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21. 发明申请

US20140171563A1 Composition including a semi-aromatic polyamide and uses thereof, in particular for a reflector having a light-emitting diode 审中-公开
标题翻译：包括半芳族聚酰胺及其用途的组合物，特别是具有发光二极管的反射体
公开(公告)号：US20140171563A1
公开(公告)日：2014-06-19
申请号：US14127532
申请日：2012-06-21
申请人： Thierry Briffaud , Philippe Blondel , Quentin Pineau , Shinya Matsuno
发明人： Thierry Briffaud , Philippe Blondel , Quentin Pineau , Shinya Matsuno
IPC分类号： C08K13/04
CPC分类号： C08K13/04 , C08K3/22 , C08K5/524 , G02B1/04 , G02B1/041 , H01L33/60 , C08L77/00
摘要： The invention relates to a composition including 30 to 97 wt % of at least one semi-aromatic polyamide, 2 to 50 wt % of white pigments, 0 to 50 wt % of strengthening agents, 0.1, to 10 wt % of at least one metal hydroxide and/or of at least one metal oxide other than a metal oxide, and up to 3 wt % of an organic phosphite. The invention also relates to the use of said composition for forming all or part of an electronic component, as well as to a reflector having a light-emitting diode (LED) and entirely or partially consisting of a material obtained form said composition.
摘要翻译：本发明涉及包含30-97重量％的至少一种半芳族聚酰胺，2-50重量％的白色颜料，0-50重量％的增强剂，0.1-10重量％的至少一种金属氢氧化物和/或至少一种金属氧化物以外的金属氧化物和至多3重量％的有机亚磷酸酯。本发明还涉及所述组合物用于形成电子部件的全部或部分的用途，以及具有发光二极管（LED）的反射器，并且完全或部分地由从所述组合物获得的材料组成。

22. 发明申请

US20120040115A1 REINFORCED FLAME-RETARDANT POLYAMIDE COMPOSITION 失效
标题翻译：强化阻燃聚酰胺组合物
公开(公告)号：US20120040115A1
公开(公告)日：2012-02-16
申请号：US13146407
申请日：2010-01-27
申请人： Philippe Blondel , Eric Gamache , Benjamin Saillard , Barbara Ramfel
发明人： Philippe Blondel , Eric Gamache , Benjamin Saillard , Barbara Ramfel
IPC分类号： C08L77/06 , C08K13/04 , B29C47/00 , B32B1/08 , B32B27/18 , B29C45/00 , C08K5/5313 , C08K13/02
CPC分类号： C08L77/00 , C08K5/5313 , C08K7/02 , Y10T428/1314 , Y10T428/1372
摘要： The invention relates to a composition comprising, relative to the total weight of the composition: between 25% and 52% by weight of at least one semi-crystalline or amorphous polyamide, having an amine chain-end content of less than 0.040 meq/g, between 24% and 40% by weight of at least one reinforcer, and between 24% and 35% by weight of at least one metal salt, optionally contained in a polymer, chosen from a metal salt of phosphinic acid, a metal salt of diphosphinic acid, and a mixture thereof. The invention also relates to the process for preparing this composition and its use.
摘要翻译：本发明涉及一种组合物，其相对于组合物的总重量：25重量％至52重量％的至少一种半结晶或无定形聚酰胺，其胺链端含量小于0.040meq / g ，至少一种增强剂的24重量％至40重量％，以及24重量％至35重量％的至少一种金属盐，任选地包含在聚合物中，其选自次膦酸金属盐，金属盐二次膦酸及其混合物。本发明还涉及制备该组合物及其用途的方法。

23. 发明申请

US20110135860A1 BLENDS OF TRANSPARENT AMORPHOUS POLYAMIDES BASED ON DIAMINES AND ON TETRADECANEDIOIC ACID AND SEMICRYSTALLINE POLYAMIDES 审中-公开
标题翻译：基于DIAMINES和十四烷酸和半结晶聚酰胺的透明非晶性聚酰胺的共混
公开(公告)号：US20110135860A1
公开(公告)日：2011-06-09
申请号：US13016042
申请日：2011-01-28
申请人： Annett Linemann , Philippe Bussi , Philippe Blondel
发明人： Annett Linemann , Philippe Bussi , Philippe Blondel
IPC分类号： C08L77/06 , B32B1/08
CPC分类号： C08G69/26 , C08G69/265 , Y10T428/139
摘要： The present invention relates to a transparent amorphous polyamide which results from the condensation of at least one diamine chosen from aromatic, arylaliphatic and cycloaliphatic diamines, of tetradecanedioic acid or of a mixture comprising at least 50 mol % of tetradecanedioic acid and at least one diacid chosen from aliphatic, aromatic and cycloaliphatic dicarboxylic acids. The invention also relates to a composition comprising, by weight, 1 to 100% of the preceding polyamide and 99 to 0% of a semicrystalline polyamide. The invention also relates to the objects composed of the composition of the invention, such as panels, films, sheets, pipes, profiles or objects obtained by injection moulding. The invention also relates to objects covered with a transparent protective layer composed of the composition of the invention.
摘要翻译：本发明涉及透明无定形聚酰胺，其由选自芳族，芳基脂族和脂环族二胺，十四烷二酸的至少一种二胺或包含至少50mol％十四烷二酸和至少一种二酸的混合物缩合而得到来自脂族，芳族和脂环族二羧酸。本发明还涉及一种组合物，其包含按重量计1至100％的前述聚酰胺和99至0％的半结晶聚酰胺。本发明还涉及由本发明的组合物构成的物体，例如通过注射成型获得的面板，膜，片，管，轮廓或物体。本发明还涉及由本发明的组合物构成的透明保护层所覆盖的物体。

24. 发明申请

US20090264601A1 COPOLYMERS HAVING AMIDE UNITS AND ETHER UNITS WITH IMPROVED OPTICAL PROPERTIES 有权
标题翻译：具有改进光学特性的单元和单元的共聚物
公开(公告)号：US20090264601A1
公开(公告)日：2009-10-22
申请号：US12302668
申请日：2007-06-08
申请人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
发明人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
IPC分类号： C08G69/26 , C08G69/48
CPC分类号： C08G69/40
摘要： A subject-matter of the present invention is a copolymer based on amide units and based on ether units, the amide units being composed predominantly of an equimolar combination of at least one diamine and of at least one dicarboxylic acid, the diamine or diamines being predominantly cycloaliphatic and the dicarboxylic acid or acids being predominantly linear aliphatic, it being possible for the amide units optionally to comprise, but to a minor extent, at least one other polyamide comonomer, the respective proportions of monomers of the ether and amide units being chosen so that: the said copolymer exhibits a high transparency which is such that the transmission at 560 nm through a sheet with a thickness of 2 mm is greater than 75%; the said copolymer exhibits a crystallinity such that the enthalpy of fusion during the second heating of an ISO DSC (delta Hm(2)) is at most equal to 30 J/g, the weight being with respect to the amount of amide units present or of polyamide present, this melting corresponding to that of the amide units; the said copolymer has a glass transition temperature at least equal to 75° C.
摘要翻译：本发明的主题是基于酰胺单元并基于醚单元的共聚物，酰胺单元主要由至少一种二胺和至少一种二羧酸的等摩尔组合组成，二胺或二胺主要是脂环族和二羧酸或酸主要是直链脂肪族，酰胺单元可能任选地包含至少一种其它聚酰胺共聚单体，所以单独的醚和酰胺单元的相应比例被选择为所述共聚物表现出高透明度，使得通过厚度为2mm的片材在560nm的透射率大于75％; 所述共聚物显示出结晶度，使得在ISO DSC（ΔHm（2））的第二次加热期间的熔化焓最多等于30J / g，其重量相对于存在的酰胺单元的量或的聚酰胺存在，这种熔融对应于酰胺单元的熔融; 所述共聚物的玻璃化转变温度至少等于75℃

25. 发明申请

US20060074158A1 Flexible semicrystalline polyamides 有权
标题翻译：柔性半结晶聚酰胺
公开(公告)号：US20060074158A1
公开(公告)日：2006-04-06
申请号：US11243532
申请日：2005-10-05
申请人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
发明人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
IPC分类号： C08K5/43
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide Al of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.
摘要翻译：本发明涉及一种组合物和具有由所述组合物制成的层的结构，其中所述组合物的总重量为100％：50至100％的至少一种式XY / Z或6的聚酰胺Al。 Y2 / Z，其中：X表示具有6至10个碳原子的脂族二胺的残基，Y表示具有10至14个碳原子的脂族二羧酸的残基，Y2表示具有 15〜20个碳原子，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基，Y1表示脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比在0〜15％之间; 0〜40％的增塑剂; 0至50％的抗冲改性剂; 和0〜50％的聚酰胺A2。

26. 发明授权

US6143862A Copolyamides and polyamide compositions, process of manufacture and applications 失效
标题翻译：共聚酰胺和聚酰胺组合物，制造和应用的过程
公开(公告)号：US6143862A
公开(公告)日：2000-11-07
申请号：US156876
申请日：1998-09-18
申请人： Philippe Blondel , Thierry Briffaud , Patrick Dang , Thibaut Montanari , Michael Werth
发明人： Philippe Blondel , Thierry Briffaud , Patrick Dang , Thibaut Montanari , Michael Werth
IPC分类号： C08G69/08 , C08G69/14 , C08K3/32 , C08K5/10 , C08K5/1515 , C08K5/34 , C08K5/435 , C08K5/49 , C08L77/02 , C08G73/00
CPC分类号： C08G69/14 , C08G69/08
摘要： Colpolyamides resulting from the polycondensation of a mixture of (a) dodecanelactam (L12) or of 12-aminododecanoic acid (A12) and of (b) 11-aminoundecanoic acid (A11) are characterized in that the monomer L12 or A12 represents 1 to 15% or 85 to 99% by weight of the mixture, and the copolyamides have melting points (mp) as a function of the composition, the units originating from the monomer A12 and L12 being in a majority or minority respectively:(1) A12 or L12 is a majority: mp (.degree. C.).gtoreq.176-0.567.times.(% A11)(2) A12 or L12 is a majority: mp (.degree.).gtoreq.187-0.5.times.(% A12 or L12),the melting points being determined by taking the peaks of the exotherm signals obtained in differential thermal analysis with a rate of heating of 10.degree. C./minute for the second heating run. Such copolyamides have a property of resilience at low temperature and a property of improved suppleness, especially when plasticizer is added to them. Their ductile/brittle transition temperature is shifted towards a lower temperature.
摘要翻译：由（a）十二内酰胺（L12）或12-氨基十二烷酸（A12）和（b）11-氨基十一烷酸（A11）的混合物缩聚得到的共聚酰胺的特征在于，单体L12或A12表示1〜15 ％或85至99重量％，共聚酰胺具有作为组合物的函数的熔点（mp），源自单体A12和L12的单元分别为多数或少数：（1）A12或 L12为多数：mp（℃）> / = 176-0.567x（％A11）（2）A12或L12为多数：mp（℃）= 187-0.5倍（％A12或L12）通过在差热分析中获得的放热信号的峰值以10℃/分钟的速率进行第二次加热运行来确定熔点。这种共聚酰胺在低温下具有回弹性能，并具有改善柔软性的特性，特别是当添加增塑剂时。它们的延性/脆性转变温度向较低的温度转移。

27. 发明授权

US08952103B2 Copolymers having amide units and ether units with improved optical properties 有权
标题翻译：具有酰胺单元和醚单元的共聚物具有改进的光学性能
公开(公告)号：US08952103B2
公开(公告)日：2015-02-10
申请号：US12302668
申请日：2007-06-08
申请人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
发明人： Philippe Blondel , Inci Turan , Thibaut Montanari , Frederic Malet
IPC分类号： C08L77/12 , C08G69/40
CPC分类号： C08G69/40
摘要： The present invention is a copolymer based on amide units and ether units, wherein the amide units being comprise a major portion of an equimolar combination of at least one diamine and at least one dicarboxylic acid, the diamine(s) is/are mainly cycloaliphatic and the dicarboxylic acid(s) is/are mainly linear and aliphatic, the amide units optionally comprise, but in a minor proportion, at least one other polyamide comonomer, the respective proportions of ether and amide unit monomers are selected in such a way that said copolymer is highly transparent to such an extent that the transmittance at 560 nm on a plate 2 mm thick is greater than 75%; the crystallinity of said copolymer is such that the enthalpy of fusion during the first heating of a ISO DSC (delta Hm(2)) is at least 30 J/g, where the mass is related to the number of amide units contained or of polyamide contained, which fusion corresponds to that of the amide units; and said copolymer has a glass transition temperature of at least 75° C.
摘要翻译：本发明是基于酰胺单元和醚单元的共聚物，其中酰胺单元包含至少一种二胺和至少一种二羧酸的等摩尔组合的主要部分，二胺主要是脂环族和二羧酸主要是直链和脂族的，酰胺单元任选地包含但少量的至少一种其它聚酰胺共聚单体，醚和酰胺单元单体的各自比例选择为使得所述共聚物高度透明，使得2mm厚的560nm处的透射率大于75％; 所述共聚物的结晶度使得在ISO DSC（ΔHm（2））的第一次加热期间的熔融焓为至少30J / g，其中质量与所含酰胺单元或聚酰胺的数量有关包含，该融合对应于酰胺单元的融合; 并且所述共聚物的玻璃化转变温度至少为75℃

28. 发明申请

US20110195215A1 SEMI-AROMATIC COPOLYAMIDE AND PROCESS FOR PREPARING SAME 审中-公开
标题翻译：半芳族共聚酰胺及其制备方法
公开(公告)号：US20110195215A1
公开(公告)日：2011-08-11
申请号：US12996417
申请日：2009-08-06
申请人： Thierry Briffaud , Philippe Blondel , Thierry Lefebvre
发明人： Thierry Briffaud , Philippe Blondel , Thierry Lefebvre
IPC分类号： C08L77/06 , C08G69/14 , B32B1/08
CPC分类号： C08G69/36 , C08G69/04 , C08G69/26 , C08G69/265 , C08G69/28 , C08K3/32 , C08L77/06 , C09D177/06 , Y10T428/139
摘要： The invention relates to a copolyamide comprising at least two units corresponding to the following general formula: A/10,T in which: A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb (cyclo)aliphatic diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36; 10,T denotes a unit obtained from the polycondensation of 1,10-decanediamine and terephthalic acid, characterized in that it has a polydispersity index, denoted by Ip, of less than or equal to 3.5, measured by gel permeation chromatography. The invention also relates to the process for preparing said copolyamide, a composition comprising this polyamide and also the use of this polyamide and of such a composition.
摘要翻译：本发明涉及一种共聚酰胺，其包含对应于以下通式的至少两个单元：A / 10，T，其中：A选自由氨基酸获得的单元，从内酰胺获得的单元和对应于式（Ca二胺）（Cb（环）脂族二酸），代表二胺的碳原子数，b表示二酸的碳原子数，a和b各自在4和36之间; 10，T表示由1,10-癸二胺和对苯二甲酸的缩聚获得的单元，其特征在于其通过凝胶渗透色谱法测定的多分散性指数（以Ip表示）小于或等于3.5。本发明还涉及制备所述共聚酰胺的方法，包含该聚酰胺的组合物以及该聚酰胺和这种组合物的用途。

29. 发明申请

US20090318630A1 BLENDS AND ALLOYS BASED ON AN AMORPHOUS TO SEMICRYSTALLINE COPOLYMER, COMPRISING AMIDE UNITS AND COMPRISING ETHER UNITS, WHEREIN THESE MATERIALS HAVE IMPROVED OPTICAL PROPERTIES 有权
标题翻译：基于非晶形式的半合成共聚物的混合和合金，包括酰胺单元和包含醚单元，由于这些材料具有改进的光学性质
公开(公告)号：US20090318630A1
公开(公告)日：2009-12-24
申请号：US12302660
申请日：2007-06-11
申请人： Thibaut Montanari , Philippe Blondel
发明人： Thibaut Montanari , Philippe Blondel
IPC分类号： C08L77/00
CPC分类号： C08L77/00 , C08L2205/02 , C08L2666/20
摘要： Transparent blend or alloy comprising, by weight, the total being 100%: (A) 1 to 99% of at least one copolymer constituent: which is amorphous or has a crystallinity ranging up to semicrystallinity; and which comprises: (A1) amide units, among which is at least one cycloaliphatic unit; (A2) flexible ether units; (B) 99 to 1% of at least one polymer constituent selected from: (Ba) semicrystalline copolyamides comprising amide units (Ba1) and comprising ether units (Ba2), (Bb) semicrystalline polyamides or copolyamides without ether units, (Bc) transparent polyamides or copolyamides without ether units, which are amorphous or weakly crystalline, and alloys based on such polyamides or copolyamides; and (C) 0 to 50% by weight of at least one polyamide, copolyamide, copolyamide comprising ether units or alloy based on such polyamides or copolyamides other than those used in (A) and (B) above. The resulting blend or alloy has a high transparency such that the transmission at 560 nm on a plate 2 mm thick is greater than 50%.
摘要翻译：包含总重量为100％的透明共混物或合金：（A）1至99％的至少一种共聚物组分：其是无定形的或具有直至半结晶度的结晶度; 并且其包含：（A1）酰胺单元，其中至少一个脂环族单元; （A2）柔性醚单元; （B）99至1％的选自以下的至少一种聚合物成分：（Ba）包含酰胺单元（Ba1）并包含醚单元（Ba2），（Bb）半结晶聚酰胺或无乙醚单元的共聚酰胺的半结晶共聚酰胺（Bc）透明不含醚单元的无机或弱结晶的聚酰胺或共聚酰胺以及基于这种聚酰胺或共聚酰胺的合金; 和（C）0至50重量％的至少一种聚酰胺，共聚酰胺，包含醚单元的共聚酰胺或基于除上述（A）和（B）中使用的那些之外的这种聚酰胺或共聚酰胺的合金。所得共混物或合金具有高透明度，使得2mm厚的板上的560nm处的透射率大于50％。

30. 发明授权

US07625972B2 Flexible semiaromatic polyamides with a low moisture uptake 有权
标题翻译：具有低吸湿性的柔性半芳族聚酰胺
公开(公告)号：US07625972B2
公开(公告)日：2009-12-01
申请号：US12135385
申请日：2008-06-09
申请人： Philippe Blondel , Thierry Briffaud , Annett Linemann , Helene Egret , Pierre Nogues
发明人： Philippe Blondel , Thierry Briffaud , Annett Linemann , Helene Egret , Pierre Nogues
IPC分类号： C08G69/10 , C08G69/14 , C08G69/26
CPC分类号： C08L77/02 , B32B27/08 , C08G69/36 , C08K5/0008 , C08L23/00 , C08L23/02 , C08L25/00 , C08L51/00 , C08L51/06 , C08L53/02 , C08L77/00 , C08L77/06 , H01B3/305 , C08L2666/14 , C08L2666/02 , C08L2666/06 , C08L2666/24
摘要： The present invention relates to a flexible semiaromatic polyamide composition with a low moisture uptake, made up by weight, the total being 100: A) 60 to 99.5% (preferably 70 to 93%) of at least one copolyamide of formula X/Y,Ar in which there are between 0.5 and 0.7 mol of X per 1 mol of Y, and in which Y denotes the residues of 1,10-decanediamine, Ar denotes the residues of terephthalic acid, X denotes the residue of aminoundecanoic acid NH2—(CH2)10—COOH, the unit Y,I residue from the condensation of the diamine (Y) with isophthalic acid, wherein said composition is a flexible semiaromatic copolyamide; B) 0.5 to 40% (preferably 7 to 30%) of at least one product chosen from plasticizers, nanofillers, polyolefins, crosslinked polyolefins and additives.
摘要翻译：本发明涉及一种具有低吸湿性的柔性半芳族聚酰胺组合物，其重量百分比为100:A）60-99.5％（优选70-93％）的至少一种式X / Y的共聚酰胺，其中每1摩尔Y为0.5至0.7摩尔的X，其中Y表示1,10-癸二胺的残基，Ar表示对苯二甲酸的残基，X表示氨基十一烷酸NH 2（ CH2）10-COOH，来自二胺（Y）与间苯二甲酸缩合的单元Y，I残基，其中所述组合物是柔性半芳族共聚酰胺; B）选自增塑剂，纳米填料，聚烯烃，交联聚烯烃和添加剂中的至少一种产品的0.5至40％（优选7至30％）。

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