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    • 22. 发明授权
    • Aqueous solutions of direct dyes
    • 直接染料的水溶液
    • US08034129B2
    • 2011-10-11
    • US11919103
    • 2006-05-08
    • Holger LautenbachAdolf Käser
    • Holger LautenbachAdolf Käser
    • C09B67/00C09B67/26C09B67/34
    • C09B67/0073C09B67/0076D21H21/28Y10S8/919Y10S8/921
    • The invention relates to an aqueous dye solution comprising a) 5 to 30% by weight of an anionic or cationic direct dye, b) 0.01 to 5% by weight of the compound of formula (1), in which M represents hydrogen, an alkali metal or alkaline earth metal, ammonium or ammonium, that is mono-, di-, tri- or tetra-substituted by C1-C4alkyl or C2-C4hydroxyalkyl or mixtures thereof, c) 0 to 10% by weight of an inorganic or an organic acid, d) 0 to 20% by weight of further additives and e) water to complete to 100%, with the proviso that direct dyes of the formula (2) in which K is a residue of a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series and M is as defined above, are excluded, a process for their preparation and the use thereof for dyeing paper.
    • 本发明涉及一种含水染料溶液,其包含a)5至30重量%的阴离子或阳离子直接染料,b)0.01至5重量%的式(1)化合物,其中M表示氢,碱 金属或碱土金属,铵或铵,其是被C 1 -C 4烷基或C 2 -C 4羟烷基或其混合物单,二,三或四取代,c)0-10重量%的无机或有机 酸,d)0至20重量%的其它添加剂,e)水完成至100%,条件是式(2)的直接染料其中K是乙酰乙酰苯胺的偶联组分的残基,吡啶酮 ,吡唑啉酮或嘧啶系列和M如上所定义,其制备方法及其用于染色纸的用途。
    • 24. 发明授权
    • Disazo dyes and dye compositions for shading white paper
    • 用于遮蔽白皮书的双偶氮染料和染料组合物
    • US07682406B2
    • 2010-03-23
    • US11922451
    • 2006-06-26
    • Adolf KäserWolfgang Schlenker
    • Adolf KäserWolfgang Schlenker
    • C09B67/00C09B45/00C09B31/08C09B41/00
    • D21H21/28C09B31/08
    • The invention relates to novel dyes of the formula (1) in which D represents a phenyl or naphthalene residue which is substituted by one or two sulphonic Acid or carboxylic acid groups and, optionally, by one or two groups selected from C1-C4alkyl, hydroxyl and nitro, each R1 and R2, independently, represent hydrogen or, a C1-C4alkyl group, R′1 represents hydrogen, hydroxyl, C1-C4alkyl or C1-C4hydroxyalkyl, R3 represents hydrogen, C1-C4alkyl or phenyl, which is unsubstituted or substituted by one or two groups selected from C1-C4alkyl, C1-C4alkoxy, halogen, hydroxyl, —NH2, nitro, —SO3M and —CO2M and M represents hydrogen, an alkaline or alkaline earth metal, ammonium or ammonium that is mono-, di-, tri- or tetrasubstituted by C1-C4alkyl or C2-C4hydroxyalkyl or a polyglycolammonium cation and also known dyes of formula (5), in which D′ represents a phenyl or naphthalene residue which is substituted by one or two sulphonic acid or carboxylic acid groups and, optionally, by one or two groups selected from C1-C4alkyl and C1-C4alkoxy and R3 and M are as defined above, and their mixtures suitable for shading white paper, a process for shading, a process for the preparation of the novel dyes and white paper which has been treated with such shading components.
    • 本发明涉及式(1)的新型染料,其中D表示被一个或两个磺酸或羧酸基团取代的苯基或萘残基,且任选地通过一个或两个选自C 1 -C 4烷基,羟基 和硝基,每个R 1和R 2独立地代表氢或C 1 -C 4烷基,R 1表示氢,羟基,C 1 -C 4烷基或C 1 -C 4羟烷基,R 3表示氢,C 1 -C 4烷基或苯基,其是未取代的或 被选自C 1 -C 4烷基,C 1 -C 4烷氧基,卤素,羟基,-NH 2,硝基,-SO 3 M和-CO 2 M中的一个或两个基团取代,M代表氢,碱金属或碱土金属,铵或铵, 被C 1 -C 4烷基或C 2 -C 4羟烷基或聚乙二醇铵阳离子和还有已知的式(5)的染料二取代,三取代或四取代,其中D'表示被一个或两个磺酸或羧酸取代的苯基或萘残基 酸基和任选的一个 或选自C 1 -C 4烷基和C 1 -C 4烷氧基的两个基团,且R 3和M如上所定义,并且它们的混合物适合于遮蔽白皮书,遮蔽方法,制备新染料和白皮书的方法 用这种阴影部件处理。