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21. 发明申请

US20110061782A1 INNER TUBE FOR A PNEUMATIC TYRE BASED ON A THERMOPLASTIC ELASTOMER 审中-公开
标题翻译：基于热塑性弹性体的气动轮胎内管
公开(公告)号：US20110061782A1
公开(公告)日：2011-03-17
申请号：US12920257
申请日：2009-03-10
申请人： Jose Merino Lopez , Pierre Lesage , Frederic Pialot , Michel Ahouanto
发明人： Jose Merino Lopez , Pierre Lesage , Frederic Pialot , Michel Ahouanto
IPC分类号： B60C5/04 , B60C19/12 , B29C73/16 , B29D23/24
CPC分类号： B60C19/127 , B29D30/0685 , B60C5/04 , B60C19/122 , Y10T152/10675
摘要： Inner tube for a pneumatic tyre, notably for a bicycle, characterized in that it has an elastomeric gastight layer consisting of an elastomeric composition comprising at least one styrene/isobutylene/styrene thermoplastic elastomer (called “SIBS”) and in that it includes a self-sealing material disposed inside the cavity formed by the airtight elastomeric layer.
摘要翻译：用于充气轮胎的内胎，特别是用于自行车，其特征在于，其具有由包含至少一种苯乙烯/异丁烯/苯乙烯热塑性弹性体（称为“SIBS”）的弹性体组合物组成的弹性体气密层，并且其包括自身 - 密封材料，其设置在由气密弹性体层形成的空腔内。

22. 发明授权

US07504454B2 Process for the preparation of block copolymers for tire tread compositions, and these copolymers 有权
标题翻译：制备轮胎胎面组合物的嵌段共聚物的方法，以及这些共聚物
公开(公告)号：US07504454B2
公开(公告)日：2009-03-17
申请号：US11267260
申请日：2005-11-07
申请人： Pierre Lesage
发明人： Pierre Lesage
IPC分类号： C08K3/04
CPC分类号： C08L53/00 , C08F297/023 , C08F297/044 , C08L53/02 , C08L2666/02
摘要： A process for the preparation of a functionalized, coupled or starred block copolymer which is usable in a sulphur-cross-linkable rubber composition of reduced hysteresis in the cross-linked state, one at least of said blocks consisting of a polyisoprene and at least one other block consisting of a diene elastomer other than a polyisoprene the molar ratio of units originating from one or more conjugated dienes of which is greater than 15%. The process includes the steps of: copolymerization of one or more monomers comprising a conjugated diene other than isoprene using a catalytic system comprising at least one hydrocarbon solvent, a compound A of a metal of group IIIA, a compound B of an alkaline-earth metal and a polymer initiator C comprising a C—Li bond which is formed of a monolithiated polyisoprene intended to form the polyisoprene block, and addition to the product of the copolymerization of a functionalizing, coupling or starring agent comprising an acetoxy group and of formula Rn—Sn—(O—CO—R′)4−n, where n is a natural integer of from 0 to 4 and where R and R′ are each alkyl, cycloalkyl, aryl or aralkyl groups which may be identical or different, so that said or each block formed of a diene elastomer other than a polyisoprene is functionalized, coupled or starred.
摘要翻译：一种制备功能化，偶联或加星型嵌段共聚物的方法，其可用于交联状态下具有降低的滞后的硫交联橡胶组合物，至少所述嵌段由聚异戊二烯和至少一种由除了聚异戊二烯以外的二烯弹性体组成的其它嵌段，源自一种或多种共轭二烯的单元的摩尔比大于15％。该方法包括以下步骤：使用包含至少一种烃溶剂的催化体系，IIIA族金属的化合物A，碱土金属的化合物B，共聚一种或多种包含异戊二烯以外的共轭二烯的单体以及包含由用于形成聚异戊二烯嵌段的聚酯聚异戊二烯形成的C-Li键的聚合物引发剂C，以及包含乙酰氧基和式Rn- Sn-（O-CO-R'）4-n，其中n为0至4的整数，R和R'各自可以相同或不同的烷基，环烷基，芳基或芳烷基，使得所述或由除聚异戊二烯以外的二烯弹性体形成的每个嵌段被官能化，偶联或加成。

23. 发明授权

US07205360B2 Preparation process for block copolymers for tire tread compositions, and such copolymers 有权
标题翻译：用于轮胎胎面组合物的嵌段共聚物的制备方法和这种共聚物
公开(公告)号：US07205360B2
公开(公告)日：2007-04-17
申请号：US10835409
申请日：2004-04-30
申请人： Pierre Robert , Jean-Michel Favrot , Pierre Lesage
发明人： Pierre Robert , Jean-Michel Favrot , Pierre Lesage
IPC分类号： C08F297/02 , C08K3/36
CPC分类号： C08F297/046 , C08F297/02 , C08L53/00 , C08L53/02 , Y10S152/905
摘要： A preparation process for a copolymer having two blocks usable in a sulphur-cross-linkable rubber composition of reduced hysteresis in the cross-linked state, such a block copolymer in which one of the blocks is a polyisoprene and the other a diene elastomer other than a polyisoprene, and this rubber composition for tire treads. A process for the preparation of this copolymer involves copolymerizing one or more monomers including a conjugated diene other than isoprene using a catalytic system including at least one hydrocarbon solvent, a compound A of a metal of group IIIA, a compound B of an alkaline-earth metal and a polymeric initiator C having a C—Li bond which is constituted of a monolithiated polyisoprene intended to form the polyisoprene block, the number-average molecular weight Mn1 of the polyisoprene block being between 2,500 and 20,000 g/mol. A copolymer is obtained in which the block composed of the diene elastomer has a number-average molecular weight Mn2 of between 65,000 and 350,000 g/mol and a content of trans-1,4 linkages equal to or greater than 70%.
摘要翻译：一种共聚物的制备方法，其具有可用于交联状态下滞后性降低的可硫交联橡胶组合物中的两个嵌段，其中一个嵌段是聚异戊二烯，另一个嵌段共聚物是除二聚异戊二烯和用于轮胎胎面的该橡胶组合物。制备该共聚物的方法包括使用包括至少一种烃溶剂，IIIA族金属的化合物A，碱土金属化合物B的催化体系共聚一种或多种包括异戊二烯以外的共轭二烯的单体金属和具有C-Li键的聚合物引发剂C，其由旨在形成聚异戊二烯嵌段的聚酯聚异戊二烯构成，聚异戊二烯嵌段的数均分子量M n1为2,500至20,000 g / mol。得到共聚物，其中由二烯弹性体组成的嵌段具有65,000至350,000g / mol的数均分子量M N2，并且反式-1,4键的含量等于或等于大于70％。

24. 发明申请

US20140235751A1 TIRE WITH IMPROVED GRIP ON WET GROUND 审中-公开
标题翻译：轮胎与湿地接触改善
公开(公告)号：US20140235751A1
公开(公告)日：2014-08-21
申请号：US14347083
申请日：2012-09-26
申请人： Pierre Lesage , Garance Lopitaux , Didier Vasseur
发明人： Pierre Lesage , Garance Lopitaux , Didier Vasseur
IPC分类号： C08L7/00
CPC分类号： C08L7/00 , C08K3/36 , C08K5/0016 , C08L9/00 , C08L57/02
摘要： A tire having an improved wet grip, in particular for a passenger vehicle, a van, or a two-wheel vehicle, includes a tread formed of a rubber composition. The rubber composition includes at least (phr meaning parts by weight per hundred parts of elastomer): as a first diene elastomer, from 55 to 95 phr of natural rubber or synthetic polyisoprene; as a second diene elastomer, from 5 to 45 phr of a polybutadiene or butadiene copolymer having a glass transition temperature (Tg) which is greater than −70° C.; as a reinforcing filler, more than 90 phr and less than 150 phr of an inorganic filler; and as a plasticizer, more than 10 phr of a thermoplastic hydrocarbon resin exhibiting a glass transition temperature (Tg) greater than 20° C.
摘要翻译：具有改进的湿抓地力的轮胎，特别是用于客车，厢式货车或两轮车辆的轮胎包括由橡胶组合物形成的胎面。橡胶组合物至少包括（phr表示每100份弹性体重量份）：作为第一二烯弹性体，55至95phr的天然橡胶或合成的聚异戊二烯; 作为第二二烯弹性体，5至45phr的玻璃化转变温度（Tg）大于-70℃的聚丁二烯或丁二烯共聚物; 作为增强填料，超过90phr和小于150phr的无机填料; 并且作为增塑剂，超过10phr的玻璃化转变温度（Tg）大于20℃的热塑性烃树脂。

25. 发明申请

US20130296471A1 TYRE TREAD 审中-公开
标题翻译： TIRE TREAD
公开(公告)号：US20130296471A1
公开(公告)日：2013-11-07
申请号：US13988703
申请日：2011-11-24
申请人： Pierre Lesage , Philippe Labrunie , Didier Vasseur , Xavier Saintigny
发明人： Pierre Lesage , Philippe Labrunie , Didier Vasseur , Xavier Saintigny
IPC分类号： C08L9/06
CPC分类号： C08L9/06 , B60C1/0016 , C08K3/34 , C08K5/0016 , C08L7/00 , C08L9/04 , C08L19/006 , C08L45/00 , C08L47/00 , C08L2666/04 , C08L2666/08
摘要： A tyre, which has an improved grip on wet ground, includes a tread formed of at least a rubber composition. The rubber composition includes: 20 to 100 phr of a first diene elastomer bearing at least one SiOR function, with R being hydrogen or a hydrocarbon radical, and with phr referring to parts by weight per hundred parts of elastomer; 100 to 160 phr of a reinforcing inorganic filler; and a plasticizing system. The plasticizing system includes: a content A of between 5 and 60 phr of a hydrocarbon resin having a Tg above 20° C.; and a content B of between 5 and 60 phr of a liquid plasticizing agent. A total content A+B is greater than 45 phr. The rubber composition optionally includes 0 to 80 phr of a second diene elastomer.
摘要翻译：具有改进的对湿地的抓地力的轮胎包括由至少橡胶组合物形成的胎面。橡胶组合物包括：20至100phr的具有至少一个SiOR官能团的第一二烯弹性体，其中R为氢或烃基，phr为每百份弹性体重量份; 100〜160phr的增强无机填料; 和塑化系统。塑化系统包括：5至60phr的Tg高于20℃的烃树脂的含量A; 和5至60phr的液体增塑剂的含量B。总含量A + B大于45phr。橡胶组合物任选地包含0至80phr的第二二烯弹性体。

26. 发明申请

US20100300593A1 TYRE WITH SELF-SEALING LAYER 有权
标题翻译：轮胎与自密封层
公开(公告)号：US20100300593A1
公开(公告)日：2010-12-02
申请号：US12666413
申请日：2008-06-19
申请人： Jose Merino Lopez , Michel Ahouanto , Pierre Lesage , Frederic Pialot
发明人： Jose Merino Lopez , Michel Ahouanto , Pierre Lesage , Frederic Pialot
IPC分类号： B60C19/00 , B29C73/16 , B29D30/00
CPC分类号： B60C19/122 , B29C73/163 , B29C73/20 , B29C73/22 , B29D30/0685 , B29D2030/0695 , B29L2030/00 , B60C5/14
摘要： Tubeless tyre in the form of a torus open radially inwards with an outer wall and an inner wall, characterized in that at least part of the inner wall is covered with a self-sealing layer comprising a thermoplastic styrene (TPS) elastomer having a Shore 0 hardness of less than 35.
摘要翻译：圆筒状的无内胎轮胎与外壁和内壁径向向内敞开，其特征在于，内壁的至少一部分用自密封层覆盖，所述自密封层包括具有肖氏0（S）的热塑性苯乙烯（TPS）弹性体硬度小于35。

27. 发明授权

US07625983B2 Process for the preparation of block copolymers for tire tread compositions and these copolymers 有权
标题翻译：制备轮胎胎面组合物和这些共聚物的嵌段共聚物的方法
公开(公告)号：US07625983B2
公开(公告)日：2009-12-01
申请号：US11267259
申请日：2005-11-07
申请人： Pierre Lesage
发明人： Pierre Lesage
IPC分类号： C08F4/00 , C08F251/00 , C08F253/00 , C08F16/26 , C08F20/32 , C08F116/16 , C08F36/00 , C08F8/34 , C08F36/08 , C08F236/08
CPC分类号： C08L53/00 , C08F297/023 , C08F297/044 , C08L53/02 , C08L2666/02
摘要： A process for the preparation of a functionalized, coupled or starred block copolymer which is usable in a sulphur-cross-linkable rubber composition of reduced hysteresis in the cross-linked state, one at least of said blocks consisting of a polyisoprene and at least one other block consisting of a diene elastomer other than a polyisoprene the molar ratio of units originating from one or more conjugated dienes of which is greater than 15%. The process includes the steps of: (i) copolymerization of one or more monomers comprising a conjugated diene other than isoprene using a catalytic system comprising a hydrocarbon solvent, a compound A of a metal of group IIIA, a compound B of an alkaline-earth metal and a polymer initiator C comprising a C—Li bond which is formed of a monolithiated polyisoprene intended to form the polyisoprene, said polyisoprene block(s) having a number-average molecular weight Mn1 of between 2,500 and 20,000 g/mol, so that said block(s) other than a polyisoprene has/have a content of trans-1,4 linkages equal to or greater than 70% and a number-average molecular weight Mn2 of between 65,000 and 350,000 g/mol, and (ii) addition to the product of copolymerization of a functionalizing, coupling or starring agent comprising one, two or at least three epoxy groups respectively, so that said block other than a polyisoprene is functionalized, coupled or starred.
摘要翻译：一种制备功能化，偶联或加星型嵌段共聚物的方法，其可用于交联状态下具有降低的滞后的硫交联橡胶组合物，至少所述嵌段由聚异戊二烯和至少一种由除了聚异戊二烯以外的二烯弹性体组成的其它嵌段，源自一种或多种共轭二烯的单元的摩尔比大于15％。该方法包括以下步骤：（i）使用包含烃溶剂，IIIA族金属的化合物A，碱土金属化合物B的催化体系，共聚一种或多种包含异戊二烯以外的共轭二烯的单体金属和聚合物引发剂C，其包含由旨在形成聚异戊二烯的整体式聚异戊二烯形成的C-Li键，所述聚异戊二烯嵌段的数均分子量Mn1为2500〜20,000g / mol，使得除聚异戊二烯之外的所述嵌段具有等于或大于70％的反式-1,4-键的含量和65,000至350,000g / mol的数均分子量Mn2，和（ii）加成涉及分别包含一个，两个或至少三个环氧基团的官能化，偶联或起始原料共聚的产物，使得除聚异戊二烯以外的所述嵌段被官能化，偶联或加成。

28. 发明申请

US20060148994A1 Process for the preparation of block copolymers for tire tread compositions and these copolymers 有权
标题翻译：制备轮胎胎面组合物和这些共聚物的嵌段共聚物的方法
公开(公告)号：US20060148994A1
公开(公告)日：2006-07-06
申请号：US11267259
申请日：2005-11-07
申请人： Pierre Lesage
发明人： Pierre Lesage
IPC分类号： C08F297/02
CPC分类号： C08L53/00 , C08F297/023 , C08F297/044 , C08L53/02 , C08L2666/02
摘要： A process for the preparation of a functionalized, coupled or starred block copolymer which is usable in a sulphur-cross-linkable rubber composition of reduced hysteresis in the cross-linked state, one at least of said blocks consisting of a polyisoprene and at least one other block consisting of a diene elastomer other than a polyisoprene the molar ratio of units originating from one or more conjugated dienes of which is greater than 15%. The process includes the steps of: (i) copolymerization of one or more monomers comprising a conjugated diene other than isoprene using a catalytic system comprising a hydrocarbon solvent, a compound A of a metal of group IIIA, a compound B of an alkaline-earth metal and a polymer initiator C comprising a C—Li bond which is formed of a monolithiated polyisoprene intended to form the polyisoprene, said polyisoprene block(s) having a number-average molecular weight Mn1 of between 2,500 and 20,000 g/mol, so that said block(s) other than a polyisoprene has/have a content of trans-1,4 linkages equal to or greater than 70% and a number-average molecular weight Mn2 of between 65,000 and 350,000 g/mol, and (ii) addition to the product of copolymerization of a functionalizing, coupling or starring agent comprising one, two or at least three epoxy groups respectively, so that said block other than a polyisoprene is functionalized, coupled or starred.
摘要翻译：一种制备功能化，偶联或加星型嵌段共聚物的方法，其可用于交联状态下具有降低的滞后的硫交联橡胶组合物，至少所述嵌段由聚异戊二烯和至少一种由除了聚异戊二烯以外的二烯弹性体组成的其它嵌段，源自一种或多种共轭二烯的单元的摩尔比大于15％。该方法包括以下步骤：（i）使用包含烃溶剂，IIIA族金属的化合物A，碱土金属化合物B的催化体系，共聚一种或多种包含异戊二烯以外的共轭二烯的单体金属和聚合物引发剂C，其包含由旨在形成所述聚异戊二烯的聚酯聚异戊二烯形成的C-Li键，所述聚异戊二烯嵌段的数均分子量M N 2≤2,500 和20,000g / mol，使得除聚异戊二烯之外的所述嵌段具有等于或大于70％的反式-1,4键含量和数均分子量M N 2，和（ii）分别加入包含一个，两个或至少三个环氧基团的官能化，偶联或引发剂的共聚产物，使得除聚异戊二烯以外的所述嵌段是功能化，耦合或加星标。

29. 发明授权

US10160847B2 Tyre tread 有权
公开(公告)号：US10160847B2
公开(公告)日：2018-12-25
申请号：US13988703
申请日：2011-11-24
申请人： Pierre Lesage , Philippe Labrunie , Didier Vasseur , Xavier Saintigny
发明人： Pierre Lesage , Philippe Labrunie , Didier Vasseur , Xavier Saintigny
IPC分类号： B60C1/00 , C08L9/06 , C08L19/00 , C08L7/00 , C08L9/04 , C08L47/00 , C08L45/00 , C08K3/34 , C08K5/00
摘要： A tire, which has an improved grip on wet ground, includes a tread formed of at least a rubber composition. The rubber composition includes: 20 to 100 phr of a first diene elastomer bearing at least one SiOR function, with R being hydrogen or a hydrocarbon radical, and with phr referring to parts by weight per hundred parts of elastomer; 100 to 160 phr of a reinforcing inorganic filler; and a plasticizing system. The plasticizing system includes: a content A of between 5 and 60 phr of a hydrocarbon resin having a Tg above 20° C.; and a content B of between 5 and 60 phr of a liquid plasticizing agent. A total content A+B is greater than 45 phr. The rubber composition optionally includes 0 to 80 phr of a second diene elastomer.

30. 发明授权

US08573271B2 Tyre with self-sealing layer 有权
标题翻译：轮胎具有自密封层
公开(公告)号：US08573271B2
公开(公告)日：2013-11-05
申请号：US12666413
申请日：2008-06-19
申请人： José´ Merino Lopez , Michel Ahouanto , Pierre Lesage , Frédéric Pialot
发明人： José´ Merino Lopez , Michel Ahouanto , Pierre Lesage , Frédéric Pialot
IPC分类号： B60C5/14 , B60C19/12
CPC分类号： B60C19/122 , B29C73/163 , B29C73/20 , B29C73/22 , B29D30/0685 , B29D2030/0695 , B29L2030/00 , B60C5/14
摘要： Tubeless tire in the form of a torus open radially inwards with an outer wall and an inner wall, characterized in that at least part of the inner wall is covered with a self-sealing layer comprising a thermoplastic styrene (TPS) elastomer having a Shore 0 hardness of less than 35.
摘要翻译：圆筒状的无内胎轮胎与外壁和内壁径向向内敞开，其特征在于，所述内壁的至少一部分用自密封层覆盖，所述自密封层包括具有肖氏0的热塑性苯乙烯（TPS）弹性体硬度小于35。

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