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1. 发明授权

US08298985B2 Catalyst for dehydrogenating primary alcohols 有权
标题翻译：用于脱氢伯醇的催化剂
公开(公告)号：US08298985B2
公开(公告)日：2012-10-30
申请号：US12859668
申请日：2010-08-19
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk
IPC分类号： B01J23/70 , B01J23/72 , B01J25/00 , B01J23/00 , B01J23/74 , B01J23/02 , B01J23/06 , C22C38/16
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed to catalysts for dehydrogenating primary alcohols. Catalysts comprising a metal support comprising (a) from about 2% to about 30% by weight copper, and (b) at least about 50% by weight non-copper metal selected from the group consisting of nickel, zinc, tin, cobalt, iron and combinations thereof; and a copper-containing coating are described.
摘要翻译：本发明涉及用于使伯醇脱氢的催化剂。包含金属载体的催化剂，其包含（a）约2重量％至约30重量％的铜，和（b）至少约50重量％的非铜金属，其选自镍，锌，锡，钴，铁及其组合; 并描述了含铜涂层。

2. 发明授权

US06376708B1 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts 有权
标题翻译：用于使伯醇脱氢以制备羧酸盐的方法和催化剂
公开(公告)号：US06376708B1
公开(公告)日：2002-04-23
申请号：US09547373
申请日：2000-04-11
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
IPC分类号： C07C5116
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol. In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) coated with copper. The support comprises at least about 10% (by weight) non-copper metal, and the copper-containing coating comprises from about 0.005 to about 0.5 grams of copper (per gram of said metal support). In another embodiment, the catalyst comprises a metal support (preferably a metal sponge support) coated with silver. The support comprises at least about 10% (by weight) non-silver metal, and the silver-containing coating comprises from about 0.005 to about 0.5 grams of copper (per gram of said metal support). In another embodiment, the catalyst comprises at least about 15% (by weight) non-copper metal, and at least about 10% (by weight) copper. In yet another embodiment, the catalyst comprises at least about 15% (by weight) non-silver metal, and at least about 10% (by weight) silver. In both these embodiments, it is particularly preferable for the catalyst to be in the form of a metal sponge. This invention is also directed to copper-containing and silver-containing catalysts which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts.
摘要翻译：本发明涉及一种制备羧酸盐的方法。该方法包括使催化剂与包含伯醇的碱性混合物接触。在一个实施方案中，例如，催化剂包含涂覆有铜的金属载体（优选金属海绵载体）。载体包含至少约10％（重量）的非铜金属，并且含铜涂层包含约0.005至约0.5克铜（每克所述金属载体）。在另一个实施方案中，催化剂包含金属支撑体（优选金属海绵支撑体）涂覆银。载体包含至少约10％（重量）的非银金属，并且含银涂层包含约0.005至约0.5克铜（每克所述金属载体）。在另一个实施方案中，催化剂包含至少约15％（重量）的非铜金属和至少约10％（重量）的铜。在另一个实施方案中，催化剂包含至少约15％（重量）的非银金属和至少约10％（重量）的银。在这两个实施方案中，特别优选催化剂为金属海绵形式。本发明还涉及可以在上述方法中使用的含铜和含银催化剂。本发明还涉及制备这种催化剂的方法。

3. 发明授权

US08450523B2 Process for preparation of a carboxylic acid salt by dehydrogenation of a primary alcohol 有权
标题翻译：通过伯醇脱氢制备羧酸盐的方法
公开(公告)号：US08450523B2
公开(公告)日：2013-05-28
申请号：US13435184
申请日：2012-03-30
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
IPC分类号： C07C229/08 , C07C229/12
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed a process for preparation of a carboxylic acid salt by dehydrogenation of a primary alcohol. The invention is also directed to a catalyst for dehydrogenating primary alcohols. In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) having a copper-containing coating at the surface thereof. In another embodiment, the catalyst comprises a metal selected from the group consisting of zinc, cobalt, iron, tin and combinations thereof having a copper-containing coating at the surface thereof.
摘要翻译：本发明涉及一种通过伯醇脱氢制备羧酸盐的方法。本发明还涉及用于使伯醇脱氢的催化剂。在一个实施方案中，例如，催化剂包括在其表面具有含铜涂层的金属载体（优选金属海绵载体）。在另一个实施方案中，催化剂包括选自锌，钴，铁，锡及其在其表面具有含铜涂层的组合的金属。

4. 发明授权

US06555706B2 Process for making iminodiacetic acid compounds from monoethanolamine substrates 有权
标题翻译：从单乙醇胺底物制备亚氨基二乙酸化合物的方法
公开(公告)号：US06555706B2
公开(公告)日：2003-04-29
申请号：US09858117
申请日：2001-05-15
申请人： Howard C. Berk , Thaddeus S. Franczyk, II , Robert B. Weisenfeld , David A. Morgenstern , Juan P. Arhancet , William L. Moench , James C. Peterson
发明人： Howard C. Berk , Thaddeus S. Franczyk, II , Robert B. Weisenfeld , David A. Morgenstern , Juan P. Arhancet , William L. Moench , James C. Peterson
IPC分类号： C07C5116
CPC分类号： C07C253/30 , C07C227/02 , C07C227/12 , C07C227/18 , C07F9/3813 , C07C229/12 , C07C229/16 , C07C255/25 , C07C229/18
摘要： This invention is directed to a process for making an iminodiacetic acid compound from a monoethanolamine substrate having the formula: wherein R1 is hydrogen, hydrocarbyl, or substituted hydrocarbyl. The process includes a series of reactions comprising a cyanomethylation, a hydrolysis and a dehydrogenation with the hydrolysis and dehydrogenation steps being carried out either sequentially or concurrently. In a particular embodiment, the iminodiacetic acid produced is disodium iminodiacetic acid and the monoethanolamine substrate used is 2-aminoethanol.
摘要翻译：本发明涉及由具有下式的单乙醇胺底物制备亚氨基二乙酸化合物的方法：其中R 1是氢，烃基或取代的烃基。该方法包括一系列反应，包括氰甲基化，水解和脱氢，水解和脱氢步骤依次或同时进行。在一个具体实施方案中，产生的亚氨基二乙酸是亚氨基二乙酸二钠，所用的单乙醇胺底物是2-氨基乙醇。

5. 发明授权

US5317003A Herbicidal compositions comprising glyphosate salts and alkoxylated quaternary amine surfactants 失效
标题翻译：包含草甘膦盐和烷氧基化季胺表面活性剂的除草组合物
公开(公告)号：US5317003A
公开(公告)日：1994-05-31
申请号：US914089
申请日：1992-07-16
申请人： James W. Kassebaum , Howard C. Berk
发明人： James W. Kassebaum , Howard C. Berk
IPC分类号： A01N25/02 , A01N25/30 , A01N33/12 , A01N57/20 , A01N57/04
CPC分类号： A01N25/30 , A01N57/20
摘要： A herbicidal composition is provided which is substantially non-irritant to the eyes and which comprises a stable aqueous concentrate solution of one or more agriculturally acceptable salts-of N-phosphonomethylglycine and a surfactant represented by the formula ##STR1## wherein R is an alkyl group having from about 6 to about 14 carbon atoms, R.sup.1 is ethyl, propyl, or a mixture of ethyl and propyl, the sum of n and m is between about 5 and about 50, R.sup.2 is an alkyl group with 1-4 carbon atoms, X is an agriculturally acceptable anion, and the weight ratio of surfactant to N-phosphonomethylglycine (expressed as the acid equivalent) is between about 1:5 and about 5:1.
摘要翻译：提供了对眼睛基本上无刺激性的除草组合物，其包含N-膦酰基甲基甘氨酸的一种或多种农业上可接受的盐的稳定的浓缩水溶液和由式“IMAGE”表示的表面活性剂，其中R是烷基具有约6至约14个碳原子，R 1为乙基，丙基或乙基和丙基的混合物，n和m之和为约5至约50，R 2为具有1-4个碳原子的烷基， X是农业上可接受的阴离子，表面活性剂与N-膦酰基甲基甘氨酸的重量比（以酸当量表示）为约1:5至约5:1。

6. 发明申请

US20110071018A1 CATALYST FOR DEHYDROGENATING PRIMARY ALCOHOLS 有权
标题翻译：用于脱氢初级醇的催化剂
公开(公告)号：US20110071018A1
公开(公告)日：2011-03-24
申请号：US12859668
申请日：2010-08-19
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, JR. , James C. Peterson
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, JR. , James C. Peterson
IPC分类号： B01J25/02 , B01J23/755 , B01J23/80
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed a catalyst for dehydrogenating primary alcohols.In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) having a copper-containing coating at the surface thereof.In another embodiment, the catalyst comprises a metal selected from the group consisting of zinc, cobalt, iron, tin and combinations thereof having a copper-containing coating at the surface thereof.
摘要翻译：本发明涉及用于使伯醇脱氢的催化剂。在一个实施方案中，例如，催化剂包括在其表面具有含铜涂层的金属载体（优选金属海绵载体）。在另一个实施方案中，催化剂包括选自锌，钴，铁，锡及其在其表面具有含铜涂层的组合的金属。

7. 发明授权

US07064235B2 Process for making iminodiacetic acid compounds from monoethanolamine substrates 有权
标题翻译：从单乙醇胺底物制备亚氨基二乙酸化合物的方法
公开(公告)号：US07064235B2
公开(公告)日：2006-06-20
申请号：US10356867
申请日：2003-02-03
申请人： Howard C. Berk , Thaddeus S. Franczyk, II , Robert B. Weisenfeld , David A. Morgenstern , Juan P. Arhancet , William L. Moench, Jr. , James C. Peterson
发明人： Howard C. Berk , Thaddeus S. Franczyk, II , Robert B. Weisenfeld , David A. Morgenstern , Juan P. Arhancet , William L. Moench, Jr. , James C. Peterson
IPC分类号： C07F9/38 , C07C229/00
CPC分类号： C07C253/30 , C07C227/02 , C07C227/12 , C07C227/18 , C07F9/3813 , C07C229/12 , C07C229/16 , C07C255/25 , C07C229/18
摘要： This invention is directed to a process for making an iminodiacetic acid compound from a monoethanolamine substrate having the formula: wherein R1 is hydrogen, hydrocarbyl, or substituted hydrocarbyl. The process includes a series of reactions comprising a cyanomethylation, a hydrolysis and a dehydrogenation. In a particular embodiment, the iminodiacetic acid produced is disodium iminodiacetic acid and the monoethanolamine substrate used is 2-aminoethanol.
摘要翻译：本发明涉及由具有下式的单乙醇胺底物制备亚氨基二乙酸化合物的方法：其中R 1是氢，烃基或取代的烃基。该方法包括一系列包括氰甲基化，水解和脱氢的反应。在一个具体实施方案中，产生的亚氨基二乙酸是亚氨基二乙酸二钠，所用的单乙醇胺底物是2-氨基乙醇。

8. 发明授权

US06706662B2 Catalyst for dehydrogenating primary alcohols to make carboxylic acid salts 有权
标题翻译：用于使伯醇脱氢以制备羧酸盐的催化剂
公开(公告)号：US06706662B2
公开(公告)日：2004-03-16
申请号：US10085337
申请日：2002-02-28
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
IPC分类号： B01J2372
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed to a process for dehydrogenating primary alcohols to make salts of carboxylic acids. The process comprises contacting a catalyst, preferably a metal support coated with copper or silver, with an alkaline mixture comprising a primary alcohol. The invention further provides for novel copper-containing and silver-containing catalysts which may be used, for example, in the above process as well as processes for making such catalysts.
摘要翻译：本发明涉及使伯醇脱氢以制备羧酸盐的方法。该方法包括使涂覆有铜或银的催化剂，优选金属载体与包含伯醇的碱性混合物接触。本发明还提供了可用于例如上述方法中的新型含铜和含银催化剂以及制备这种催化剂的方法。

9. 发明授权

US07329778B2 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts 有权
标题翻译：用于使伯醇脱氢以制备羧酸盐的方法和催化剂
公开(公告)号：US07329778B2
公开(公告)日：2008-02-12
申请号：US09832541
申请日：2001-04-11
申请人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
发明人： David A. Morgenstern , Juan P. Arhancet , Howard C. Berk , William L. Moench, Jr. , James C. Peterson
IPC分类号： C07C51/00 , C07C51/16 , C07C207/00 , C07C229/00
CPC分类号： C07F9/3813 , B01J23/70 , B01J23/72 , B01J23/80 , B01J23/835 , B01J35/04 , B01J37/348 , C07C51/235 , C07C227/02 , C07C229/16
摘要： This invention is directed to a process for making a salt of a carboxylic acid. The process comprises contacting a catalyst with an alkaline mixture comprising a primary alcohol.In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) having a copper-containing active phase at the surface thereof. The support is resistant to deformation under the conditions of the dehydrogenation reaction.In another embodiment, the catalyst comprises a metal sponge having a copper-containing active phase at the surface thereof and a supporting structure containing at least 10% non-copper metal.This invention is also directed to copper-containing catalysts which may, for example, be used in the above process. This invention is further directed to processes for making such catalysts.
摘要翻译：本发明涉及一种制备羧酸盐的方法。该方法包括使催化剂与包含伯醇的碱性混合物接触。在一个实施方案中，例如，催化剂包括在其表面具有含铜活性相的金属载体（优选金属海绵载体）。该载体在脱氢反应条件下耐变形。在另一个实施方案中，催化剂包括在其表面具有含铜活性相的金属海绵和含有至少10％非铜金属的支撑结构。本发明还涉及可以在上述方法中使用的含铜催化剂。本发明还涉及制备这种催化剂的方法。

10. 发明授权

US5389598A Aqueous concentrate formulations having reduced eye irritancy 失效
标题翻译：具有降低眼睛刺激性的浓缩水配方
公开(公告)号：US5389598A
公开(公告)日：1995-02-14
申请号：US169693
申请日：1993-12-17
申请人： Howard C. Berk , James W. Kassebaum
发明人： Howard C. Berk , James W. Kassebaum
IPC分类号： A01N25/02 , A01N25/30 , A01N25/32 , A01N33/08 , A01N37/02 , A01N37/06 , A01N57/20 , A01N63/02 , A01N57/04 , A01N28/30
CPC分类号： A01N25/32 , A01N57/20
摘要： Disclosed are storage-stable aqueous concentrate formulations of pesticides or plant growth modifying agents containing sufficient amounts of an alkoxylated alkylamine surfactant to insure a high degree of pesticidal or plant growth modifying efficacy, wherein irritancy to eyes resulting from the presence of said surfactant is reduced by the presence of an effective amount of a C.sub.6-22 saturated or unsaturated alkyl monocarboxylic or dicarboxylic acid or mixture of such acids.
摘要翻译：公开了含有足够量的烷氧基化烷基胺表面活性剂的农药或植物生长调节剂的储存稳定含水浓缩物制剂，以确保高度的杀虫剂或植物生长调节效力，其中由所述表面活性剂的存在引起的对眼睛的刺激性由存在有效量的C6-22饱和或不饱和烷基单羧酸或二羧酸或这些酸的混合物。

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