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21. 发明授权

US4980458A Mixed sodium, ammonium and/or calcium salt crystals of laked monoazo disulfonated pyrazolone pigments 失效
标题翻译：浸渍的单偶氮二磺化吡唑啉酮颜料的混合的钠，铵和/或钙盐晶体
公开(公告)号：US4980458A
公开(公告)日：1990-12-25
申请号：US349907
申请日：1989-05-08
申请人： Stefan Hari , Arnold Grubenmann , Andreas Burkhard
发明人： Stefan Hari , Arnold Grubenmann , Andreas Burkhard
IPC分类号： C09B67/48 , C08K5/22 , C08K5/23 , C08K5/41 , C08K5/42 , C09B63/00 , C09B67/22 , C09B69/02
CPC分类号： C09B67/0051 , C09B69/02 , Y10S534/01
摘要： Mixed crystals of at least two different compounds of formula I ##STR1## wherein R is --CH.sub.3, phenyl, --COOCH.sub.3, --COOCH.sub.3, --COOC.sub.2 H.sub.5, --NHCO--C.sub.1 -C.sub.4 alkyl or --CONH--C.sub.1 -C.sub.4 alkyl, M.sup.+ and M.sub.1.sup.+ are each independently of the other an alkali metal cation, an alkaline earth metal cation or a heavy metal cation or NH.sub.4.sup.+ ; wherein X, Y, X' and Y' are each independently hydrogen, halogen, --CH.sub.3, --C.sub.2 H.sub.5, --OCH.sub.3, --OC.sub.2 H.sub.5, --NO.sub.2 or the group of formula --NHCO--C.sub.1 -C.sub.4 alkyl, wherein at least two of the cations M.sup.+ and M.sub.1.sup.+ in the compounds forming the mixed crystals of formula I are different and the X-ray diffraction patterns of the mixed crystals differ from the X-ray diffraction patterns of the individual components and of their sum. Such mixed crystals are most suitable as pigments for coloring high molecular organic material and are distinguished in particular by surprisingly high color strength and pure shade.
摘要翻译：至少两种不同的式I化合物的混合晶体（I）其中R是-CH 3，苯基，-COOCH 3，-COOCH 3，-COOC 2 H 5，-NHCO-C 1 -C 4烷基或-CONH-C 1 -C 4烷基， M +和M1 +各自独立地为碱金属阳离子，碱土金属阳离子或重金属阳离子或NH4 +; 其中X，Y，X'和Y'各自独立地为氢，卤素，-CH 3，-C 2 H 5，-OCH 3，-OC 2 H 5，-NO 2或式-NHCO-C 1 -C 4烷基的基团，其中至少两个形成式I的混合晶体的化合物中的阳离子M +和M1 +是不同的，并且混晶的X射线衍射图与各个组分的X射线衍射图和它们的和不同。这种混合晶体最适合作为着色高分子有机材料的颜料，特别是出人意料地高的着色强度和纯净的色调。

22. 发明授权

US4737581A Phenyl-azo-hydroxynaphthoic acid amide pigments containing at least one carbonamide group 失效
标题翻译：含有至少一个碳酰胺基团的苯基偶氮羟基萘甲酸酰胺颜料
公开(公告)号：US4737581A
公开(公告)日：1988-04-12
申请号：US724424
申请日：1985-04-18
申请人： Stefan Hari
发明人： Stefan Hari
IPC分类号： C08K5/23 , C09B29/20 , C09B67/48 , D06P1/04 , D06P1/44
CPC分类号： C09B29/20 , C08K5/23
摘要： Azo compounds of the formula I ##STR1## wherein X is --H, --CH.sub.3, --CF.sub.3, --NO.sub.2, --COOR.sub.1, --NHCOR.sub.2 or --COHN.sub.2, and R.sub.1 and R.sub.2 are as defined in claim 1, are suitable for pigmenting high-molecular organic material.
摘要翻译：式I的偶氮化合物其中X是-H，-CH 3，-CF 3，-NO 2，-COOR 1，-NHCOR 2或-COHN 2，R 1和R 2如权利要求1中所定义，它们适用于着色高分子有机材料。

23. 发明授权

US4602961A Process for pigmenting high molecular weight organic material 失效
标题翻译：高分子量有机材料着色方法
公开(公告)号：US4602961A
公开(公告)日：1986-07-29
申请号：US648190
申请日：1984-09-07
申请人： Stefan Hari
发明人： Stefan Hari
IPC分类号： C08K5/00 , C08K5/45 , C08K5/46 , C08K5/47 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L67/00 , C09B29/33 , C08J3/20
CPC分类号： C09B29/338 , C08K5/47
摘要： A process for pigmenting high molecular weight organic material, which comprises using, as pigment, a monoazo compound of the formula ##STR1## wherein A is a carbocyclic aromatic radical, R is an aliphatic, cycloaliphatic, araliphatic or aromatic radical or an alkoxy group, and Q is a hydrogen or a halogen atom or a methyl group.The colorations obtained, for example in plastics, filaments, lacquers and prints, have very high color strength, high saturation, good dispersibility, good fastness to overspraying, migration, heat, light and atmospheric influences, and good gloss.
摘要翻译：用于着色高分子量有机材料的方法，其包括使用下式的单偶氮化合物作为颜料：其中A是碳环芳族基团，R是脂族，脂环族，芳脂族或芳族基团或烷氧基，Q为氢或卤素原子或甲基。获得的着色例如在塑料，细丝，漆和印刷品中具有非常高的着色强度，高饱和度，良好的分散性，良好的耐喷涂性，迁移性，耐热性，光和大气影响以及良好的光泽度。

24. 发明授权

US4400319A Monoazo pigments containing heterocycles, and high-molecular organic materials dyed therewith 失效
标题翻译：含有杂环的单偶氮颜料和与其染色的高分子有机材料
公开(公告)号：US4400319A
公开(公告)日：1983-08-23
申请号：US305305
申请日：1981-09-24
申请人： Stefan Hari , Arnold Wick
发明人： Stefan Hari , Arnold Wick
IPC分类号： C08K5/00 , C08K5/45 , C08K5/46 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09B29/033 , C09B29/33 , C09B29/34 , C09B29/32
CPC分类号： C09B29/338 , C09B29/0025 , Y10S534/01
摘要： Compounds of the formula I ##STR1## wherein the symbols Z, R.sub.1, R.sub.2, m and n have the meanings defined in claim 1, are suitable, as high-grade pigments, for dyeing high-molecular organic material. They are characterized in particular by good fastness to migration and to cross-lacquering, as well as to weather and light.
摘要翻译：其中符号Z，R1，R2，m和n具有权利要求1中定义的含义的式I的化合物（I）适用于高分子颜料用于染色高分子有机材料。它们的特征特别是具有良好的移动牢度和交叉漆，以及天气和光线。

25. 发明授权

US4263205A Monoazo pigments derived from substituted aminothiophenes 失效
标题翻译：衍生自取代的氨基噻吩的单偶氮颜料
公开(公告)号：US4263205A
公开(公告)日：1981-04-21
申请号：US44123
申请日：1979-05-31
申请人： Stefan Hari
发明人： Stefan Hari
IPC分类号： C09B29/20 , C09B43/32 , D06P3/00 , C09B29/22 , C09D3/48 , C09D11/02
CPC分类号： C09B43/32 , C09B29/20
摘要： Monoazo pigments of the formula I ##STR1## in which R is the radical of a carbocyclic or heterocyclic aromatic amine and R.sub.1, R.sub.2 and R.sub.3 are hydrogen, halogen, alkyl, alkoxy, alkoxycarbonyl, substituted or unsubstituted aminocarbonyl, nitro, cyano or trifluoromethyl. These pigments are suitable for coloring high molecular weight organic material and are distinguished by their easy accessibility and good general fastness properties and in particular by high clarity of color shade.
摘要翻译：式I的单偶氮颜料（I）其中R是碳环或杂环芳族胺基团，R 1，R 2和R 3是氢，卤素，烷基，烷氧基，烷氧基羰基，取代或未取代的氨基羰基，硝基，氰基或三氟甲基。这些颜料适用于着色高分子量有机材料，其特征在于它们易于获得和良好的通用牢度特性，特别是通过色度的高清晰度。

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