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    • 26. 发明授权
    • Alkylamines as biofilm deactivation agents
    • 烷基胺作为生物膜失活剂
    • US06379563B1
    • 2002-04-30
    • US09487743
    • 2000-01-19
    • Christopher J. Nalepa
    • Christopher J. Nalepa
    • C02F150
    • C02F1/72A01N33/04C02F1/50A01N2300/00
    • Aqueous industrial, recreational, and drilling systems comprising a biofilm deactivation agent consisting essentially of one or more alkylamines. The biofilm deactivation agent has a “minimum biofilm deactivation concentration” (“MBEC”) of about 200 ppm or less. In a preferred embodiment, the biofilm deactivation agent consists essentially of primary alkylamines having from about 12 to about 14 carbon atoms, and a MBEC of about 50 ppm or less, most preferably about 30 ppm or less. A most preferred embodiment comprises a synergistic combination of specific quaternary ammonium salts with a primary alkylamine having from about 12 to about 14 carbon atoms. The invention also relates to the method of treating an aqueous system with these biofilm deactivation agents, either alone, or in the presence of an oxidizing agent for static control.
    • 水性工业,娱乐和钻井系统,其包含基本上由一种或多种烷基胺组成的生物膜失活剂。 生物膜失活剂具有约200ppm或更低的“最小生物膜失活浓度”(“MBEC”)。 在优选的实施方案中,生物膜失活剂基本上由具有约12至约14个碳原子的伯烷基胺和约50ppm或更低,最优选约30ppm或更少的MBEC组成。 最优选的实施方案包括特定季铵盐与具有约12至约14个碳原子的伯烷基胺的协同组合。 本发明还涉及用这些生物膜去活化剂单独处理或在用于静电控制的氧化剂存在下处理含水体系的方法。
    • 29. 发明授权
    • Methods for microbiological control in aqueous systems
    • 水系统微生物控制方法
    • US07371397B2
    • 2008-05-13
    • US10688124
    • 2003-10-17
    • Jonathan N. HowarthChristopher J. NalepaMichael J. Sanders
    • Jonathan N. HowarthChristopher J. NalepaMichael J. Sanders
    • A01N25/32A01N43/50
    • A01N43/50A01N59/00C02F1/50C02F1/766C02F2103/023C02F2103/42A01N25/34A01N25/14A01N25/12A01N25/00A01N2300/00
    • Microbiological control in aqueous media and/or eradication or reduction of biofilm on a surface in contact with such media is achieved by introducing into the aqueous medium a microbiocidally effective quantity of one or more 1,3-dibromo-5,5-dialkylhydantoins where one of the alkyls is methyl and the other is a C1-4 alkyl, wherein (i) the molar quantity of 1,3-dibromo-5,5-dialkylhydantoin introduced is less than the molar quantity of N,N′-bromochloro-5,5-dimethylhydantoin that would be required to effect the same degree of microbiological control in that medium, (ii) the molar quantity of the 1,3-dibromo-5,5-dialkylhydantoin introduced releases an amount of “free chlorine” that is greater than the amount of “free chlorine” that would be released in that medium by an equimolar quantity of N,N′-bromochloro-5,5-dimethylhydantoin, and (iii) the amount of “free chlorine” released by the quantity of the 1,3-dibromo-5,5-dialkylhydantoin introduced is greater than the amount of “free chlorine” that could be predicted to be released by that quantity of 1,3-dibromo-5,5-dialkylhydantoin on the basis of the amount of “free chlorine” that would be released in that medium by an equimolar quantity of N,N′-bromochloro-5,5-dimethylhydantoin.
    • 通过向水性介质中引入微生物有效量的一种或多种1,3-二溴-5,5-二烷基乙内酰脲,其中一个或多个1,3-二溴-5,5-二烷基乙内酰脲通过将水介质中的微生物控制和/或根除或减少与这种介质接触的表面上的生物膜来实现 的烷基是甲基,另一个是C 1-4烷基,其中(i)引入的1,3-二溴-5,5-二烷基乙内酰脲的摩尔量小于 N,N'-溴氯-5,5-二甲基乙内酰脲需要在该培养基中进行相同程度的微生物控制,(ii)引入的1,3-二溴-5,5-二烷基乙内酰脲的摩尔量释放出 “游离氯”的量大于通过等摩尔量的N,N'-溴氯-5,5-二甲基乙内酰脲在该介质中释放的“游离氯”的量,和(iii)“游离氯” 引入的1,3-二溴-5,5-二烷基乙内酰脲的量释放的游离氯“大于”fr 可以预测由该量的1,3-二溴-5,5-二烷基乙内酰脲以基于等摩尔量的N释放在该介质中的“游离氯”的量释放的“ee氯” N'-溴氯-5,5-二甲基乙内酰脲。