization 有权
标题翻译：加氢脱硫剂回收应用于处理器原料加压上游
公开(公告)号：US08557452B2
公开(公告)日：2013-10-15
申请号：US12736137
申请日：2008-05-22
申请人： Peter F. Foley , Joshua D. Isom , John L. Preston
发明人： Peter F. Foley , Joshua D. Isom , John L. Preston
IPC分类号： H01M8/06 , H01M8/04 , H01M8/22 , B01J19/00 , B01J8/00 , C01B3/24
CPC分类号： C10G45/02 , C01B3/34 , C01B3/38 , C01B3/48 , C01B2203/0216 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/1241 , C01B2203/1258 , C01B2203/148 , C01B2203/1638 , C01B2203/169 , C10G59/02 , C10G63/02
摘要： Fuel processing by a reformer (42) and a shift reactor (44) converts hydrocarbon feedstock (12) and steam (36) to hydrogen-rich reformate (11), such as for use in a fuel cell power plant (47). Some of the reformate is recycled through a restriction (18) to the inlet (15) of a feedstock pump (14), thereby increasing its pressure sufficiently to cause recycle flow through a hydrodesulfurizer (21) and the secondary inlet (26) of an ejector (28) driven by the steam (36). Recycle pressure (48) is maintained by steam pressure through a valve (34) regulated by a controller (17).
摘要翻译：通过重整器（42）和换档反应器（44）的燃料处理将烃原料（12）和蒸汽（36）转化为富氢重整产物（11），例如用于燃料电池发电厂（47）中。一些重整产物通过限制（18）再循环到原料泵（14）的入口（15），从而增加其压力以使再循环流通过加氢脱硫剂（21）和次级进料口（26）由蒸汽（36）驱动的喷射器（28）。循环压力（48）通过蒸汽压力通过由控制器（17）调节的阀（34）来维持。

24. 发明授权

US08486166B2 Fuel reforming apparatus 有权
标题翻译：燃料重整装置
公开(公告)号：US08486166B2
公开(公告)日：2013-07-16
申请号：US12744691
申请日：2009-01-26
申请人： Hideo Yahagi , Isamu Nakada , Keiichiro Aoki , Takanori Sasaki
发明人： Hideo Yahagi , Isamu Nakada , Keiichiro Aoki , Takanori Sasaki
IPC分类号： B01J7/00
CPC分类号： F02D41/1441 , C01B3/323 , C01B3/384 , C01B2203/0233 , C01B2203/0238 , C01B2203/025 , C01B2203/0435 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1229 , C01B2203/1247 , C01B2203/148 , C01B2203/1619 , C01B2203/1676 , C01B2203/169 , F01N3/2889 , F01N5/02 , F01N13/009 , F01N2240/30 , F01N2560/025 , F01N2610/03 , F02D19/0623 , F02D19/0634 , F02D19/0644 , F02D19/0671 , F02D19/0692 , F02D19/084 , F02D41/0025 , F02D41/0027 , F02D41/0065 , F02D41/1439 , F02D41/1454 , F02D2041/147 , F02M26/36 , G01N33/005 , Y02P20/128 , Y02P20/142 , Y02T10/16 , Y02T10/36 , Y02T10/47
摘要： Fuel reforming catalysts 28 generate a hydrogen-containing reformed gas when they come into contact with exhaust gas that contains a reforming fuel. Upstream and downstream air-fuel ratio sensors 58, 60 are respectively installed upstream and downstream of the fuel reforming catalysts 28. The upstream air-fuel ratio sensor 58 outputs a upstream sensor signal in accordance with oxygen concentration. The downstream air-fuel ratio sensor 60 outputs a downstream sensor signal in accordance with oxygen concentration and hydrogen concentration by using zirconia's oxygen detection capability and a change of a diffusion layer's hydrogen-concentration-dependent oxygen detection capability. An ECU 50 detects the hydrogen concentration without being affected by the oxygen concentration through the use of the upstream sensor signal in which only the oxygen concentration is reflected and the downstream sensor signal in which the oxygen concentration and hydrogen concentration are reflected. This makes it possible to establish a hydrogen concentration detection system with the common air-fuel ratio sensors 58, 60.
摘要翻译：当燃料重整催化剂28与含重整燃料的废气接触时，产生含氢重整气体。上游和下游空燃比传感器58,60分别安装在燃料重整催化剂28的上游和下游。上游空燃比传感器58根据氧浓度输出上游传感器信号。下游空燃比传感器60通过使用氧化锆的氧检测能力和扩散层的氢浓度依赖性氧检测能力的变化，根据氧浓度和氢浓度输出下游传感器信号。 ECU50通过使用仅反映氧浓度的上游传感器信号和反映氧浓度和氢浓度的下游传感器信号，检测氢浓度而不受氧浓度的影响。这使得可以建立具有共用空燃比传感器58,60的氢浓度检测系统。

25. 发明申请

US20130137151A1 PROCESSES FOR THE CONVERSION OF BIOMASS TO OXYGENATED ORGANIC COMPOUND, APPARATUS THEREFOR AND COMPOSITIONS PRODUCED THEREBY 有权
公开(公告)号：US20130137151A1
公开(公告)日：2013-05-30
申请号：US13304902
申请日：2011-11-28
申请人： RICHARD E. TOBEY , Jianxin Du , Ralph Corley
发明人： RICHARD E. TOBEY , Jianxin Du , Ralph Corley
IPC分类号： C12P7/06 , C12M1/00 , C12P7/00 , B01D53/00 , C01B3/00
CPC分类号： C01B3/02 , B01D2257/408 , C01B3/36 , C01B2203/0255 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/0495 , C01B2203/0877 , C01B2203/0894 , C01B2203/141 , C01B2203/142 , C01B2203/146 , C01B2203/1671 , C01B2203/1676 , C01B2203/169 , C12M21/12 , C12M45/06 , C12P7/065 , C12P7/08 , C12P7/16 , C12P7/52 , C12P7/54 , Y02E50/10 , Y02E50/16 , Y02E50/17
摘要： Processes are disclosed for the conversion of biomass to oxygenated organic compound using a simplified syngas cleanup operation that is cost effective and protects the fermentation operation. The processes of this invention treat the crude syngas from the gasifier by non-catalytic partial oxidation. The partial oxidation reduces the hydrocarbon content of the syngas such as methane, ethylene and acetylene to provide advantageous gas feeds for anaerobic fermentations to produce oxygenated organic compounds such as ethanol, propanol and butanol. Additionally, the partial oxidation facilitates any additional cleanup of the syngas as may be required for the anaerobic fermentation. Producer gases and partial oxidation processes are also disclosed.

26. 发明申请

US20130130138A1 HYDROGEN GENERATION APPARATUS, FUEL CELL SYSTEM, AND METHOD OF OPERATING THE SAME 有权
标题翻译：氢气发生装置，燃料电池系统及其运行方法
公开(公告)号：US20130130138A1
公开(公告)日：2013-05-23
申请号：US13816092
申请日：2012-04-20
申请人： Kunihiro Ukai , Tomoya Takeuchi
发明人： Kunihiro Ukai , Tomoya Takeuchi
IPC分类号： G05D23/00 , H01M8/06
CPC分类号： G05D23/00 , C01B3/34 , C01B3/48 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/1258 , C01B2203/1288 , C01B2203/1614 , C01B2203/169 , H01M8/04022 , H01M8/0444 , H01M8/04738 , H01M8/0612 , H01M8/0618 , Y02E60/50
摘要： A hydrogen generation apparatus (100) includes: a reformer (1) configured to generate a hydrogen-containing gas by causing a reforming reaction of a raw material; a combustor (2) configured to heat the reformer; and a controller (5) configured to set a controlled temperature of the reformer to a first temperature when an oxygen concentration in the raw material is in a first state where the oxygen concentration is relatively low, and change the controlled temperature of the reformer to a second temperature higher than the first temperature when the oxygen concentration in the raw material is in a second state where the oxygen concentration is relatively higher than the oxygen concentration in the first state.
摘要翻译：氢产生装置（100）包括：重整器（1），其通过引起原料的重整反应而产生含氢气体; 构造成加热重整器的燃烧器（2）; 以及控制器（5），其被配置为当所述原料中的氧浓度处于氧浓度相对低的第一状态时将所述重整器的受控温度设定为第一温度，并且将所述重整器的控制温度改变为当原料中的氧浓度处于氧浓度相对高于第一状态下的氧浓度的第二状态时，第二温度高于第一温度。

27. 发明申请

US20130122384A1 HYDROGEN GENERATOR, METHOD OF OPERATION THEREOF AND FUEL CELL SYSTEM 审中-公开
标题翻译：氢发生器，其运行方法和燃料电池系统
公开(公告)号：US20130122384A1
公开(公告)日：2013-05-16
申请号：US13700385
申请日：2011-05-20
申请人： Yukimune Kani , Kunihiro Ukai , Hiroaki Kaneko
发明人： Yukimune Kani , Kunihiro Ukai , Hiroaki Kaneko
IPC分类号： C01B3/16 , H01M8/06
CPC分类号： C01B3/16 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/1064 , C01B2203/1288 , C01B2203/1609 , C01B2203/1628 , C01B2203/1633 , C01B2203/169 , C01B2203/82 , H01M8/0618 , H01M2250/10 , Y02B90/14
摘要： The invention discloses a hydrogen generator (100A) comprising: a reformer (1) having a reforming catalyst (1a); a material gas supply device (13); an evaporator (3); a water supply device; and a controller (10) which controls the material gas supply device (13) and the water supply device to stop supplying of a material gas to the reformer (1) and supplying of water to the evaporator (3) and then controls the material gas supply device (13) to supply the material gas to the reformer (1) in a period during which residual water evaporates in at least either the evaporator (3) or the reformer (1).
摘要翻译：本发明公开了一种氢发生器（100A），包括：具有重整催化剂（1a）的重整器（1）; 材料气体供应装置（13）; 蒸发器（3）; 供水装置; 以及控制器（10），其控制所述原料气体供给装置（13）和所述供水装置停止向所述重整器（1）供给原料气体并将水供给到所述蒸发器（3），然后控制所述原料气体供应装置（13），用于在至少蒸发器（3）或重整器（1）中残留水蒸发的时间段内将原料气体供应至重整器（1）。

28. 发明授权

US08439992B2 Auto ignition type autothermal reformer and fuel cell system having the same 失效
标题翻译：自动点火型自热重整器和具有相同功能的燃料电池系统
公开(公告)号：US08439992B2
公开(公告)日：2013-05-14
申请号：US12700168
申请日：2010-02-04
申请人： Jin-Goo Ahn , Sung-Chul Lee , In-Hyuk Son , Woo-Cheol Shin , In-Seob Song , Ju-Yong Kim , Yong-Kul Lee , Tae-Keun Kim
发明人： Jin-Goo Ahn , Sung-Chul Lee , In-Hyuk Son , Woo-Cheol Shin , In-Seob Song , Ju-Yong Kim , Yong-Kul Lee , Tae-Keun Kim
IPC分类号： B01J7/00 , C01B3/36 , B01J8/00
CPC分类号： B01J8/0496 , B01J8/0453 , B01J19/2485 , B01J23/42 , B01J23/63 , B01J35/0006 , B01J35/04 , B01J2208/00495 , B01J2208/0053 , B01J2208/00628 , C01B3/326 , C01B2203/0244 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/1064 , C01B2203/107 , C01B2203/1217 , C01B2203/1223 , C01B2203/1229 , C01B2203/143 , C01B2203/146 , C01B2203/169 , C01B2203/82 , H01M8/0432 , H01M8/0618 , H01M2008/1095 , Y02P20/52
摘要： An auto ignition type autothermal reformer (ATR) performs reproducible ignition using a catalyst that performs ignition without a separate ignition unit, such as an igniter or heating wire, and a fuel cell system having the ATR. The ATR includes a reaction container having a first opening through which a fuel is introduced into the reaction container and a second opening through which a reformate is discharged from the reaction container, the fuel having a mixture of an aqueous primary fuel solution and hydrogen peroxide; a first catalyst disposed adjacent to the first opening in the reaction container, the first catalyst being a granular catalyst; a second catalyst disposed at the rear portion of the first catalyst to promote an autothermal reforming reaction; and a third catalyst disposed at the rear portion of the second catalyst to promote an oxidation reaction.
摘要翻译：自动点火型自热重整器（ATR）使用不具有点火器或加热丝等单独点火装置进行点火的催化剂和具有ATR的燃料电池系统，进行可再现点火。 ATR包括具有第一开口的反应容器，通过该第一开口将燃料引入反应容器中，以及第二开口，重整产物从反应容器排出，燃料具有初级燃料溶液和过氧化氢的混合物; 第一催化剂，邻近反应容器中的第一开口设置，第一催化剂为粒状催化剂; 第二催化剂，其设置在第一催化剂的后部以促进自热重整反应; 以及设置在第二催化剂的后部以促进氧化反应的第三催化剂。

29. 发明申请

US20130108514A1 HYDROGEN PURIFICATION MEMBRANES, COMPONENTS AND FUEL PROCESSING SYSTEMS CONTAINING THE SAME 失效
公开(公告)号：US20130108514A1
公开(公告)日：2013-05-02
申请号：US13598295
申请日：2012-08-29
申请人： David J. Edlund , William A. Pledger , R. Todd Studebaker
发明人： David J. Edlund , William A. Pledger , R. Todd Studebaker
IPC分类号： C01B3/32
CPC分类号： C01B3/32 , B01D53/22 , B01D53/229 , B01D63/06 , B01D63/08 , B01D69/02 , B01D2313/20 , B01D2313/22 , B01D2313/42 , B01D2325/22 , B01J8/006 , B01J8/009 , B01J8/0257 , B01J8/0285 , B01J8/04 , B01J8/0465 , B01J8/0469 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/2475 , B01J2208/00061 , B01J2208/00088 , B01J2208/00106 , B01J2208/00132 , B01J2208/00141 , B01J2208/00256 , B01J2208/00309 , B01J2208/00371 , B01J2208/00415 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00548 , C01B3/323 , C01B3/38 , C01B3/382 , C01B3/384 , C01B3/503 , C01B3/505 , C01B3/586 , C01B2203/0227 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0475 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0888 , C01B2203/1011 , C01B2203/1041 , C01B2203/1058 , C01B2203/1076 , C01B2203/1217 , C01B2203/1223 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/1604 , C01B2203/1628 , C01B2203/1633 , C01B2203/1657 , C01B2203/1676 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , H01M8/0612 , H01M8/0618 , H01M8/0631 , H01M8/0687 , Y02P20/128 , Y02P20/129 , Y10S48/05
摘要： Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.

30. 发明授权

US08409427B2 Hydrocarbon treatment method and apparatus 有权
标题翻译：烃处理方法和装置
公开(公告)号：US08409427B2
公开(公告)日：2013-04-02
申请号：US12535051
申请日：2009-08-04
申请人： Troy M. Raybold , Raymond Francis Drnevich , Vasilis Papavassiliou
发明人： Troy M. Raybold , Raymond Francis Drnevich , Vasilis Papavassiliou
IPC分类号： C07C4/06
CPC分类号： C10G70/02 , C01B3/38 , C01B3/56 , C01B3/58 , C01B2203/043 , C01B2203/045 , C01B2203/0485 , C01B2203/0894 , C01B2203/1011 , C01B2203/1023 , C01B2203/1029 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/127 , C01B2203/1276 , C01B2203/141 , C01B2203/1642 , C01B2203/169 , C10G65/02 , C10G69/02 , C10G70/00 , C10G2300/1025 , C10G2300/1088 , C10G2300/202 , C10G2300/207
摘要： The present invention provides a method and apparatus for producing a treated hydrocarbon containing stream for use as a feed to a steam methane reformer of a hydrogen plant. In accordance with such method, amounts of olefins and organic sulfur species within an untreated feed are decreased in a reactor that is operated in either a hydrogenation mode to hydrogenate the olefins into saturated hydrocarbons or a pre-reforming mode in which hydrocarbon containing two or more carbon atoms including the olefins are reacted with oxygen and steam to form saturated hydrocarbons, methane, additional hydrogen and carbon monoxide. The reactor is configured and operates at a sufficiently high space velocity that olefin and organic species slip occurs that is further treated in a hydrotreater. The reactor contains a catalyst capable of promoting both hydrogenation and oxidation reactions and the hydrotreater contains a catalyst that is capable of only promoting hydrogenation reactions.
摘要翻译：本发明提供一种用于生产用于氢气设备的蒸汽甲烷重整器的进料的经处理的含烃流的方法和装置。根据这种方法，在以氢化方式操作以将烯烃氢化成饱和烃或预重整模式的反应器中，未处理的进料中的烯烃和有机硫物质的量减少，其中含有两个或更多个烃包括烯烃的碳原子与氧和蒸汽反应以形成饱和烃，甲烷，额外的氢和一氧化碳。反应器被构造并以足够高的空间速度运行，发生烯烃和有机物质滑动，在加氢处理器中进一步处理。反应器含有能够促进氢化反应和氧化反应的催化剂，加氢处理装置含有仅能促进氢化反应的催化剂。

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