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21. 发明授权

US5859020A Substituted 4-Alkoxypyrimidines, Process for their preparation, agents containing them, and their use as pesticides 失效
标题翻译：取代的4-烷氧基嘧啶，其制备方法，含有它们的试剂及其作为农药的用途
公开(公告)号：US5859020A
公开(公告)日：1999-01-12
申请号：US783072
申请日：1997-01-15
申请人： Rainer Preuss , Gerhard Salbeck, deceased , Wolfgang Schaper , Peter Braun , Werner Knauf , Burkhard Sachse , Anna Waltersdorfer , Manfred Kern , Peter Lummen
发明人： Rainer Preuss , Gerhard Salbeck, deceased , Wolfgang Schaper , Peter Braun , Werner Knauf , Burkhard Sachse , Anna Waltersdorfer , Manfred Kern , Peter Lummen
IPC分类号： A01N43/54 , A01N43/90 , C07D239/34 , C07D239/47 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/88 , C07D409/12 , C07D495/04 , C07F7/18 , A61K31/505
CPC分类号： C07F7/1856 , A01N43/54 , A01N43/90 , C07D239/34 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/88 , C07D409/12 , C07D495/04
摘要： The invention relates to substituted 4-alkoxypyrimidines of the formula ##STR1## in which R.sup.1 is hydrogen, halogen, alkyl or cycloalkyl, R.sup.2 is hydrogen, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted alkylthio, alkylamino or dialkylamino, R.sup.3 is hydrogen, alkyl, alkoxy, haloalkoxy, halogen, alkylthio, amino, alkylamino or dialkylamino, and R.sup.4 is hydrogen, alkyl, cycloalkyl or haloalkyl, where R.sup.2 and R.sup.3 together with the carbon atoms to which they are attached can also form a ring, and Q is as defined in the description.The invention furthermore relates to a process for their preparation, to agents containing them, and to their use as pesticides.
摘要翻译：本发明涉及式“IMAGE”的取代的4-烷氧基嘧啶，其中R 1是氢，卤素，烷基或环烷基，R 2是氢，任选取代的烷基，任选取代的烷氧基，任选取代的烷硫基，烷氨基或二烷基氨基，R 3是氢，烷基，烷氧基，卤代烷氧基，卤素，烷硫基，氨基，烷基氨基或二烷基氨基，R 4是氢，烷基，环烷基或卤代烷基，其中R 2和R 3与它们所连接的碳原子一起也可以形成环，如说明书中所定义。本发明还涉及其制备方法，含有它们的试剂以及它们作为农药的用途。

22. 发明授权

US4954529A (Thio)benzoylureas and functional derivatives thereof, processes for their preparation, agents containing them and their use as agents for combating pests 失效
标题翻译：（Thio）苯甲酰脲及其功能衍生物，其制备方法，含有它们的药剂及其作为防治害虫的药剂的用途
公开(公告)号：US4954529A
公开(公告)日：1990-09-04
申请号：US278966
申请日：1988-12-02
申请人： Volker Koch , Stefan Schnatterer , Werner Bonin , Manfred Kern , Werner Knauf , Anna Waltersdorfer
发明人： Volker Koch , Stefan Schnatterer , Werner Bonin , Manfred Kern , Werner Knauf , Anna Waltersdorfer
IPC分类号： A01N43/88 , A01N47/30 , A01N47/34 , A01P7/02 , A01P7/04 , C07C317/42 , C07C323/27 , C07C323/44 , C07C335/26 , C07D273/04
CPC分类号： C07C317/42 , A01N43/88 , A01N47/34 , C07C323/27 , C07C335/26 , C07D273/04
摘要： Compounds of the general formula I ##STR1## in which A denotes a radical of the formula A.sup.1, A.sup.2 or A.sup.3 ##STR2## R.sup.1 to R.sup.3 in each case independently of one another denote hydrogen or halogen,the radicals R.sup.4 in each case independently of one another denote halogen, (C.sub.1 -C.sub.3)halogenoalkyl or nitro,R.sup.5 denotes (C.sub.1 -C.sub.5)alkyl, which can be halogenated,X denotes oxygen or sulfur,n denotes a number from 0 to 2 andm denotes a number from 1 to 4 with the proviso that (R.sup.4).sub.m does not by itself denote halogen or by itself denote nitro, and where A=A.sup.1, salts thereof which can be used in agriculture, have advantageous acaricidal and insecticidal properties.Processes for the preparation of the compounds of the formula I are furthermore described.
摘要翻译：其中A表示式A1，A2或A3的基团的化合物（I）其中A表示式A1，A2或A3的基团（A1）（IMA）（A2）彼此独立地表示氢或卤素，基团R4各自独立地表示卤素，（C1-C3）卤代烷基或硝基，R5表示可被卤化的（C1-C5）烷基，X表示氧或硫，n表示0〜2的数，m表示1至4的数，条件是（R4）m本身不表示卤素或本身表示硝基，并且其中A = A1，可以使用的盐在农业中具有有利的杀螨和杀虫特性。进一步描述制备式I化合物的方法。

23. 发明授权

US06265350B1 1,3-oxazoline and 1,3-thiazoline derivatives, their preparation, and their use as pesticides 失效
标题翻译： 1,3-恶唑啉和1,3-噻唑啉衍生物，它们的制备及其作为农药的用途
公开(公告)号：US06265350B1
公开(公告)日：2001-07-24
申请号：US09332225
申请日：1999-06-14
申请人： Stefan Schnatterer , Manfred Kern , Ulrich Sanft
发明人： Stefan Schnatterer , Manfred Kern , Ulrich Sanft
IPC分类号： A01N4340
CPC分类号： C07D413/10 , A01N43/74 , C07D413/14 , C07D417/10
摘要： 1,3-Oxazoline and 1,3-thiazoline derivatives, their preparation, and their use as pesticides 1,3-Oxazoline and 1,3-thiazoline derivatives of the formula (I) where the symbols have the following meanings: A is phenyl, pyridyl, pyrimidinyl, pyrazinyl, pyrazolyl or thienyl, E is a single bond, (C1-C4)alkylene, —O—CH2— or —CH2—O—; G is a radical selected from the group consisting of Z is oxygen or sulfur. Compounds of the formula (I) have, in particular, a very good acaricidal and insecticidal action with regard to the spectrum of action and the potency.
摘要翻译： 1,3-唑啉和1,3-噻唑啉衍生物，它们的制备及其作为农药的用途，1,3-恶唑啉和式（I）的1,3-噻唑啉衍生物，其中符号具有以下含义：A是苯基，吡啶基，嘧啶基，吡嗪基，吡唑基或噻吩基，E是单键，（C1-C4）亚烷基，-O-CH2-或-CH2-O-; G是选自Z是氧或硫的基团。式（I）化合物尤其具有关于作用光谱和效力的非常好的杀螨和杀虫作用。

24. 发明授权

US06521610B2 4-Haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclyl-pyrimidines, processes for their preparation, compositions comprising them, and their use as pesticides 失效
标题翻译： 4-卤代烷基-3-杂环基吡啶和4-卤代烷基-5-杂环基嘧啶，其制备方法，包含它们的组合物及其作为农药的用途
公开(公告)号：US06521610B2
公开(公告)日：2003-02-18
申请号：US09808194
申请日：2001-03-14
申请人： Jörg Tiebes , Thomas Taapken , Burkhard Rook , Manfred Kern , Ulrich Sanft
发明人： Jörg Tiebes , Thomas Taapken , Burkhard Rook , Manfred Kern , Ulrich Sanft
IPC分类号： A61K3133
CPC分类号： C07D401/04 , A01N43/76 , A01N43/82 , C07D413/04 , C07D413/14 , C07D417/04 , C07D417/14
摘要： 4-Haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclyl-pyrimidines, processes for their preparation, compositions comprising them, and their use as pesticides The present invention relates to 4-haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclylpyrimidines of the formula (I), to processes for their preparation, to compositions comprising them, and to the use of these compounds for controlling animal pests, in particular insects, spider mites, ectoparasites and helminths. In the formula (I), Q is a 5-membered heterocyclic group which is optionally substituted by halogen or organic radicals, Y is halo-C1-C6-alkyl, X is CH or N and m is 0 or 1.
摘要翻译： 4-卤代烷基-3-杂环基吡啶和4-卤代烷基-5-杂环基嘧啶，其制备方法，包含它们的组合物及其作为农药的用途本发明涉及4-卤代烷基-3-杂环基吡啶和4-卤代烷基-3-杂环基嘧啶，式（I）的杂环基嘧啶，其制备方法，包含它们的组合物，以及这些化合物用于防治动物害虫，特别是昆虫，蜘蛛螨，外寄生虫和蠕虫的用途。在式（I）中，Q 是任选被卤素或有机基团取代的5元杂环基，Y是卤代-C 1 -C 6 - 烷基，X是CH或N，m是0或1。

25. 发明授权

US06670307B2 1,3-oxazoline and 1,3-thiazoline derivatives, their preparation, and their use as pesticides 失效
标题翻译： 1,3-恶唑啉和1,3-噻唑啉衍生物，它们的制备及其作为农药的用途
公开(公告)号：US06670307B2
公开(公告)日：2003-12-30
申请号：US09886551
申请日：2001-06-21
申请人： Stefan Schnatterer , Manfred Kern , Ulrich Sanft , Christina Mertens
发明人： Stefan Schnatterer , Manfred Kern , Ulrich Sanft , Christina Mertens
IPC分类号： C07D41314
CPC分类号： C07D413/10 , A01N43/74 , C07D413/14 , C07D417/10
摘要： 1,3-Oxazoline and 1,3-thiazoline derivatives, their preparation, and their use as pesticides 1,3-Oxazoline and 1,3-thiazoline derivatives of the formula (I) where the symbols have the following meanings: A is phenyl, pyridyl, pyrimidinyl, pyrazinyl, pyrazolyl or thienyl, E is a single bond, (C1-C4)alkylene, —O—CH2— or —CH2—O—; G is a radical selected from the group consisting of Z is oxygen or sulfur. Compounds of the formula (I) have, in particular, a very good acaricidal and insecticidal action with regard to the spectrum of action and the potency.
摘要翻译： 1,3-唑啉和1,3-噻唑啉衍生物，它们的制备及其作为农药的用途，1,3-恶唑啉和式（I）的1,3-噻唑啉衍生物，其中符号具有以下含义：A是苯基，吡啶基，嘧啶基，吡嗪基，吡唑基或噻吩基，E是单键，（C1-C4）亚烷基，-O-CH2-或-CH2-O-; G是选自Z是氧或硫的基团。式（I）化合物尤其具有关于作用光谱和效力的非常好的杀螨和杀虫作用。

26. 发明授权

US06239160B1 4-haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclylpyrimidines, processes for their preparation, compositions comprising them, and their use as pesticides 失效
标题翻译： 4-卤代烷基-3-杂环基吡啶和4-卤代烷基-5-杂环基嘧啶，其制备方法，包含它们的组合物及其作为农药的用途
公开(公告)号：US06239160B1
公开(公告)日：2001-05-29
申请号：US09096748
申请日：1998-06-12
申请人： Jörg Tiebes , Thomas Taapken , Burkhard Rook , Manfred Kern , Ulrich Sanft
发明人： Jörg Tiebes , Thomas Taapken , Burkhard Rook , Manfred Kern , Ulrich Sanft
IPC分类号： A61K3141
CPC分类号： C07D401/04 , A01N43/76 , A01N43/82 , C07D413/04 , C07D413/14 , C07D417/04 , C07D417/14
摘要： The present invention relates to 4-haloalkyl-3-heterocyclylpyridines and 4-haloalkyl-5-heterocyclylpyrimidines of the formula (I), to processes for their preparation, to compositions comprising them, and to the use of these compounds for controlling animal pests, in particular insects, spider mites, ectoparasites and helminths. In the formula (I), Q is a 5-membered heterocyclic group which is optionally substituted by halogen or organic radicals, Y is halo-C1-C8-alkyl, X is CH or N and m is 0 or 1.
摘要翻译：本发明涉及式（I）的4-卤代烷基-3-杂环基吡啶和4-卤代烷基-5-杂环基嘧啶，其制备方法，包含它们的组合物以及这些化合物用于防治动物害虫，特别是昆虫，蜘蛛螨，外寄生虫和蠕虫。在式（I）中，Q是任选被卤素或有机基团取代的5元杂环基，Y是卤代-C 1 -C 8 - 烷基，X是CH或 N和m为0或1。

27. 发明授权

US5002957A Azaneophyl sulfides, and their use as pesticides 失效
标题翻译：硫唑烷酮和它们作为农药的用途
公开(公告)号：US5002957A
公开(公告)日：1991-03-26
申请号：US327971
申请日：1989-03-23
申请人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Werner Knauf , Anna Waltersdorfer , Manfred Kern
发明人： Hans H. Schubert , Gerhard Salbeck , Hans-Peter Krause , Werner Knauf , Anna Waltersdorfer , Manfred Kern
IPC分类号： C07D253/06 , A01N43/40 , A01N55/00 , A01N55/10 , C07D213/32 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/70 , C07D237/12 , C07D237/14 , C07D237/18 , C07D239/26 , C07D239/32 , C07D239/34 , C07D241/16 , C07D241/18 , C07D257/08 , C07D401/12 , C07D409/12 , C07D491/056 , C07F7/10
CPC分类号： C07D213/64 , A01N43/40 , A01N55/00 , C07D213/643 , C07D213/70 , C07D409/12
摘要： Azaneophyl and silazaneophyl sulfides, processes for their preparation, agents containing them, and their use as pesticides.Compounds of the formula I, their optical isomers and mixtures thereof ##STR1## where M denotes C or Si,R.sup.1 denotes unsubstituted or substituted pyridyl, unsubstituted or substituted pyrimidyl, andwhen M=C- denotes unsubstituted or substituted pyridazinyl, unsubstituted or substituted pyrazinyl, unsubstituted or substituted 1,2,4-triazinyl, unsubstituted or substituted 1,2,4,5-tetrazinyl, R.sup.2, R.sup.3 independently or one another denote alkyl, alkenyl, haloalkyl, phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which - together with the quaternary central atom (M) - form an unsubstituted or fluorine-substituted ring having four to six ring members (when M=Si) or having three to six ring members (when M=C),R.sup.4 denotes H, F, --CN, --CCl.sub.3, --C.dbd.CH, (C.sub.1 -C.sub.4)alkyl, ##STR2## R.sup.5 denotes pyridyl, furyl, thienyl, all of which can be substituted, phthalimidyl, dialkylmaleinimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl, substituted phenylor R.sup.4 and R.sup.5 - together with the carbon atom bridging them denote an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical,and to their salts and quaternization products for advantageous insecticidal, acaricidal or nematocidal properties.
摘要翻译： Azaneophyl和silazaneophyl硫化物，它们的制备方法，含有它们的试剂，以及它们作为农药的用途。式I化合物，其旋光异构体及其混合物，其中M表示C或Si，R1表示未取代或取代的吡啶基，未取代或取代的嘧啶基，当M = C-表示未取代或取代的哒嗪基时，未取代的或取代的吡嗪基，未取代或取代的1,2,4-三嗪基，未取代或取代的1,2,4,5-四嗪基，R2，R3独立地或者彼此表示烷基，烯基，卤代烷基，苯基或R2和R3表示亚烷基链与四元中心原子（M）一起形成具有四至六个环成员（当M = Si）或具有三至六个环成员（当M = C时）的未取代或氟取代的环，R4表示 H，F，-CN，-CCl 3，-C = CH，（C 1 -C 4）烷基，R 5表示吡啶基，呋喃基，噻吩基，它们都可被取代，苯二酰亚氨基，二烷基马来酰亚胺基，硫代邻苯二甲酰亚胺基，二氢邻苯二甲酰亚氨基，四氢邻苯二甲酰亚胺基，取代的苯基或R 4和R 5 - 与碳原子一起桥接它们表示任选取代的茚满基，环戊烯基或环戊烯基，以及它们的盐和季铵化产物，用于有利的杀虫，杀螨或杀线虫性质。

28. 发明授权

US5728696A Acaricidal, insecticidal and nematicidal substituted (hetero)arylalkyl ketone oxime O-ethers, processes for their preparation, agents containing them, and their use as pesticides 失效
标题翻译：杀螨剂，杀虫剂和杀线虫剂取代（杂）芳基烷基酮肟O-醚，其制备方法，含有它们的药剂及其作为农药的用途
公开(公告)号：US5728696A
公开(公告)日：1998-03-17
申请号：US460977
申请日：1995-06-05
申请人： Birgit Kuhn , Gerhard Salbeck, deceased , Uwe Doller , Stefan Schnatterer , Hans-Herbert Schubert , Werner Knauf , Anna Waltersdorfer , Manfred Kern
发明人： Birgit Kuhn , Gerhard Salbeck, deceased , Uwe Doller , Stefan Schnatterer , Hans-Herbert Schubert , Werner Knauf , Anna Waltersdorfer , Manfred Kern
IPC分类号： C07D239/26 , A01N35/10 , A01N37/32 , A01N43/06 , A01N43/08 , A01N43/10 , A01N43/32 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/74 , A01N43/78 , A01N43/82 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07D207/333 , C07D207/34 , C07D213/53 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/74 , C07D213/76 , C07D213/78 , C07D261/06 , C07D263/08 , C07D277/22 , C07D277/32 , C07D307/42 , C07D307/79 , C07D317/58 , C07D333/22 , C07D333/62 , C07D401/12 , C07D405/12 , C07D417/12 , C07D401/00 , A61K31/535 , A61K31/54 , C07D401/02 , C07D403/00 , C07D403/02
CPC分类号： C07D213/53 , A01N35/10 , A01N43/06 , A01N43/36 , A01N43/40 , A01N43/74 , A01N43/82 , C07C251/48 , C07C251/52 , C07C251/54 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/74 , C07D333/22 , C07D401/12 , C07D405/12 , C07D417/12
摘要： Acaricidal, insecticidal and nematicidal substituted (hetero)arylalkyl ketone oxime O-ethers, processes for their preparation, agents containing them, and their use as pesticides. The invention relates to compounds of the formula ##STR1## in which Ar.sup.1 and Ar.sup.2 are aryl or heteroaryl, each of which is optionally substituted, and R is an optionally substituted aliphatic or alicyclic radical, to processes for their preparation, and to agents containing these compounds, and to their use for controlling animal pests.
摘要翻译：杀螨剂，杀虫剂和杀线虫剂的取代（杂）芳基烷基酮肟O-醚，其制备方法，含有它们的药剂及其作为农药的用途。本发明涉及式（I）的化合物，其中Ar 1和Ar 2是任选被取代的芳基或杂芳基，R是任选取代的脂族或脂环族基团，用于其制备方法，以及含有这些化合物的药剂及其用于控制动物害虫的用途。

29. 发明授权

US5646147A Acaricidal, insecticidal and nematicidal substituted (hetero)arylalkyl ketone oxime O-ethers, processes for their preparation, agents containing them, and their use as pesticides 失效
标题翻译：杀螨剂，杀虫剂和杀线虫剂取代（杂）芳基烷基酮肟O-醚，其制备方法，含有它们的药剂及其作为农药的用途
公开(公告)号：US5646147A
公开(公告)日：1997-07-08
申请号：US230134
申请日：1994-04-20
申请人： Birgit Kuhn , Gerhard Salbeck, deceased , Uwe Doller , Stefan Schnatterer , Hans-Herbert Schubert , Werner Knauf , Anna Waltersdorfer , Manfred Kern
发明人： Birgit Kuhn , Gerhard Salbeck, deceased , Uwe Doller , Stefan Schnatterer , Hans-Herbert Schubert , Werner Knauf , Anna Waltersdorfer , Manfred Kern
IPC分类号： C07D239/26 , A01N35/10 , A01N37/32 , A01N43/06 , A01N43/08 , A01N43/10 , A01N43/32 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/74 , A01N43/78 , A01N43/82 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07D207/333 , C07D207/34 , C07D213/53 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/74 , C07D213/76 , C07D213/78 , C07D261/06 , C07D263/08 , C07D277/22 , C07D277/32 , C07D307/42 , C07D307/79 , C07D317/58 , C07D333/22 , C07D333/62 , C07D401/12 , C07D405/12 , C07D417/12 , C07D401/00 , A61K31/38 , A61K31/44 , A61K31/495 , A61K31/50 , C07D401/02 , C07D403/00 , C07D403/02
CPC分类号： C07D213/53 , A01N35/10 , A01N43/06 , A01N43/36 , A01N43/40 , A01N43/74 , A01N43/82 , C07C251/48 , C07C251/52 , C07C251/54 , C07D213/61 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/74 , C07D333/22 , C07D401/12 , C07D405/12 , C07D417/12
摘要： Acaricidal, insecticidal and nematicidal substituted (hetero)arylalkyl ketone oxime O-ethers, processes for their preparation, agents containing them, and their use as pesticides.The invention relates to compounds of the formula ##STR1## in which Ar.sup.1 and Ar.sup.2 are aryl or heteroaryl, each of which is optionally substituted, and R is an optionally substituted aliphatic or alicyclic radical, to processes for their preparation, and to agents containing these compounds, and to their use for controlling animal pests.
摘要翻译：杀螨剂，杀虫剂和杀线虫剂的取代（杂）芳基烷基酮肟O-醚，其制备方法，含有它们的药剂及其作为农药的用途。本发明涉及式（I）的化合物，其中Ar 1和Ar 2是任选被取代的芳基或杂芳基，R是任选取代的脂族或脂环族基团，用于其制备方法，以及含有这些化合物的药剂及其用于控制动物害虫的用途。

30. 发明授权

US5139785A Pesticides 失效
标题翻译：农药
公开(公告)号：US5139785A
公开(公告)日：1992-08-18
申请号：US657285
申请日：1991-02-19
申请人： Anna Waltersdorfer , Manfred Kern , Werner Knauf , Hans H. Schubert
发明人： Anna Waltersdorfer , Manfred Kern , Werner Knauf , Hans H. Schubert
IPC分类号： A01N55/00
CPC分类号： A01N55/00
摘要： Pesticides containing at least one compound of the formula I ##STR1## where M denotes carbon or silicon,X denotes CH.sub.2, O, S, NR.sup.6,R.sup.1 denotes (C.sub.2 -C.sub.18)alkyl, (C.sub.5 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, phenyl, naphthyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl, 1,2,4-triazinyl or 1,2,4,5-tetrazinyl, it being possible for all these substituents to be monosubstituted or polysubstituted,R.sup.2, R.sup.3 independently of one another denote (C.sub.1 -C.sub.3)alkyl, (C.sub.2 -C.sub.8)alkenyl or phenyl, or R.sup.2 and R.sup.3 denote an alkylene chain which--together with the quaternary central atom (M)--form an unsubstituted or fluorine-substituted ring having four to six ring members (where M=Si) or having three to six ring members (where M=C),R.sup.4 denotes --H, --CN, --CCl.sub.3, --C.tbd.CH, (C.sub.1 -C.sub.4)alkyl, F, ##STR2## R.sup.5 denotes pyridyl, furyl or thienyl, each of which can be substituted, phthalimidyl, di(C.sub.1 -C.sub.4)alkylmaleimidyl, thiophthalimidyl, dihydrophthalimidyl, tetrahydrophthalimidyl or substituted phenyl, or R.sup.4 and R.sup.5 --together with the carbon atom linking them--form an optionally substituted indanyl, cyclopentenoyl or cyclopentenyl radical, andR.sup.6 denotes H, (C.sub.1 -C.sub.3)alkyl or phenyl,in combination with a compound from the group comprising endosulfan (IX), buprofezin (X), cyromazine (XI), flubenzimine (XIII), flufenoxuron (XIII), deltamethrin (XIIIa), triazophos (XIIIb) and heptenophos (XIIIc), or a compound of the formula XIV ##STR3## where R.sub.15, R.sub.16, R.sub.17 and R.sub.18 independently of one another denote hydrogen or halogen,R.sub.19 denotes CH.sub.3, CF.sub.3 or halogen andR.sub.20 denotes (C.sub.1 -C.sub.3)haloalkyl, or a compound of the formula XV ##STR4## where R.sub.21 and R.sub.22 independently of one another denote H or halogen, show advantageous synergistic effects.
摘要翻译：含有至少一种式I化合物的农药，其中M表示碳或硅，X表示CH 2，O，S，NR 6，R 1表示（C 2 -C 18）烷基，（C 5 -C 7）环烷基，（C 2 -C 8 ）链烯基，苯基，萘基，吡啶基，嘧啶基，哒嗪基，吡嗪基，1,2,4-三嗪基或1,2,4,5-四嗪基，所有这些取代基可能是单取代或多取代的，R2，R3独立地彼此表示（C 1 -C 3）烷基，（C 2 -C 8）烯基或苯基，或者R 2和R 3表示亚烷基链，其与四元中心原子（M）一起形成未取代或氟取代的环，其具有四个至六个环成员（其中M = Si）或具有三至六个环成员（其中M = C），R4表示-H，-CN，-CCl3，-C3BCH，（C1-C4）烷基，图示R5表示吡啶基，呋喃基或噻吩基，其各自可以被取代，苯二酰亚氨基，二（C1-C4）烷基马来酰亚胺基，硫代邻苯二甲酰亚胺基，二氢邻苯二甲酰亚胺基，四氢邻苯二甲酰亚胺基或取代的苯基，或R4和R5与碳一起连接它们 - 形成任选取代的茚满基，环戊烯酰基或环戊烯基，R 6表示H，（C 1 -C 3）烷基或苯基，与来自包含硫丹（IX），布吡嗪（X），环丙嗪 XI），氟西坦（XIII），氟草酮（XIII），溴氰菊酯（XIIIa），三唑磷（XIIIb）和庚烯磷（XIIIc））或式XIV的化合物，其中R15，R16，R17和R18彼此独立地表示氢或卤素，R 19表示CH 3，CF 3或卤素，R 20表示（C 1 -C 3）卤代烷基，或其中R 21和R 22彼此独立地表示H或卤素的式XV化合物（XV）协同效应。

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