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    • 23. 发明授权
    • Semiconductor device with a conductive layer including a copper layer with a dopant
    • 具有包括具有掺杂剂的铜层的导电层的半导体器件
    • US07187080B2
    • 2007-03-06
    • US10964963
    • 2004-10-14
    • Qing-Tang JiangChangming JinJoseph D. Luttmer
    • Qing-Tang JiangChangming JinJoseph D. Luttmer
    • H01L23/48
    • H01L21/76844H01L21/76849H01L21/76864H01L21/76867H01L21/76873H01L21/76874H01L21/76877H01L21/76888
    • A method of manufacturing a semiconductor device includes the steps of providing a semiconductor substrate (202), forming a dielectric layer (204) over the semiconductor substrate (202), and etching a trench or a via (206) in the dielectric layer (204) to expose a portion of the surface of the semiconductor substrate (202). The method also includes the step of forming a conductive layer (212, 220) within in the trench or the via (206). The method further includes the steps of polishing a portion of the conductive layer (220) and annealing the conductive layer (212, 220) at a predetermined temperature. Moreover, the conductive layer (212, 220) also includes a dopant, and the dopant diffuses substantially to the surface of the top side of the conductive layer (212, 220) to form a dopant oxide layer (212a, 220a) when the conductive layer (212, 220) is annealed at the predetermined temperature and the dopant is exposed to oxygen.
    • 一种制造半导体器件的方法包括以下步骤:提供半导体衬底(202),在半导体衬底(202)上形成电介质层(204),并蚀刻电介质层(204)中的沟槽或通孔(206) )以暴露半导体衬底(202)的表面的一部分。 该方法还包括在沟槽或通孔(206)内形成导电层(212,220)的步骤。 该方法还包括以下步骤:抛光导电层(220)的一部分并在预定温度下退火导电层(212,220)。 此外,导电层(212,220)还包括掺杂剂,并且掺杂剂基本上扩散到导电层(212,220)的顶侧的表面,以形成掺杂剂氧化物层(212a,220a),当 导电层(212,220)在预定温度下退火,掺杂剂暴露于氧气。