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21. 发明授权

US08658849B2 Process for the separation of unbranched hydrocarbons from their branched isomers 失效
标题翻译：从支链异构体中分离未分支烃的方法
公开(公告)号：US08658849B2
公开(公告)日：2014-02-25
申请号：US12668436
申请日：2008-06-30
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Ingo Richter , William Dolan , Frank Poplow
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Ingo Richter , William Dolan , Frank Poplow
IPC分类号： C07C7/13
CPC分类号： C07C7/12 , B01J20/22 , B01J20/226 , B01J2220/56 , C07C7/135 , C10G25/003 , C07C9/00
摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.
摘要翻译：本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括使流体混合物与吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环，衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基：的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，苯基和OC 1-6 - 烷基，其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，和OC 1-6烷基。本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。

22. 发明申请

US20110011805A1 POROUS METAL ORGANIC FRAMEWORKS AS DESICCANTS 审中-公开
标题翻译：多孔金属有机框架作为干燥剂
公开(公告)号：US20110011805A1
公开(公告)日：2011-01-20
申请号：US12863339
申请日：2009-01-23
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener
IPC分类号： B01D15/08
CPC分类号： B01J20/226 , B01D2253/204 , B01D2257/80 , B01J20/0233 , B01J2220/50
摘要： The present invention relates to the use of a porous metal organic framework comprising at least one at least bidentate organic compound coordinate to at least one metal ion as desiccant for reducing the water content of an organic liquid or for removing water from an organic liquid.
摘要翻译：本发明涉及多孔金属有机骨架的用途，所述多孔金属有机骨架包含至少一种至少二齿有机化合物与至少一种金属离子的配位作为干燥剂，用于降低有机液体的含水量或从有机液体中除去水分。

23. 发明授权

US07847115B2 Process for preparing porous organic framework materials 有权
标题翻译：制备多孔有机骨架材料的方法
公开(公告)号：US07847115B2
公开(公告)日：2010-12-07
申请号：US12161024
申请日：2007-02-08
申请人： Markus Schubert , Ulrich Mueller , Hendrick Mattenheimer
发明人： Markus Schubert , Ulrich Mueller , Hendrick Mattenheimer
IPC分类号： C07F3/00 , C07F15/00 , C07F5/02
CPC分类号： C07F3/003 , C07F19/005
摘要： The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.
摘要翻译：本发明涉及一种制备多孔有机骨架的方法，该方法通过在非水有机溶剂存在下和/或与水的释放下在包含合适的起始化合物的液相中反应混合物进行反应，其中后者在反应期间从反应混合物的液相中排出。这里，可以以可再现的方式获得比表面积相对较高的框架。

24. 发明申请

US20100154635A1 ALUMINIUM AMINOCAROBXYLATES AS POROUS METAL ORGANIC FRAMEWORKS 失效
标题翻译：作为多孔金属有机骨架的氨基铝酸铵
公开(公告)号：US20100154635A1
公开(公告)日：2010-06-24
申请号：US12601022
申请日：2008-05-20
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener
IPC分类号： B01D53/02 , C07F5/06
CPC分类号： B01D53/02 , B01D2253/204 , B01D2253/306 , B01D2257/108 , B01D2257/504 , B01D2257/702 , B01D2259/4525 , B01J20/226 , B01J20/28042 , B01J20/28066 , B01J20/30 , B01J31/1691 , B01J31/1805 , B01J31/2226 , B01J2531/31 , C07F5/069 , F17C11/00 , F17C11/005 , Y02C10/08 , Y02P20/152
摘要： The present invention relates to a porous metal organic framework comprising an at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is AlIII and the at least bidentate organic compound is an at least monoamino-substituted aromatic dicarboxylic acid selected from the group consisting of terephthalic acid, 2,6-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid and derivatives thereof in which at least one CH group in the ring has been replaced by nitrogen, wherein the framework in powder form has a specific surface area determined by the Langmuir method (N2, 77 K) of at least 2500 m2/g.In addition, the invention relates to shaped bodies comprising these materials, their preparation and their use for the storage and separation of gases.
摘要翻译：本发明涉及一种多孔金属有机骨架，其包含与至少一种金属离子配位的至少二齿有机化合物，其中至少一种金属离子是AlIII，并且该至少二齿有机化合物是至少一个氨基取代的芳族二羧酸选自对苯二甲酸，2,6-萘二甲酸，1,4-萘二甲酸，1,5-萘二甲酸及其衍生物的酸，其中环中的至少一个CH基团已被氮取代，其中粉末形式的框架具有由Langmuir方法（N2，77K）确定的至少2500m2 / g的比表面积。此外，本发明涉及包含这些材料的成型体，它们的制备及其用于储存和分离气体的用途。

25. 发明授权

US08313559B2 Aluminum aminocarboxylates as porous metal organic frameworks 失效
标题翻译：铝氨基羧酸铝作为多孔金属有机骨架
公开(公告)号：US08313559B2
公开(公告)日：2012-11-20
申请号：US12601022
申请日：2008-05-20
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener
IPC分类号： B01J20/28 , B01J20/30 , F17C11/00
CPC分类号： B01D53/02 , B01D2253/204 , B01D2253/306 , B01D2257/108 , B01D2257/504 , B01D2257/702 , B01D2259/4525 , B01J20/226 , B01J20/28042 , B01J20/28066 , B01J20/30 , B01J31/1691 , B01J31/1805 , B01J31/2226 , B01J2531/31 , C07F5/069 , F17C11/00 , F17C11/005 , Y02C10/08 , Y02P20/152
摘要： A porous metal organic framework containing an at least bidentate organic compound coordinated to a metal ion, wherein the metal ion is AlIII and the at least bidentate organic compound is 2-aminoterephthalic acid, and wherein the framework is in powder form and has a specific surface area determined by the Langmuir method (N2, 77 K) of at least 2500 m2/g. In addition, a shaped body containing the metal organic framework, processes for preparing the metal organic framework and shaped body, and processes for storing and separating gases with the metal organic framework and shaped body.
摘要翻译：一种多孔金属有机骨架，其含有与金属离子配位的至少二齿有机化合物，其中所述金属离子为AlIII，所述至少二齿有机化合物为2-氨基对苯二甲酸，并且其中所述骨架为粉末形式并具有比表面积由Langmuir法测定的面积（N2，77K）至少为2500m2 / g。此外，含有金属有机骨架的成形体，用于制备金属有机骨架和成形体的方法，以及用金属有机骨架和成形体储存和分离气体的方法。

26. 发明申请

US20100257873A1 METHOD FOR CONTROLLING THE WITHDRAWAL OF GAS 审中-公开
标题翻译：控制气体排放的方法
公开(公告)号：US20100257873A1
公开(公告)日：2010-10-14
申请号：US12746705
申请日：2008-11-17
申请人： Ulrich Mueller , Frank Poplow , Markus Schubert , Jan-Michael Graehn , Werner Gruenwald , Ian Faye
发明人： Ulrich Mueller , Frank Poplow , Markus Schubert , Jan-Michael Graehn , Werner Gruenwald , Ian Faye
IPC分类号： F17C11/00 , B65B3/00
CPC分类号： F17C11/005
摘要： The invention relates to a method for controlling the withdrawal of gas from a sorption reservoir. The temperature in the sorption reservoir having a decreasing amount of gas therein is increased until a maximum acceptable temperature is reached such that a predetermined minimum pressure in the sorption reservoir does not fall below that threshold. The invention also relates to a device for storing at least one gas, having a sorption reservoir that has at least one attachment via which the sorption reservoir can be filled with gas or via which gas can be withdrawn from the sorption reservoir. The invention also relates to a device having at least one heating element which can warm the sorption reservoir, also a control system that can increase the temperature in the sorption reservoir when withdrawing the gas in such a manner that a predetermined minimum temperature in the sorption reservoir is not fallen below in order to attain a maximum acceptable pressure.
摘要翻译：本发明涉及一种用于控制从吸附容器中排出气体的方法。吸附容器内的气体的温度降低，直至达到最大可接受的温度，使得吸附容器中的预定的最小压力不低于该阈值。本发明还涉及一种用于存储至少一种气体的装置，其具有吸附储存器，所述吸附储存器具有至少一个附件，吸附容器可通过该附件填充气体，或者可以通过该气体从吸附容器中排出气体。本发明还涉及一种具有至少一个加热元件的装置，该加热元件可以使吸附储存器温暖，也是一种控制系统，该控制系统可以在抽吸气体时增加吸附储存器中的温度，使得吸附储存器中的预定最小温度不能下降以达到最大可接受的压力。

27. 发明申请

US20100160661A1 PROCESS FOR PREPARING POROUS ORGANIC FRAMEWORK MATERIALS 有权
标题翻译：制备多孔有机骨架材料的方法
公开(公告)号：US20100160661A1
公开(公告)日：2010-06-24
申请号：US12161024
申请日：2007-02-08
申请人： Markus Schubert , Ulrich Mueller , Hendrick Mattenheimer
发明人： Markus Schubert , Ulrich Mueller , Hendrick Mattenheimer
IPC分类号： C07F3/06
CPC分类号： C07F3/003 , C07F19/005
摘要： The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.
摘要翻译：本发明涉及一种制备多孔有机骨架的方法，该方法通过在非水有机溶剂存在下和/或与水的释放下在包含合适的起始化合物的液相中反应混合物进行反应，其中后者在反应期间从反应混合物的液相中排出。这里，可以以可再现的方式获得比表面积相对较高的框架。

28. 发明申请

US20100029476A1 MAGNESIUM BUTYLISOPHTHALATE AS A POROUS METAL ORGANIC FRAMEWORK 审中-公开
标题翻译：作为多孔金属有机骨架的芒硝
公开(公告)号：US20100029476A1
公开(公告)日：2010-02-04
申请号：US12445322
申请日：2007-11-05
申请人： Natalia Trukhan , Ulrich Mueller , Markus Schubert
发明人： Natalia Trukhan , Ulrich Mueller , Markus Schubert
IPC分类号： C07C55/02 , B01J20/22
CPC分类号： B01J31/1691 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J2531/22 , C01B3/0015 , C01B6/003 , C01B7/00 , C01B13/0281 , C01B21/0455 , C01B23/0057 , C07C63/24 , C07F3/003 , F17C11/005 , Y02C10/08 , Y02E60/328
摘要： The present invention relates to a porous metal organic framework formed by Mg2+ ions to which 5-tert-butylisophthalate ions are coordinated to form a framework structure. The invention further provides a process for preparing it and its use, for example for the storage, separation or controlled release of a substance such as a gas or gas mixture.
摘要翻译：本发明涉及由Mg 2+离子形成的多孔金属有机骨架，其中5-叔丁基间苯二甲酸酯离子被配位以形成骨架结构。本发明进一步提供其制备方法及其用途，例如用于诸如气体或气体混合物的物质的储存，分离或控制释放。

29. 发明申请

US20090306420A1 PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS 审中-公开
标题翻译：制备包含金属有机骨架的方法
公开(公告)号：US20090306420A1
公开(公告)日：2009-12-10
申请号：US12375218
申请日：2007-07-13
申请人： Markus Schubert , Faruk Oezkirim , Christoph Kiener , Ulrich Mueller , Markus Tonigold
发明人： Markus Schubert , Faruk Oezkirim , Christoph Kiener , Ulrich Mueller , Markus Tonigold
IPC分类号： C07F1/08
CPC分类号： C07F1/005
摘要： The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.
摘要翻译：本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种铜离子配位的第一和至少一种第二至少二齿有机化合物，其包括以下步骤：（a）将反应混合物在液体包含至少一种铜化合物和第一至少二齿有机化合物以形成包含至少一种铜离子和第一至少二齿有机化合物的中间体络合物，第一至少二齿有机化合物衍生自二羧酸并且具有作为烃的骨架，和（b）中间体络合物与至少第二至少二齿有机化合物的反应，至少第二至少二齿有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳原子被杂原子所取代由N，O和S组成，其中步骤（a）中的反应混合物包含基于所使用的铜化合物的铜少于3倍过量的甲酸。

30. 发明申请

US20060167323A1 Two-stage method for producing butane diol with intermediated separation of succinic anhydride 失效
标题翻译：制备丁二酸酐中间分离丁二醇的两阶段方法
公开(公告)号：US20060167323A1
公开(公告)日：2006-07-27
申请号：US10516922
申请日：2003-06-11
申请人： Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rosch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rosch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： C07C31/18
CPC分类号： C07C29/149 , C07C31/207
摘要： The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C4-dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C4-dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 2 to 60 bar into a first reactor and catalytically hydrogenating it in the gas phase to a product which contains mainly optionally alkyl-substituted γ-butyrolactone; b) removing succinic anhydride from the product obtained in step a), preferably to a residual level of from
摘要翻译：本发明涉及通过在具有下列物质的C 4 - 二羧酸和/或其衍生物的气相中通过两阶段催化氢化制备任选的烷基取代的1,4-丁二醇的方法步骤：a）将200-300℃和2-60巴的C 4-14二羧酸或其衍生物的气流引入第一反应器，并将其催化氢化为气相至主要含有烷基取代的γ-丁内酯的产物; b）从步骤a）中获得的产物中除去琥珀酸酐，优选残留量为约0.3至0.2重量％; c）将步骤b）中获得的产物流在150℃至240℃的温度和15至100巴的压力下引入第二反应器，并将其在气相中催化氢化为任选的烷基 - 取代的1,4-丁二醇; d）从中间体，副产物和任何未转化的反应物中除去所需的产物; e）任选地将未转化的中间体再循环到一个或两个氢化步骤中，所述氢化步骤各自使用催化剂，所述催化剂包含95重量％，优选5至95重量％，特别是10至80重量％的CuO ，和> = 5重量％，优选5至95重量％，特别是20至90重量％的氧化载体，并且所述第二反应器具有比所述第一反应器更高的压力。

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