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    • 21. 发明授权
    • Method for detecting and measuring CH.sub.4 with GA.sub.2 O.sub.3 sensor
    • 使用GA2O3传感器检测和测量CH4的方法
    • US5889198A
    • 1999-03-30
    • US853927
    • 1997-05-09
    • Norbert ReitmeierMaximilian FleischerHans Meixner
    • Norbert ReitmeierMaximilian FleischerHans Meixner
    • G01N27/04G01N27/12G01N33/00G01N25/00
    • G01N27/124
    • A method for detecting CH.sub.4 with a Ga.sub.2 O.sub.3 sensor, and a method for measuring CH.sub.4 concentration with a Ga.sub.2 O.sub.3 sensor is provided. In order to solve the problem associated with the masking or disturbing effect alcohol has on the detection of methane with a gallium oxide detector, the present invention provides a method where the sensor conductivity ((G(t.sub.1)) is acquired at a first sensor temperature, and is compared with a first threshold value. If the conductivity ((G(t.sub.1)) exceeds this threshold value, it is determined that alcohol is present in the gas mixture to be examined. The sensor is then heated, and a second conductivity (G(t.sub.2)) is acquired. If the ratio of the second to the first conductivity exceeds a second threshold value, CH.sub.4 is likewise present in the gas mixture. The measurement of the CH.sub.4 concentration ensues by means of an acquisition of two conductivities (G(t.sub.1), G(t.sub.2)) at different temperatures. The corresponding CH.sub.4 value can be taken from a table or reference plot.
    • 提供了用Ga 2 O 3传感器检测CH 4的方法,以及用Ga 2 O 3传感器测量CH 4浓度的方法。 为了解决与使用氧化镓检测器检测甲烷的掩蔽或扰乱效应相关的问题,本发明提供了一种在第一传感器温度下获取传感器电导率((G(t1))的方法, ,并与第一阈值进行比较,如果电导率((G(t1))超过该阈值,则判定在待检查的气体混合物中存在醇,然后将传感器加热,将第二导电率 (G(t2)),如果第二电导率与第一电导率的比值超过第二阈值,CH4同样存在于气体混合物中,CH4浓度的测量通过获得两个电导率 G(t1),G(t2)),相应的CH4值可以从表格或参考图中取出。
    • 24. 发明授权
    • Gas sensor
    • 气体传感器
    • US5824271A
    • 1998-10-20
    • US809264
    • 1997-03-13
    • Joachim FrankMaximilian FleischerHans Meixner
    • Joachim FrankMaximilian FleischerHans Meixner
    • G01N27/12G01N33/00G01N27/403
    • G01N33/0031G01N27/12Y10T436/205831Y10T436/208339Y10T436/214
    • A substrate carrying a first electrode and a second electrode, the first and second electrodes being disposed adjacent to one another, the first electrode being disposed between the substrate and a gas-sensitive component, the gas sensitive component comprising an n-type semiconductor, the gas-sensitive component having a resistance that is gas-dependent and temperature-dependent, and the second electrode being disposed between the substrate and a non-gas-sensitive component, the non-gas-sensitive component comprising a n-type semiconductor and a p-type semiconductor, the non-gas-sensitive component having a resistance that is temperature-dependent and that is not gas-dependent and wherein the n-type semiconductor of the non-gas-sensitive component is Ga.sub.2 O.sub.3 and the p-type semiconductor of the non-gas-sensitive component is ZrO.sub.2.
    • PCT No.PCT / DE95 / 01242 Sec。 371日期1997年3月13日 102(e)1997年3月13日PCT PCT 1995年9月11日PCT公布。 出版物WO96 / 0871200 日期1996年3月21日具有第一电极和第二电极的基板,第一和第二电极彼此相邻配置,第一电极设置在基板和气体敏感部件之间,气体敏感元件包括n 所述气敏元件具有气体依赖性和温度依赖性的电阻,所述第二电极设置在所述基板和非气体敏感性部件之间,所述非气敏元件包括n型半导体 型半导体和p型半导体,非气敏元件具有温度依赖性且不依赖于气体的电阻,其中非气敏元件的n型半导体为Ga 2 O 3, 非气敏组分的p型半导体是ZrO 2。
    • 26. 发明授权
    • Gas sensor array for detecting individual gas constituents in a gas mixture
    • 气体传感器阵列,用于检测气体混合物中的各种气体成分
    • US06235243B1
    • 2001-05-22
    • US07928443
    • 1992-08-12
    • Maximilian FleischerHans Meixner
    • Maximilian FleischerHans Meixner
    • G01N3112
    • G01N27/12G01N33/0031
    • A gas sensor array for detecting individual gas constituents in a gas sensor, said array being composed of a carrier member of a non-conductive substrate having a plurality of individual sensor elements formed by semiconductor oxides being applied thereon in a planar arrangement and the array is provided with contact electrode arrangements for measuring electrical conductivity, with a heating arrangement for heating a predetermined operating temperature and with protective sheaths for protecting the arrangement against external influences along with a fastening base so that the individual operating temperatures allocated to the various sensors and wherein the differences between respective sensor signals are formed for detecting the individual gas constituents, with these differences being supplied to a processing unit. In a preferred embodiment, at least one part of the individual sensor element is composed of a &bgr;-Ga2O3 thin film.
    • 一种用于检测气体传感器中的各种气体成分的气体传感器阵列,所述阵列由非导电基底的载体构件组成,所述非导电基底具有以半导体氧化物形成的多个单独的传感器元件,所述多个传感器元件以平面布置施加在其上, 设置有用于测量导电性的接触电极装置,具有用于加热预定工作温度的加热装置和用于保护装置与保护基座一起保护装置免受外部影响的加热装置,使得分配给各种传感器的各个操作温度,并且其中 形成各个传感器信号之间的差异,用于检测各个气体成分,这些差异被提供给处理单元。 在优选实施例中,单个传感器元件的至少一部分由β-Ga 2 O 3薄膜构成。
    • 29. 发明授权
    • Method for detecting methane in a gas mixture
    • 用于检测气体混合物中的甲烷的方法
    • US5635628A
    • 1997-06-03
    • US635517
    • 1996-04-22
    • Maximilian FleischerHans Meixner
    • Maximilian FleischerHans Meixner
    • G01N27/12G01N27/72G01N33/00G01N27/00G01N31/12
    • G01N33/0047G01N27/123G01N33/0016
    • A method and apparatus for detecting methane in a gas mixture that may contain commonly used solvents including alcohols and acetones is provided which measures a change in electrical resistivity, electrical conductivity or relative permeability caused by the presence of methane gas at a chemically active sensing structure. The apparatus includes two spaced-apart electrodes that are covered with a thin methane-sensitive semi-conductive metal oxide layer. The gas to be tested is heated to a temperature exceeding 740.degree. C. before it contacts the metal oxide layer. Alcohols, acetones and other solvents are oxidized to electrical carbon dioxide and water before they reach the metal oxide layer so that only the less reactive and reducing gas methane reaches the metal oxide layer where it is reduced and increases the conductivity of the metal oxide layer as measured between the two spaced-apart electrodes with an appropriate electrical meter instrument.
    • 提供了一种用于检测气体混合物中甲烷的方法和装置,其可以包含常用的溶剂,包括醇和丙酮,其测量由化学活性感测结构处的甲烷气体存在引起的电阻率,导电性或相对渗透率的变化。 该装置包括被薄的甲烷敏感的半导体金属氧化物层覆盖的两个间隔开的电极。 将待测试的气体在与金属氧化物层接触之前被加热至超过740℃的温度。 醇,丙酮和其他溶剂在它们到达金属氧化物层之前被氧化成电二氧化碳和水,使得只有较少的反应性和还原性气体甲烷到达其中被还原的金属氧化物层,并且将金属氧化物层的导电性提高为 在两个间隔开的电极之间用适当的电表仪器测量。