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21. 发明授权

US07091384B2 Process for increasing the selectivity of the hydrogenation of 4,4′-diaminodiphenylmethane to 4,4′-diaminodicyclohexylmethane in the presence of an N-alkyl-4,4′-diaminodiphenylmethane 有权
标题翻译：在N-烷基-4,4'-二氨基二苯基甲烷存在下增加4,4'-二氨基二苯基甲烷氢化为4,4'-二氨基二环己基甲烷的选择性的方法
公开(公告)号：US07091384B2
公开(公告)日：2006-08-15
申请号：US10516319
申请日：2003-06-25
申请人： Bernd Jaeger , Thomas Haas , Guido Stochniol , Christian Lettmann , Willi Hofen , Klaus Stadtmueller , Joerg Lotz
发明人： Bernd Jaeger , Thomas Haas , Guido Stochniol , Christian Lettmann , Willi Hofen , Klaus Stadtmueller , Joerg Lotz
IPC分类号： C07C209/72
CPC分类号： C07C209/72 , C07C211/36
摘要： The invention relates to a process for increasing the selectivity of the hydrogenation of 4,4′-diaminodiphenylmethane (4,4′-MDA) to diaminodicyclohexylmethane (4,4′-HMDA) by catalytic hydrogenation of a mixture containing 4,4′-MDA as the main component and its mono-N-methyl derivative as a secondary component. According to the invention, the hydrogenation is terminated before a conversion of 4,4′-MDA to 4,4′-HMDA of 99% is achieved. Under these conditions, a substantially smaller proportion of the N-methyl-4,4′-MDA is hydrogenated to N-methyl-4,4-HMDA.
摘要翻译：本发明涉及通过催化氢化含有4,4'-二氨基二苯基甲烷（4,4'-MDA）的混合物的方法提高4,4'-二氨基二苯基甲烷（4,4'-MDA） MDA为主要成分，其单-N-甲基衍生物为次要成分。根据本发明，在将4,4'-MDA转化为99％的4,4'-HMDA之前终止氢化。在这些条件下，将大部分比例的N-甲基-4,4'-MDA氢化成N-甲基-4,4-HMDA。

22. 发明申请

US20060079717A1 Process for hydrogenating an aromatic amine in the presence of a supported ruthenium catalyst 有权
公开(公告)号：US20060079717A1
公开(公告)日：2006-04-13
申请号：US11284932
申请日：2005-11-23
申请人： Guido Stochniol , Bernd Jaeger , Thomas Haas , Norbert Finke , Werner Burkhardt , Juergen Grunert
发明人： Guido Stochniol , Bernd Jaeger , Thomas Haas , Norbert Finke , Werner Burkhardt , Juergen Grunert
IPC分类号： C07C209/72
CPC分类号： C07C209/72 , B01J23/462 , B01J35/10 , B01J35/108 , C07C2601/14 , C07C211/36
摘要： The invention relates to a process for hydrogenating an aromatic amine that has at least one amino group bound to an aromatic nucleus with hydrogen in the presence of a supported catalyst that contains at least ruthenium as active metal. The catalyst support has a BET surface area in the range from greater than 30 m2/g to less than 70 m2/g and more than 50% of the pore volume of the catalyst support is formed by macropores having a pore diameter of greater than 50 nm and less than 50% are mesopores having a pore diameter of 2 to 50 nm.

23. 发明申请

US20050063896A1 Process for the production of hydrogen peroxide 有权
标题翻译：过氧化氢生产工艺
公开(公告)号：US20050063896A1
公开(公告)日：2005-03-24
申请号：US10476202
申请日：2003-03-04
申请人： Bernd Jaeger , Thomas Haas , Jurgen Glenneberg , Jurgen Grunert
发明人： Bernd Jaeger , Thomas Haas , Jurgen Glenneberg , Jurgen Grunert
IPC分类号： B01J23/96 , B01J35/02 , C01B15/023
CPC分类号： C01B15/023 , B01J23/96 , B01J35/023 , Y02P20/584
摘要： The invention relates to a process for the production of hydrogen peroxide by the anthraquinone process, comprising a hydrogenation stage, an oxidation stage and an extraction stage. According to the invention, catalytic hydrogenation of anthraquinone derivatives dissolved in a working solution is carried out in the presence of added molecular oxygen. Per mol hydrogen, 0.1 to 10 mmol oxygen is preferably introduced into the hydrogenation stage with the hydrogenating gas, in mixture with an inert gas and/or dissolved and/or dispersed in the working solution. This increases the residence time of the catalyst.
摘要翻译：本发明涉及一种通过蒽醌法生产过氧化氢的方法，包括氢化阶段，氧化阶段和萃取阶段。根据本发明，溶解在工作溶液中的蒽醌衍生物的催化氢化在加入的分子氧的存在下进行。每摩尔氢气，优选将0.1至10mmol氧气与氢化气体一起引入氢化阶段，与惰性气体混合和/或溶解和/或分散在工作溶液中。这增加了催化剂的停留时间。

24. 发明授权

US10450590B2 Process for preparing an alpha, omega-alkanediol 有权
公开(公告)号：US10450590B2
公开(公告)日：2019-10-22
申请号：US14763378
申请日：2014-01-10
申请人： Thomas Haas , Philip Engel , Jan Christoph Pfeffer , Oliver Thum , Christian Gehring
发明人： Thomas Haas , Philip Engel , Jan Christoph Pfeffer , Oliver Thum , Christian Gehring
IPC分类号： C12P7/18 , C07C67/08 , C07C29/136 , C12P7/62
摘要： The invention relates to a process for preparing an α,ω-alkanediol comprising the steps of a) reacting an alkanoic acid with an alkanol to give an ester, b) oxidizing at least one terminal carbon atom of the ester by contacting with a whole-cell catalyst, which expresses an alkane hydroxylase, in aqueous solution and in the presence of molecular oxygen, to give an oxidized ester, c) hydrogenating the oxidized ester to form the alkanediol and alkanol, and d) removing the alkanol by distillation, forming a reaction mixture depleted with respect to the alkanol, and recycling the alkanol in step b).

25. 发明申请

US20180142266A1 A METHOD OF PRODUCING ALCOHOLS 审中-公开
公开(公告)号：US20180142266A1
公开(公告)日：2018-05-24
申请号：US15579442
申请日：2016-06-10
申请人： Thomas Haas , Anja Hecker , Stefan Gilch , Thomas Bülter
发明人： Thomas Haas , Anja Hecker , Stefan Gilch , Thomas Bülter
IPC分类号： C12P7/04 , C12N9/02 , C12N9/04 , C12P7/16
CPC分类号： C12P7/04 , C12N9/0006 , C12N9/0008 , C12N15/52 , C12P7/16 , C12P7/40 , C12P7/62 , C12Y101/01001 , C12Y102/0101 , Y02E50/10
摘要： There is provided a microbial cell which is capable of producing at least one higher alcohol, wherein the microbial cell is genetically modified to include an increased expression relative to its wild type cell of at least one acyl-CoA reductase (E11). In particular, there is provided a microbial cell capable of producing at least one higher alcohol, wherein the microbial cell is genetically modified to include an increased expression relative to its wild type cell of at least one acyl-CoA reductase (E11) and wherein the cell is capable of producing a carboxylic acid and/or ester thereof using ethanol-carboxylate fermentation.

26. 发明授权

US09150890B2 Candida tropicalis cells and use thereof 有权
公开(公告)号：US09150890B2
公开(公告)日：2015-10-06
申请号：US14609714
申请日：2015-01-30
申请人： Markus Poetter , Hans-Georg Hennemann , Steffen Schaffer , Thomas Haas
发明人： Markus Poetter , Hans-Georg Hennemann , Steffen Schaffer , Thomas Haas
IPC分类号： C12P7/62 , C12N1/16 , C12N9/02 , C12P7/42 , C12P13/04 , C07C51/347 , C07C67/42 , C07C227/06 , C07C227/08
CPC分类号： C12P7/62 , C07C51/347 , C07C67/42 , C07C227/06 , C07C227/08 , C12N1/16 , C12N9/004 , C12N9/0042 , C12P7/42 , C12P7/625 , C12P13/04 , C12Y101/01001
摘要： The invention relates to genetically engineered Candida tropicalis cells, use thereof and a method of production of ω-hydroxycarboxylic acids and ω-hydroxycarboxylic acid esters.

27. 发明授权

US09108473B2 Method for the operation of wheel electronics, wheel electronics, and tire checking system 有权
标题翻译：车轮电子，车轮电子和轮胎检查系统的运行方法
公开(公告)号：US09108473B2
公开(公告)日：2015-08-18
申请号：US12675910
申请日：2008-08-21
申请人： Thomas Haas , Gregor Kuchler
发明人： Thomas Haas , Gregor Kuchler
IPC分类号： B60C23/00 , B60C23/04
CPC分类号： B60C23/041 , B60C23/0462
摘要： A method for operating wheel electronics of a tire checking system includes providing wheel electronics having a battery-free power supply encompassing at least one rechargeable power storage medium for supplying power to the wheel electronics. The wheel electronics can be operated in a reduced-power transmission mode and a subsequent normal transmission mode. In the modes, data that relate to tire-specific parameters and are determined by the wheel electronics are transmitted to a vehicle-mounted communication device in the form of modulated transmission signals, with less transmission power being used for the transmission signals in the power-reduced transmission mode than in the normal transmission mode. Wheel electronics and a tire checking system are also provided.
摘要翻译：一种用于操作轮胎检查系统的轮子电子装置的方法包括提供具有无电池电源的车轮电子装置，其包含用于向车轮电子装置供电的至少一个可再充电电力存储介质。车轮电子装置可以在低功率传输模式和随后的正常传输模式下工作。在这些模式中，与轮胎特定参数相关并且由车轮电子装置确定的数据以调制传输信号的形式发送到车载通信装置，其中较少的发射功率被用于功率传输信号中的传输信号，传输模式比正常传输模式低。还提供车轮电子和轮胎检查系统。

28. 发明申请

US20150209775A1 BRANCHED-CHAIN FATTY ACIDS AS LIQUID CATION EXCHANGERS 有权
标题翻译：分支链脂肪酸作为液体交换剂
公开(公告)号：US20150209775A1
公开(公告)日：2015-07-30
申请号：US14419580
申请日：2013-07-24
申请人： Frank Erhardt , Lukas Falke , Ralf Kelle , Harald Haeger , Thomas Haas , Hans-Georg Hennemann , Oliver Thum , Martin Roos , Markus Poetter
发明人： Frank Erhardt , Lukas Falke , Ralf Kelle , Harald Haeger , Thomas Haas , Hans-Georg Hennemann , Oliver Thum , Martin Roos , Markus Poetter
IPC分类号： B01J39/04 , B01J39/16 , C07C209/90
CPC分类号： B01J39/04 , B01J39/16 , C02F1/26 , C02F1/42 , C02F2001/425 , C02F2101/30 , C02F2101/38 , C02F2103/36 , C07C209/84 , C07C209/90 , C07C227/40 , C07C2601/14
摘要： The present invention relates to a method for removing an organic compound from an aqueous solution, comprising the steps of providing the aqueous solution which contains the organic compound, and a hydrophobic organic solution, where the latter comprises a liquid hydrophobic cation exchanger, contacting the aqueous solution and the hydrophobic organic solution, and separating off the hydrophobic organic solution from the aqueous solution, wherein the liquid hydrophobic cation exchanger is a saturated alkanoic acid having at least one alkyl substituent, where the organic compound is an organic compound having at least one positive charge and a neutral or positive total charge.
摘要翻译：本发明涉及一种从水溶液中除去有机化合物的方法，包括提供含有有机化合物的水溶液和疏水性有机溶液的步骤，其中后者包括液体疏水性阳离子交换剂，溶液和疏水性有机溶液，并从水溶液中分离疏水性有机溶液，其中液体疏水性阳离子交换剂是具有至少一个烷基取代基的饱和链烷酸，其中有机化合物是具有至少一个阳性的有机化合物充电和中性或正电荷。

29. 发明申请

US20150111253A1 ENZYMATIC OMEGA-OXIDATION AND OMEGA-AMINATION OF FATTY ACIDS 有权
标题翻译：脂肪酸的氧化欧米茄氧化和欧米加氨基酸
公开(公告)号：US20150111253A1
公开(公告)日：2015-04-23
申请号：US14384301
申请日：2013-03-12
申请人： Steffen Schaffer , Michaela Hauberg , Mirja Wessel , Hans-Georg Hennemann , Jan Christoph Pfeffer , Thomas Haas , Harald Haeger
发明人： Steffen Schaffer , Michaela Hauberg , Mirja Wessel , Hans-Georg Hennemann , Jan Christoph Pfeffer , Thomas Haas , Harald Haeger
IPC分类号： C12P7/64 , C07K14/21
CPC分类号： C12P7/6436 , C07K14/21 , C07K14/79 , C12N9/0006 , C12N9/0016 , C12N9/0077 , C12N9/0095 , C12N9/1096 , C12P7/42 , C12P7/62 , C12P7/6409 , C12P13/005 , C12Y114/14001
摘要： The invention relates to a method for oxidizing a fatty acid or an ester thereof of formula (I) H3C—(CH2)n-COOR, wherein R is selected from the group that comprises H, methyl, ethyl, propyl, and butyl, wherein n is 0 to 30, preferably 6 to 24, comprising the step of oxidizing the fatty acid or the ester thereof by contacting the fatty acid or the ester thereof with a cytochrome P450 monooxygenase of the CYP153 family in the presence of molecular oxygen and NAD(P)H and a whole-cell catalyst that expresses a recombinant cytochrome P450 monooxygenase of the CYP153 family, a recombinant alcohol dehydrogenase, a recombinant transaminase, and optionally one or more than one recombinant enzyme from the group comprising alanine dehydrogenase, ferredoxin, and ferredoxin reductase, and the use of said whole-cell catalyst to oxidize a fatty acid or an ester thereof.
摘要翻译：本发明涉及一种氧化式（I）的H3C-（CH2）n-COOR的脂肪酸或其酯的方法，其中R选自H，甲基，乙基，丙基和丁基，其中 n为0至30，优选6至24，包括通过在分子氧和NAD存在下使脂肪酸或其酯与CYP153家族的细胞色素P450单加氧酶接触来氧化脂肪酸或其酯的步骤 P）H和表达CYP153家族的重组细胞色素P450单加氧酶，重组醇脱氢酶，重组转氨酶以及任选的一种或多于一种重组酶的全细胞催化剂，其包含丙氨酸脱氢酶，铁氧还蛋白和铁氧还蛋白还原酶，以及所述全细胞催化剂用于氧化脂肪酸或其酯的用途。

30. 发明授权

US08840797B2 Multilayer ceramic structure and method for producing the same 有权
标题翻译：多层陶瓷结构及其制造方法
公开(公告)号：US08840797B2
公开(公告)日：2014-09-23
申请号：US13542746
申请日：2012-07-06
申请人： Thomas Haas , Dieter Schwanke , Achim Bittner , Ulrich Schmid
发明人： Thomas Haas , Dieter Schwanke , Achim Bittner , Ulrich Schmid
IPC分类号： C03C15/00
CPC分类号： H01L23/49822 , B32B18/00 , C03C15/00 , C04B2235/656 , C04B2237/32 , C04B2237/64 , C04B2237/68 , C04B2237/704 , H01L21/4807 , H01L23/473 , H01L2924/0002 , Y10T428/249953 , H01L2924/00
摘要： A unique and cost-effective method for producing a multilayer ceramic structure by using a first green film that contains a ceramic material, and the multilayer ceramic structure produced thereby. The method including the steps of:(a) producing at least one porous region in the first green film, the at least one porous region extending from the surface of the first green film;(b) applying a first layer, in sections, to the surface of the first green film, wherein one section of the first layer is located above the at least one porous region produced in step (a);(c) positioning at least one additional green film on the surface of the first green film, to which the first layer has been applied;(d) laminating the first green film and the at least one additional green film to form a green film composite; and(e) sintering the green film composite.
摘要翻译：通过使用包含陶瓷材料的第一生坯膜和由此制造的多层陶瓷结构来制造多层陶瓷结构的独特且成本有效的方法。该方法包括以下步骤：（a）在第一生坯膜中产生至少一个多孔区域，至少一个从第一绿膜表面延伸的多孔区域; （b）将第一层分段施加到第一生坯膜的表面，其中第一层的一个部分位于步骤（a）中产生的至少一个多孔区域上方; （c）在已经施加了第一层的第一绿色膜的表面上定位至少一个附加的绿色膜; （d）层压第一生坯膜和至少一层附加的生膜以形成绿膜复合材料; 和（e）烧结绿色膜复合材料。

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