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21. 发明授权

US09190288B2 Pattern forming method 有权
公开(公告)号：US09190288B2
公开(公告)日：2015-11-17
申请号：US14550637
申请日：2014-11-21
申请人： Hiroki Tanaka , Ryosuke Yamamoto , Naoko Kihara
发明人： Hiroki Tanaka , Ryosuke Yamamoto , Naoko Kihara
IPC分类号： H01L21/302 , H01L21/461 , C03C15/00 , C03C25/68 , B44C1/22 , C08F2/00 , C08F4/00 , H01L21/308 , B82Y10/00 , G11B5/74 , G11B5/82 , G11B5/855 , B81C1/00 , H01L21/027 , H01L21/306
CPC分类号： H01L21/3086 , B81C1/00031 , B81C2201/0149 , B82Y10/00 , G11B5/743 , G11B5/82 , G11B5/855 , H01L21/0271 , H01L21/30604 , H01L21/3081
摘要： A pattern forming method includes forming a coating film containing a hydrophilic first homopolymer having a first bonding group and a hydrophobic second homopolymer having a second bonding group capable of bonding with the first bonding group, forming a bond between the first and second bonding group to produce a block copolymer of the first and second homopolymers, and heating the coating film to microphase-separating the copolymer into a hydrophilic domain and a hydrophobic domain. The hydrophilic and hydrophobic domains are arranged alternately. The bond is broken, then selectively dissolving-removing either domain by a solvent to provide a polymer pattern of a remainder domain.

22. 发明申请

US20120231213A1 STRUCTURE 有权
标题翻译：结构体
公开(公告)号：US20120231213A1
公开(公告)日：2012-09-13
申请号：US13425676
申请日：2012-03-21
申请人： Ryosuke Yamamoto , Hiroki Tanaka , Naoko Kihara , Toshiro Hiraoka
发明人： Ryosuke Yamamoto , Hiroki Tanaka , Naoko Kihara , Toshiro Hiraoka
IPC分类号： B32B3/30
CPC分类号： B82Y30/00 , B32B27/08 , Y10T428/24174 , Y10T428/261 , Y10T428/31678 , Y10T428/31855
摘要： A structure includes a substrate, a first layer formed on the substrate, and a second layer formed on the first layer. The first layer is comprised of a self-assembled monolayer and contains 4-(6-hydroxyhexyloxy)-4′-methoxybiphenyl. The second layer is obtained by micro-phase separation of a block copolymer containing a hydrophilic polymer comprised of polyethylene oxide and a hydrophobic polymer comprised of polymethacrylic acid containing azobenzene at the side chain. The second layer contains a cylinder phase with its long axis being oriented perpendicular to the substrate. The thickness T of the second layer is within a range of A≦T≦50 nm, where A is a phase separation period length satisfying 5 nm≦A≦50 nm.
摘要翻译：一种结构包括基板，形成在基板上的第一层和形成在第一层上的第二层。第一层由自组装单层组成并含有4-（6-羟基己氧基）-4'-甲氧基联苯。第二层通过包含由聚环氧乙烷构成的亲水性聚合物和由侧链上含有偶氮苯的聚甲基丙烯酸构成的疏水性聚合物的嵌段共聚物进行微相分离而获得。第二层包含圆柱相，其长轴垂直于基底取向。第二层的厚度T在A＆lt; NlE; T＆nlE; 50nm的范围内，其中A是满足5nm＆amp; NlE; A＆amp; NlE; 50nm的相分离周期长度。

23. 发明授权

US08974680B2 Pattern forming method 有权
标题翻译：图案形成方法
公开(公告)号：US08974680B2
公开(公告)日：2015-03-10
申请号：US13426166
申请日：2012-03-21
申请人： Hiroki Tanaka , Ryosuke Yamamoto , Naoko Kihara
发明人： Hiroki Tanaka , Ryosuke Yamamoto , Naoko Kihara
IPC分类号： H01L21/302 , H01L21/461 , C03C15/00 , C03C25/68 , B44C1/22 , C08F2/00 , C08F4/00 , G11B5/82 , H01L21/308 , B81C1/00 , B82Y10/00 , G11B5/74 , G11B5/855
CPC分类号： H01L21/3086 , B81C1/00031 , B81C2201/0149 , B82Y10/00 , G11B5/743 , G11B5/82 , G11B5/855 , H01L21/0271 , H01L21/30604 , H01L21/3081
摘要： A pattern forming method includes forming a coating film containing a hydrophilic first homopolymer having a first bonding group and a hydrophobic second homopolymer having a second bonding group capable of bonding with the first bonding group, forming a bond between the first and second bonding group to produce a block copolymer of the first and second homopolymers, and heating the coating film to microphase-separating the copolymer into a hydrophilic domain and a hydrophobic domain. The hydrophilic and hydrophobic domains are arranged alternately. The bond is broken, then selectively dissolving-removing either domain by a solvent to provide a polymer pattern of a remainder domain.
摘要翻译：图案形成方法包括形成含有具有第一接合基团的亲水性第一均聚物和具有能够与第一接合基团键合的第二接合基团的疏水性第二均聚物的涂膜，在第一和第二接合基团之间形成键，以产生第一和第二均聚物的嵌段共聚物，并加热涂膜以将共聚物微相分离成亲水结构域和疏水结构域。亲水和疏水畴交替排列。该键断裂，然后通过溶剂选择性溶解除去任一结构域，以提供其余结构域的聚合物图案。

24. 发明授权

US08377551B2 Structure for recording medium 有权
标题翻译：记录介质结构
公开(公告)号：US08377551B2
公开(公告)日：2013-02-19
申请号：US13425676
申请日：2012-03-21
申请人： Ryosuke Yamamoto , Hiroki Tanaka , Naoko Kihara , Toshiro Hiraoka
发明人： Ryosuke Yamamoto , Hiroki Tanaka , Naoko Kihara , Toshiro Hiraoka
IPC分类号： B32B7/06 , B32B18/00 , B32B27/06 , B32B33/00
CPC分类号： B82Y30/00 , B32B27/08 , Y10T428/24174 , Y10T428/261 , Y10T428/31678 , Y10T428/31855
摘要： A structure includes a substrate, a first layer formed on the substrate, and a second layer formed on the first layer. The first layer is comprised of self-assembled monolayer and contains 4-(6-hydroxyhexyloxy)-4′-methoxybiphenyl. The second layer is obtained by micro-phase separation of a block copolymer containing a hydrophilic polymer comprised of polyethylene oxide and a hydrophobic polymer comprised of polymethacrylic acid containing azobenzene at the side chain. The second layer contains a cylinder phase with its long axis being oriented perpendicular to the substrate. The thickness T of the second layer is within a range of A≦T≦50 nm, where A is a phase separation period length satisfying 5 nm≦A≦50 nm.
摘要翻译：一种结构包括基板，形成在基板上的第一层和形成在第一层上的第二层。第一层由自组装单层组成并含有4-（6-羟基己氧基）-4'-甲氧基联苯。第二层通过包含由聚环氧乙烷构成的亲水性聚合物和由侧链上含有偶氮苯的聚甲基丙烯酸构成的疏水性聚合物的嵌段共聚物进行微相分离而获得。第二层包含圆柱相，其长轴垂直于基底取向。第二层的厚度T在A＆lt; NlE; T＆nlE; 50nm的范围内，其中A是满足5nm＆amp; NlE; A＆amp; NlE; 50nm的相分离周期长度。

25. 发明授权

US07081328B2 Optical disk having super-resolution film 失效
标题翻译：具有超分辨率胶片的光盘
公开(公告)号：US07081328B2
公开(公告)日：2006-07-25
申请号：US09819621
申请日：2001-03-29
申请人： Kenji Todori , Toshihiko Nagase , Katsutaro Ichihara , Naoko Kihara
发明人： Kenji Todori , Toshihiko Nagase , Katsutaro Ichihara , Naoko Kihara
IPC分类号： G11B7/24
CPC分类号： G11B7/257 , B82Y10/00 , B82Y20/00 , G02F1/3556 , G11B7/24 , G11B7/243 , G11B7/244 , G11B7/251 , G11B7/2533 , G11B2007/24308 , G11B2007/2431 , G11B2007/24316 , G11B2007/2432 , G11B2007/24322 , G11B2007/24324 , G11B2007/24326 , Y10S430/146
摘要： An optical disk from which recorded data are read out by means of light irradiation has a substrate having recording pits as data on a surface thereof, and stacked films formed on the substrate. The stacked films contain a super-resolution film of a polymer matrix and semiconductor particles having an organic group covalently bonded thereto, and a reflective film reflecting light. The super-resolution film and the reflective film are provided in this order from a light incident side.
摘要翻译：通过光照射从其读出记录数据的光盘具有作为其表面上的数据的记录坑的基板和形成在基板上的叠层膜。层叠膜包含聚合物基质的超分辨率膜和与其共价键合的有机基团的半导体粒子和反射光的反射膜。超分辨率膜和反射膜从光入射侧依次设置。

26. 发明申请

US20050026079A1 Recording medium 失效
标题翻译：录音媒体
公开(公告)号：US20050026079A1
公开(公告)日：2005-02-03
申请号：US10868803
申请日：2004-06-17
申请人： Naoko Kihara , Katsutaro Ichihara , Akiko Hirao , Kazuki Matsumoto , Hideyuki Nishizawa , Urara Ichihara
发明人： Naoko Kihara , Katsutaro Ichihara , Akiko Hirao , Kazuki Matsumoto , Hideyuki Nishizawa , Urara Ichihara
IPC分类号： G03F7/038 , G03C1/73 , G03F7/00 , G03F7/004 , G03F7/039 , G03H1/02 , G11B7/24 , G11B7/244
CPC分类号： G03F7/001 , G03F7/0045 , G03F7/039 , Y10S430/111 , Y10S430/115 , Y10S430/128
摘要： Disclosed is a recording medium comprising a recording layer including a photo-acid generating agent that generates an acid upon irradiation with an actinic radiation and a polymer having a polymerizable substituent group bonded to a main chain of the polymer via a functional group that cleaves in the presence of the acid.
摘要翻译：公开了一种记录介质，其包括记录层，该记录层包括在通过光化辐射照射时产生酸的光酸产生剂和具有通过在聚合物主链中切割的官能团而与聚合物主链键合的聚合性取代基的聚合物存在酸。

27. 发明授权

US5853952A Color developing organic material, color developing resin composition and colored thin film pattern 失效
标题翻译：显色有机材料，彩色显影树脂组合物和着色薄膜图案
公开(公告)号：US5853952A
公开(公告)日：1998-12-29
申请号：US705265
申请日：1996-08-29
申请人： Toru Ushirogouchi , Makoto Nakase , Akira Yoshizumi , Naoko Kihara , Takuya Naito , Naomi Shida , Koji Asakawa
发明人： Toru Ushirogouchi , Makoto Nakase , Akira Yoshizumi , Naoko Kihara , Takuya Naito , Naomi Shida , Koji Asakawa
IPC分类号： C08G12/06 , C08G73/00 , G02B5/22 , G03F7/00 , G03F7/004 , G03F7/105 , G03C1/73
CPC分类号： C08G12/06 , G03F7/0007 , G03F7/0045 , G03F7/105 , G02B5/22 , Y10S430/163
摘要： There is disclosed a color developing resin composition comprising a base polymer, a dialdehyde represented by the general formula OHC--R.sup.1' --CHO, a diamine represented by the general formula H.sub.2 N--R.sup.2' --NH.sub.2 (at least one of R.sup.1' and R.sup.2' is an aromatic group), a compound which produces an acid by light irradiating and a resin which is crosslinked with the acid.
摘要翻译：公开了一种显色树脂组合物，其包含基础聚合物，由通式OHC-R1'-CHO表示的二醛，由通式H2N-R2'-NH2表示的二胺（R1'和R2'中的至少一个）是芳族基团），通过光照射产生酸的化合物和与酸交联的树脂。

28. 发明授权

US06811897B2 Ink for forming a hole injection layer of organic EL display devices and manufacturing method thereof, organic EL display devices, and manufacturing method of the same 失效
标题翻译：用于形成有机EL显示装置的空穴注入层的油墨及其制造方法，有机EL显示装置及其制造方法
公开(公告)号：US06811897B2
公开(公告)日：2004-11-02
申请号：US10395253
申请日：2003-03-25
申请人： Katsuyuki Naito , Naoko Kihara , Rei Hasegawa , Shintaro Enomoto , Yutaka Nakai , Kazushige Yamamoto , Hiroki Iwanaga , Kimito Sakai , Yasushi Mori
发明人： Katsuyuki Naito , Naoko Kihara , Rei Hasegawa , Shintaro Enomoto , Yutaka Nakai , Kazushige Yamamoto , Hiroki Iwanaga , Kimito Sakai , Yasushi Mori
IPC分类号： H05B3312
CPC分类号： H05B33/14 , C09K11/06 , C09K2211/1029 , C09K2211/1425 , H01L27/3244 , H01L51/0005 , H01L51/0025 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0062 , H01L51/5088 , Y10S428/917
摘要： There is disclosed an organic electro luminescence display device comprising a two-dimensional array of pixels comprising organic electro luminescence elements capable of emitting a of color or different plural colors, each of the organic electro luminescence elements being provided with an anode, a cathode, a polymeric luminescence layer located between the anode and the cathode, and a hole injection layer. The hole injection layer is constituted by solid matters containing a donor molecule comprising polythiophene and/or a derivative thereof, and an acceptor molecule comprising polystyrenesulfonic acid and/or a derivative thereof, a concentration of sulfate ion in the hole injection layer is 125 ppm or less, and components having a molecular weight of 110,000 or less is 35% or less based on an entire solid matters, the molecular weight being converted as sodium polystyrenesulfonate in an aqueous gel permeation chromatography measured by using UV of 254 nm in wavelength.
摘要翻译：公开了一种有机电致发光显示装置，其包括能够发射颜色或不同多种颜色的有机电致发光元件的二维像素阵列，每个有机电致发光元件设置有阳极，阴极，位于阳极和阴极之间的聚合物发光层和空穴注入层。空穴注入层由包含聚噻吩和/或其衍生物的供体分子和包含聚苯乙烯磺酸和/或其衍生物的受体分子的固体物质构成，空穴注入层中的硫酸根离子的浓度为125ppm或更少，分子量为11万以下的成分相对于整个固体成分为35％以下，分子量在通过使用波长为254nm的UV测定的水性凝胶渗透色谱中被转化为聚苯乙烯磺酸钠。

29. 发明授权

US06197473B1 Photosensitive composition and a pattern forming process using the same 有权
标题翻译：光敏组合物和使用其的图案形成方法
公开(公告)号：US06197473B1
公开(公告)日：2001-03-06
申请号：US09154733
申请日：1998-09-17
申请人： Naoko Kihara , Satoshi Saito , Toru Ushirogouchi
发明人： Naoko Kihara , Satoshi Saito , Toru Ushirogouchi
IPC分类号： G03F7023
CPC分类号： G03F7/0045 , G03F7/022 , Y10S430/106
摘要： The objectives of the present invention are to provide a photosensitive composition having high solubility to organic solvents as well as to alkaline developers or water-base developers of pH 11 or less, and to provide a pattern forming process for obtaining a high-resolution resist pattern. These objectives are achieved by means of a photosensitive composition comprising a compound which is glassy at room temperature and has a cyclic structure with three or more aromatic rings containing an acid-decomposable substituent, and a pattern forming process wherein a photosensitive material using said photosensitive composition is exposed to a light pattern and developed with an aqueous solution of an alkali or with a water-base developer of pH 11 or less.
摘要翻译：本发明的目的是提供一种对有机溶剂以及碱性显影剂或pH11或更低的水基显影剂具有高溶解度的光敏组合物，并提供用于获得高分辨抗蚀剂图案的图案形成方法这些目的通过光敏组合物实现，该组合物包含在室温下为玻璃状的化合物，并且具有带有三个或更多个含有酸可分解取代基的芳环的环状结构，以及图案形成方法，其中使用所述感光组合物暴露于光图案，并用碱的水溶液或pH11或更低的水性显影剂显影。

30. 发明授权

US5348838A Photosensitive composition comprising alkali soluble binder and photoacid generator having sulfonyl group 失效
标题翻译：包含碱溶性粘合剂和具有磺酰基的光致酸发生剂的光敏组合物
公开(公告)号：US5348838A
公开(公告)日：1994-09-20
申请号：US921692
申请日：1992-07-30
申请人： Toru Ushirogouchi , Naoko Kihara , Osamu Sasaki , Tsukasa Tada , Takuya Naito , Satoshi Saito
发明人： Toru Ushirogouchi , Naoko Kihara , Osamu Sasaki , Tsukasa Tada , Takuya Naito , Satoshi Saito
IPC分类号： C08G8/28 , C08K5/41 , G03F7/004 , G03C1/492
CPC分类号： C08G8/28 , C08K5/41 , G03F7/0045 , Y10S430/11
摘要： A photosensitive composition comprises an alkali-soluble resin, a compound which has a substituent group decomposable by an acid and generates an alkali-soluble group upon decomposition of the substituent group, or a compound which has a substituent group capable of crosslinking the alkali-soluble resin in the presence of an acid, and a compound which generates an acid upon exposure, which is represented by formula (1) given below: ##STR1## wherein R.sub.11 represents a monovalent organic group or a monovalent organic group into which at least one selected from the group consisting of a halogen atom, a nitro group, and a cyano group is introduced, each of R.sub.12, R.sub.13, and R.sub.14 independently represents hydrogen, a halogen atom, a nitro group, a cyano group, a monovalent organic group, or a monovalent organic group into which at least one selected from the group consisting of a halogen atom, a nitro group, and a cyano group is introduced.
摘要翻译：感光性组合物包含碱溶性树脂，具有可被酸分解的取代基的化合物，在分解取代基时产生碱溶性基团，或具有能够使碱溶性交联的取代基的化合物（1）表示的曝光时产生酸的化合物：其中R11表示一价有机基团或一价有机基团，其中在引入选自卤素原子，硝基和氰基中的至少一个，R 12，R 13和R 14各自独立地表示氢，卤素原子，硝基，氰基，一价有机基基团或其中引入选自卤素原子，硝基和氰基中的至少一种的一价有机基团。

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