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    • 25. 发明授权
    • Modified magnesium based hydrogen storage alloys
    • 改性镁基储氢合金
    • US06328821B1
    • 2001-12-11
    • US09444812
    • 1999-11-22
    • Stanford R. OvshinskyRosa T. Young
    • Stanford R. OvshinskyRosa T. Young
    • C22C2300
    • C01B3/0031B22F2998/00C01B3/0047C22C1/0408C22C23/00C22C23/06H01M4/383H01M4/46H01M8/065Y02E60/327Y10S420/90B22F9/10
    • A magnesium based hydrogen storage alloy powder which is useful as a hydrogen supply material for powering internal combustion engine or fuel cell vehicles. The alloy contains greater than about 85 atomic percent magnesium, about 2-8 atomic percent nickel, about 0.5-5 atomic percent aluminum and about 2-7 atomic percent rare earth metals or mixtures of rare earth metals. The rare earth elements may be Misch metal and may predominantly contain Ce and/or La. The alloy may also contain about 0.5-5 atomic percent silicon. The alloys can be modified to store more than 4 wt. % hydrogen, with a reduced hydride bond strength (i.e. about 64 kJ/mole) which allows for economic recovery of the stored hydrogen. Also, they have a plateau pressure about two times greater than pure Mg and comparable bond energies and plateau pressures to Mg2Ni alloys, while reducing the amount of incorporated nickel by 25-30 atomic %. Also, the storage capacity of the alloy is significantly greater than the 3.6 wt. % of Mg2Ni material.
    • 一种镁基储氢合金粉末,其可用作为内燃机或燃料电池车辆供电的氢供应材料。 该合金含有大于约85原子%的镁,约2-8原子%的镍,约0.5-5原子%的铝和约2-7原子%的稀土金属或稀土金属的混合物。 稀土元素可以是杂质金属,并且可以主要含有Ce和/或La。合金还可以含有约0.5-5原子%的硅。 可以将合金改性以储存超过4wt。 %氢,具有降低的氢化物键强度(即约64kJ /摩尔),其允许储存的氢的经济回收。 此外,它们的平台压力比纯Mg高大约两倍,并且对Mg2Ni合金具有相当的粘结能和平台压力,同时将引入的镍的量减少25-30原子%。 此外,合金的储存容量明显大于3.6wt。 %的Mg2Ni材料。
    • 26. 发明授权
    • Solid state battery having a disordered hydrogenated carbon negative
electrode
    • 具有无序氢化碳负极的固态电池
    • US5985485A
    • 1999-11-16
    • US831150
    • 1997-04-01
    • Stanford R. OvshinskyRosa T. Young
    • Stanford R. OvshinskyRosa T. Young
    • H01M4/58H01M6/18H01M10/36H01M2/30
    • H01M10/0525H01M10/0562H01M4/587H01M6/188
    • A solid state battery comprising a substrate; at least one multilayered electrochemical cell deposited onto the substrate, each multilayered electrochemical cell comprising: a layer of disordered hydrogenated carbon material negative electrode material capable of electrochemically adsorbing and desorbing lithium ions or both lithium and hydrogen ions during charge and discharge; a layer of positive electrode material capable of electrochemically desorbing and adsorbing lithium ions or both lithium and hydrogen ions during charge and discharge; and a layer of insulating/conducting material disposed between the layer of positive electrode material and the layer of negative electrode material, where the layer of insulating/conducting material is electrically insulating and capable of readily conducting or transporting lithium ions or both lithium and hydrogen ions from the layer positive electrode material to the layer of negative electrode material while the battery is charging and from the layer of negative electrode material to the layer of positive electrode material while the battery is discharging; and an electrically conductive layer deposited a top the last of the at least one multilayered electrochemical cells, the electrically conductive layer providing one battery terminal.
    • 一种固态电池,包括基板; 每个多层电化学电池包括:在充电和放电期间能够电化学吸附和解吸锂离子或锂离子和氢离子的无序氢化碳材料负极材料层;至少一层多层电化学电池, 能够在充放电期间电解吸附和吸附锂离子或锂离子和氢离子的正极材料层; 以及设置在正极材料层和负极材料层之间的绝缘/导电材料层,其中绝缘/导电材料层是电绝缘的并且能够容易地导电或输送锂离子或锂离子和氢离子 在电池正在充电时,从正极材料层到负极材料层,在电池放电时从负极材料层到正极材料层; 并且导电层在所述至少一个多层电化学电池中的最后一层沉积顶部,所述导电层提供一个电池端子。