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21. 发明授权

US06893683B1 Process for the preparation of a coating, a coated substrate, an adhesive, a film or sheet 有权
标题翻译：制备涂料，涂布基材，粘合剂，薄膜或薄片的方法
公开(公告)号：US06893683B1
公开(公告)日：2005-05-17
申请号：US10089423
申请日：2000-09-29
申请人： Laurentius Cornelius Josephus Hesselmans , Dirk Pieter Spek
发明人： Laurentius Cornelius Josephus Hesselmans , Dirk Pieter Spek
IPC分类号： C08J5/18 , C08G18/08 , C08G18/10 , C08G18/32 , C09J175/02 , C09J201/00 , B05D3/02
CPC分类号： C09J175/02 , C08G18/0871 , C08G18/10 , C08G18/3834
摘要： The invention comprises a process for the preparation of a coating, adhesive, film or sheet. In this process a mixture of a polyisocyanate functional, a polyepoxide functional, a polyanhydride functional or a polyketone functional compound or polymer and a compound containing reactive hydrogen, in which the compound containing reactive hydrogen is used in a material which is non-reactive towards the compound containing reactive hydrogen which mixture is not or low reactive at ambient conditions and high reactive under selected conditions, is applied onto a substrate at ambient temperature, followed by reacting the above compounds at elevated temperatures. At ambient temperature said compound containing reactive hydrogen is a solid material, a powder, a granule, a flake or grind or a mixture thereof which is preferably ground. The invention comprises further the coating mixtures to be used in the process and the coatings, coated substrates, adhesives, films, sheets, impregnated substrates, synthetic leathers, inmould coatings, coated leathers, coated polyvinylchlorides, coated non-wovens, coated coagulated polyurethane substrates, breathable coated substrates, obtained by applying the process.
摘要翻译：本发明包括一种制备涂料，粘合剂，薄膜或薄片的方法。在该方法中，多异氰酸酯官能团，聚环氧化物官能团，聚酐官能团或聚酮官能化合物或聚合物和含有反应性氢的化合物的混合物，其中含有反应性氢的化合物用于对化合物含有反应性氢，该混合物在环境条件下不是或低反应性，并且在选择的条件下具有高反应性，在环境温度下施加到基材上，随后在升高的温度下使上述化合物反应。在环境温度下，所述含有反应性氢的化合物是优选研磨的固体材料，粉末，颗粒，片状物或研磨剂或其混合物。本发明还包括在该方法中使用的涂料混合物和涂料，涂覆的基材，粘合剂，薄膜，片材，浸渍的基材，合成皮革，模塑涂料，涂覆的皮革，涂覆的聚氯乙烯，涂布的无纺布，涂覆的凝结聚氨酯基材，透气涂层的基材，通过应用该方法获得。

22. 发明申请

US20050003093A1 Process for the preparation of a coating, a coated substrate, an adhesive, film or sheet 审中-公开
标题翻译：制备涂料，涂布基材，粘合剂，薄膜或薄片的方法
公开(公告)号：US20050003093A1
公开(公告)日：2005-01-06
申请号：US10783165
申请日：2004-02-19
申请人： Laurentis Hesselmans , Johanna Van den Goorberg
发明人： Laurentis Hesselmans , Johanna Van den Goorberg
IPC分类号： C08G18/08 , C08G18/12 , C09D175/04 , C09D175/16 , C09D201/02 , C09J175/04 , C09J175/16 , C09J201/02 , B05D3/02
CPC分类号： C09J175/16 , C08G18/12 , C09D175/16 , C08G18/3834
摘要： A process for the preparation of a coating, a coated substrate, an adhesive, film or sheet or the like, which process comprises the application of a coating mixture containing a reactive system onto a substrate. According to the invention a coating mixture is used which comprising at least two reactive system and after application of the coating mixture the first reactive system is substantially reacted under conditions where the second reactive system is substantially not reacted. Thereafter the coated substrate is remoulded at elevated temperature and the second reactive system is substantially reacted during or after the remoulding of the coated substrate resulting in a fixed remoulded coating.
摘要翻译：用于制备涂层，涂布的基材，粘合剂，薄膜或薄片等的方法，该方法包括将含有反应性体系的涂料混合物施加到基材上。根据本发明，使用包含至少两种反应性体系的涂料混合物，并且在施加涂料混合物之后，第一反应体系基本上在第二反应体系基本上不反应的条件下反应。此后，涂覆的基材在升高的温度下被重塑，并且第二反应体系在涂覆的基材的再塑造期间或之后基本上反应，导致固定的重新涂覆的涂层。

23. 发明申请

US20220195544A1 Method for Upgrading and Embossing Leather 有权
公开(公告)号：US20220195544A1
公开(公告)日：2022-06-23
申请号：US17600887
申请日：2020-04-09
申请人： Stahl International B.V.
发明人： Riccardo Giovanni RUELLA , Christian SCHERKL , Harald BAUER
IPC分类号： C14B7/02 , B32B9/02 , B32B9/04 , C14B1/56
摘要： A method for making an upgraded and embossed laminar supporting element, in particular leather, by applying several layers on the surface of the leather, including an aqueous base coat and a lacquer coat and partially removing water and/or solvent from said layers followed by embossing and optionally further drying.

24. 发明授权

US09447477B2 Fat-liquoring 有权
标题翻译：加油
公开(公告)号：US09447477B2
公开(公告)日：2016-09-20
申请号：US14374867
申请日：2013-01-03
申请人： Stahl International B.V.
发明人： Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Claus Reineking
IPC分类号： C14C9/02 , C14C3/28 , C14C9/00 , C08G77/26 , C08G77/388 , C07F7/08
CPC分类号： C14C3/28 , C07F7/0838 , C07F7/0874 , C08G77/26 , C08G77/388 , C14C9/00
摘要： A process for the production of fat-liquored, tanned leather or pelt is provided. The process comprises the steps of fat-liquoring and tanning, wherein an animal hide, skin or pelt is fat-liquored with a substituted acylaminopolyorganosiloxane (A) in the presence of a surfactant or surfactant mixture (B), which is an anionic or nonionic surfactant or mixture of anionic or/and non-ionic surfactants, before, during or/and after tanning, wherein the substituted acylaminopolyorganosiloxane (A) is a polyorganosiloxane containing substituted acylamino groups linked to silicon atoms of the polysiloxane skeleton via alkylene bridges or mono- or oligo-[alkylene-amino or alkylene-(substituted acyl)amino]-alkylene bridges. Also provided are tanned pelt or leather, certain substituted acylaminopolyorganosiloxanes (A′) and related processes and compositions.
摘要翻译：提供了生产油脂，鞣制的皮革或毛皮的方法。该方法包括以下步骤：油脂和鞣制，其中在表面活性剂或表面活性剂混合物（B）的存在下，用阴离子或非离子表面活性剂混合物（B）将动物皮，皮肤或毛皮用取代的酰基氨基多有机硅氧烷（A）脂肪醇化表面活性剂或阴离子或/和非离子表面活性剂的混合物，其中取代的酰基氨基多有机基硅氧烷（A）是含有通过亚烷基桥或单 - 链烷氧基连接到聚硅氧烷骨架的硅原子的取代的酰基氨基的聚有机硅氧烷，或低级 - [亚烷基 - 氨基或亚烷基 - （取代的酰基）氨基] - 亚烷基桥。还提供了晒黑的皮革或皮革，某些取代的酰基氨基多有机硅氧烷（A'）及相关方法和组合物。

25. 发明授权

US09404019B2 Aqueous polyurethane-polyurea dispersions 有权
标题翻译：水性聚氨酯 - 聚脲分散体
公开(公告)号：US09404019B2
公开(公告)日：2016-08-02
申请号：US14792458
申请日：2015-07-06
申请人： Stahl International BV
发明人： Juergen Muenter , Thomas Fischer
IPC分类号： C08G18/00 , C09D175/06 , C08G18/38 , C08G18/36 , C08G18/44 , C08G18/61 , C08G18/66 , C08G18/75 , C09D175/04 , C14C11/00 , C08L75/12 , C09D175/12
CPC分类号： C09D175/06 , C08G18/36 , C08G18/3893 , C08G18/3897 , C08G18/44 , C08G18/61 , C08G18/6659 , C08G18/755 , C08L75/12 , C09D175/04 , C09D175/12 , C14C11/006 , Y10T428/31558
摘要： The invention relates to a method for producing aqueous polyurethane-polyurea dispersions, where A) first a polyurethane prepolymer containing NCO groups is produced by reacting A1) polyisocyanates with A2) polymeric polyols and/or polyamines having number-average molecular weights of more than 400 to 8,000 g/mol, A3) possibly low-molecular-weight compounds having number-average molecular weights of 17-400 g/mol selected from the group comprising mono- and polyalcohols, mono- and polyamines, and amino alcohols, A4) isocyanate-reactive, ionically or potentially ionically hydrophilic compounds and/or isocyanate-reactive non-ionically hydrophilic compounds, A5) isocyanate-reactive compounds, which contain at least one C7 to C24 alkyl group or C7 to C24 alkenyl group, and A6) isocyanate-reactive compounds, which contain at least one polysiloxane group, and B); the NCO groups of the prepolymer that are not yet free are reacted with isocyanate-reactive monoamines, polyamines, hydrazine, and/or hydrazides, dimensioned in such a way that a calculated ratio of the isocyanate-reactive NH groups to the NCO groups of 0.7 to 1.2 is achieved.
摘要翻译：本发明涉及一种生产水性聚氨酯 - 聚脲分散体的方法，其中A）首先含有NCO基团的聚氨酯预聚物通过使A1）多异氰酸酯与A2）数均分子量大于400的聚合多元醇和/或多胺至8,000g / mol，A3）可能的低分子量化合物，其数均分子量为17-400g / mol，选自单醇和多元醇，单胺和多胺，氨基醇，A4）异氰酸酯 - 反应性，离子或潜在的离子亲水性化合物和/或异氰酸酯反应性非离子亲水性化合物，A5）含有至少一个C 7至C 24烷基或C 7至C 24烯基的异氰酸酯反应性化合物，和A6）异氰酸酯 - 含有至少一个聚硅氧烷基团的反应性化合物，和B）; 尚未游离的预聚物的NCO基团与异氰酸酯反应性单胺，多胺，肼和/或酰肼反应，其尺寸使得异氰酸酯反应性NH基团与NCO基团的计算比例为0.7 达到1.2。

26. 发明授权

US09006304B2 Aqueous polyurethane-polyurea dispersions 有权
标题翻译：水性聚氨酯 - 聚脲分散体
公开(公告)号：US09006304B2
公开(公告)日：2015-04-14
申请号：US12993708
申请日：2009-05-19
申请人： Juergen Muenter
发明人： Juergen Muenter
IPC分类号： C08G18/28 , C08G18/08 , C08G18/12 , C08G18/32 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/65
CPC分类号： C08G18/0823 , C08G18/0866 , C08G18/12 , C08G18/282 , C08G18/283 , C08G18/3231 , C08G18/4238 , C08G18/44 , C08G18/4854 , C08G18/6505 , Y10T428/249953 , Y10T428/31551 , Y10T428/31558
摘要： The present invention relates to aqueous polyurethane-polyurea dispersions which stabilize a foam—produced by mechanical expansion—without addition of further foam-stabilizing components in such a way that aqueous foams are obtainable which are stable both during temporary storage and during processing, so that they can be applied in the form of foam also by customary application methods and substantially retain the foam structure even after drying.
摘要翻译：本发明涉及稳定通过机械膨胀产生的泡沫的水性聚氨酯 - 聚脲分散体，而不添加另外的泡沫稳定组分，使得可以获得在临时储存期间和加工期间都稳定的水性泡沫，使得它们也可以通过常规的施用方法以泡沫的形式施用，并且甚至在干燥后基本上保持泡沫结构。

27. 发明授权

US08795389B2 Non metal tanning 有权
标题翻译：非金属鞣制
公开(公告)号：US08795389B2
公开(公告)日：2014-08-05
申请号：US13879172
申请日：2011-10-05
申请人： Claus Reineking , Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Markus Gisler , Rainer Nusser
发明人： Claus Reineking , Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Markus Gisler , Rainer Nusser
IPC分类号： C14C3/26 , C14C3/00 , C14C3/02 , C14C3/04 , C14C3/08 , C07D253/00 , C07D253/065 , C07D253/07 , C07D253/075
CPC分类号： C14C3/00 , C07D251/44 , C07D253/00 , C07D253/065 , C07D253/07 , C07D253/075 , C14C3/02 , C14C3/04 , C14C3/08 , C14C3/26 , C14C3/28
摘要： Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of a formula (I), wherein X signifies fluorine or chlorine, and/or (+NR3)0-1, wherein R is a substituted or unsubstituted C1 to C6 alkyl group, a substituted or unsubstituted C6 to C10 aryl or a C5 to C6heteroaryl group, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of a formula (Ia), -(—C2-3 alkylene-O—)q—H (Ia), R2 signifies hydrogen or hydroxyl, m, signifies 1, 2 or 3, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
摘要翻译：鞣制的皮革，皮肤或毛皮是通过非金属鞣制制成的，包括用鞣剂（A）鞣制皮肤，皮肤或皮肤的步骤，鞣剂（A）是至少一种式（I ），其中X表示氟或氯，和/或（+ NR3）0-1，其中R是取代或未取代的C1至C6烷基，取代或未取代的C6至C10芳基或C5至C6杂芳基，R1表示氢，C1-8烷基或式（Ia）的亚烷基氧基， - （ - C2-3亚烷基-O-）q-H（Ia），R2表示氢或羟基，m表示1,2或3 q为1〜10，M表示在鞣制开始时pH为6〜10的鞣制浴中的氢或碱金属阳离子或铵阳离子，为质子化叔胺或季铵阳离子步。

28. 发明授权

US08790416B2 Non-metal tanning process 有权
标题翻译：非金属鞣制工艺
公开(公告)号：US08790416B2
公开(公告)日：2014-07-29
申请号：US13879207
申请日：2011-10-05
申请人： Claus Reineking , Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Markus Gisler , Rainer Nusser
发明人： Claus Reineking , Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Markus Gisler , Rainer Nusser
IPC分类号： C14C3/26 , C14C3/00 , C14C3/02 , C14C3/04 , C14C3/08 , C07D251/44 , C07D253/00 , C07D253/07 , C07D253/075
CPC分类号： C14C3/00 , C07D251/44 , C07D253/00 , C07D253/07 , C07D253/075 , C14C3/02 , C14C3/04 , C14C3/08 , C14C3/26 , C14C3/28
摘要： Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of a formula (I), wherein X signifies fluorine or chlorine, and/or (+NR3)0-1, wherein R is a substituted or unsubstituted C1 to C6 alkyl group, a substituted or unsubstituted C6 to C10 aryl or a C5 to C6 heteroaryl group, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of a formula (Ia), —(—C2-3 alkylene-O—)q—H (Ia), R2 signifies hydrogen, hydroxyl, C1-4-alkyl or C1-4-alkoxy, m, signifies 1 or 2, n signifies 0 to 2, q is of from 1 to 10, M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step, wherein the bated hide or skin or pelt is subjected to tanning with (A) without previous pickling.
摘要翻译：鞣制的皮革，皮肤或毛皮是通过非金属鞣制制成的，包括用鞣剂（A）鞣制皮肤，皮肤或皮肤的步骤，鞣剂（A）是至少一种式（I ），其中X表示氟或氯，和/或（+ NR3）0-1，其中R是取代或未取代的C1至C6烷基，取代或未取代的C6至C10芳基或C5至C6杂芳基，R1 表示氢，C 1-8 - 烷基或式（Ia）的亚烷氧基， - （ - C 2-3亚烷基-O-）q -H（Ia），R 2表示氢，羟基，C 1-4 - 烷基或C 1 -4-烷氧基，m表示1或2，n表示0至2，q表示1至10，M表示氢或碱金属阳离子或铵阳离子，铵阳离子为质子化叔胺或季铵铵阳离子，在鞣制浴中，在鞣制步骤开始时，鞣制浴的pH为6至10，其中所述皮肤或皮肤或毛皮用（A）进行鞣制，不需要预先我们酸洗

29. 发明授权

US08790415B2 Non metal tanning 有权
标题翻译：非金属鞣制
公开(公告)号：US08790415B2
公开(公告)日：2014-07-29
申请号：US13879152
申请日：2011-10-05
申请人： Claus Reineking , Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Markus Gisler , Rainer Nusser
发明人： Claus Reineking , Roberta Gamarino , Licia Trimarco , Maurizio Quaglierini , Markus Gisler , Rainer Nusser
IPC分类号： C14C3/26
CPC分类号： C14C3/26 , C07D251/44 , C14C3/28
摘要： Tanned leather, skin or pelt is produced by non-metal tanning, comprising the step of tanning a bated hide, skin or pelt with a tanning agent (A), the tanning agent (A) being at least one compound of a formula (I), wherein X signifies fluorine or chlorine, and/or (+NR3)0-1, wherein R is a substituted or unsubstituted C1 to C6 alkyl group, a substituted or unsubstituted C6 to C10 aryl group or a C5 to C6 heteroaryl group, R1 signifies hydrogen, C1-8-alkyl or an alkyleneoxy radical of a formula (Ia), —(—C2-3 alkylene-O—)q—H (Ia), R2 signifies substituted or unsubstituted C2 to C8 alkylenesulphonic acid, substituted or unsubstituted C2 to C8 alkylenecarboxylic acid or an alkyleneoxy radical of formula (Ib), —(—C2-3 alkylene-O—)m—Y (Ib) or an alkylene sulfonyl alkyleneoxy radical of formula (Ic), —(—C2-3 alkylene-O—)p—C2-3 alkylene- SO2CH2O—Y (Ic), m signifies 1 or 2, p signifies 0 or 1, q is of from 1 to 10, Y signifies hydrogen or —SO3M, M signifies hydrogen or an alkali metal cation or an ammonium cation, the ammonium cation being a protonated tertiary amine or a quaternary ammonium cation, in a tanning bath, the tanning bath having a pH of from 6 to 10 at the beginning of tanning step.
摘要翻译：鞣制的皮革，皮肤或毛皮是通过非金属鞣制制成的，包括用鞣剂（A）鞣制皮肤，皮肤或皮肤的步骤，鞣剂（A）是至少一种式（I ），其中X表示氟或氯，和/或（+ NR3）0-1，其中R是取代或未取代的C1至C6烷基，取代或未取代的C6至C10芳基或C5至C6杂芳基， R1表示氢，C1-8 - 烷基或式（Ia）的亚烷基氧基， - （ - C2-3亚烷基-O-）q-H（Ia），R2表示取代或未取代的C2至C8亚烷基磺酸，取代或（C 1 -C 6）的 - （ - C 2-3亚烷基-O-）m-Y（Ib）或亚烷基磺酰基亚烷基氧基， - （ - C2 -3亚烷基-O-）对-C2-3亚烷基-SO2CH2O-Y（Ic），m表示1或2，p表示0或1，q表示1至10，Y表示氢或-SO3M，M表示氢气碱金属阳离子或铵阳离子，铵阳离子是质子化叔胺或季铵阳离子，在鞣制浴中，鞣制浴在鞣制步骤开始时的pH为6至10。

30. 发明申请

US20130144006A1 Process for the Preparation of Multifunctional Polycarbodiimides Which are Used as Crosslinking Agents 有权
标题翻译：用作交联剂的多官能聚碳化二亚胺的制备方法
公开(公告)号：US20130144006A1
公开(公告)日：2013-06-06
申请号：US13751463
申请日：2013-01-28
申请人： Stahl International B.V.
发明人： Andries Johannes Derksen , Robrecht Leonardus Johannes Van Der Bruggen
IPC分类号： C09D179/00 , C08G18/79
CPC分类号： C09D179/00 , C07F9/65685 , C08G18/025 , C08G18/095 , C08G18/227 , C08G18/2825 , C08G18/283 , C08G18/289 , C08G18/797 , C08G73/00 , C08L75/00 , C08L75/04 , C08L79/00 , C09D175/04 , C08L2666/20
摘要： A process for the preparation of multifunctional polycarbodiimides, which are used as crosslinking agents, in which the polycarbodiimide is prepared by reacting mono- and polyisocyanates in the presence of a mono- or polyisocyanate that contains one or multiple additional reactive functional groups and in the presence of a carbodiimide catalyst, and thereafter terminating or chain extending the polycarbodiimide chain. Between 0 and 10% of an organic solvent and/or between 0 and 30% of a plasticizer and/or between 0 and 30% of a surface active component is added to the product during, before or after the polycarbodiimide forming reaction and/or the capping reaction and/or the chain extending reaction. Further, the invention relates to a coating mixture in which the polycarbodiimide is used as crosslinking agent and to the cured material obtained with the coating mixture.
摘要翻译：用于制备多官能聚碳化二亚胺的方法，其用作交联剂，其中聚碳化二亚胺通过单 - 和多异氰酸酯在含有一个或多个另外的反应性官能团的单或多异氰酸酯存在下反应制备，的碳二亚胺催化剂，然后终止或延伸聚碳二亚胺链。在聚碳二亚胺形成反应期间，之前或之后，将0至10％的有机溶剂和/或0至30％的增塑剂和/或0至30％的表面活性组分加入产物中，和/或封端反应和/或扩链反应。此外，本发明涉及其中使用聚碳二亚胺作为交联剂的涂料混合物和与涂料混合物获得的固化物质。

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