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21. 发明授权

US09164298B2 Wettable silicone hydrogel contact lenses 有权
标题翻译：可湿性硅酮水凝胶隐形眼镜
公开(公告)号：US09164298B2
公开(公告)日：2015-10-20
申请号：US13983577
申请日：2012-02-23
申请人： Ye Hong , Li Yao , Yuwen Liu , Charlie Chen , Arthur Back
发明人： Ye Hong , Li Yao , Yuwen Liu , Charlie Chen , Arthur Back
IPC分类号： G02C7/04 , G02B1/04 , C08L83/12
CPC分类号： G02C7/049 , C08L83/12 , G02B1/043 , C08L101/14 , C08L83/04 , C08L51/085
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one acrylate-containing siloxane monomer, at least one hydrophilic vinyl-containing monomer, and at least one vinyl-containing cross-linking agent, wherein the polymerizable composition has a molar ratio of total amount of hydrophilic vinyl-containing monomer to total amount of acrylate-containing siloxane monomer of from 5:1 to 30:1, respectively. The silicone hydrogel contact lenses have good manufacturing processability, can be manufactured without the use of alcohol solvents, and have excellent surface wettability.
摘要翻译：硅氧烷水凝胶隐形眼镜由包含至少一种含丙烯酸酯的硅氧烷单体，至少一种亲水性含乙烯基单体和至少一种含乙烯基交联剂的可聚合组合物的反应产物形成，其中可聚合组合物具有亲水性含乙烯基单体的总量与含丙烯酸酯的硅氧烷单体的总量的摩尔比分别为5:1至30:1。硅酮水凝胶隐形眼镜具有良好的制造加工性，可以在不使用醇溶剂的情况下制造，并且具有优异的表面润湿性。

22. 发明授权

US08445614B2 Dimensionally stable silicone hydrogel contact lenses 有权
标题翻译：尺寸稳定的硅酮水凝胶隐形眼镜
公开(公告)号：US08445614B2
公开(公告)日：2013-05-21
申请号：US13404034
申请日：2012-02-24
申请人： Charles A. Francis , Ying Zheng , Yuan Xu , Li Yao , Arthur Back , Ye Hong , Charlie Chen
发明人： Charles A. Francis , Ying Zheng , Yuan Xu , Li Yao , Arthur Back , Ye Hong , Charlie Chen
IPC分类号： C08F230/08 , C08F290/06 , G02B1/04
CPC分类号： C08F230/08 , C08F222/1006
摘要： Dimensionally stable silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including a first siloxane monomer represented by formula (1): wherein m of formula (1) represents one integer from 3 to 10, n of formula (1) represents one integer from 1 to 10, R1 of formula (1) is an alkyl group having from 1 to 4 carbon atoms, and each R2 of formula (1) is independently either a hydrogen atom or a methyl group; the lenses also include units derived from a second siloxane monomer represented by formula (2): wherein R1 of formula (2) is selected from either hydrogen atom or a methyl group; R2 of formula (2) is selected from either of hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; m of formula (2) represents an integer of from 0 to 10; n of formula (2) represents an integer of from 4 to 100; a and b represent integers of 1 or more; a+b is equal to 20-500; b/(a+b) is equal to 0.01-0.22; the configuration of siloxane units includes a random configuration, the second siloxane monomer having a number average molecular weight of at least 3,000 daltons that is present in the polymerizable composition in an amount such that ratio of the first siloxane monomer to the second siloxane monomer is at least 2:1 based on unit parts by weight. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了尺寸稳定的硅酮水凝胶隐形眼镜。透镜衍生自包含由式（1）表示的第一硅氧烷单体的可聚合组合物：其中式（1）的m表示3至10的一个整数，式（1）的n表示1至10的整数，R 1 式（1）的烷基是碳原子数为1〜4的烷基，式（1）的各R 2独立地为氢原子或甲基。透镜还包括衍生自由式（2）表示的第二硅氧烷单体的单元：其中式（2）的R 1选自氢原子或甲基; 式（2）的R2选自氢原子或碳原子数为1〜4的烃基; 式（2）的m表示0〜10的整数，式（2）的n表示4〜100的整数， a和b表示1以上的整数; a + b等于20-500; b /（a + b）等于0.01-0.22; 硅氧烷单元的构型包括随机构型，第二硅氧烷单体的数均分子量为至少3,000道尔顿，其存在于可聚合组合物中，其量使得第一硅氧烷单体与第二硅氧烷单体的比率在至少2：1，单位重量份。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

23. 发明申请

US20120220743A1 Dimensionally Stable Silicone Hydrogel Contact Lenses 有权
标题翻译：尺寸稳定的硅胶水凝胶隐形眼镜
公开(公告)号：US20120220743A1
公开(公告)日：2012-08-30
申请号：US13404034
申请日：2012-02-24
申请人： Charles A. Francis , Ying Zheng , Yuan Xu , Li Yao , Arthur Back , Ye Hong , Charlie Chen
发明人： Charles A. Francis , Ying Zheng , Yuan Xu , Li Yao , Arthur Back , Ye Hong , Charlie Chen
IPC分类号： C08F230/08
CPC分类号： C08F230/08 , C08F222/1006
摘要： Dimensionally stable silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including a first siloxane monomer represented by formula (1): wherein m of formula (1) represents one integer from 3 to 10, n of formula (1) represents one integer from 1 to 10, R1 of formula (1) is an alkyl group having from 1 to 4 carbon atoms, and each R2 of formula (1) is independently either a hydrogen atom or a methyl group; the lenses also include units derived from a second siloxane monomer represented by formula (2): wherein R1 of formula (2) is selected from either hydrogen atom or a methyl group; R2 of formula (2) is selected from either of hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms; m of formula (2) represents an integer of from 0 to 10; n of formula (2) represents an integer of from 4 to 100; a and b represent integers of 1 or more; a+b is equal to 20-500; b/(a+b) is equal to 0.01-0.22; the configuration of siloxane units includes a random configuration, the second siloxane monomer having a number average molecular weight of at least 3,000 daltons that is present in the polymerizable composition in an amount such that ratio of the first siloxane monomer to the second siloxane monomer is at least 2:1 based on unit parts by weight. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了尺寸稳定的硅酮水凝胶隐形眼镜。透镜衍生自包含由式（1）表示的第一硅氧烷单体的可聚合组合物：其中式（1）的m表示3至10的一个整数，式（1）的n表示1至10的整数，R 1 式（1）的烷基是碳原子数为1〜4的烷基，式（1）的各R 2独立地为氢原子或甲基。透镜还包括衍生自由式（2）表示的第二硅氧烷单体的单元：其中式（2）的R 1选自氢原子或甲基; 式（2）的R2选自氢原子或碳原子数为1〜4的烃基; 式（2）的m表示0〜10的整数，式（2）的n表示4〜100的整数， a和b表示1以上的整数; a + b等于20-500; b /（a + b）等于0.01-0.22; 硅氧烷单元的构型包括随机构型，第二硅氧烷单体的数均分子量为至少3,000道尔顿，其存在于可聚合组合物中，其量使得第一硅氧烷单体与第二硅氧烷单体的比率在至少2：1，单位重量份。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

24. 发明申请

US20140024738A1 Silicone Hydrogel Contact Lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US20140024738A1
公开(公告)日：2014-01-23
申请号：US13983578
申请日：2012-02-23
申请人： Charlie Chen , Yuwen Liu , Yuan Xu , Ying Zheng , Junhao Ge , Li Yao , Arthur Back
发明人： Charlie Chen , Yuwen Liu , Yuan Xu , Ying Zheng , Junhao Ge , Li Yao , Arthur Back
IPC分类号： G02B1/04
CPC分类号： G02B1/043 , C08L51/085 , C08L83/04 , C08L101/14
摘要： Silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including 30-60 unit parts by weight of a hydrophilic monomer(s) having one N-vinyl group, 10 to 50 unit parts by weight of 2-hydroxyethyl methacrylate (HEMA), and a first siloxane monomer component comprising a siloxane monomer of formula (1) as described herein or a siloxane monomer of formula (2) as described herein or a siloxane monomer of formula (3) as described herein or any combination thereof, where the total amount of siloxane monomer(s) present in the polymerizable composition is from 15 to 40 unit parts by weight. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了硅酮水凝胶隐形眼镜。透镜衍生自可聚合组合物，其包含30-60单位重量份的具有一个N-乙烯基的亲水性单体，10-50单位重量份的甲基丙烯酸2-羟乙酯（HEMA）和第一个硅氧烷单体组分，其包含本文所述的式（1）的硅氧烷单体或本文所述的式（2）的硅氧烷单体或本文所述的式（3）的硅氧烷单体或其任何组合，其中硅氧烷单体的总量存在于聚合性组合物中的重量比为15〜40单位份。还描述了硅胶水凝胶隐形眼镜的批次和制造硅酮水凝胶隐形眼镜的方法。

25. 发明授权

US09121998B2 Silicone hydrogel contact lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US09121998B2
公开(公告)日：2015-09-01
申请号：US13983578
申请日：2012-02-23
申请人： Charlie Chen , Yuwen Liu , Yuan Xu , Ying Zheng , Junhao Ge , Li Yao , Arthur Back
发明人： Charlie Chen , Yuwen Liu , Yuan Xu , Ying Zheng , Junhao Ge , Li Yao , Arthur Back
IPC分类号： C08L101/14 , C08L83/04 , G02C7/04 , G02B1/04
CPC分类号： G02B1/043 , C08L51/085 , C08L83/04 , C08L101/14
摘要： Silicone hydrogel contact lenses are described. The lenses are derived from a polymerizable composition including 30-60 unit parts by weight of a hydrophilic monomer(s) having one N-vinyl group, 10 to 50 unit parts by weight of 2-hydroxyethyl methacrylate (HEMA), and a first siloxane monomer component comprising a siloxane monomer of formula (1) as described herein or a siloxane monomer of formula (2) as described herein or a siloxane monomer of formula (3) as described herein or any combination thereof, where the total amount of siloxane monomer(s) present in the polymerizable composition is from 15 to 40 unit parts by weight. Batches of silicone hydrogel contact lenses and methods of making silicone hydrogel contact lenses are also described.
摘要翻译：描述了硅酮水凝胶隐形眼镜。透镜衍生自可聚合组合物，其包含30-60单位重量份的具有一个N-乙烯基的亲水性单体，10-50单位重量份的甲基丙烯酸2-羟乙酯（HEMA）和第一个硅氧烷单体组分，其包含本文所述的式（1）的硅氧烷单体或本文所述的式（2）的硅氧烷单体或本文所述的式（3）的硅氧烷单体或其任何组合，其中硅氧烷单体的总量存在于聚合性组合物中的重量比为15〜40单位份。还描述了硅胶水凝胶隐形眼镜的批次和制备硅酮水凝胶隐形眼镜的方法。

26. 发明申请

US20140016085A1 Silicone Hydrogel Contact Lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US20140016085A1
公开(公告)日：2014-01-16
申请号：US13982032
申请日：2012-02-23
申请人： Junhao Ge , Yuwen Liu , Charlie Chen , Yuan Xu , Ye Hong , Hongjin Qiu
发明人： Junhao Ge , Yuwen Liu , Charlie Chen , Yuan Xu , Ye Hong , Hongjin Qiu
IPC分类号： G02C7/04
CPC分类号： G02C7/049 , G02B1/043 , C08L83/04 , C08L101/14
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one hydrophilic vinyl amide-containing monomer, at least one acrylate-containing siloxane monomer, and at least one hydrophilic vinyl ether-containing monomer. The contact lenses have ophthalmically-acceptable surface wettability and can be manufactured without the use of volatile organic solvents.
摘要翻译：硅氧水凝胶隐形眼镜由包含至少一种含亲水性乙烯基酰胺的单体，至少一种含丙烯酸酯的硅氧烷单体和至少一种含亲水性乙烯基醚的单体的可聚合组合物的反应产物形成。隐形眼镜具有眼科可接受的表面润湿性，并且可以在不使用挥发性有机溶剂的情况下制造。

27. 发明授权

US09140908B2 Silicone hydrogel contact lenses 有权
标题翻译：硅胶水凝胶隐形眼镜
公开(公告)号：US09140908B2
公开(公告)日：2015-09-22
申请号：US13982032
申请日：2012-02-23
申请人： Junhao Ge , Yuwen Liu , Charlie Chen , Yuan Xu , Ye Hong , Hongjin Qiu
发明人： Junhao Ge , Yuwen Liu , Charlie Chen , Yuan Xu , Ye Hong , Hongjin Qiu
IPC分类号： G02C7/04 , G02B1/04
CPC分类号： G02C7/049 , G02B1/043 , C08L83/04 , C08L101/14
摘要： Silicone hydrogel contact lenses are formed from the reaction product of a polymerizable composition comprising at least one hydrophilic vinyl amide-containing monomer, at least one acrylate-containing siloxane monomer, and at least one hydrophilic vinyl ether-containing monomer. The contact lenses have ophthalmically-acceptable surface wettability and can be manufactured without the use of volatile organic solvents.
摘要翻译：硅氧水凝胶隐形眼镜由包含至少一种含亲水性乙烯基酰胺的单体，至少一种含丙烯酸酯的硅氧烷单体和至少一种含亲水性乙烯基醚的单体的可聚合组合物的反应产物形成。隐形眼镜具有眼科可接受的表面润湿性，并且可以在不使用挥发性有机溶剂的情况下制造。

28. 发明授权

US08642677B2 Phosphine-containing hydrogel contact lenses 有权
标题翻译：含磷的水凝胶隐形眼镜
公开(公告)号：US08642677B2
公开(公告)日：2014-02-04
申请号：US13404028
申请日：2012-02-24
申请人： Guigui Wang , Yun Zhang , Yuwen Liu , Ye Hong , Charlie Chen , Peter Zhu
发明人： Guigui Wang , Yun Zhang , Yuwen Liu , Ye Hong , Charlie Chen , Peter Zhu
IPC分类号： C08F8/00
CPC分类号： G02B1/043 , A45C11/005 , B65D81/22 , C08L83/04
摘要： Hydrogel contact lenses that are derived from a polymerizable composition including at least one hydrophilic monomer and at least one phosphine-containing component are described. The hydrogel of the contact lenses can be a silicone hydrogel or a non-silicone hydrogel. Use of polymerizable compositions comprising a phosphine-containing component can be cured under both inert and air atmospheres, and can be used to form hydrogel contact lenses having improved shape retention properties, having improved resistance to discoloration. Batches of hydrogel contact lenses and methods of making hydrogel contact lenses are also described.
摘要翻译：描述了衍生自包含至少一种亲水性单体和至少一种含膦组分的可聚合组合物的水凝胶隐形眼镜。隐形眼镜的水凝胶可以是硅酮水凝胶或非硅氧水凝胶。包含含膦组分的可聚合组合物的使用可以在惰性和空气气氛下固化，并且可用于形成具有改善的变色保持性能的具有改进的抗变色性的水凝胶隐形眼镜。还描述了水凝胶隐形眼镜的批次和制备水凝胶隐形眼镜的方法。

29. 发明申请

US20120220688A1 Phosphine-Containing Hydrogel Contact Lenses 有权
标题翻译：含磷的水凝胶隐形眼镜
公开(公告)号：US20120220688A1
公开(公告)日：2012-08-30
申请号：US13404028
申请日：2012-02-24
申请人： Guigui Wang , Yun Zhang , Yuwen Liu , Ye Hong , Charlie Chen , Peter Zhu
发明人： Guigui Wang , Yun Zhang , Yuwen Liu , Ye Hong , Charlie Chen , Peter Zhu
IPC分类号： G02B1/04 , G02C7/04 , B65D85/00
CPC分类号： G02B1/043 , A45C11/005 , B65D81/22 , C08L83/04
摘要： Hydrogel contact lenses that are derived from a polymerizable composition including at least one hydrophilic monomer and at least one phosphine-containing component are described. The hydrogel of the contact lenses can be a silicone hydrogel or a non-silicone hydrogel. Use of polymerizable compositions comprising a phosphine-containing component can be cured under both inert and air atmospheres, and can be used to form hydrogel contact lenses having improved shape retention properties, having improved resistance to discoloration. Batches of hydrogel contact lenses and methods of making hydrogel contact lenses are also described.
摘要翻译：描述了衍生自包含至少一种亲水性单体和至少一种含膦组分的可聚合组合物的水凝胶隐形眼镜。隐形眼镜的水凝胶可以是硅酮水凝胶或非硅氧水凝胶。包含含膦组分的可聚合组合物的使用可以在惰性和空气气氛下固化，并且可用于形成具有改善的变色保持性能的具有改进的抗变色性的水凝胶隐形眼镜。还描述了水凝胶隐形眼镜的批次和制备水凝胶隐形眼镜的方法。

30. 发明授权

US08865929B2 Reactive dyes for contact lenses 有权
标题翻译：隐形眼镜用活性染料
公开(公告)号：US08865929B2
公开(公告)日：2014-10-21
申请号：US14131915
申请日：2012-07-17
申请人： Yuan Xu , Charlie Chen , Charles A. Francis , Shane Mao , Hong Xue , Xining Zhang
发明人： Yuan Xu , Charlie Chen , Charles A. Francis , Shane Mao , Hong Xue , Xining Zhang
IPC分类号： C09B62/465 , C09B1/34 , G02B1/04 , C09B62/80 , C09B69/10 , C09B1/16
CPC分类号： C09B1/343 , C09B1/16 , C09B1/34 , C09B62/80 , C09B69/101 , G02B1/043 , C08L101/14 , C08L101/12
摘要： A method for preparing a polymerizable monomer-dye compound is provided in which a monomer, a reactive dye, and base are combined under substantially anhydrous reaction conditions to form the polymerizable monomer-dye compound, wherein the monomer comprises a pendant reactive group that covalently links to the reactive dye to form the monomer-dye compound.
摘要翻译：提供了一种制备可聚合单体 - 染料化合物的方法，其中单体，活性染料和碱在基本上无水的反应条件下组合以形成可聚合单体 - 染料化合物，其中单体包括共价连接与活性染料反应形成单体 - 染料化合物。

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