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    • 22. 发明授权
    • Process for the preparation of polybenzazole filaments and fibers
    • 制备聚吲哚长丝和纤维的方法
    • US5525638A
    • 1996-06-11
    • US500651
    • 1995-07-12
    • Ashish SenYoshihiko Teramoto
    • Ashish SenYoshihiko Teramoto
    • D01F6/74C08F6/00C08J9/26C08J9/28
    • D01F6/74
    • Described is a continuous process for removing polyphosphoric acid from a polybenzazole dope filament, which comprises: (a) contacting the dope filament with water or a mixture of water and polyphosphoric acid under conditions sufficient to reduce the phosphorous content of the filament to less than about 10,000 ppm by weight; and then (b) contacting the dope filament with an aqueous solution of an inorganic base under conditions sufficient to convert at least about 50 percent of the polyphosphoric acid groups present in the filament to a salt of the base and the acid. It has been discovered that contacting the dope filament with a solution of a base after washing the filament to remove most of the residual phosphorous advantageously leads to an improvement in the initial tensile strength of the filament, as well as improved retention of tensile strength and/or molecular weight (of the polybenzazole polymer) following exposure to light and/or high temperatures.
    • 描述了从聚吲哚染料丝中除去多磷酸的连续方法,该方法包括:(a)在足以将丝的磷含量降低到小于约的条件下将纺丝原液丝与水或水和多磷酸的混合物接触 10,000重量ppm; 然后(b)在足以将存在于长丝中的至少约50%的多聚磷酸基团转化为碱和酸的盐的条件下,将纺丝原液丝与无机碱的水溶液接触。 已经发现,在洗涤丝之后将涂料丝与碱的溶液接触以去除大部分残留的磷,有利地导致丝的初始拉伸强度的改善,以及改善拉伸强度和/ 或分子量(聚苯并恶唑聚合物的)在暴露于光和/或高温之后。
    • 29. 发明授权
    • Thermoplastic polymer compositions with modified electrical conductivity
    • 具有改进导电性的热塑性聚合物组合物
    • US5844037A
    • 1998-12-01
    • US686634
    • 1996-07-24
    • Richard A. LundgardSusan J. BabinecRobert D. MussellAshish Sen
    • Richard A. LundgardSusan J. BabinecRobert D. MussellAshish Sen
    • C08J3/20C08J3/22C08L101/00H01B1/24C08K3/04C08L23/04H01B1/06
    • C08J3/226H01B1/24C08J2423/00Y10S524/901
    • A process for preparing an electronically-conductive thermoplastic composition having at least two phases, which includes (A) combining an amorphous or semi-crystalline thermoplastic polymer or miscible blend of polymers with an electronically-conductive carbon under conditions sufficient to disperse the conductive carbon, thereby forming a mixture having at least one phase, with at least 60 percent of the carbon dispersed in a first phase which comprises at least 90 percent by weight of the mixture; and (B) combining the mixture obtained from step (A) with an amorphous or semi-crystalline thermoplastic polymer or miscible blend of polymers, at least a portion of which is immiscible in the first phase, thereby forming a composition having at least two phases. Compositions prepared by this process are sufficiently conductive to be useful for a variety of applications, such as structural materials for applications requiring electromotively-paintable substrates.
    • 一种用于制备具有至少两相的电子导电热塑性组合物的方法,其包括(A)在足以分散导电碳的条件下将非晶或半结晶热塑性聚合物或可混合的聚合物共混物与电子导电碳组合, 从而形成具有至少一相的混合物,其中至少60%的碳分散在包含至少90重量%混合物的第一相中; 和(B)将从步骤(A)获得的混合物与无定形或半结晶热塑性聚合物或可混合的聚合物共混物组合,其至少一部分在第一相中是不混溶的,从而形成具有至少两相的组合物 。 通过该方法制备的组合物具有足够的导电性,可用于各种应用,例如需要电动涂漆基材的应用的结构材料。