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21. 发明授权

US08198479B2 Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts 有权
标题翻译：含过渡金属的催化剂和催化剂组合，包括含过渡金属的催化剂及其制备和用作氧化催化剂的方法
公开(公告)号：US08198479B2
公开(公告)日：2012-06-12
申请号：US11357900
申请日：2006-02-17
申请人： Juan P. Arhancet , Fuchen Liu
发明人： Juan P. Arhancet , Fuchen Liu
IPC分类号： C07C227/18
CPC分类号： B01J37/086 , B01J21/18 , B01J23/75 , B01J27/22 , B01J27/24 , B01J37/084 , C07F9/3813
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having compositions which comprise one or more transition metals in combination with nitrogen and/or carbon formed on or over the surface of the carbon support. The present invention also relates to catalyst combinations comprising catalysts including carbon supports having compositions which comprise one or more transition metals in combination with nitrogen and/or carbon formed on or over the surface of a carbon support and a secondary catalyst or, co-catalyst, including a secondary transition metal. The invention further relates to the field of catalytic oxidation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines.
摘要翻译：本发明涉及非均相催化领域，更具体地涉及包括具有组合物的碳载体的催化剂，所述组合物包含一个或多个过渡金属与在碳载体的表面上或上方形成的氮和/或碳结合。本发明还涉及包含催化剂的催化剂，其包括具有组合物的碳载体，所述组合物包含在碳载体和辅助催化剂的表面上形成的一种或多种与氮和/或碳结合的过渡金属，或助催化剂，包括二次过渡金属。本发明还涉及催化氧化反应领域，包括通过叔胺的催化氧化制备仲胺。

22. 发明授权

US06555706B2 Process for making iminodiacetic acid compounds from monoethanolamine substrates 有权
标题翻译：从单乙醇胺底物制备亚氨基二乙酸化合物的方法
公开(公告)号：US06555706B2
公开(公告)日：2003-04-29
申请号：US09858117
申请日：2001-05-15
申请人： Howard C. Berk , Thaddeus S. Franczyk, II , Robert B. Weisenfeld , David A. Morgenstern , Juan P. Arhancet , William L. Moench , James C. Peterson
发明人： Howard C. Berk , Thaddeus S. Franczyk, II , Robert B. Weisenfeld , David A. Morgenstern , Juan P. Arhancet , William L. Moench , James C. Peterson
IPC分类号： C07C5116
CPC分类号： C07C253/30 , C07C227/02 , C07C227/12 , C07C227/18 , C07F9/3813 , C07C229/12 , C07C229/16 , C07C255/25 , C07C229/18
摘要： This invention is directed to a process for making an iminodiacetic acid compound from a monoethanolamine substrate having the formula: wherein R1 is hydrogen, hydrocarbyl, or substituted hydrocarbyl. The process includes a series of reactions comprising a cyanomethylation, a hydrolysis and a dehydrogenation with the hydrolysis and dehydrogenation steps being carried out either sequentially or concurrently. In a particular embodiment, the iminodiacetic acid produced is disodium iminodiacetic acid and the monoethanolamine substrate used is 2-aminoethanol.
摘要翻译：本发明涉及由具有下式的单乙醇胺底物制备亚氨基二乙酸化合物的方法：其中R 1是氢，烃基或取代的烃基。该方法包括一系列反应，包括氰甲基化，水解和脱氢，水解和脱氢步骤依次或同时进行。在一个具体实施方案中，产生的亚氨基二乙酸是亚氨基二乙酸二钠，所用的单乙醇胺底物是2-氨基乙醇。

23. 发明授权

US5344993A Process or making 3-hydroxyaldehydes 失效
标题翻译：制备或制备3-羟基醛
公开(公告)号：US5344993A
公开(公告)日：1994-09-06
申请号：US130258
申请日：1993-10-01
申请人： Lynn H. Slaugh , Juan P. Arhancet
发明人： Lynn H. Slaugh , Juan P. Arhancet
IPC分类号： C07C29/16 , C07C31/20 , C07C45/58 , C07C45/50 , C07C45/57
CPC分类号： C07C45/58 , C07C29/16 , C07C31/20
摘要： This invention relates to a process for making 3-hydroxyaldehydes having 4 or more carbon atoms by intimately contacting(a) 1,2-epoxides having 3 or more carbon numbers,(b) ditertiary phosphine-modified cobalt carbonyl catalyst, said phosphine being a hydrocarbylene-bis(monophosphabicyclononane) in which each phosphorus atom is joined to hydrocarbylene and is a member of a bridge linkage without being a bridgehead atom and which hydrocarbylene-bis(monophosphabicyclononane) has 11 to 80 carbon atoms, 5 to 12 carbon atoms thereof together with a phosphorus atom being members of each of the two bicyclic skeletal structures,(c) carbon monoxide, and(d) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6, in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi. Acids and promoter salts may be added to the reaction mixture to promote the hydroformylation reaction.
摘要翻译：本发明涉及一种通过紧密接触（a）具有3个或更多个碳数的1,2-环氧化物制备具有4个或更多个碳原子的3-羟基醛的方法，（b）二膦膦改性的羰基钴催化剂，所述膦是其中每个磷原子连接到亚烃基并且不是桥头原子的桥连构件的亚烃基 - 双（单磷酰基二环壬烷），并且亚烃基 - 双（单磷杂二环壬烷）具有11至80个碳原子，5至12个碳原子在一起其中磷原子是两个双环骨架结构中的每一个的成员，（c）一氧化碳和（d）氢，一氧化碳与氢的摩尔比为约4:1至约1:6，在惰性反应溶剂中，在约30℃至约150℃的温度和约50psi至约10,000psi的压力下进行。可以向反应混合物中加入酸和促进剂盐以促进加氢甲酰化反应。

24. 发明申请

US20090130502A1 TRANSITION METAL-CONTAINING CATALYSTS AND PROCESSES FOR THEIR PREPARATION AND USE AS FUEL CELL CATALYSTS 审中-公开
标题翻译：过渡金属含量催化剂及其制备和使用作为燃料电池催化剂的方法
公开(公告)号：US20090130502A1
公开(公告)日：2009-05-21
申请号：US12278738
申请日：2007-02-19
申请人： Fuchen Liu , Juan P. Arhancet , Matthew M. Mench
发明人： Fuchen Liu , Juan P. Arhancet , Matthew M. Mench
IPC分类号： H01M8/04 , H01M4/90 , H01M8/10
CPC分类号： H01M4/923 , H01M4/9008 , H01M4/9016 , H01M4/9083 , H01M4/926 , H01M2008/1095
摘要： This invention relates to the field of fuel cell catalysts, and more particularly to fuel cell catalysts including carbon supports having compositions which comprise one or more transition metals in combination with nitrogen (e.g., a transition metal nitride) formed on or over the surface of a carbon support. The present invention also relates to methods for preparation of fuel cell catalysts. The present invention further relates to the use of fuel cell catalysts described herein in processes for the generation of electric power.
摘要翻译：本发明涉及燃料电池催化剂领域，更具体地说，涉及包括碳载体的燃料电池催化剂，其中碳载体具有包含一个或多个与氮组合的过渡金属（例如，过渡金属氮化物）的组合物，其形成在碳支持。本发明还涉及制备燃料电池催化剂的方法。本发明还涉及本文所述的燃料电池催化剂在产生电力的方法中的用途。

25. 发明申请

US20080318768A1 OXIDATION CATALYST AND PROCESS 审中-公开
标题翻译：氧化催化剂和工艺
公开(公告)号：US20080318768A1
公开(公告)日：2008-12-25
申请号：US12124497
申请日：2008-05-21
申请人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan P. Arhancet
发明人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan P. Arhancet
IPC分类号： B01J21/18
CPC分类号： B01J21/18 , B01J23/40 , B01J23/626 , B01J23/72 , B01J23/74 , B01J23/89 , B01J23/8906 , B01J23/8913 , B01J27/22 , B01J27/24 , B01J31/1616 , B01J31/1805 , B01J31/183 , B01J35/0033 , B01J35/023 , B01J35/10 , B01J35/1033 , B01J37/0203 , B01J37/0205 , B01J37/082 , B01J37/084 , B01J2231/70 , B01J2231/763 , B01J2531/64 , B01J2531/66 , B01J2531/842 , B01J2531/845 , C07C209/68 , C07C249/02 , C07F9/3813 , Y02P20/588 , C07C251/06
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation, including the preparation of secondary amines by the catalytic oxidation of tertiary amines.
摘要翻译：本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。本发明还涉及催化氧化领域，包括通过叔胺的催化氧化制备仲胺。

26. 发明授权

US07329778B2 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts 有权
标题翻译：用于使伯醇脱氢以制备羧酸盐的方法和催化剂
公开(公告)号：US07329778B2
公开(公告)日：2008-02-12
申请号：US09832541
申请日：2001-04-11
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
IPC分类号： C07C51/00 , C07C51/16 , C07C207/00 , C07C229/00
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol.In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) having a copper-containing active phase at the surface thereof. The support is resistant to deformation under the conditions of the dehydrogenation reaction.In another embodiment, the catalyst comprises a metal sponge having a copper-containing active phase at the surface thereof and a supporting structure containing at least 10% non-copper metal.This invention is also directed to copper-containing catalysts which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts.
摘要翻译：本发明涉及一种制备羧酸盐的方法。该方法包括使催化剂与包含伯醇的碱性混合物接触。在一个实施方案中，例如，催化剂包括在其表面具有含铜活性相的金属载体（优选金属海绵载体）。该载体在脱氢反应条件下耐变形。在另一个实施方案中，催化剂包括在其表面具有含铜活性相的金属海绵和含有至少10％非铜金属的支撑结构。本发明还涉及可以在上述方法中使用的含铜催化剂。本发明还涉及制备这种催化剂的方法。

27. 发明授权

US5463144A Process for preparing 1,3-propanediol 失效
标题翻译： 1,3-丙二醇制备方法
公开(公告)号：US5463144A
公开(公告)日：1995-10-31
申请号：US316671
申请日：1994-09-30
申请人： Joseph B. Powell , Lynn H. Slaugh , Thomas C. Forschner , Terry B. Thomason , Thomas C. Semple , Paul R. Weider , Juan P. Arhancet
发明人： Joseph B. Powell , Lynn H. Slaugh , Thomas C. Forschner , Terry B. Thomason , Thomas C. Semple , Paul R. Weider , Juan P. Arhancet
IPC分类号： C07C29/141 , C07C29/16 , C07C45/58 , C07C45/80 , C07C27/20 , C07C45/49 , C07C47/17
CPC分类号： C07C45/58 , C07C29/141 , C07C29/16 , C07C45/80
摘要： 1,3-propanediol is prepared in a process comprising the steps of:contacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of an effective amount of a non-phosphine-ligated cobalt catalyst and an effective amount of a lipophilic quaternary ammonium salt at a temperature within the range of about 50.degree. to about 100.degree. C. and a, pressure within the range of about 500 to about 5000 psig, under reaction conditions effective to produce an intermediate product mixture comprising less than 15 wt % 3-hydroxypropanal;adding an aqueous liquid to said intermediate product mixture and extracting into said aqueous liquid at a temperature less than about 100.degree. C. a major portion of the 3-hydroxypropanal so as to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the-concentration of 3-hydroxypropanal in said intermediate product mixture and an organic phase comprising at least a portion of the cobalt catalyst or a cobalt-containing derivative thereof and at least a portion of the lipophilic quaternary ammonium salt;contacting the aqueous phase comprising 3-hydroxypropanal with hydrogen in, the presence of a hydrogenation catalyst at a pressure of at least about 100 psig and a temperature during at least a portion of the hydrogenation step of at least 40.degree. C. to provide a hydrogenation product mixture comprising 1,3-propanediol.
摘要翻译：以包括以下步骤的方法制备1,3-丙二醇：在有效量的非磷化氢连接的钴催化剂存在下，将环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中接触，在有效量的亲油性季铵盐的温度范围为约50至约100℃，和a，压力范围为约500至约5000psig，在有效产生中间产物混合物的反应条件下，包括小于15重量％的3-羟基丙醛; 向所述中间产物混合物中加入水性液体，并在低于约100℃的温度下将3-羟基丙醛的主要部分萃取到所述含水液体中，以提供包含比所述中间产物混合物更高浓度的3-羟基丙醛的水相，所述中间产物混合物中的3-羟基丙醛的浓度和包含至少一部分钴催化剂或其含钴衍生物和至少一部分亲脂性季铵盐的有机相; 在氢化催化剂存在下，在至少约100psig的压力和在至少40℃的至少一部分氢化步骤期间的温度下使包含3-羟基丙醛的水相与氢接触以提供氢化产物混合物包含1,3-丙二醇。

28. 发明授权

US5304686A Process for making 3-hydroxypropanal and 1,3-propanediol 失效
标题翻译：制备3-羟基丙醛和1,3-丙二醇的方法
公开(公告)号：US5304686A
公开(公告)日：1994-04-19
申请号：US91107
申请日：1993-07-13
申请人： Lynn H. Slaugh , Juan P. Arhancet
发明人： Lynn H. Slaugh , Juan P. Arhancet
IPC分类号： C07C29/16 , C07C31/20 , C07C45/58 , C07C47/19
CPC分类号： C07C31/20 , C07C29/141 , C07C45/58
摘要： This invention relates to a process for making 3-hydroxypropanal by intimately contacting(a) ethylene oxide,(b) ditertiary phosphine-modified cobalt carbonyl catalyst, said phosphine being a hydrocarbylene-bis(monophosphabicyclononane) in which each phosphorus atom is joined to hydrocarbylene and is a member of a bridge linkage without being a bridgehead atom and which hydrocarbylene-bis(monophosphabicyclononane) has 18 to 50 carbon atoms, 8 carbon atoms thereof together with a phosphorus atom being members of each of the two bicyclic skeletal structures,(c) a catalyst promoter comprising an acid and a metal salt promoter selected from a salt of a metal of Group IIA, Group IIB, Group IIIB and the Rare Earth Series of the Periodic Table of the Elements (CAS version),(d) carbon monoxide, and(e) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6,in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi. The use of the acid/metal salt promoter enhances the activity of the catalyst.
摘要翻译：本发明涉及一种通过使（a）环氧乙烷紧密接触来制备3-羟基丙醛的方法，（b）二膦膦改性的羰基钴催化剂，所述膦是其中每个磷原子连接到亚烃基的亚烃基 - 二（单磷酰基二环壬烷）并且是桥联原子的成员，而不是桥头原子，并且亚烃基 - 双（单磷杂二环壬烷）具有18至50个碳原子，其8个碳原子和作为两个双环骨架结构中的每一个的成员的磷原子（c ）催化剂促进剂，其包含酸和选自IIA族，IIB族，IIIB族的金属和元素周期表的稀土系列（CAS版）的金属盐助催化剂，（d）一氧化碳，和（e）氢气，一氧化碳与氢的摩尔比约为4:1至约1:6，在惰性反应溶剂中的液相溶液中，温度为约30℃。至约150℃和约50psi至约10,000psi的压力。酸/金属盐助催化剂的使用增强了催化剂的活性。

29. 发明授权

US4994427A Supported aqueous phase organometallic catalyst useful for hydroformylation and other reactions, and a method for its preparation 失效
标题翻译：用于加氢甲酰化和其他反应的支持的水相有机金属催化剂及其制备方法
公开(公告)号：US4994427A
公开(公告)日：1991-02-19
申请号：US276825
申请日：1988-11-28
申请人： Mark E. Davis , Juan P. Arhancet , Brian E. Hanson
发明人： Mark E. Davis , Juan P. Arhancet , Brian E. Hanson
IPC分类号： B01J31/24 , C07C45/49 , C07C45/50
CPC分类号： B01J31/2404 , B01J31/1616 , B01J31/24 , C07C45/49 , C07C45/50 , B01J21/08 , B01J2231/321 , B01J2531/822 , B01J2531/96 , Y02P20/588
摘要： This invention relates to a catalyst comprising a solid surface having immobilized thereon an aqueous solution of one or more organic complexes of rhodium. The catalyst is useful for promoting hydroformylation, hydrogenation and other chemical reactions in essentially water-immiscible organic liquid reactant phases.
摘要翻译：本发明涉及一种催化剂，其包含在其上固定有一种或多种铑有机配合物的水溶液的固体表面。该催化剂可用于在基本上与水不混溶的有机液体反应物相中促进加氢甲酰化，氢化和其它化学反应。

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