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21. 发明授权

US5268123A Liquid crystal composition, liquid crystal device, display apparatus and display method 失效
公开(公告)号：US5268123A
公开(公告)日：1993-12-07
申请号：US834389
申请日：1992-02-12
申请人： Shosei Mori , Masataka Yamashita , Kazuharu Katagiri , Kenji Shinjo , Masahiro Terada
发明人： Shosei Mori , Masataka Yamashita , Kazuharu Katagiri , Kenji Shinjo , Masahiro Terada
IPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46 , G02F1/13 , C09K19/32
CPC分类号： C09K19/46 , C09K19/348 , C09K19/3491 , C09K19/3497 , C09K19/42 , C09K19/44
摘要： A liquid crystal composition, comprising: at least one mesomorphic compound represented by the following formula (I): ##STR1## and at least one mesomorphic compound represented by the following formula (II):R.sup.3 --X.sup.3 --A.sup.2 --B--A.sup.3 --X.sup.4 --R.sup.4(II),The liquid crystal composition is easily aligned by a simple rubbing method to provide a uniform monodomain and further provides wider driving voltage and temperature margins effective for providing a practical ferroelectric liquid crystal device.

22. 发明授权

US5453861A Chiral smectic liquid crystal device and display apparatus 失效
标题翻译：手性近晶体液晶装置及显示装置
公开(公告)号：US5453861A
公开(公告)日：1995-09-26
申请号：US252535
申请日：1994-06-01
申请人： Kenji Shinjo , Hiroyuki Kitayama , Masanobu Asaoka , Masahiro Terada , Syuji Yamada , Hiroshi Mizuno
发明人： Kenji Shinjo , Hiroyuki Kitayama , Masanobu Asaoka , Masahiro Terada , Syuji Yamada , Hiroshi Mizuno
IPC分类号： G02F1/1337 , G02F1/141 , G02F1/13 , G02F1/1343
CPC分类号： G02F1/1416 , G02F2001/133746
摘要： A liquid crystal device showing improved uniform alignment characteristic and switching characteristic is constituted by a pair of an upper substrate and a lower substrate, and a chiral smectic liquid crystal disposed between the upper and lower substrates. Each of the upper and lower substrates has thereon an electrode for applying a voltage to the liquid crystal and a uniaxial alignment film. The alignment films on the upper and lower substrates are provided with uniaxial alignment axes which cross each other so that the direction of crossing of the uniaxial alignment axes from the lower substrate to the upper substrate is identical to the direction of helical twist in cholesteric phase of the chiral smectic liquid crystal, and the chiral smectic liquid crystal is disposed in such an alignment state that the liquid crystal shows a pretilt angle .alpha., a cone angle H, an inclination angle .delta. of SmC.sup.* layer, and an apparent tilt angle .theta.a satisfying relationships of: H .theta.a>H/2. The crossing direction may preferably have a polarity (taken as "positive" in clockwise direction and "negative" in anticlockwise direction) which is the same as the polarity of the spontaneous polarization of the liquid crystal.
摘要翻译：显示出改善的均匀取向特性和切换特性的液晶装置由一对上基板和下基板以及设置在上基板和下基板之间的手性近晶液晶构成。上基板和下基板都具有用于向液晶施加电压的电极和单轴取向膜。上基板和下基板上的取向膜具有彼此交叉的单轴对准轴，使得单轴对准轴从下基板到上基板的交叉方向与胆甾醇相的螺旋扭转方向相同手性近晶液晶和手性近晶液晶以这样的取向状态设置，使得液晶显示预倾角α，锥角+ E，crc / H /，SmC *层的倾斜角度δ，以及满足以下关系的明显倾斜角θa：+ E，crc / H /α+δ和+ E，crc / H />θa> + E，crc / H / / 2。交叉方向可以优选地具有与液晶的自发极化的极性相同的极性（顺时针方向为“正”，逆时针方向为“负”）。

23. 发明授权

US5262083A Liquid crystal composition, liquid crystal device, display apparatus and display method 失效
公开(公告)号：US5262083A
公开(公告)日：1993-11-16
申请号：US833156
申请日：1992-02-10
申请人： Shosei Mori , Masataka Yamashita , Kazuharu Katagiri , Kenji Shinjo , Masahiro Terada
发明人： Shosei Mori , Masataka Yamashita , Kazuharu Katagiri , Kenji Shinjo , Masahiro Terada
IPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46 , G02F1/13 , C09K19/32
CPC分类号： C09K19/3491 , C09K19/3477 , C09K19/3497 , C09K19/42 , C09K19/44 , C09K19/46
摘要： A liquid crystal composition, comprising: at least one mesomorphic compound represented by the following formula (I):R.sup.1 --X.sup.1 --A.sup.1 --B--A.sup.2 --X.sup.2 --R.sup.2(I)and at least one mesomorphic compound represented by the following formula (II): ##STR1## The liquid crystal composition is easily aligned by a simple rubbing method to provide a uniform monodomain and further provides wider driving voltage and temperature margins effective for providing a practical ferroelectric liquid crystal device.

24. 发明授权

US5250218A Liquid crystal composition, liquid crystal device, display apparatus and display method 失效
标题翻译：液晶组合物，液晶装置，显示装置及显示方法
公开(公告)号：US5250218A
公开(公告)日：1993-10-05
申请号：US836964
申请日：1992-02-19
申请人： Shosei Mori , Masataka Yamashita , Kazuharu Katagiri , Kenji Shinjo , Masahiro Terada
发明人： Shosei Mori , Masataka Yamashita , Kazuharu Katagiri , Kenji Shinjo , Masahiro Terada
IPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46 , G02F1/13 , G09G3/36 , C09K19/30
CPC分类号： C09K19/42 , C09K19/3491 , C09K19/3497 , C09K19/44 , C09K19/46
摘要： A liquid crystal composition, comprising: at least one mesomorphic compound represented by the following formula (I): ##STR1## wherein R.sup.1 and R.sup.2 independently denote a linear or branched alkyl group having 1-18 carbon atoms capable of including one or non-neighboring two or more methylene groups which can be replaced with at least one species of --O--, --CO--, --COO--, --OCO--, --OCOO-- or --CH(X)-- with the proviso that --O-- cannot directly be connected to --O-- and X denotes halogen; Z.sup.1 denotes --COO-- or --CH.sub.2 O--; X.sup.1 and X.sup.2 independently denote a single bond, --O--, --COO--, --OCO--, --CO-- or --OCOO--; A.sup.1 denotes a single bond, ##STR2## Y.sup.1 and Y.sup.2 independently denote hydrogen, halogen, --CH.sub.3 -- or CF.sub.3 --; and at least one mesomorphic compound represented by the following formula (II): ##STR3## wherein R.sup.3 and R.sup.4 independently denote a linear or branched alkyl group having 1-18 carbon atoms capable of including one or non-neighboring two or more methylene groups which can be replaced with at least one species of --O--, --CO--, --COO--, --OCO--, --OCOO-- or --CH(X)-- with the proviso that --O-- cannot directly be connected to --O-- and X denotes halogen; X.sup.3 and X.sup.4 independently denotes a single bond, --O--, --COO--, --OCO-- or --CO--; Z.sup.2 denotes a single bond, --COO-- or --OCO--; A.sup.2, A.sup.3 and A.sup.4 independently denote a single bond, ##STR4## Y.sup.3 and Y.sup.4 independently denote hydrogen, halogen, --CH.sub.3 or --CF.sub.3 ; and k is 0 or 1 with the proviso that X.sup.3 is a single bond when A.sup.2 is a single bond, and X.sup.4 is a single bond when A.sup.3 is a single bond and k is 0. The liquid crystal composition is easily aligned by a simple rubbing method to provide a uniform monodomain and further provides wider driving voltage and temperature margins effective for providing a practical ferroelectric liquid crystal device.

25. 发明授权

US5512208A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：铁电手性近晶液晶组合物和使用其的液晶装置
公开(公告)号：US5512208A
公开(公告)日：1996-04-30
申请号：US53828
申请日：1993-04-30
申请人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takashi Iwaki , Shosei Mori , Kenji Shinjo
发明人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takashi Iwaki , Shosei Mori , Kenji Shinjo
IPC分类号： C09K19/30 , C09K19/34 , C09K19/42 , C09K19/12 , G02F1/13
CPC分类号： C09K19/3066 , C09K19/3463 , C09K19/42
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, R.sub.2 denotes a linear or branched alkyl group having 1-12 carbon atoms; X.sub.1 denotes a single bond, ##STR2## and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, at least one of R.sub.3 and R.sub.4 being optically active; and X.sub.2 and X.sub.3 respectively denote a single bond, ##STR4##
摘要翻译：一种铁电手性近晶液晶组合物，其包含至少一种由下式（I）表示的化合物：其中R 1表示具有1-18个能够具有取代基的碳原子的直链或支链烷基，R2 表示具有1-12个碳原子的直链或支链烷基; （II）表示的至少一种化合物：其中R 3和R 4分别表示直链或支链烷基，具有能够具有取代基的1-18个碳原子，R3和R4中的至少一个是光学活性的; X2和X3分别表示单键，

26. 发明授权

US5183586A Ferroelectric chiral smectic liquid crystal composition and liquid crystal device using same 失效
标题翻译：微电子手电筒液晶组合物及使用其的液晶装置
公开(公告)号：US5183586A
公开(公告)日：1993-02-02
申请号：US378923
申请日：1989-07-12
申请人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takashi Iwaki , Shosei Mori , Kenji Shinjo
发明人： Masahiro Terada , Takeshi Togano , Masataka Yamashita , Takashi Iwaki , Shosei Mori , Kenji Shinjo
IPC分类号： C09K19/20 , C09K19/34 , C09K19/42
CPC分类号： C09K19/42 , C09K19/20 , C09K19/3463
摘要： A ferroelectric chiral smectic liquid crystal composition, comprising at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent, R.sub.2 denotes a linear or branched alkyl group having 1-14 carbon atoms capable of having a substituent; X.sub.1 and X.sub.2 respectively denote a single bond, --O--, ##STR2## m is 0-7; and n is 0 or 1; and at least one compound represented by the following formula (II): ##STR3## wherein R.sub.3 and R.sub.4 respectively denote a linear or branched alkyl group having 1-18 carbon atoms capable of having a substituent; X.sub.3 and X.sub.4 respectively denote a single bond, --O--, ##STR4## Y.sub.1 denotes --CH.sub.2 O-- or --OCH.sub.2 --; and p and q are respectively 1 or 2.

27. 发明授权

US5389296A Liquid crystal composition and liquid crystal device containing same 失效
标题翻译：液晶组合物和含有它的液晶装置
公开(公告)号：US5389296A
公开(公告)日：1995-02-14
申请号：US980116
申请日：1992-11-23
申请人： Kenji Shingo , Masahiro Terada , Toshiharu Uchimi , Akio Yoshida , Takeshi Togano , Masanobu Asaoka , Takashi Iwaki
发明人： Kenji Shingo , Masahiro Terada , Toshiharu Uchimi , Akio Yoshida , Takeshi Togano , Masanobu Asaoka , Takashi Iwaki
IPC分类号： C09K19/30 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/141 , C09K19/12
CPC分类号： C09K19/3452 , C09K19/3068 , C09K19/3458 , C09K19/3463 , C09K19/42 , C09K19/46 , G02F1/141
摘要： A ferroelectric chiral smectic liquid crystal composition is provided with a fast response speed and a less temperature dependency of the response speed by containing at least one mesomorphic compound represented by the formula (1) below: ##STR1## wherein R.sub.1 denotes an alkyl group having 1-16 carbon atoms and capable of having a substituent; R.sub.2 denotes an alkyl group, alkoxy group, alkoxycarbonyl group, acyloxy group or alkoxycarbonyloxy group each having 1-16 carbon atoms and capable of having a substituent; and ##STR2## respectively denotes ##STR3## each capable of having a substituent.
摘要翻译：通过含有至少一种由下式（1）表示的介晶化合物，铁电手性近晶液晶组合物具有快速的响应速度和较小的响应速度的温度依赖性：其中R1表示烷基具有1-16个碳原子并具有取代基的基团; R2表示具有1-16个碳原子并能够具有取代基的烷基，烷氧基，烷氧基羰基，酰氧基或烷氧基羰基氧基; 和分别表示能够具有取代基的。

28. 发明授权

US5885482A Liquid crystal device, production process thereof and liquid crystal apparatus 失效
标题翻译：液晶装置及其制造方法以及液晶装置
公开(公告)号：US5885482A
公开(公告)日：1999-03-23
申请号：US775792
申请日：1996-12-27
申请人： Masanobu Asaoka , Yukio Hanyu , Kenji Shinjo , Koichi Sato , Masahiro Terada , Shosei Mori , Shinichi Nakamura , Syuji Yamada , Ikuo Nakazawa , Koji Noguchi
发明人： Masanobu Asaoka , Yukio Hanyu , Kenji Shinjo , Koichi Sato , Masahiro Terada , Shosei Mori , Shinichi Nakamura , Syuji Yamada , Ikuo Nakazawa , Koji Noguchi
IPC分类号： C09K19/04 , G02F1/1337 , G02F1/1339 , G02F1/141 , C09K19/56 , C09K19/52
CPC分类号： G02F1/13392 , C09K19/04 , G02F1/1337 , G02F1/141 , G02F2001/13373
摘要： A liquid crystal device is constituted by a pair of oppositely disposed substrates including a first substrate provided with a first alignment control layer which has been subjected to a uniaxial aligning treatment and a second substrate provided with a second alignment control layer which has not been subjected to a uniaxial aligning treatment, a sealing member disposed so as to seal up a peripheral portion of the first and second substrates to form a spacing therebetween, and a dispersion member (e.g., spacer beads or adhesive particles) and a liquid crystal disposed in the spacing while contacting the first and second aligning control layers. The dispersion member has been subjected to a surface treatment with a material constituting the second alignment control layer. The surface-treated dispersion member is effective in suppressing an occurrence of a reverse domain within a display region of the liquid crystal device, thus preventing flickering and improving a contrast.
摘要翻译：液晶装置由一对相对设置的基板构成，该基板包括：第一基板，设置有经受单轴取向处理的第一取向控制层;以及第二基板，设置有未经受单轴取向处理，密封构件，其被设置为密封第一和第二基板的周边部分以在其间形成间隔;以及分散构件（例如间隔珠或粘合剂颗粒）和以间隔设置的液晶同时接触第一和第二对准控制层。分散体已经用构成第二取向控制层的材料进行了表面处理。经表面处理的分散体有效地抑制液晶显示装置的显示区域内的反向畴的发生，防止闪烁，提高对比度。

29. 发明授权

US5728318A Liquid crystal composition, liquid crystal device and liquid crystal display apparatus 失效
标题翻译：液晶组合物，液晶装置和液晶显示装置
公开(公告)号：US5728318A
公开(公告)日：1998-03-17
申请号：US555063
申请日：1995-11-08
申请人： Masataka Yamashita , Kazuharu Katagiri , Masahiro Terada , Shosei Mori , Syuji Yamada , Hiroshi Mizuno
发明人： Masataka Yamashita , Kazuharu Katagiri , Masahiro Terada , Shosei Mori , Syuji Yamada , Hiroshi Mizuno
IPC分类号： C09K19/34 , C09K19/46 , C09K19/12 , C09K19/32 , G02F1/133
CPC分类号： C09K19/46 , C09K19/34
摘要： A liquid crystal composition is composed of at least three types of mesomorphic compounds. The liquid crystal composition may preferably contain a mesomorphic compound having an indan skeleton represented by the formula (1) or (3) and a mesomorphic compound having a terminal cyclic group represented by the formula (2) or (4). The liquid crystal composition may also preferably further contain an optically active compound to be formulated as a chiral smectic (or ferroelectric) liquid crystal composition. When the chiral smectic liquid crystal composition is disposed between a pair of electrode substrates provided with uniaxial alignment axes, the liquid crystal composition may preferably be placed in an alignment state in C1 uniform alignment, so that a resultant liquid crystal device provides a higher contrast ratio and a wider drive voltage margin.
摘要翻译：液晶组合物由至少三种类型的介晶化合物组成。液晶组合物可以优选含有具有由式（1）或（3）表示的茚满骨架的介晶化合物和具有由式（2）或（4）表示的末端环状基团的介晶化合物。液晶组合物还优选还含有配制成手性近晶（或铁电体）液晶组合物的光学活性化合物。当手性近晶液晶组合物配置在具有单轴取向轴的一对电极基板之间时，液晶组合物优选地可以以C1均匀取向放置在取向状态，使得所得到的液晶装置提供更高的对比度和更宽的驱动电压裕度。

30. 发明授权

US5413735A Liquid crystal composition, liquid crystal device using the liquid crystal composition, and display method and apparatus using the liquid crystal composition and device 失效
标题翻译：液晶组合物，使用液晶组合物的液晶装置以及使用该液晶组合物和装置的显示方法和装置
公开(公告)号：US5413735A
公开(公告)日：1995-05-09
申请号：US130427
申请日：1993-10-01
申请人： Masataka Yamashita , Masahiro Terada , Shousei Mori , Kazuharu Katagiri
发明人： Masataka Yamashita , Masahiro Terada , Shousei Mori , Kazuharu Katagiri
IPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46 , G02F1/13 , C09K19/12
CPC分类号： C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46
摘要： A liquid crystal composition comprises at least one type of liquid crystal compound having the following general formula (I) and at least one type of liquid crystal compound having the following general formula (II): ##STR1## wherein R.sub.1 and R.sub.2 each is a straight-chain or branched-chain alkyl group having 1 to 18 carbon atoms. These alkyl groups may have alkoxy groups having 1 to 12 carbon atoms as substituents. Both R.sub.1 and R.sub.2 are optically inactive. Z.sub.1 is a single bond, --O--, ##STR2## wherein R.sub.3 and R.sub.4 each is a straight-chain or branched-chain alkyl group having 1 to 18 carbon atoms. Z.sub.2 and Z.sub.3 each is single bond, ##STR3## A.sub.1 is --A.sub.2 -- or --A.sub.2 --A.sub.3 --, wherein A.sub.2 and A.sub.3 are ##STR4##
摘要翻译：液晶组合物包含至少一种具有以下通式（I）的液晶化合物和至少一种具有以下通式（II）的液晶化合物：其中R 1和R 2各自是具有1至18个碳原子的直链或支链烷基。这些烷基可以具有1〜12个碳原子的烷氧基作为取代基。 R1和R2都是光学无活性的。 Z1是具有1至18个碳原子的单键，-O-，高链或支链烷基。 Z2和Z3各自是单键，A3是

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