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    • 2. 发明申请
    • Propylene Random Block Copolymer, Resin Composition Containing the Copolymer and Molded Article Made Thereof
    • 丙烯无规嵌段共聚物,含有共聚物的树脂组合物及其制成的模制品
    • US20090069523A1
    • 2009-03-12
    • US12225689
    • 2007-03-27
    • Keita ItakuraSatoshi HashizumeKunihiko TakesueMunehito Funaya
    • Keita ItakuraSatoshi HashizumeKunihiko TakesueMunehito Funaya
    • C08F210/00
    • C08F297/083C08L23/142C08L2207/02C08L23/16
    • The invention provides a propylene random block copolymer (A) that has a melt flow rate from 0.1 to 100 g/10 min and a melting point from 100 to 155° C. and includes 90 to 60% by weight of a portion insoluble (Dinsol) in n-decane at room temperature and 10 to 40% by weight of a portion soluble (Dsol) in n-decane at room temperature, wherein the Dinsol satisfies the following requirements (1) through (3) and the Dsol satisfies the following requirements (4) through (6). The invention further provides molded articles such as sheets, films, injection molded articles, hollow molded articles, injection blow molded articles and fibers, which are formed of the propylene random block copolymer (A) or a propylene resin composition containing the propylene random block copolymer (A). (1) The molecular weight distribution (Mw/Mn) obtained by GPC of the Dinsol is from 1.0 to 3.5, (2) the content of skeletons derived from ethylene in the Dinsol is from 0.5 to 13% by mole, (3) the total amount of 2,1- and 1,3-propylene units in the Dinsol is 0.2% by mole or less, (4) the molecular weight distribution (Mw/Mn) obtained by GPC of the Dsol is from 1.0 to 3.5, (5) the intrinsic viscosity [η] in decalin at 135° C. of the Dsol is from 1.5 to 4 dl/g and (6) the content of skeletons derived from ethylene in the Dsol is from 15 to 35% by mole.
    • 本发明提供一种丙烯无规嵌段共聚物(A),其熔体流动速率为0.1-100g / 10min,熔点为100-155℃,包括90-60wt%的不溶物(Dinsol )和室温下正癸烷中可溶解部分(Dsol)的10〜40重量%,其中,D insol为(1)〜(3),Dsol满足下述式 要求(4)至(6)。 本发明还提供了由丙烯无规嵌段共聚物(A)形成的成型制品,例如片材,薄膜,注塑制品,中空成型制品,注塑吹塑制品和纤维,或含丙烯无规嵌段共聚物 (一个)。 (1)由Dinsol得到的分子量分布(Mw / Mn)为1.0〜3.5,(2)由Dinsol得到的乙烯的骨架含量为0.5〜13摩尔%,(3) D insol中的2,1-和1,3-丙烯单元的总量为0.2摩尔%以下,(4)通过Dsol的GPC得到的分子量分布(Mw / Mn)为1.0〜3.5( 5)Dsol的135℃萘烷中的特性粘度η为1.5〜4dl / g,(6)Dsol中衍生自乙烯的骨架含量为15〜35摩尔%。
    • 4. 发明授权
    • Process for preparing organic alkali metal compound and organic transition metal compound
    • 制备有机碱金属化合物和有机过渡金属化合物的方法
    • US08409480B2
    • 2013-04-02
    • US12745868
    • 2008-12-02
    • Atsushi SakumaMunehito Funaya
    • Atsushi SakumaMunehito Funaya
    • C07F3/04
    • C07F1/02C07F17/00
    • [Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp   (1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound. In the formula (2), Ra to Rc are each an atom or a group selected from a hydrogen atom, a hydrocarbon group, a heteroatom-containing group and a silicon-containing group and may be the same as or different from each other, and the neighboring substituents may be bonded to each other to form a ring.
    • 提供一种以高产率获得有机碱金属化合物的制备方法和使用有机碱金属化合物制备有机过渡金属化合物的方法。 [解决问题的方法]一种制备有机碱金属化合物的方法,其特征在于在下式(1)表示的含活性质子的化合物的反应中加入下式(2)表示的化合物, 与碱金属化合物。 RHp(1)在式(1)中,R为烃基或氨基,可以含有卤原子,硅原子,氧原子或氮原子,H为活性质子,p为数 的氢原子与碱金属化合物的反应中抽出。 在式(2)中,Ra至Rc各自为选自氢原子,烃基,含杂原子的基团和含硅基团的原子或基团,并且可以彼此相同或不同, 并且相邻的取代基可以彼此键合形成环。
    • 5. 发明申请
    • PROCESS FOR PREPARING ORGANIC ALKALI METAL COMPOUND AND ORGANIC TRANSITION METAL COMPOUND
    • 制备有机碱金属化合物和有机过渡金属化合物的方法
    • US20120049391A1
    • 2012-03-01
    • US12745868
    • 2008-12-02
    • Atsushi SakumaMunehito Funaya
    • Atsushi SakumaMunehito Funaya
    • C07F1/02C07F17/00
    • C07F1/02C07F17/00
    • [Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp  (1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound. In the formula (2), Ra to Rc are each an atom or a group selected from a hydrogen atom, a hydrocarbon group, a heteroatom-containing group and a silicon-containing group and may be the same as or different from each other, and the neighboring substituents may be bonded to each other to form a ring.
    • 提供一种以高产率获得有机碱金属化合物的制备方法和使用有机碱金属化合物制备有机过渡金属化合物的方法。 [解决问题的方法]一种制备有机碱金属化合物的方法,其特征在于在下式(1)表示的含活性质子的化合物的反应中加入下式(2)表示的化合物, 与碱金属化合物。 RHp(1)在式(1)中,R为烃基或氨基,可以含有卤原子,硅原子,氧原子或氮原子,H为活性质子,p为数 的氢原子与碱金属化合物的反应中抽出。 在式(2)中,Ra至Rc各自为选自氢原子,烃基,含杂原子的基团和含硅基团的原子或基团,并且可以彼此相同或不同, 并且相邻的取代基可以彼此键合形成环。