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21. 发明申请

US20120129689A1 PEROVSKITE CATALYST AND METHOD OF MANUFACTURING THE SAME 有权
标题翻译： PEROVSKITE催化剂及其制备方法
公开(公告)号：US20120129689A1
公开(公告)日：2012-05-24
申请号：US13299833
申请日：2011-11-18
申请人： Takeshi YOSHII , Tomohiko Nakanishi
发明人： Takeshi YOSHII , Tomohiko Nakanishi
IPC分类号： B01J37/08 , C01F17/00 , C01B13/14
CPC分类号： C01B13/185 , B01J23/002 , B01J23/83 , B01J23/8892 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J37/22 , B01J37/24 , C01B13/14 , C01G45/1264 , C01G49/0054 , C01G51/68 , C01P2002/34 , C01P2002/72 , C01P2006/12 , C01P2006/14
摘要： A method of manufacturing a perovskite catalyst composed of perovskite oxide includes mixing step, firing step and acid-treating step. In the mixing step, an A-site material and a B-site material are mixed at a stoichiometric ratio such that the A-site is increased, compared to that of a theoretical composition ABO3 of perovskite oxide in which a ratio of A-site and B-site is 1:1. In the firing step, the obtained mixed powder is fired. In the acid-treating step, the obtained fired powder is acid-treated with acid of pH 2 or more and less than pH 7.
摘要翻译：由钙钛矿氧化物构成的钙钛矿催化剂的制造方法包括混合工序，烧成工序和酸处理工序。在混合步骤中，与化学计量比相比，A位点材料和B位点材料与A位点的A位点的理论组成ABO3相比，A位点增加， B站点为1：1。在烧成工序中，烧成所得混合粉末。在酸处理步骤中，将得到的烧制粉末用pH2以上且小于pH7的酸进行酸处理。

22. 发明授权

US06764716B2 Ceramic honeycomb structural body and methods of preparing the same 失效
标题翻译：陶瓷蜂窝结构体及其制备方法
公开(公告)号：US06764716B2
公开(公告)日：2004-07-20
申请号：US10617710
申请日：2003-07-14
申请人： Keiji Ito , Masanori Yamada , Tomohiko Nakanishi
发明人： Keiji Ito , Masanori Yamada , Tomohiko Nakanishi
IPC分类号： B05D302
CPC分类号： C04B41/009 , B01J35/04 , C04B38/0006 , C04B41/5024 , C04B2111/0081 , F01N3/2828 , Y10T428/131 , Y10T428/24149 , C04B41/0072 , C04B41/4539 , C04B41/4578 , C04B35/195 , C04B38/007
摘要： The present invention provides a ceramic honeycomb structural body, and method for preparing the same, which can satisfactorily support a catalyst and can demonstrate superior mechanical strength, even if far thinner walls are used. Said structural body comprises lattice walls formed by a large number of cells 10 which are channels for fluid and a peripheral wall 12 which covers at least the circumference of said lattice walls 11. The outer peripheral portion 112 of said lattice walls 11 located in the vicinity of said peripheral wall 12 (area B) contain a densified portion of smaller porosity than that of an inner peripheral portion 111, of said lattice walls 11, which is located inside said outer peripheral portion 112 (area A).
摘要翻译：本发明提供了一种陶瓷蜂窝结构体及其制备方法，即使使用更薄的壁，也能令人满意地支撑催化剂并且能够表现出优异的机械强度。所述结构体包括由许多细胞10形成的格子壁，这些孔是用于流体的通道和至少覆盖所述格子壁11的圆周的周壁12.位于附近的格子壁11的外周部分112 的周壁12（区域B）包含比位于所述外周部112（区域A）内的所述格子壁11的内周部111的孔隙率小的致密部。

23. 发明授权

US4476236A Method for producing a cordierite body 失效
标题翻译：堇青石体的制造方法
公开(公告)号：US4476236A
公开(公告)日：1984-10-09
申请号：US511723
申请日：1983-07-08
申请人： Kazuhiro Inoguchi , Mitsuru Asano , Kunio Okamoto , Tomohiko Nakanishi
发明人： Kazuhiro Inoguchi , Mitsuru Asano , Kunio Okamoto , Tomohiko Nakanishi
IPC分类号： C04B35/195 , C04B35/04 , C04B35/18
CPC分类号： C04B35/195
摘要： A method for producing a cordierite body having no anisotropic property in coefficient of thermal expansion comprises the steps of preparing a raw material containing kaolin mineral and talc as main ingredients, and preformed cordierite particles formed from the raw material, mixing and kneading the raw material together with the preformed cordierite particles into a slurry, forming the slurry into a formed body and firing the formed body.
摘要翻译：一种不具有热膨胀系数的各向异性的堇青石体的制造方法，其特征在于，准备含有高岭土矿物和滑石粉的原料作为主要成分，由原料形成的预先形成的堇青石颗粒，将原料混合并捏合在一起将预成型的堇青石颗粒加入浆料中，将浆料形成成形体并焙烧成形体。

24. 发明授权

US4207188A Open tubular capillary column for high-speed micro liquid chromatography 失效
标题翻译：开放式管状毛细管柱，用于高速微量液相色谱
公开(公告)号：US4207188A
公开(公告)日：1980-06-10
申请号：US938350
申请日：1978-08-31
申请人： Takao Tsuda , Kiyokatsu Hibi , Toyohide Takeuchi , Tomohiko Nakanishi , Daido Ishii , Koichi Mochizuki
发明人： Takao Tsuda , Kiyokatsu Hibi , Toyohide Takeuchi , Tomohiko Nakanishi , Daido Ishii , Koichi Mochizuki
IPC分类号： G01N30/60 , B01D15/08
CPC分类号： G01N30/482 , G01N30/6078 , B01J2220/54
摘要： An open tubular capillary column, for high-speed micro liquid chromatography made of a glass tube of the inner diameter not more than 0.10 mm, having the net inside capacity not less than 0.5 .mu.l, the inner surface of which hollow glass tube being chemically bonded, in order to provide a stationary phase there, with at least one silane or its derivative such as octadecylsilane to form a polymeric layer. This invention includes the manufacturing method of such a column.
摘要翻译：一个开放的管状毛细管柱，用于由内径不大于0.10mm的玻璃管制成的高速微量液相色谱，其净内容不小于0.5μl，其中空玻璃管的内表面化学键合，以便在其中提供至少一种硅烷或其衍生物如十八烷基硅烷的固定相以形成聚合物层。本发明包括这种柱的制造方法。

25. 发明授权

US08951932B2 Perovskite catalyst and method of manufacturing the same 有权
标题翻译：钙钛矿催化剂及其制造方法
公开(公告)号：US08951932B2
公开(公告)日：2015-02-10
申请号：US13299833
申请日：2011-11-18
申请人： Takeshi Yoshii , Tomohiko Nakanishi
发明人： Takeshi Yoshii , Tomohiko Nakanishi
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J23/10 , C01B13/18 , C01B13/14 , C01G45/12 , C01G49/00 , C01G51/00 , B01J37/24 , B01J23/889 , B01J23/83 , B01J35/10 , B01J37/22
CPC分类号： C01B13/185 , B01J23/002 , B01J23/83 , B01J23/8892 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J37/22 , B01J37/24 , C01B13/14 , C01G45/1264 , C01G49/0054 , C01G51/68 , C01P2002/34 , C01P2002/72 , C01P2006/12 , C01P2006/14
摘要： A method of manufacturing a perovskite catalyst composed of perovskite oxide includes mixing step, firing step and acid-treating step. In the mixing step, an A-site material and a B-site material are mixed at a stoichiometric ratio such that the A-site is increased, compared to that of a theoretical composition ABO3 of perovskite oxide in which a ratio of A-site and B-site is 1:1. In the firing step, the obtained mixed powder is fired. In the acid-treating step, the obtained fired powder is acid-treated with acid of pH 2 or more and less than pH 7.
摘要翻译：由钙钛矿氧化物构成的钙钛矿催化剂的制造方法包括混合工序，烧成工序和酸处理工序。在混合步骤中，与化学计量比相比，A位点材料和B位点材料与A位点的A位点的理论组成ABO3相比，A位点增加， B站点为1：1。在烧成工序中，烧成所得混合粉末。在酸处理步骤中，将得到的烧制粉末用pH2以上且小于pH7的酸进行酸处理。

26. 发明申请

US20090239741A1 FORMED ARTICLE OF CORDIERITE AND METHOD FOR MANUFACTURING THE FORMED ARTICLE 有权
标题翻译：形成的CORDIERITE文章和制造形式的文章的方法
公开(公告)号：US20090239741A1
公开(公告)日：2009-09-24
申请号：US12408146
申请日：2009-03-20
申请人： Kentaro Makino , Kazushige Uchiyama , Yoshihide Segawa , Tomohiko Nakanishi , Yuichi Kobayashi
发明人： Kentaro Makino , Kazushige Uchiyama , Yoshihide Segawa , Tomohiko Nakanishi , Yuichi Kobayashi
IPC分类号： B01J21/08
CPC分类号： C04B38/0009 , B01J35/04 , C04B35/195 , C04B35/62655 , C04B2111/0037 , C04B2111/00413 , C04B2111/0081 , C04B2235/787 , C04B2235/96 , C04B2235/9607 , Y10T428/24149
摘要： A formed article is made of cordierite. The cordierite has a plurality of domains and a plurality of crystal grains placed in each domain to form a domain structure. The crystal grains in each domain are substantially aligned in the same direction, and an average size of the domains ranges from 40 μm to 150 μm. The article of cordierite is formed in a honeycomb structure having a plurality of cell walls arranged in a honeycomb form, and a plurality of cells divided by the cell walls are formed. The article of cordierite has a porosity ranging from 36% to 38%, a coefficient of linear thermal expansion equal to or lower than 0.2×106/K and a mechanical strength equal to or higher than 60×106 Pa.
摘要翻译：成型制品由堇青石制成。堇青石具有多个晶畴和多个晶粒，放置在每个畴中以形成畴结构。每个结构域中的晶粒基本上在相同的方向上对齐，并且结构域的平均尺寸范围为40μm至150μm。堇青石制品形成为具有以蜂窝状布置的多个单元壁的蜂窝结构体，并且形成有被单元壁分隔的多个单元。堇青石制品的孔隙率为36％至38％，线性热膨胀系数等于或低于0.2×10 6 / K，机械强度等于或高于60×10 6 Pa。

27. 发明授权

US07129193B2 Catalyst body 失效
公开(公告)号：US07129193B2
公开(公告)日：2006-10-31
申请号：US10364532
申请日：2003-02-12
申请人： Miho Ito , Jun Hasegawa , Tosiharu Kondo , Tomohiko Nakanishi
发明人： Miho Ito , Jun Hasegawa , Tosiharu Kondo , Tomohiko Nakanishi
IPC分类号： B01J23/00 , B01J35/00
CPC分类号： C04B35/46 , B01J23/58 , B01J23/652 , B01J23/6527 , B01J23/6562 , B01J35/002 , B01J37/0207 , C04B35/117 , C04B35/195 , C04B38/0067 , C04B38/0093 , C04B2111/0081 , C04B2235/3217 , C04B2235/3218 , C04B2235/3232 , C04B2235/3244 , C04B2235/3258 , C04B2235/3275 , C04B2235/3445 , C04B2235/349 , C04B38/0006 , C04B35/185 , C04B35/565 , C04B35/04
摘要： This invention aims at providing a catalyst body exhibiting a lower degradation of a catalyst due to thermal durability and capable of keeping higher catalyst performance for a long time. A catalyst component such as Pt is directly supported by Zr, W, etc, replacing elements inside a support such as Al of cordierite to provide a catalyst body without forming a coating layer. A combination of the catalyst component and the element inside the support is selected so that support strength is greater than 5 eV by simulation using a density functional method. Coarsening of catalyst particles can be suppressed and a high-performance catalyst body excellent in thermal durability can be obtained.

28. 发明授权

US06596372B2 Ceramic honeycomb structural body and methods of preparing the same 失效
标题翻译：陶瓷蜂窝结构体及其制备方法
公开(公告)号：US06596372B2
公开(公告)日：2003-07-22
申请号：US09729847
申请日：2000-12-06
申请人： Keiji Ito , Masanori Yamada , Tomohiko Nakanishi
发明人： Keiji Ito , Masanori Yamada , Tomohiko Nakanishi
IPC分类号： B32B312
CPC分类号： C04B41/009 , B01J35/04 , C04B38/0006 , C04B41/5024 , C04B2111/0081 , F01N3/2828 , Y10T428/131 , Y10T428/24149 , C04B41/0072 , C04B41/4539 , C04B41/4578 , C04B35/195 , C04B38/007
摘要： A ceramic honeycomb structural body, and method for preparing the same, which can satisfactorily support a catalyst and can demonstrate superior mechanical strength, even if far thinner walls are used. The structural body comprises lattice walls formed by a large number of cells which are channels for a fluid and a peripheral wall which covers at least the circumference of the lattice walls. The outer peripheral portion of the lattice walls located in the vicinity of the peripheral wall (area B) contains a densified portion of smaller porosity than that of an inner peripheral portion, of the lattice walls, which is located inside the outer peripheral portion (area A).
摘要翻译：陶瓷蜂窝结构体及其制备方法，即使使用更薄的壁，也能够令人满意地支撑催化剂并且能够表现出优异的机械强度。结构体包括由大量细胞形成的晶格壁，所述细胞是流体的通道和至少覆盖格子壁周长的周壁。位于周壁（区域B）附近的格子壁的外周部包含位于外周部（面积）内的格子壁的内周部的孔隙率小的致密化部分一个）。

29. 发明授权

US06589627B1 Cordierite honeycomb structural body and its production process 失效
标题翻译：堇青石蜂窝结构体及其生产工艺
公开(公告)号：US06589627B1
公开(公告)日：2003-07-08
申请号：US09526630
申请日：2000-03-16
申请人： Tomohiko Nakanishi , Masanori Yamada , Yosiyasu Andou
发明人： Tomohiko Nakanishi , Masanori Yamada , Yosiyasu Andou
IPC分类号： B32B312
CPC分类号： C04B35/6365 , C04B38/0645 , C04B2111/0081 , C08K3/34 , C08K7/00 , Y10T428/131 , Y10T428/1352 , Y10T428/24149 , Y10T428/24661 , Y10T428/24744 , C04B35/195 , C04B38/0006
摘要： There is provided a cordierite honeycomb structural body that allows the thickness of the cell walls to be reduced and heat capacity to be decreased by improving the fluidity of the molding material when passing through a mold for extrusion molding while maintaining the shape retention of the molding material. A water-soluble cellulose ether is used as a binder that is added to a cordierite-converted starting material. This water-soluble cellulose ether contains methoxyl groups substituted for the cellulose hydroxyl groups within the range of a substitution rate of 27.5 to 31.5%, does not contain hydroxypropoxyl groups and hydroxyethoxyl groups in an amount greater than the amount of unavoidable impurities (0.1 wt %), and has a viscosity in a 2 wt % aqueous solution at 20° C. of less than 8000 centipoise. As a result of adding this water-soluble cellulose ether in an amount of 3 wt % to 10 wt % relative to the amount of the cordierite-converted starting material, frictional resistance is decreased allowing improvement of fluidity while maintaining adequate hardness of the molding material.
摘要翻译：提供了一种堇青石蜂窝结构体，通过提高成形材料在通过挤出成型用模具时的流动性，能够降低单元壁的厚度，降低热容量，同时保持成型材料的形状保持性。使用水溶性纤维素醚作为添加到堇青石转化的原料中的粘合剂。该水溶性纤维素醚在取代率为27.5〜31.5％的范围内含有取代纤维素羟基的甲氧基，不含羟基丙氧基和羟基乙氧基，其量大于不可避免的杂质（0.1重量％），并且在20℃的2重量％水溶液中具有小于8000厘泊的粘度。作为相对于堇青石转化原料的量添加3重量％〜10重量％的水溶性纤维素醚的结果，摩擦阻力降低，从而提高流动性，同时保持成型材料的适当的硬度。

30. 发明授权

US4434117A Method for producing a cordierite body 失效
标题翻译：堇青石体的制造方法
公开(公告)号：US4434117A
公开(公告)日：1984-02-28
申请号：US250150
申请日：1981-04-02
申请人： Kazuhiro Inoguchi , Tomohiko Nakanishi , Mitsuru Asano
发明人： Kazuhiro Inoguchi , Tomohiko Nakanishi , Mitsuru Asano
IPC分类号： C04B35/195 , C04B35/18
CPC分类号： C04B35/195
摘要： A method for producing a cordierite body having a lower coefficient of thermal expansion and excellent thermal shock resistance which comprises the steps of mixing and kneading a batch raw material containing plate-shaped talc particles and non-plate shaped particles of other ceramic material, anisostatically forming the mixed batch raw material so as to impart a planar orientation to the plate-shaped talc particles and drying and firing the obtained formed body. By firing the plate-shaped talc particles, the shrinkage of the cordierite body can be decreased.
摘要翻译：一种具有较低的热膨胀系数和优异的耐热冲击性的堇青石体的制造方法，其特征在于，将含有板状滑石粒子和其他陶瓷材料的非平板状粒子的批料原料混合，混合批料原料，以赋予板状滑石颗粒平面取向，并干燥并焙烧得到的成形体。通过烧制板状滑石颗粒，可以减少堇青石体的收缩。

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