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    • 23. 发明申请
    • NANOTUBE-ENHANCED INTERLAYERS FOR COMPOSITE STRUCTURES
    • 纳米级增强复合结构中间层
    • US20140020825A1
    • 2014-01-23
    • US13587567
    • 2012-08-16
    • Thomas K. Tsotsis
    • Thomas K. Tsotsis
    • B29C70/02
    • B29C70/025B29C70/44B29C70/48B29C70/543B29K2105/167B32B5/26B32B5/28B32B27/04C09D7/70Y10T428/26
    • Carbon nanotube interlayer assemblies, methods of manufacturing carbon nanotube interlayer assemblies, and methods of manufacturing composite parts with carbon nanotube interlayer assemblies are disclosed herein. In one embodiment, a method of manufacturing a composite structure in accordance with an embodiment of the invention includes producing a plurality of carbon nanotubes on one or both sides of a substrate, and attaching the substrate to a first fiber layer. The method can further include positioning a second fiber layer adjacent to the first fiber layer to position the plurality of carbon nanotubes between the first and second fiber layers. The method can additionally include infusing the first and second fiber layers with resin, and curing the resin. In one embodiment, the carbon nanotube substrate can be attached to the first fiber layer by melt-bonding. In another embodiment, the carbon nanotube substrate can be attached to the first fiber layer with stitches.
    • 本文公开了碳纳米管夹层组件,制造碳纳米管中间层组件的方法,以及制造具有碳纳米管夹层组件的复合部件的方法。 在一个实施例中,根据本发明的实施例的制造复合结构的方法包括在基板的一侧或两侧制造多个碳纳米管,并将基板附接到第一纤维层。 该方法还可以包括将邻近第一纤维层的第二纤维层定位以将多个碳纳米管定位在第一和第二纤维层之间。 该方法还可以包括用树脂浸渍第一和第二纤维层并固化树脂。 在一个实施方案中,可以通过熔融粘合将碳纳米管基底附接到第一纤维层。 在另一个实施例中,碳纳米管基底可以用针迹附接到第一纤维层。
    • 25. 发明授权
    • Polyacetylinic oligomers
    • 聚乙炔低聚物
    • US08106142B2
    • 2012-01-31
    • US12582394
    • 2009-10-20
    • Thomas K. TsotsisNorman R. Byrd
    • Thomas K. TsotsisNorman R. Byrd
    • C08G8/26
    • C08G73/101C08G63/21C08L79/08
    • Polyacetylinic oligomers suitable for high-temperature polymer-matrix composites are provided. The polyacetylinic oligomers have the formula: D-A-D wherein D is an endcap including at least one crosslinking functionality; and A is backbone selected from the group consisting of imidesulfone; ether; ethersulfone; amide; imide; ester; estersulfone; etherimide; amideimide; oxazole; oxazole sulfone; thiazole; thiazole sulfone; imidazole; and imidazole sulfone. At least one ethynyl functional group, however, is incorporated into the backbone such that crosslinking is not only realized at the endcaps but also at the ethynyl groups within the backbone of the oligomer itself.
    • 提供了适用于高温聚合物基质复合材料的聚乙炔低聚物。 聚乙炔低聚物具有下式:D-A-D其中D是包含至少一个交联官能团的端基; A是选自由亚胺砜组成的组的骨架; 醚; 醚砜; 酰胺; 酰亚胺 酯; 酯砜; 醚酰亚胺; 酰胺酰亚胺; 恶唑 恶唑砜 噻唑 噻唑砜 咪唑 和咪唑砜。 然而,至少一个乙炔基官能团被引入到主链中,使得交联不仅在末端封端实现,而且在低聚物本身的主链内的乙炔基上实现。
    • 26. 发明申请
    • POLYACETYLINIC OLIGOMERS
    • 聚乙烯醇低聚物
    • US20100204485A1
    • 2010-08-12
    • US12582394
    • 2009-10-20
    • Thomas K. TsotsisNorman R. Byrd
    • Thomas K. TsotsisNorman R. Byrd
    • C07D209/60
    • C08G73/101C08G63/21C08L79/08
    • Polyacetylinic oligomers suitable for high-temperature polymer-matrix composites are provided. The polyacetylinic oligomers have the formula: D-A-D wherein D is an endcap including at least one crosslinking functionality; and A is backbone selected from the group consisting of imidesulfone; ether; ethersulfone; amide; imide; ester; estersulfone; etherimide; amideimide; oxazole; oxazole sulfone; thiazole; thiazole sulfone; imidazole; and imidazole sulfone. At least one ethynyl functional group, however, is incorporated into the backbone such that crosslinking is not only realized at the endcaps but also at the ethynyl groups within the backbone of the oligomer itself.
    • 提供了适用于高温聚合物基质复合材料的聚乙炔低聚物。 聚乙炔低聚物具有下式:D-A-D其中D是包含至少一个交联官能团的端基; A是选自由亚胺砜组成的组的骨架; 醚; 醚砜; 酰胺; 酰亚胺 酯; 酯砜; 醚酰亚胺; 酰胺酰亚胺; 恶唑 恶唑砜 噻唑 噻唑砜 咪唑 和咪唑砜。 然而,至少一个乙炔基官能团被引入到主链中,使得交联不仅在末端封端实现,而且在低聚物本身的主链内的乙炔基上实现。