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    • 22. 发明授权
    • Separator for polymer electrolyte fuel cells and processes for production thereof
    • 聚合物电解质燃料电池用分离器及其制造方法
    • US06242124B1
    • 2001-06-05
    • US09374004
    • 1999-08-16
    • Kazuo SaitoAtsushi HagiwaraFumio Tanno
    • Kazuo SaitoAtsushi HagiwaraFumio Tanno
    • H01M802
    • C04B35/536H01M8/0213H01M8/0226H01M2300/0082Y02P70/56Y10T29/49108
    • The present invention provides: a separator for a polymer electrolyte fuel cell, interposed between the gas diffusion electrodes of the fuel cell and having, in at least one side, a groove for supply of an oxidizing agent or a fuel gas, which separator is made of a carbon composite material comprising (a) 100 parts by weight of an expanded graphite powder and (b) 10-45 parts by weight of a thermosetting resin dispersed in the expanded graphite powder (a), wherein the expanded graphite powder has an average particle diameter of 5-12 &mgr;m and at least 80% of the total particles of the expanded graphite powder have particle diameters of 0.1-20 &mgr;m. The separator for polymer electrolyte fuel cells according to the present invention is lightweight, can be grooved precisely and easily, and has a high gas barrier property, strength and electroconductivity.
    • 本发明提供一种用于固体高分子型燃料电池的隔板,插入在燃料电池的气体扩散电极之间,至少在一侧具有用于供给氧化剂或燃料气体的槽,该隔板被制成 的碳复合材料,其包含(a)100重量份的膨胀石墨粉末和(b)10-45重量份分散在所述膨胀石墨粉末(a)中的热固性树脂,其中所述膨胀石墨粉末具有平均 5-12μm的粒径和至少80%的膨胀石墨粉末的总颗粒的粒径为0.1-20μm。 根据本发明的聚合物电解质燃料电池用隔膜是轻质的,可以精确且容易地开槽,并且具有高阻气性,强度和导电性。
    • 23. 发明授权
    • Polarizable electrode for electric double-layer capacitor, and electric
double-layer capacitor using polarizable electrode
    • 用于双电层电容器的可极化电极和使用可极化电极的双电层电容器
    • US5838531A
    • 1998-11-17
    • US672602
    • 1996-06-28
    • Kazuo SaitoAtsushi HagiwaraToshiharu Okamoto
    • Kazuo SaitoAtsushi HagiwaraToshiharu Okamoto
    • H01G9/00H01G9/155H01G9/04
    • H01G9/155Y02E60/13
    • The present invention provides; (1) a polarizable electrode for an electric double-layer capacitor, which includes a solid activated carbon obtained by pyrolyzing a mixture mainly containing an activated carbon and a thermosetting resin and which has, on the surface and/or inside, holes free from the solid activated carbon, and holes having a diameter of 5 .mu.m-70 .mu.m possessing a capacity of 0.01 cc/g-1.0 cc/g; (2) a process for producing the above polarizable electrode for an electric double-layer capacitor, which includes heat-treating, as necessary, a mixture mainly containing an activated carbon, a thermosetting resin and a fiber capable of vaporizing upon heating and then pyrolyzing the resulting materiall and (3) an electric double-layer capacitor including at least a pair of the above polarizable electrodes for an electric double-layer capacitor and an electroyte impregnated between the polarizable electrodes. The above polarizable electrode for an electric double-layer capacitor is free from the drawbacks of conventoinal polarizable electrodes, has a low internal resistance and can be charged with or can discharge a large electric current of several amperes to several hundreds of amperes momentarily.
    • 本发明提供: (1)用于双电层电容器的可极化电极,其包括通过热解主要含有活性炭的混合物和热固性树脂而获得的固体活性炭,并且在表面和/或内部没有 固体活性炭和直径为5μm-70μm的孔,其容量为0.01cc / g-1.0cc / g; (2)上述的双电层电容器用极化电极的制造方法,其特征在于,在必要时进行热处理,所述混合物主要含有活性炭,热固性树脂和加热后能够蒸发的纤维,然后热解 所得材料和(3)包含至少一对上述用于双电层电容器的可极化电极和浸渍在可极化电极之间的电极的双电层电容器。 上述用于双电层电容器的可极化电极没有常规可极化电极的缺点,具有低内阻,并且可以瞬间充电或可以放电几安培到几百安培的大电流。
    • 27. 发明授权
    • Current collector for molten salt battery, process for producing
material for said current collector, and molten salt battery using said
current collector
    • 用于熔融盐电池的集电器,用于生产用于所述集电器的材料的方法,以及使用所述集电器的熔融盐电池
    • US5972538A
    • 1999-10-26
    • US856316
    • 1997-05-14
    • Kazuo SaitoAtsushi Hagiwara
    • Kazuo SaitoAtsushi Hagiwara
    • H01M4/80H01M4/66H01M10/39
    • H01M10/399H01M4/663
    • A current collector for a molten salt battery using liquid sodium as an anode active material, which current collector has excellent electrolyte resistance and low electrical resistance and is able to be produced simply and rapidly at a low cost, and includes a current collector material in which a carbon composite material obtained by calcining a mixture of expanded powder with a thermosetting resin under a non-oxidizing atmosphere is bonded to a porous carbon material having a porosity of 99 to 30% and an average pore diameter of 0.5 mm to 5 .mu.m. The above current collector is produced by a process including bonding a carbon composite material obtained by calcining a mixture of an expanded graphite powder with a thermosetting resin under a non-oxidizing atmosphere, to a porous carbon material having a porosity of 99 to 30% and an average pore diameter of 0.5 mm to 5 .mu.m, or alternatively, bonding a carbon composite material precursor composed of a mixture of an expanded graphite powder with a thermosetting resin, to the above porous carbon material and then calcining the resulting assembly under a non-oxidizing atmosphere.
    • 使用液态钠作为负极活性物质的熔融盐电池用集电体,该集电体具有优异的耐电解性和低电阻,能够以低成本简单快速地制造,并且包括集电体材料,其中 通过在非氧化性气氛下将发泡粉末与热固性树脂的混合物煅烧而获得的碳复合材料与孔隙率为99〜30%,平均孔径为0.5〜5μm的多孔碳材料接合。 上述集电体是通过将非膨胀石墨粉末与热固化性树脂的混合物在非氧化性气氛下进行煅烧而得到的碳复合材料粘合到孔隙率为99〜30%的多孔碳材料上的工序, 平均孔径为0.5〜5μm,或者将由膨胀石墨粉末与热固性树脂的混合物组成的碳复合材料前体粘合到上述多孔碳材料上,然后在非水溶液下煅烧所得组合物, 氧化气氛。