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21. 发明授权

US08409480B2 Process for preparing organic alkali metal compound and organic transition metal compound 有权
标题翻译：制备有机碱金属化合物和有机过渡金属化合物的方法
公开(公告)号：US08409480B2
公开(公告)日：2013-04-02
申请号：US12745868
申请日：2008-12-02
申请人： Atsushi Sakuma , Munehito Funaya
发明人： Atsushi Sakuma , Munehito Funaya
IPC分类号： C07F3/04
CPC分类号： C07F1/02 , C07F17/00
摘要： [Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp (1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound. In the formula (2), Ra to Rc are each an atom or a group selected from a hydrogen atom, a hydrocarbon group, a heteroatom-containing group and a silicon-containing group and may be the same as or different from each other, and the neighboring substituents may be bonded to each other to form a ring.
摘要翻译：提供一种以高产率获得有机碱金属化合物的制备方法和使用有机碱金属化合物制备有机过渡金属化合物的方法。 [解决问题的方法]一种制备有机碱金属化合物的方法，其特征在于在下式（1）表示的含活性质子的化合物的反应中加入下式（2）表示的化合物，与碱金属化合物。 RHp（1）在式（1）中，R为烃基或氨基，可以含有卤原子，硅原子，氧原子或氮原子，H为活性质子，p为数的氢原子与碱金属化合物的反应中抽出。在式（2）中，Ra至Rc各自为选自氢原子，烃基，含杂原子的基团和含硅基团的原子或基团，并且可以彼此相同或不同，并且相邻的取代基可以彼此键合形成环。

22. 发明申请

US20120049391A1 PROCESS FOR PREPARING ORGANIC ALKALI METAL COMPOUND AND ORGANIC TRANSITION METAL COMPOUND 有权
标题翻译：制备有机碱金属化合物和有机过渡金属化合物的方法
公开(公告)号：US20120049391A1
公开(公告)日：2012-03-01
申请号：US12745868
申请日：2008-12-02
申请人： Atsushi Sakuma , Munehito Funaya
发明人： Atsushi Sakuma , Munehito Funaya
IPC分类号： C07F1/02 , C07F17/00
CPC分类号： C07F1/02 , C07F17/00
摘要： [Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp (1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound. In the formula (2), Ra to Rc are each an atom or a group selected from a hydrogen atom, a hydrocarbon group, a heteroatom-containing group and a silicon-containing group and may be the same as or different from each other, and the neighboring substituents may be bonded to each other to form a ring.
摘要翻译：提供一种以高产率获得有机碱金属化合物的制备方法和使用有机碱金属化合物制备有机过渡金属化合物的方法。 [解决问题的方法]一种制备有机碱金属化合物的方法，其特征在于在下式（1）表示的含活性质子的化合物的反应中加入下式（2）表示的化合物，与碱金属化合物。 RHp（1）在式（1）中，R为烃基或氨基，可以含有卤原子，硅原子，氧原子或氮原子，H为活性质子，p为数的氢原子与碱金属化合物的反应中抽出。在式（2）中，Ra至Rc各自为选自氢原子，烃基，含杂原子的基团和含硅基团的原子或基团，并且可以彼此相同或不同，并且相邻的取代基可以彼此键合形成环。

23. 发明申请

US20100029877A1 SOLID CATALYST FOR OLEFIN POLYMERIZATION, OLEFIN POLYMERIZATION METHOD, AND OLEFIN POLYMER PARTICLE PRODUCED BY THE METHOD 审中-公开
标题翻译：用于烯烃聚合的固体催化剂，烯烃聚合方法和由方法生产的烯烃聚合物颗粒
公开(公告)号：US20100029877A1
公开(公告)日：2010-02-04
申请号：US12448138
申请日：2007-12-19
申请人： Munehito Funaya , Atsushi Sakuma , Masahiro Yamashita
发明人： Munehito Funaya , Atsushi Sakuma , Masahiro Yamashita
IPC分类号： C08F4/00 , B01J31/02
CPC分类号： C08F10/00 , C08F4/6592 , C08F4/65927 , C08F210/06 , C08F210/16 , C08F4/65916 , C08F4/65912 , C08F2500/26
摘要： An object of the present invention is to provide solid catalyst component for manufacturing an olefin polymer having an excellent particulate morphology without the concern of causing fouling, and a polymerization of olefin in the presence of said solid catalyst component.A solid catalyst (K) for olefin polymerization of the invention is characterized by meeting the following requirements [1] and [2]: [1] a loss of ignition is 30 wt % or less as measured on a differential thermogravimeter; and [2] after treating the catalyst with water vapor of room temperature and then contacting it with acetonitrile, a component eluted into the acetonitrile comprises a compound having a molecular skeleton represented by the following general formula [I]. (R in the above formula [I] is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms.)
摘要翻译：本发明的目的是提供用于制造具有优异颗粒形态的烯烃聚合物的固体催化剂组分，而不关心引起结垢，并且在所述固体催化剂组分存在下聚合烯烃。本发明的烯烃聚合用固体催化剂（K）的特征在于满足以下要求[1]和[2]：[1]在差示热重分析仪上测得的点火损失为30重量％以下; 和[2]在用室温水蒸汽处理催化剂之后，然后与乙腈接触，洗脱到乙腈中的组分包含具有由以下通式[I]表示的分子骨架的化合物。（上述式[I]中的R是氢原子或碳原子数1〜12的烷基）

24. 发明授权

US07244808B2 Thiourethane-based optical material 有权
标题翻译：硫代氨基甲酸酯类光学材料
公开(公告)号：US07244808B2
公开(公告)日：2007-07-17
申请号：US10509765
申请日：2003-12-12
申请人： Mamoru Tanaka , Shigetoshi Kuma , Munehito Funaya , Seiichi Kobayashi
发明人： Mamoru Tanaka , Shigetoshi Kuma , Munehito Funaya , Seiichi Kobayashi
IPC分类号： C08G75/00 , C08G75/04
CPC分类号： C08G18/7642 , C08G18/3876 , G02B1/04 , C08L75/04 , C08L81/00
摘要： A composition for making a high-refractive-index resin contains a polythiol compound and a compound containing at least two iso(thio)cyanato groups, the polythiol compound having a dithioacetal, dithioketal, orthotrithioformic ester, or orthotetrathiocarbonic ester skeleton. The molar ratio of the mercapto group to the iso(thio)cyanato group in the composition is greater than 1.0 but not more than 3.0. A method for making a resin by curing the composition, a resin prepared by curing the composition, an optical element made from the resin, and a lens made from the optical element are also provided.
摘要翻译：用于制备高折射率树脂的组合物含有多硫醇化合物和含有至少两个异（硫）氰酸基的化合物，多硫醇化合物具有二硫缩醛，二硫缩酮，邻二硫代甲酸酯或邻四硫代碳酸酯骨架。组合物中巯基与异（硫）氰酸基的摩尔比大于1.0但不大于3.0。还提供了通过固化组合物制备树脂的方法，通过固化组合物制备的树脂，由树脂制成的光学元件和由光学元件制成的透镜。

25. 发明授权

US07396900B2 Thiourethane-based optical material 有权
标题翻译：硫代氨基甲酸酯类光学材料
公开(公告)号：US07396900B2
公开(公告)日：2008-07-08
申请号：US11707919
申请日：2007-02-20
申请人： Mamoru Tanaka , Shigetoshi Kuma , Munehito Funaya , Seiichi Kobayashi
发明人： Mamoru Tanaka , Shigetoshi Kuma , Munehito Funaya , Seiichi Kobayashi
IPC分类号： C08G75/00 , C08G75/04
CPC分类号： C08G18/7642 , C08G18/3876 , G02B1/04 , C08L75/04 , C08L81/00
摘要： A composition for making a high-refractive-index resin contains a polythiol compound and a compound containing at least two iso(thio)cyanato groups, the polythiol compound having a dithioacetal, dithioketal, orthotrithioformic ester, or orthotetrathiocarbonic ester skeleton. The molar ratio of the mercapto group to the iso(thio)cyanato group in the composition is greater than 1.0 but not more than 3.0. A method for making a resin by curing the composition, a resin prepared by curing the composition, an optical element made from the resin, and a lens made from the optical element are also provided.
摘要翻译：用于制备高折射率树脂的组合物含有多硫醇化合物和含有至少两个异（硫）氰酸基的化合物，多硫醇化合物具有二硫缩醛，二硫缩酮，邻二硫代甲酸酯或邻四硫代碳酸酯骨架。组合物中巯基与异（硫）氰酸基的摩尔比大于1.0但不大于3.0。还提供了通过固化组合物制备树脂的方法，通过固化组合物制备的树脂，由树脂制成的光学元件和由光学元件制成的透镜。

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