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    • 21. 发明授权
    • Nonaqueous electrolytic solution and nonaqueous electrolyte battery
    • 非水电解液和非水电解质电池
    • US08962192B2
    • 2015-02-24
    • US12525188
    • 2008-03-17
    • Minoru KotatoShinichi Kinoshita
    • Minoru KotatoShinichi Kinoshita
    • H01M6/18H01M10/0567H01M10/052H01M10/0568
    • H01M10/0567H01M10/052H01M10/0568Y02E60/122
    • A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics contains an electrolyte and a nonaqueous solvent dissolving the electrolyte and further contains 0.001 vol % or more and less than 1 vol % of a compound represented by Formula (1) in the nonaqueous solvent. Alternatively, the nonaqueous electrolytic solution contains 0.001 vol % or more and less than 5 vol % of a compound represented by Formula (1) in the nonaqueous solvent and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group of 1 to 12 carbon atoms, which may be substituted by a halogen atom; and n represents an integer of 0 to 6.
    • 能够提供气体发生量低的电池的非水电解液容量大,储存特性和循环特性优异,含有电解质和溶解电解质的非水溶剂,进一步含有0.001体积%以上 在非水溶剂中的1体积%以下的式(1)表示的化合物。 或者,非水电解液在非水溶剂中含有0.001体积%以上且小于5体积%的式(1)表示的化合物,并且还含有选自碳酸酯化合物的环状碳酸酯化合物中的至少一种, 碳不饱和键,具有氟原子的环状碳酸酯化合物,单氟磷酸盐和二氟磷酸盐。 式(1)中,R 1〜R 3各自独立地表示可被卤素原子取代的碳原子数1〜12的烷基, n表示0〜6的整数。
    • 25. 发明申请
    • NONAQUEOUS ELECTROLYTIC SOLUTIONS AND NONAQUEOUS-ELECTROLYTE BATTERIES
    • 非电解电解液和非电解电池
    • US20120115042A1
    • 2012-05-10
    • US13353803
    • 2012-01-19
    • Minoru KOTATOShinichi Kinoshita
    • Minoru KOTATOShinichi Kinoshita
    • H01M10/0569
    • H01M10/0567H01M6/168H01M10/052H01M10/0525H01M10/0566H01M2300/0025Y02E60/122
    • Nonaqueous electrolytes which can produce a battery of high capacity and excellent storability and cycle characteristics are provided, as are batteries produced with the electrolytes. The electrolytes include ones with (i) an aromatic compound having 7-18 carbon atoms in total and a fluorinated cyclic carbonate having two or more fluorine atoms, (ii) diethyl carbonate and a fluorinated cyclic carbonate having two or more fluorine atoms, (iii) at least one of a cyclic sulfonic acid ester compound, disulfonic acid ester compound, nitrile compound, and a compound of formula (1) and a fluorinated cyclic carbonate having two or more fluorine atoms, or (iv) a nonaqueous electrolyte solution for use in a high-voltage battery having a final charge voltage of 4.3 V or higher and having a fluorinated cyclic carbonate with two or more fluorine atoms.
    • 提供了可以生产高容量电池和优异的储存性和循环特性的非水电解质,电解质产生的电池也是如此。 电解质包括(i)总共具有7-18个碳原子的芳族化合物和具有两个或更多个氟原子的氟化环状碳酸酯,(ii)碳酸二乙酯和具有两个或更多个氟原子的氟化环状碳酸酯的(i) )环状磺酸酯化合物,二磺酸酯化合物,腈化合物和式(1)化合物中的至少一种和具有两个或更多个氟原子的氟化环状碳酸酯,或(iv)使用的非水电解质溶液 在具有4.3V或更高的最终充电电压的高压电池中,并具有具有两个或更多个氟原子的氟化环状碳酸酯。
    • 30. 发明授权
    • Nonaqueous electrolytic solution and nonaqueous electrolyte battery
    • 非水电解液和非水电解质电池
    • US08685562B2
    • 2014-04-01
    • US13397197
    • 2012-02-15
    • Minoru KotatoShinichi Kinoshita
    • Minoru KotatoShinichi Kinoshita
    • H01M6/14
    • H01M10/0567H01M10/052H01M10/0568Y02E60/122
    • A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics. The solution contains an electrolyte, a nonaqueous solvent dissolving the electrolyte, 0.001 vol % to 5 vol % of a compound represented by Formula (1), and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group having 1 to 12 carbon atoms, optionally substituted by a halogen atom; and n is an integer of 0 to 6.
    • 能够提供气体发生量低的电池的非水电解液具有大容量,并且具有优异的储存特性和循环特性。 溶液含有电解质,溶解电解质的非水溶剂,0.001体积%〜5体积%的式(1)表示的化合物,还含有至少一种选自具有碳 - 碳的环状碳酸酯化合物 不饱和键,具有氟原子的环状碳酸酯化合物,单氟磷酸盐和二氟磷酸盐。 式(1)中,R 1〜R 3各自独立地表示可以被卤素原子取代的碳原子数1〜12的烷基, n为0〜6的整数。