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21. 发明授权

US6046287A Process for the preparation of elastomeric copolymers of ethylene 失效
标题翻译：制备乙烯弹性共聚物的方法
公开(公告)号：US6046287A
公开(公告)日：2000-04-04
申请号：US825660
申请日：1997-04-03
申请人： Maurizio Galimberti , Enrico Albizzati
发明人： Maurizio Galimberti , Enrico Albizzati
IPC分类号： C08F2/02 , C08F2/14 , C08F4/60 , C08F4/622 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/16 , C08F210/18 , C08F4/68
CPC分类号： C08F210/18 , C08F210/16 , Y10S526/902 , Y10S526/916
摘要： Elastomeric ethylene/propylene or ethylene/propylene/-polyene copolymers containing small amounts of one or more .alpha.-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin. Problems due to fouling phenomena in the reactor are avoided.
摘要翻译：通过淤浆法制备含有少量一种或多种α-烯烃的弹性体乙烯/丙烯或乙烯/丙烯/ - 多烯共聚物，其中聚合反应在液态丙烯和α-烯烃的混合物中进行。避免了由于反应器中的结垢现象引起的问题。

22. 发明申请

US20090250151A1 Tire and crosslinkable elastomeric composition 审中-公开
标题翻译：轮胎和可交联弹性体组合物
公开(公告)号：US20090250151A1
公开(公告)日：2009-10-08
申请号：US12309316
申请日：2006-07-20
申请人： Maurizio Galimberti , Gaetano Guerra , Angela Lostritto , Luca Giannini
发明人： Maurizio Galimberti , Gaetano Guerra , Angela Lostritto , Luca Giannini
IPC分类号： B60C1/00 , C08L9/00 , C08K3/36 , C08K3/04
CPC分类号： B60C9/12 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C9/2006 , B60C9/22 , B60C11/005 , B60C17/0009 , B60C2001/0033 , B60C2011/0025 , B60C2017/0063 , C08K3/346 , C08K7/02 , C08K9/04 , C08L21/00 , C08L61/04 , C08L2666/16
摘要： A tire including at least one structural element includes a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition including: (a) 100 phr of at least one elastomeric polymer; (b) 0.1 phr to 15 phr, preferably 0.3 phr to 10 phr, of at least one methylene donor compound: c) 0.4 phr to 20 phr, preferably 0.8 phr to 15 phr of at least one methylene acceptor compound; (d) 1 phr to 50 phr, preferably 2 phr to 40 phr, more preferably 4 phr to 30 phr, of at least one layered material, the at least one layered material having an individual layer thickness of 0.2 nm to 30 nm, preferably 0.3 nm to 15 nm, more preferably 0.5 nm to 2 nm; wherein the at least one layered material shows, in an X-ray powder diffraction pattern, an X-ray intensity ratio (R) defined according to the following formula: (R)=[A(001)/A(hk0)max]×100 wherein: A(001) is the area of the peak (001); A(hk0)max is the area of the most intense peak (hk0), at least one of h or k being different from 0; lower than or equal to 20, preferably lower than or equal to 15, more preferably lower than or equal to 10, still more preferably lower than or equal to 5. Preferably, the at least one structural element is selected from bead filler, sidewall insert, tread underlayer and tread base.
摘要翻译：包括至少一种结构元件的轮胎包括通过交联可交联弹性体组合物获得的交联弹性体材料，其包含：（a）100phr的至少一种弹性体聚合物; （b）0.1phr至15phr，优选0.3phr至10phr的至少一种亚甲基供体化合物：c）0.4phr至20phr，优选0.8phr至15phr的至少一种亚甲基受体化合物; （d）1phr至50phr，优选2phr至40phr，更优选4phr至30phr的至少一种层状材料，所述至少一种层状材料具有0.2nm至30nm的单层厚度，优选 0.3nm〜15nm，更优选为0.5nm〜2nm; 其中所述至少一种分层材料以X射线粉末衍射图形式显示根据下式定义的X射线强度比（R）：（R）= [A（001）/ A（hk0）max] x100其中：A（001）是峰的面积（001）; A（hk0）max是最强峰（hk0）的面积，h或k中的至少一个不同于0; 低于或等于20，优选低于或等于15，更优选低于或等于10，还更优选低于或等于5.优选地，所述至少一种结构元件选自胎圈填料，侧壁插入物，胎面底层和胎面基部。

23. 发明申请

US20090194214A1 Tire and Crosslinkable Elastomeric Composition 审中-公开
标题翻译：轮胎和交联弹性组合物
公开(公告)号：US20090194214A1
公开(公告)日：2009-08-06
申请号：US12308221
申请日：2006-06-14
申请人： Maurizio Galimberti , Gaetano Guerra , Angela Lostritto
发明人： Maurizio Galimberti , Gaetano Guerra , Angela Lostritto
IPC分类号： B60C1/00 , B60C15/00 , B32B5/16 , C08K3/34 , C08L21/00
CPC分类号： B60C1/0016 , C08K3/346 , C08K9/04 , Y10T152/10819 , Y10T428/254 , Y10T428/269 , C08L21/00
摘要： A tire including at least one structural element including a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition including: (a) at least one elastomeric polymer; (b) at least one layered material, the layered material having an individual layer thickness of 0.2 nm to 30 nm, preferably 0.3 nm to 15 nm, more preferably 0.5 nm to 2 nm, wherein the layered material shows, in an X-ray powder diffraction pattern, an X-ray intensity ratio (R) defined according to the following formula: (R)=[A(001)/A(hk0)max]×100 wherein: A(001) is the area of the peak; A(hk0)max is the area of the most intense peak (hk0), at least one of h or k being different from 0; lower than or equal to 20, preferably lower than or equal to 15, more preferably lower than or equal to 10, still more preferably lower than or equal to 5. Preferably, the at least one structural element is a tire tread band.
摘要翻译：一种轮胎，其包括至少一种结构元件，其包括通过交联可交联弹性体组合物获得的交联弹性体材料，所述交联弹性体组合物包含：（a）至少一种弹性体聚合物; （b）至少一层分层材料，所述层状材料具有0.2nm至30nm，优选0.3nm至15nm，更优选0.5nm至2nm的单层厚度，其中层状材料在X射线粉末衍射图，根据下式定义的X射线强度比（R）：（R）= [A（001）/ A（hk0）max]×100其中：A（001）是峰的面积; A（hk0）max是最强峰（hk0）的面积，h或k中的至少一个不同于0; 低于或等于20，优选低于或等于15，更优选低于或等于10，还更优选低于或等于5.优选地，至少一个结构元件是轮胎胎面带。

24. 发明申请

US20090178748A1 Process for Manufacturing Tires 审中-公开
标题翻译：轮胎制造工艺
公开(公告)号：US20090178748A1
公开(公告)日：2009-07-16
申请号：US11988143
申请日：2005-07-01
申请人： Francesca Baione , Luigi Fino , Maurizio Galimberti , Luca Giannini , Attilio Citterio , Marco Martino
发明人： Francesca Baione , Luigi Fino , Maurizio Galimberti , Luca Giannini , Attilio Citterio , Marco Martino
IPC分类号： B60C9/18 , B29D30/08 , C08L9/00 , C08L23/22 , C08K3/36
CPC分类号： B29D30/0681 , B29D30/0602 , B29D2030/0682 , B60C1/00 , B60C1/0008 , Y10T152/10765
摘要： Process for manufacturing tires includes the following steps: forming at least one layer including a crosslinkable elastomeric material on an outer surface of a toroidal support the shape of which substantially matches that of the inner surface of the tire; manufacturing a green tire on the toroidal support bearing the at least one layer, the green tire including at least one structural element including a crosslinkable elastomeric material; wherein one crosslinkable elastomeric material of the at least one layer includes a crosslinkable elastomeric composition including at least one sulfur-curable elastomeric polymer and at least one compound having the following general formula (I): A-(S)p—B wherein: p is an integer of 2 to 10; and A and B, which may be the same or different from each other, represent a group having the following general formula (II):
摘要翻译：用于制造轮胎的方法包括以下步骤：在环形支撑件的外表面上形成包括可交联弹性体材料的至少一层，其形状基本上与轮胎的内表面的形状匹配; 在承载所述至少一个层的所述环形支撑件上制造生胎，所述生胎包括至少一个包括可交联弹性体材料的结构元件; 其中所述至少一层的一种可交联弹性体材料包括可交联的弹性体组合物，其包含至少一种可硫化的弹性体聚合物和至少一种具有以下通式（I）的化合物：A-（S）pB其中：p是 2〜10的整数; 和A和B可以相同或不同，表示具有以下通式（II）的基团：

25. 发明申请

US20070193669A1 High-performance tyre for vehicle wheels 审中-公开
标题翻译：用于车轮的高性能轮胎
公开(公告)号：US20070193669A1
公开(公告)日：2007-08-23
申请号：US10577020
申请日：2003-10-31
申请人： Luca Giannini , Luigi Fino , Maurizio Galimberti , Stefano Bizzi
发明人： Luca Giannini , Luigi Fino , Maurizio Galimberti , Stefano Bizzi
IPC分类号： B60C11/00
CPC分类号： B60C1/0016 , B60C1/00 , B60C1/0025 , B60C11/00 , B60C11/005 , B60C15/06 , B60C17/0009 , B60C2001/0033 , C08K7/02 , C08K9/04 , C08L7/00 , C08L9/00 , C08L21/00 , C08L61/00 , Y10T152/10513 , C08L2666/16
摘要： Tyre for vehicle wheels having a carcass structure shaped in a substantially toroidal configuration, the opposite lateral edges of which are associated with respective right-hand and left-hand bead wires to form respective beads; a belt structure applied in a radially external position with respect to the carcass structure; a tread band radially superimposed on the belt structure; at least one layer of crosslinked elastomeric material applied in a radially internal position with respect to the tread band; a pair of sidewalls applied laterally on opposite sides with respect to the carcass structure, wherein the at least one layer of crosslinked elastomeric material has a dynamic elastic modulus, measured at 70° C., not lower than 20 MPa, preferably 25 MPa to 50 MPa; a ratio between tensile modulus at 100% elongation and tensile modulus at 10% elongation not lower than 1.5, preferably 2 to 5. Preferably the at least one layer of crosslinked elastomeric material is placed between the tread band and the belt structure.
摘要翻译：具有形状为大致环形构造的胎体结构的车轮的轮胎，其相对的侧边缘与相应的右侧和左侧胎圈线相关联以形成相应的胎圈; 相对于胎体结构施加在径向外部位置的带结构; 径向叠加在带结构上的胎面带; 至少一层交联弹性体材料相对于胎面带施加在径向内部位置; 相对于胎体结构在相对侧面侧向施加的一对侧壁，其中所述至少一层交联的弹性体材料具有在70℃，不低于20MPa，优选25MPa至50℃下测量的动态弹性模量 MPa; 在100％伸长率下的拉伸模量和10％伸长率的拉伸模量之间的比率不低于1.5，优选为2至5。优选地，将至少一层交联的弹性体材料放置在胎面带和带结构之间。

26. 发明授权

US06331600B1 Elastomeric copolymers of ethylene and propylene 失效
标题翻译：乙烯和丙烯的弹性共聚物
公开(公告)号：US06331600B1
公开(公告)日：2001-12-18
申请号：US08841473
申请日：1997-04-22
申请人： Maurizio Galimberti , Enrico Albizzati
发明人： Maurizio Galimberti , Enrico Albizzati
IPC分类号： C08F21016
CPC分类号： C08F210/18 , C08F210/16 , Y10S526/943 , C08F4/6428 , C08F210/06 , C08F2500/17 , C08F2500/21 , C08F2500/15 , C08F2500/03
摘要： Novel copolymers of ethylene with propylene and optionally with minor proportions of a diene or polyene having good elastomeric properties in their uncured state. The copolymers are characterized by a structure in which the propylene is partially present in the form of short isotactic sequences. Tension set values (200%) of less than 15 are obtained by when the ethylene/propylene ratio has specific values and the intrinsic viscosity values are higher than 3.
摘要翻译：乙烯与丙烯的新型共聚物和任选的少量二烯或其未固化状态下具有良好弹性体性质的多烯的共聚物。共聚物的特征在于其中丙烯以短全同立构序列的形式部分存在的结构。当乙烯/丙烯比具有特定值并且特性粘度值高于3时，获得小于15的张力设定值（200％）。

27. 发明授权

US6160071A Elastomeric copolymers of ethylene with .alpha.-olefins and process for their preparation 失效
标题翻译：乙烯与α-烯烃的弹性共聚物及其制备方法
公开(公告)号：US6160071A
公开(公告)日：2000-12-12
申请号：US876864
申请日：1997-06-16
申请人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
IPC分类号： C08F4/642 , C08F4/42 , C08F4/60 , C08F10/00 , C08F210/16 , C08F210/18 , C08J5/00 , C08F10/04
CPC分类号： C08F210/16 , Y10S526/943 , C08F2/14 , C08F210/18 , C08F2500/03 , C08F2500/08 , C08F2500/17 , C08F2500/20 , C08F2500/21 , C08F210/08
摘要： Amorphous copolymers of ethylene with .alpha.-olefins and optionally minor amounts of polyenes are disclosed, having the following characteristics:(A) the % by mole content of .alpha.-olefin in the copolymer (%.alpha.) and the ratio between the molar amount of .alpha.-olefin diads and the molar content of .alpha.-olefin in the copolymer (.alpha..alpha./.alpha.) satisfy the following relationship:(%.alpha.)-250(.alpha..alpha./.alpha.).gtoreq.10(B) less than 2% of the CH.sub.2 groups in the polymeric chain are in sequences (CH.sub.2).sub.n, wherein n is an even number.These copolymers are obtainable by operating in the presence of particular metallocene-based catalysts having two fluorenyl groups joined together through a bridging group.
摘要翻译：公开了乙烯与α-烯烃和任选的少量多烯的无定形共聚物，具有以下特征：（A）共聚物中α-烯烃的摩尔％摩尔比（％α）和α的摩尔量之比 α-烯烃二烷基和α-烯烃在共聚物中的摩尔含量（αα/α）满足以下关系：（％α）-250（αα/α）> / = 10（B）小于聚合物链中的CH 2基团是（CH 2）n序列，其中n是偶数。这些共聚物可通过在具有通过桥连基团连接在一起的两个芴基的特定茂金属基催化剂存在下操作而获得。

28. 发明授权

US5585448A Process for the preparation of ethylene polymers and products obtained therefrom 失效
标题翻译：制备乙烯聚合物的方法及由其获得的产品
公开(公告)号：US5585448A
公开(公告)日：1996-12-17
申请号：US304379
申请日：1994-09-12
申请人： Luigi Resconi , Fabrizio Piemontesi , Maurizio Galimberti
发明人： Luigi Resconi , Fabrizio Piemontesi , Maurizio Galimberti
IPC分类号： C08F10/02 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/643
CPC分类号： C08F210/16 , C08F110/02 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Homo- and copolymers of ethylene endowed with very high molecular weights and narrow molecular weight distributions are obtainable by carrying out the polymerization reaction in the presence of a metallocene-based catalyst wherein the metallocene is stereorigid and it is in its meso isomeric form.
摘要翻译：具有非常高分子量和窄分子量分布的乙烯的均聚物和共聚物可以通过在金属茂基催化剂存在下进行聚合反应，其中金属茂是立体刚性的并且是其内消旋异构形式。

29. 发明申请

US20130280534A1 DISORDERED NANOPOROUS CRYSTALLINE FORM OF SYNDIOTACTIC POLYSTYRENE, PROCESS FOR ITS PREPARATION AND ARTICLES COMPRISING THE SAME 有权
标题翻译：异构聚苯乙烯的不规则的纳米结晶形式，其制备方法和包含其的制品
公开(公告)号：US20130280534A1
公开(公告)日：2013-10-24
申请号：US13977167
申请日：2011-12-29
申请人： Alexandra Romina Albunia , Riccardo Bianchi , Luciano Di Maio , Maurizio Galimberti , Gaetano Guerra , Roberto Pantani , Stanislao Senatore
发明人： Alexandra Romina Albunia , Riccardo Bianchi , Luciano Di Maio , Maurizio Galimberti , Gaetano Guerra , Roberto Pantani , Stanislao Senatore
IPC分类号： C08F112/08 , C09D125/06
CPC分类号： C08F112/08 , C08J5/18 , C08J7/02 , C08J7/047 , C08J9/28 , C08J2323/12 , C08J2325/06 , C08J2425/06 , C08J2433/06 , C09D125/06 , D01F6/22 , Y10T428/2982
摘要： There is described a new disordered nanoporous crystalline form of syndiotactic polystyrene, characterized by a specific X-ray diffractrogram, the process for its preparation and various articles comprising this form of s-PS. This disordered nanoporous crystalline form exhibits empty crystalline cavities of nanometric sizes, and in this case performs the function of absorbing molecules with low molecular mass and is useful in particular as functionally active packaging for plant products.
摘要翻译：描述了间同立构聚苯乙烯的新的无序纳米孔结晶形式，其特征在于特定的X射线衍射图，其制备方法和包含这种形式的s-PS的各种制品。这种无序的纳米多孔结晶形式呈现出纳米尺寸的空的晶体空腔，在这种情况下，其具有吸收低分子量分子的功能，尤其可用作植物产品的功能活性包装。

30. 发明授权

US07166665B2 Elastomeric composition and tire comprising the composition 有权
标题翻译：弹性组合物和包含该组合物的轮胎
公开(公告)号：US07166665B2
公开(公告)日：2007-01-23
申请号：US10169408
申请日：2000-12-14
申请人： Maurizio Galimberti , Luigi Fino , Claudio Zanichelli , Enrico Albizzati
发明人： Maurizio Galimberti , Luigi Fino , Claudio Zanichelli , Enrico Albizzati
IPC分类号： C08K3/04 , C08K3/36 , B60C1/00
CPC分类号： C08L9/06 , B60C1/0016 , C08K3/04 , C08K3/36 , C08L9/00 , C08L21/00 , C08L23/22 , C08L23/26 , C08L29/04 , C08L31/04 , C08L33/00 , Y10T152/10 , C08L2666/02 , C08L2666/08 , C08L2666/04
摘要： An elastomeric composition includes at least one elastomeric diene polymer, at least one thermoplastic polymer, and at least one polymer comprising functional groups. The at least one thermoplastic polymer comprises a main hydrocarbon chain. Hydrophilic groups are linked to the main hydrocarbon chain. The functional groups are reactive with the hydrophilic groups. The composition may also include at least one reinforcing filler. The at least one reinforcing filler may include carbon black, silica, or both carbon black and silica. The composition may further include a silica coupling agent, a sulfur-based vulcanizing agent, or both a silica coupling agent and a sulfur-based vulcanizing agent. A tire for vehicle wheels including at least one element including an elastomeric material, where the at least one element include the composition, is also disclosed.
摘要翻译：弹性体组合物包括至少一种弹性体二烯聚合物，至少一种热塑性聚合物和至少一种包含官能团的聚合物。所述至少一种热塑性聚合物包含主要烃链。亲水基团连接到主要烃链上。官能团与亲水基反应。组合物还可以包括至少一种增强填料。所述至少一种增强填料可包括炭黑，二氧化硅或炭黑和二氧化硅。组合物还可以包括二氧化硅偶联剂，硫基硫化剂，或二氧化硅偶联剂和硫系硫化剂二者。还公开了一种用于车轮的轮胎，其包括至少一种包括弹性体材料的元件，其中至少一种元素包括组合物。

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