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21. 发明申请

US20140031501A1 PROCESS FOR THE PRODUCTION OF (METH)ACRYLIC ACID AND DERIVATIVES AND POLYERS PRODUCED THEREFROM 有权
标题翻译：生产（甲基）丙烯酸及其衍生物的方法及其生产的聚合物
公开(公告)号：US20140031501A1
公开(公告)日：2014-01-30
申请号：US13984473
申请日：2012-02-08
申请人： David William Johnson , Graham Ronald Eastham , Martyn Poliakoff , Thomas Andrew Huddle
发明人： David William Johnson , Graham Ronald Eastham , Martyn Poliakoff , Thomas Andrew Huddle
IPC分类号： C07C51/48 , C08F20/02 , C07C51/38
CPC分类号： C07C51/48 , C07C51/38 , C08F20/02 , C08F20/06 , C07C57/04
摘要： A method of extracting (meth)acrylic acid from an aqueous reaction medium into an organic phase in contact therewith is described. The aqueous reaction medium is formed from at least one base catalyst and at least one dicarboxylic acid selected from maleic, fumaric, malic, itaconic, citraconic, mesaconic, and citramalic acid or mixtures thereof in aqueous solution and contains the base catalysed decarboxylation products of the base catalysed reaction. The method includes either the addition of at least one of the said dicarboxylic acids and/or a pre-cursor thereof to the aqueous reaction medium to enhance the solvent extraction of the (meth)acrylic acid into the organic solvent or maintaining the level of base catalyst to dicarboxylic acid and/or pre-cursor at a sub-stoichiometric level during the extraction process. The method extends to a process of producing (meth)acrylic acid, its esters and polymers and copolymers thereof.
摘要翻译：描述了从水性反应介质中提取（甲基）丙烯酸到与其接触的有机相中的方法。水性反应介质由水性溶液中的至少一种碱催化剂和至少一种选自马来酸，富马酸，苹果酸，衣康酸，柠康酸，中康酸和柠檬酸的二羧酸或其混合物形成，并含有碱催化的脱羧产物碱催化反应。该方法包括将至少一种所述二羧酸和/或其前体加入到水性反应介质中以增强（甲基）丙烯酸溶剂萃取到有机溶剂中或维持碱的水平催化剂到二羧酸和/或在提取过程中在亚化学计量水平的前体。该方法延伸至生产（甲基）丙烯酸的方法，其酯及其聚合物和共聚物。

22. 发明申请

US20130178647A1 Mixed Oxide Catalyst and a Process for the Production of Ethylenically Unsaturated Carboxylic Acids or Esters 有权
标题翻译：混合氧化物催化剂和用于生产乙烯基不饱和羧酸或酯的方法
公开(公告)号：US20130178647A1
公开(公告)日：2013-07-11
申请号：US13805052
申请日：2011-06-24
申请人： David William Johnson , Sabina Ziemian
发明人： David William Johnson , Sabina Ziemian
IPC分类号： B01J23/20 , C07C67/30 , C07C51/347 , B01J23/18
CPC分类号： B01J23/20 , B01J23/002 , B01J23/08 , B01J23/10 , B01J23/18 , B01J37/031 , B01J2523/00 , C07C51/347 , C07C51/353 , C07C67/30 , C07C67/343 , C07C57/04 , C07C69/54 , B01J2523/33 , B01J2523/53 , B01J2523/32 , B01J2523/47 , B01J2523/31 , B01J2523/48 , B01J2523/56
摘要： The invention relates to a catalyst for the reaction of formaldehyde with a carboxylic acid or ester to produce an ethylenically unsaturated carboxylic acid or ester, preferably α, β ethylenically unsaturated carboxylic acids or ester. The catalyst includes a metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is at least one metal selected from group 3 or 4 in the 4th to 6th periods of the periodic table, group 13 in the 3rd to 5th periods of the periodic table, or the remaining elements in the lanthanide series and M2 is at least one metal selected from group 5 in the 5th or 6th periods of the periodic table or group 15 in the 4th or 5th periods of the periodic table. The production includes reacting formaldehyde with a carboxylic acid or esterin the presence of the catalyst effective to catalyse the reaction.
摘要翻译：本发明涉及一种用于使甲醛与羧酸或酯反应以产生烯键式不饱和羧酸或酯，优选α，β-烯属不饱和羧酸或酯的催化剂。催化剂包括具有至少两种金属阳离子M1和M2的金属氧化物，其中M1是在周期表的第4-6阶段中选自第3或第4族中的至少一种金属，第3至第5族中的第13族周期表的周期，或镧系元素中的剩余元素和M2是选自元素周期表的第5或第6周期的第5组中的至少一种金属或周期表的第4或第5周期的第15族。生产包括在有效催化反应的催化剂存在下使甲醛与羧酸或酯反应。

23. 发明授权

US08227526B2 Removing fluorosurfactant from aqueous fluoropolymer dispersions using anion exchange polymer with functional groups resistant to degradation to trialkyl amines 有权
标题翻译：使用具有抗降解到三烷基胺的官能团的阴离子交换聚合物从含氟聚合物水分散体中除去含氟表面活性剂
公开(公告)号：US08227526B2
公开(公告)日：2012-07-24
申请号：US12641433
申请日：2009-12-18
申请人： James R. Combes , David William Johnson , Stephen Thomas Breske
发明人： James R. Combes , David William Johnson , Stephen Thomas Breske
IPC分类号： C08L1/00
CPC分类号： C08F6/16 , B01J41/04 , C02F1/42 , C02F2001/422 , C08L27/12
摘要： A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.
摘要翻译：一种降低含氟表面活性剂含水含氟聚合物分散体的含氟表面活性剂含量的方法，包括使含有稳定含氟表面活性剂的含水氟聚合物分散体与包含聚合物和季铵官能团的阴离子交换树脂接触，以降低含氟表面活性剂含量，官能团具有抗降解性其释放三烷基胺。在氟表面活性剂含量降低后，阴离子交换树脂与分散体分离。

24. 发明申请

US20070282055A1 Process for reducing fluorosurfactant content of fluoropolymer dispersions using anionic surfactant-treated anion exchange resin 失效
标题翻译：使用阴离子表面活性剂处理的阴离子交换树脂降低含氟聚合物分散体的含氟表面活性剂含量的方法
公开(公告)号：US20070282055A1
公开(公告)日：2007-12-06
申请号：US11805499
申请日：2007-05-22
申请人： Kenneth Scott Teter , David William Johnson
发明人： Kenneth Scott Teter , David William Johnson
IPC分类号： D06M15/277
CPC分类号： C08F6/16 , C08F6/20 , C08L27/12
摘要： A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion. The process includes providing a fixed bed of anion exchange resin having anion exchange groups with counter ions. The anion exchange resin is treated to replace at least some the counter ions with counter ions of non-fluorinated anionic surfactant. The stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion is passed through the treated fixed bed of anion exchange resin.
摘要翻译：一种降低含氟表面活性剂含水含氟聚合物分散体含氟表面活性剂含量的方法。该方法包括提供具有带有抗衡离子的阴离子交换基团的阴离子交换树脂固定床。处理阴离子交换树脂以用非氟化阴离子表面活性剂的抗衡离子代替至少一些抗衡离子。使稳定的含氟表面活性剂含水氟聚合物分散体通过处理的阴离子交换树脂固定床。

25. 发明授权

US06984668B1 Metal-compound catalyzed processes 失效
标题翻译：金属化合物催化工艺
公开(公告)号：US06984668B1
公开(公告)日：2006-01-10
申请号：US10048595
申请日：2000-08-02
申请人： Graham Ronald Eastham , Raymond Anthony Hadden , David William Johnson
发明人： Graham Ronald Eastham , Raymond Anthony Hadden , David William Johnson
IPC分类号： B01F17/00 , B01F3/08 , C09K3/00 , C07C67/38 , C07C51/14
CPC分类号： B01J35/0013 , B01J31/28 , C07C67/38 , C07C69/24
摘要： A liquid-phase chemical reaction medium comprises one or more reactants, optionally in the presence of a reaction product(s) and one or more solvents, diluents or other form of liquid carrier, a catalyst system comprising at least a metal or metal compound and optionally further compounds such as ligands or complexing agents; characterized in that the reaction medium further comprises a polymeric dispersant dissolved in said liquid carrier, said polymeric dispersant being capable of stabilizing a colloidal suspension of particles of said metal or metal compound within the liquid carrier. The presence of the polymeric dispersant enables metal formed by catalyst deactivation to be more easily recovered and recycled. Preferably, the polymeric dispersant has sufficiently acidic or basic functionality to stabilize the colloidal suspension of said metal or metal compound.
摘要翻译：液相化学反应介质包括一种或多种反应物，任选地在反应产物和一种或多种溶剂，稀释剂或其它形式的液体载体存在下，至少包含金属或金属化合物的催化剂体系和任选的其它化合物如配体或络合剂; 其特征在于所述反应介质还包含溶解在所述液体载体中的聚合物分散剂，所述聚合物分散剂能够稳定所述金属或金属化合物颗粒在胶体载体内的胶体悬浮液。聚合物分散剂的存在使得通过催化剂失活形成的金属更容易回收和再循环。优选地，聚合物分散剂具有足够的酸性或碱性官能度以稳定所述金属或金属化合物的胶体悬浮液。

26. 发明授权

US08329813B2 Thermal reduction of fluoroether carboxylic acids or salts from fluoropolymer dispersions 失效
标题翻译：含氟聚合物分散体中氟醚羧酸或盐的热还原
公开(公告)号：US08329813B2
公开(公告)日：2012-12-11
申请号：US12774030
申请日：2010-05-05
申请人： David William Johnson , Kenneth Scott Teter
发明人： David William Johnson , Kenneth Scott Teter
IPC分类号： C08L27/12
CPC分类号： C08F6/16 , C08F14/18 , C08L27/12 , C08F2/20 , C08F2/16
摘要： A process for reducing the fluoroether carboxylic acid or salt content of aqueous fluoropolymer dispersion. The fluoroether carboxylic acid or salt employed comprises fluoroether carboxylic acid or salt having the formula below: [R1—O-L-COO−]Y+ wherein R1 is a linear, branched or cyclic partially or fully fluorinated aliphatic group which may contain ether linkages; L is a branched partially or fully fluorinated alkylene group which may contain ether linkages; and Y+ is hydrogen, ammonium or alkali metal cation. The process comprises adding stabilizer to the aqueous fluoropolymer dispersion to form a stabilized aqueous fluoropolymer dispersion and heating the stabilized aqueous fluoropolymer dispersion to decarboxylate the fluoroether carboxylic acid or salt to produce a fluoroether byproduct. At least a portion of the fluoroether byproduct is removed.
摘要翻译：降低氟代醚羧酸含量或含氟聚合物含水分散体的盐含量的方法。所用的氟醚羧酸或其盐包括具有下式的氟醚羧酸或盐：[R 1 -O-L-COO-] Y +，其中R 1是可以含有醚键的直链，支链或环状的部分或完全氟化的脂族基团; L是可以含有醚键的支化部分或完全氟化的亚烷基; Y +是氢，铵或碱金属阳离子。该方法包括向含氟聚合物含水分散体中加入稳定剂以形成稳定的含氟聚合物含水分散体，并加热稳定的含氟聚合物水分散体以使氟代醚羧酸或盐脱羧以产生氟醚副产物。除去至少一部分氟醚副产物。

27. 发明授权

US08329782B2 Removing fluorosurfactant from aqueous fluoropolymer dispersions using anion exchange polymer with functional groups resistant to degradation to trialkylamines 有权
标题翻译：使用具有对三烷基胺降解抗性的官能团的阴离子交换聚合物从含氟聚合物水分散体中除去含氟表面活性剂
公开(公告)号：US08329782B2
公开(公告)日：2012-12-11
申请号：US12641423
申请日：2009-12-18
申请人： James R. Combes , David William Johnson , Stephen Thomas Breske
发明人： James R. Combes , David William Johnson , Stephen Thomas Breske
IPC分类号： C08L1/00
CPC分类号： C08F6/16 , B01J41/04 , C02F1/42 , C02F2001/422 , C08L27/12
摘要： A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.
摘要翻译：一种降低含氟表面活性剂含水含氟聚合物分散体的含氟表面活性剂含量的方法，包括使含有稳定含氟表面活性剂的含水氟聚合物分散体与包含聚合物和季铵官能团的阴离子交换树脂接触，以降低含氟表面活性剂含量，官能团具有抗降解性其释放三烷基胺。在氟表面活性剂含量降低后，阴离子交换树脂与分散体分离。

28. 发明申请

US20110282023A1 METHYL METHACRYLATE PURIFICATION PROCESS 有权
标题翻译：甲基丙烯酸甲酯纯化方法
公开(公告)号：US20110282023A1
公开(公告)日：2011-11-17
申请号：US13140754
申请日：2009-12-11
申请人： David William Johnson , Trevor Huw Morris
发明人： David William Johnson , Trevor Huw Morris
IPC分类号： C08F120/18 , C07C69/54 , C07C67/56
CPC分类号： C07C67/60 , C07C69/54
摘要： A process for purifying methyl methacrylate (MMA) is described. The process involves contacting liquid MMA having impurities therein with a sulphonic acid resin, in the presence of formaldehyde or a suitable source of methylene or ethylene of formula I. R5 and R6 are independently selected from C1-C12 hydrocarbons or H; X is either O or S; n is an integer from, 1 to 100; and m is 1 or 2: The compound of formula I may be suitable source of formaldehyde.
摘要翻译：描述了甲基丙烯酸甲酯（MMA）的纯化方法。该方法包括在甲醛或合适的式I的亚甲基或亚乙基的存在下使其中含有杂质的液体MMA与磺酸树脂接触.R 5和R 6独立地选自C 1 -C 12烃或H; X是O或S; n是1至100的整数; 并且m为1或2：式I化合物可以是合适的甲醛源。

29. 发明申请

US20110071311A1 PRODUCTION OF ETHYLENICALLY UNSATURATED ACIDS OR ESTERS THEREOF 有权
标题翻译：生产非均质不饱和酸或其酯
公开(公告)号：US20110071311A1
公开(公告)日：2011-03-24
申请号：US12992906
申请日：2009-05-15
申请人： David William Johnson , Trevor Huw Morris
发明人： David William Johnson , Trevor Huw Morris
IPC分类号： C07C51/347 , C07C67/08
CPC分类号： C07C67/343 , C07C51/50 , C07C67/62 , C07C57/04 , C07C69/54
摘要： A production process for the manufacture of ethylenically unsaturated acids or esters thereof is described. The process includes the steps of reaction of an alkanoic acid, or ester of an alkanoic acid, of the formula R3—CH2—COOR4 where R3 and R4 are each independently hydrogen or an alkyl group, in the presence of a catalyst system to produce an ethylenically unsaturated acid or ester product. The process is characterised in that the acid or ester product is subsequently contacted with a dienophile to thereby remove discolouration therefrom. An ethylenically unsaturated acid or ester crude product purification process is also described.
摘要翻译：描述了用于制备烯属不饱和酸或其酯的制备方法。该方法包括在催化剂体系的存在下使式R3-CH2-COOR4的链烷酸或链烷酸的酯反应的步骤，其中R 3和R 4各自独立地为氢或烷基，以产生烯属不饱和酸或酯产物。该方法的特征在于酸或酯产物随后与亲二烯体接触，从而除去其变色。还描述了烯属不饱和酸或酯粗产物纯化方法。

30. 发明申请

US20100093893A1 Removing Fluorosurfactant from Aqueous Fluoropolymer Dispersions Using Anion Exchange Polymer With Functional Groups Resistant To Degradation to Trialkylamines 有权
标题翻译：使用具有抗降解至三烷基胺的官能团的阴离子交换聚合物从含氟聚合物分散体中除去含氟表面活性剂
公开(公告)号：US20100093893A1
公开(公告)日：2010-04-15
申请号：US12641423
申请日：2009-12-18
申请人： James R. Combes , David William Johnson , Stephen Thomas Breske
发明人： James R. Combes , David William Johnson , Stephen Thomas Breske
IPC分类号： C08F6/16
CPC分类号： C08F6/16 , B01J41/04 , C02F1/42 , C02F2001/422 , C08L27/12
摘要： A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.
摘要翻译：一种降低含氟表面活性剂含水含氟聚合物分散体的含氟表面活性剂含量的方法，包括使含有稳定含氟表面活性剂的含水氟聚合物分散体与包含聚合物和季铵官能团的阴离子交换树脂接触，以降低含氟表面活性剂含量，官能团具有抗降解性其释放三烷基胺。在氟表面活性剂含量降低后，阴离子交换树脂与分散体分离。

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