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21. 发明申请

US20070117912A1 Polymer blend method, composition, and article 审中-公开
标题翻译：聚合物共混法，组合物和制品
公开(公告)号：US20070117912A1
公开(公告)日：2007-05-24
申请号：US11282902
申请日：2005-11-18
申请人： Kim Balfour , Hua Guo , Mukund Parthasarathy
发明人： Kim Balfour , Hua Guo , Mukund Parthasarathy
IPC分类号： C08L77/00
CPC分类号： C08L71/12 , C08K5/092 , C08K9/08 , C08L2666/02 , C08L2666/04
摘要： A polymer blend may be prepared by melt kneading a composition that includes a poly(arylene ether), a polystyrene, and a carboxylic acid concentrate including a carboxylic acid compound and a polymer resin having a glass transition temperature or a melting temperature of about 30 to about 175° C. Using the carboxylic acid concentrate reduces the concentrations of styrene monomer and toluene in the polymer blend.
摘要翻译：聚合物共混物可以通过将包含聚（亚芳基醚），聚苯乙烯和包含羧酸化合物的羧酸浓缩物和玻璃化转变温度或熔融温度为约30的聚合物树脂的组合物熔融捏合而制备，约175℃。使用羧酸浓缩物降低聚合物共混物中苯乙烯单体和甲苯的浓度。

22. 发明申请

US20060287439A1 CAPPED POLY(ARYLENE ETHER) COMPOSITION AND PROCESS 有权
标题翻译： CAPPED POLY（ARYLENE ETHER）组成和工艺
公开(公告)号：US20060287439A1
公开(公告)日：2006-12-21
申请号：US11467723
申请日：2006-08-28
申请人： Kenneth Zarnoch , John Campbell , Amy Freshour , Hua Guo , John Rude , Prameela Susarla , Michael Vallance , Gary Yeager
发明人： Kenneth Zarnoch , John Campbell , Amy Freshour , Hua Guo , John Rude , Prameela Susarla , Michael Vallance , Gary Yeager
IPC分类号： C08L71/00 , B32B27/00
CPC分类号： C08G65/48 , C08F283/08 , C08F290/062 , C08G65/485
摘要： A thermoset composition exhibiting reduced water absorption in the cured state includes an olefinically unsaturated monomer and a capped poly(arylene ether) prepared by the reaction of an uncapped poly(arylene ether) with an anhydride capping agent. The capped poly(arylene ether) is isolated and/or purified by methods that reduce the concentrations of polar impurities that contribute to water absorption by the cured composition.
摘要翻译：在固化状态下显示减少的吸水性的热固性组合物包括通过未封端的聚（亚芳基醚）与酸酐封端剂的反应制备的烯属不饱和单体和封端的聚（亚芳基醚）。封端的聚（亚芳基醚）是通过降低有助于固化的组合物吸水的极性杂质的浓度的方法分离和/或纯化的。

23. 发明申请

US20060135695A1 Flexible poly(arylene ether) composition and articles thereof 审中-公开
标题翻译：柔性聚（亚芳基醚）组合物及其制品
公开(公告)号：US20060135695A1
公开(公告)日：2006-06-22
申请号：US11256766
申请日：2005-10-24
申请人： Hua Guo , Vijay Mhetar , Vijay Rajamani
发明人： Hua Guo , Vijay Mhetar , Vijay Rajamani
IPC分类号： C08L53/00
CPC分类号： C08L53/025 , C08L23/10 , C08L51/04 , C08L53/00 , C08L71/12 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08L2666/14
摘要： A thermoplastic composition comprising a poly(arylene ether), a polyolefin, and a polymeric compatibilizer selected from the group consisting of (i) a block copolymer wherein a central block is a controlled distribution copolymer, and (ii) a polypropylene-polystyrene graft copolymer; is disclosed. The composition is useful in the production of covered wire.
摘要翻译：一种包含聚（亚芳基醚），聚烯烃和聚合物相容剂的热塑性组合物，其选自（i）嵌段共聚物，其中中心嵌段是受控分布共聚物，和（ii）聚丙烯 - 聚苯乙烯接枝共聚物 ; 被披露。该组合物可用于生产包线。

24. 发明授权

US06608166B2 Three-dimensional copolymers of polyphenylene ether resinsand sytrenic resins 有权
标题翻译：聚苯醚树脂苯乙烯树脂的三维共聚物
公开(公告)号：US06608166B2
公开(公告)日：2003-08-19
申请号：US09943159
申请日：2001-08-30
申请人： Hua Guo , Manuel Cavazos , John B. Yates, III
发明人： Hua Guo , Manuel Cavazos , John B. Yates, III
IPC分类号： C08G6378
CPC分类号： C08F290/062 , H05K1/0326
摘要： A three dimensional copolymer network of polyphenylene ether segments and styrenic resins such as styrene/acrylonitrile copolymers provide articles of high heat reesistance and dielectric properties suitable for use in electronic components. Methods for preparing the copolymers employ polyphenylene ether polymers with end caps having at least one pair of unsaturated aliphatic carbon atoms, i.e. carbon-carbon double bond, and polymerize styrene monomers and acrylonitrile monomers or styrene/acrylonitrile copolymers or both in the presence of these polyphenylene ether polymers.
摘要翻译：聚苯醚链段和苯乙烯类树脂如苯乙烯/丙烯腈共聚物的三维共聚物网络提供了适用于电子部件的高耐热性和介电性能的产品。制备共聚物的方法采用具有至少一对不饱和脂族碳原子（即碳 - 碳双键）的端盖的聚苯醚聚合物，并且在这些聚亚苯基存在下聚合苯乙烯单体和丙烯腈单体或苯乙烯/丙烯腈共聚物或二者醚聚合物。

25. 发明授权

US08722837B2 Poly(phenylene ether)-polysiloxane composition and method 有权
标题翻译：聚（苯醚） - 聚硅氧烷组合物和方法
公开(公告)号：US08722837B2
公开(公告)日：2014-05-13
申请号：US13362426
申请日：2012-01-31
申请人： Alvaro Carrillo , Hua Guo , Scott Fisher
发明人： Alvaro Carrillo , Hua Guo , Scott Fisher
IPC分类号： C08G65/38 , C08G77/46
CPC分类号： C08L83/12 , C08G65/44 , C08G77/46 , C08K5/34924 , C08L25/00 , C08L27/00 , C08L71/12 , C08L71/123 , C08L71/126
摘要： A composition is prepared by oxidative copolymerization of specific amounts of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and a hydroxyaryl-terminated polysiloxane. The composition exhibits an increased heat resistance relative to a corresponding composition prepared by copolymerizing 2,6-dimethylphenol and hydroxyaryl-terminated polysiloxane, without 2,3,6-trimethylphenol. The composition is useful as a flame-retardant additive in polymer compositions that require high heat resistance.
摘要翻译：通过特定量的2,6-二甲基苯酚，2,3,6-三甲基苯酚和羟基芳基封端的聚硅氧烷的氧化共聚制备组合物。该组合物相对于不含2,3,6-三甲基苯酚共聚2,6-二甲基苯酚和羟基芳基封端的聚硅氧烷制备的相应组合物，具有增加的耐热性。该组合物可用作需要高耐热性的聚合物组合物中的阻燃添加剂。

26. 发明授权

US08669332B2 Poly(arylene ether)-polysiloxane composition and method 有权
标题翻译：聚（亚芳基醚） - 聚硅氧烷组合物和方法
公开(公告)号：US08669332B2
公开(公告)日：2014-03-11
申请号：US13169137
申请日：2011-06-27
申请人： Alvaro Carrillo , Hua Guo
发明人： Alvaro Carrillo , Hua Guo
IPC分类号： C08L71/12 , C08G77/46
CPC分类号： C08G77/46 , C08G77/16 , C08G77/80 , C08G81/00 , C08G2261/126 , C08L71/12 , C08L83/12 , C08L2205/05 , C08L83/04
摘要： A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.
摘要翻译：包括聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。氧化聚合包括一元酚添加时间，其特征在于第一温度，加入时间之后的生成周期，并且特征在于大于第一温度的第二温度，以及添加周期和构建周期之间的温度斜坡期间。在温度升高期间，温度以每分钟约0.01至约0.35℃的平均速率增加，这提高了聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率。

27. 发明申请

US20120329961A1 POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD 有权
标题翻译：聚（亚乙基醚） - 聚硅氧烷组合物和方法
公开(公告)号：US20120329961A1
公开(公告)日：2012-12-27
申请号：US13169137
申请日：2011-06-27
申请人： Alvaro Carrillo , Hua Guo
发明人： Alvaro Carrillo , Hua Guo
IPC分类号： C08L83/12 , C08L71/12 , C08L25/06 , C08L77/00 , C08L23/02 , C08G77/46 , C08L67/00
CPC分类号： C08G77/46 , C08G77/16 , C08G77/80 , C08G81/00 , C08G2261/126 , C08L71/12 , C08L83/12 , C08L2205/05 , C08L83/04
摘要： A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.
摘要翻译：包含聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。氧化聚合包括一元酚添加时间，其特征在于第一温度，加入时间之后的生成周期，并且特征在于大于第一温度的第二温度，以及添加周期和构建周期之间的温度斜坡期间。在温度升高期间，温度以每分钟约0.01至约0.35℃的平均速率增加，这提高了聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率。

28. 发明申请

US20110266024A1 FLAME-RETARDANT POLY(ARYLENE ETHER) COMPOSITION AND ITS USE AS A COVERING FOR COATED WIRE 有权
标题翻译：阻燃聚（亚乙基醚）组合物及其作为涂层覆盖物的用途
公开(公告)号：US20110266024A1
公开(公告)日：2011-11-03
申请号：US12673875
申请日：2008-09-05
申请人： Weili Qiu , Jian Guo , Xiucuo Li , Hua Guo
发明人： Weili Qiu , Jian Guo , Xiucuo Li , Hua Guo
IPC分类号： H01B7/295 , C08K5/3492 , C08K5/53
CPC分类号： C08L23/02 , C08K3/016 , C08K5/0091 , C08K5/5313 , C08L23/0815 , C08L53/00 , C08L53/02 , C08L53/025 , C08L71/12 , C08L71/123 , C08L2201/02 , H01B3/427 , H01B3/441 , H01B7/295 , C08L2666/24 , C08L2666/18 , C08L2666/14 , C08L2666/04 , C08L2666/02
摘要： A flame retardant poly(arylene ether) composition is described. In addition to the poly(arylene ether), the composition includes a polyolefin component, and a flame retardant composition that includes a metal dialkyl phosphinate. The polyolefin component can be a polyolefin polymer and/or the polyolefin block of a poly(alkenyl aromatic)-polyolefin block copolymer. The composition is particularly suitable as a replacement for poly(vinyl chloride) in insulation for wire and cable.
摘要翻译：描述了阻燃聚（亚芳基醚）组合物。除了聚（亚芳基醚）之外，组合物还包括聚烯烃组分和包含二烷基次膦酸金属的阻燃组合物。聚烯烃组分可以是聚（烯基芳族） - 聚烯烃嵌段共聚物的聚烯烃聚合物和/或聚烯烃嵌段。该组合物特别适合作为电线和电缆绝缘中聚（氯乙烯）的替代品。

29. 发明授权

US08017716B2 Morpholine-substituted poly(arylene ether) and method for the preparation thereof 有权
标题翻译：吗啉取代的聚（亚芳基醚）及其制备方法
公开(公告)号：US08017716B2
公开(公告)日：2011-09-13
申请号：US12495980
申请日：2009-07-01
申请人： Alvaro Carrillo , Stephen M. Farnell , Hua Guo
发明人： Alvaro Carrillo , Stephen M. Farnell , Hua Guo
IPC分类号： C08G65/38 , C08G63/02
CPC分类号： C08G65/46
摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.
摘要翻译：使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。它还表现出高分子量级分中增加的吗啉掺入。与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚）发明显示减少的气味。与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量在复合期间建立并改善与聚酰胺的相容性。

30. 发明申请

US20110003962A1 MORPHOLINE-SUBSTITUTED POLY(ARYLENE ETHER) AND METHOD FOR THE PREPARATION THEREOF 有权
标题翻译：吗啉取代的聚（亚乙基醚）及其制备方法
公开(公告)号：US20110003962A1
公开(公告)日：2011-01-06
申请号：US12495980
申请日：2009-07-01
申请人： Alvaro Carrillo , Stephen M. Farnell , Hua Guo
发明人： Alvaro Carrillo , Stephen M. Farnell , Hua Guo
IPC分类号： C08G65/00
CPC分类号： C08G65/46
摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.
摘要翻译：使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。它还表现出高分子量级分中增加的吗啉掺入。与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚）发明显示减少的气味。与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量在复合期间建立并改善与聚酰胺的相容性。

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