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21. 发明授权

US09573116B2 Synthesis of ZSM-58 crystals with improved diffusivity for use in gas separations 有权
标题翻译：合成具有改进扩散性的ZSM-58晶体，用于气体分离
公开(公告)号：US09573116B2
公开(公告)日：2017-02-21
申请号：US14573177
申请日：2014-12-17
申请人： Ivy D. Johnson , Tilman W. Beutel , Peter I. Ravikovitch , Harry W. Deckman , Jack W. Johnson , Jean W. Beeckman , Natalie A. Fassbender , Nadya A Hrycenko , Randolph J. Smiley
发明人： Ivy D. Johnson , Tilman W. Beutel , Peter I. Ravikovitch , Harry W. Deckman , Jack W. Johnson , Jean W. Beeckman , Natalie A. Fassbender , Nadya A Hrycenko , Randolph J. Smiley
IPC分类号： C01B39/02 , B01J20/30 , C01B39/04 , B01J20/18 , B01J20/282 , B01D53/02 , C01B37/02 , C01B39/48
CPC分类号： B01J20/3078 , B01D53/02 , B01D2253/108 , B01D2256/245 , B01D2257/304 , B01D2257/504 , B01J20/18 , B01J20/186 , B01J20/282 , B01J20/30 , B01J20/3085 , B01J29/035 , B01J29/70 , B01J2220/80 , B01J2229/36 , B01J2229/40 , C01B37/02 , C01B39/026 , C01B39/04 , C01B39/48 , Y02C10/08 , Y02P20/152
摘要： Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Steaming the H-form DDR framework type crystals at a temperature from 426±° C. to 1100±° C. for a time period from about 30 minutes to about 48 hours can attain one or more of the following properties: a CH4 diffusivity of no more than 95% of the CH4 diffusivity of the unsteamed H-form DDR framework type crystals; an N2 BET surface area from 85% to 110% of the surface area of unsteamed H-form DDR framework type crystals; and an equilibrium CO2 sorption capacity from 80% to 105% of the equilibrium CO2 sorption capacity of unsteamed H-form DDR framework type crystals.
摘要翻译：提供了用于合成具有改进的形态和/或改进的尺寸分布的ZSM-58晶体的方法。通过控制合成ZSM-58晶体的条件，可以产生具有窄尺寸分布的有用尺寸的晶体。在从426℃至1100℃的温度下将H型DDR骨架型晶体蒸馏约30分钟至约48小时的时间段可以获得一种或多种以下性质：CH4扩散系数不超过95％的未蒸发的H型DDR骨架型晶体的CH4扩散性; N2 BET表面积为未蒸发的H型DDR骨架型晶体的表面积的85％至110％; 和平衡CO2吸附容量从未蒸发的H型DDR骨架型晶体的平衡CO 2吸附容量的80％至105％。

22. 发明授权

US09446961B2 MCM-56 manufacture 有权
标题翻译： MCM-56制造
公开(公告)号：US09446961B2
公开(公告)日：2016-09-20
申请号：US14238274
申请日：2012-08-16
申请人： Ivy D. Johnson , Nadya A. Hrycenko , Wieslaw J. Roth , Terry E. Helton
发明人： Ivy D. Johnson , Nadya A. Hrycenko , Wieslaw J. Roth , Terry E. Helton
IPC分类号： C01B39/48 , B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , C07C2/66
CPC分类号： C01B39/48 , B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , B01J2229/186 , B01J2229/42 , C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： The present invention provides an improved method for manufacturing high quality porous crystalline MCM-56 material. It also relates to the MCM-56 material manufactured by the improved method, catalyst compositions comprising same and use thereof in a process for catalytic conversion of hydrocarbon compounds. One such conversion process involves production of monoalkylated aromatic compounds, particularly ethylbenzene and cumene, by the liquid or partial liquid phase alkylation of alkylatable aromatic compound, particularly benzene.
摘要翻译：本发明提供了制造高品质多孔结晶MCM-56材料的改进方法。它还涉及通过改进方法制造的MCM-56材料，包含其的催化剂组合物以及在烃化合物的催化转化方法中的用途。一种这样的转化方法包括通过液体或部分液相烷基化的可烷基化芳族化合物，特别是苯来生产单烷基化芳族化合物，特别是乙苯和枯烯。

23. 发明授权

US09365431B2 Synthesis of ZSM-58 crystals with improved morphology 有权
标题翻译：合成具有改进形态的ZSM-58晶体
公开(公告)号：US09365431B2
公开(公告)日：2016-06-14
申请号：US14074881
申请日：2013-11-08
申请人： Ivy D. Johnson , Nadya A. Hrycenko , Barbara Carstensen , Machteld Mertens , Brita Engels
发明人： Ivy D. Johnson , Nadya A. Hrycenko , Barbara Carstensen , Machteld Mertens , Brita Engels
IPC分类号： C01B39/04 , B01D53/047 , B01D53/04 , B01D69/14 , B01J20/30 , C01B39/48 , B01D53/02 , C01B37/02 , B01J35/02
CPC分类号： C01B39/04 , B01D53/02 , B01D53/04 , B01D53/0423 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D69/147 , B01D2253/108 , B01D2256/245 , B01D2257/102 , B01D2257/504 , B01J20/3078 , B01J35/023 , B01J35/026 , C01B37/02 , C01B39/48 , Y02C10/08 , Y02P20/152
摘要： Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Additionally, by controlling the ratio of water content to silica content in the synthesis mixture, it has unexpectedly been found that ZSM-58 crystals can be formed with an improved morphology. The improved morphology can result in ZSM-58 crystals with a more uniform size across the various dimensions of the crystal, which allows for more uniform diffusion within the crystal. This is in contrast to conventionally synthesized crystals, where the size of the crystal can vary along different axes of the crystals.
摘要翻译：提供了用于合成具有改进的形态和/或改进的尺寸分布的ZSM-58晶体的方法。通过控制合成ZSM-58晶体的条件，可以产生具有窄尺寸分布的有用尺寸的晶体。另外，通过控制合成混合物中水含量与二氧化硅含量的比例，意外地发现可以形成具有改进的形态的ZSM-58晶体。改进的形态可以导致在晶体的各种尺寸上具有更均匀尺寸的ZSM-58晶体，这允许在晶体内更均匀的扩散。这与常规合成的晶体形成对比，其中晶体的尺寸可以沿晶体的不同轴线变化。

24. 发明授权

US08816145B2 Liquid phase alkylation process 有权
标题翻译：液相烷基化工艺
公开(公告)号：US08816145B2
公开(公告)日：2014-08-26
申请号：US13594554
申请日：2012-08-24
申请人： Matthew J. Vincent , Terry E. Helton , Ivy D. Johnson
发明人： Matthew J. Vincent , Terry E. Helton , Ivy D. Johnson
IPC分类号： C07C2/66 , B01J29/70 , C10G29/20
CPC分类号： C07C6/06 , B01J29/7038 , B01J2229/42 , C07C2/66 , C07C2521/04 , C07C2521/16 , C07C2529/70 , C10G29/205 , C10G2300/1092 , C10G2300/1096 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/30 , Y02P20/52 , C07C15/073 , C07C15/085
摘要： The present invention provides a process for producing a monoalkylated aromatic compound comprising the step of contacting an alkylatable aromatic compound with an alkylating agent in the presence of a catalyst composition under effective alkylation conditions, said catalyst composition comprising MCM-56 and a binder, such that the crystal/binder weight ratio in the catalyst composition is from above 20/80 to about 80/20.
摘要翻译：本发明提供一种制备单烷基化芳族化合物的方法，其包括在有效的烷基化条件下，在催化剂组合物存在下，使烷基化芳族化合物与烷基化剂接触的步骤，所述催化剂组合物包含MCM-56和粘合剂，使得催化剂组合物中的结晶/粘合剂重量比为20/80至约80/20。

25. 发明授权

US07842277B2 Molecular sieve composition, a method of making and a process of using the same 有权
标题翻译：分子筛组合物，制备方法及其使用方法
公开(公告)号：US07842277B2
公开(公告)日：2010-11-30
申请号：US11827953
申请日：2007-07-13
申请人： Wieslaw J. Roth , Machteld M. Mertens , Els C. De Clerck , Ivy D. Johnson
发明人： Wieslaw J. Roth , Machteld M. Mertens , Els C. De Clerck , Ivy D. Johnson
IPC分类号： C01B39/48 , C01B39/46 , C01B39/04
CPC分类号： B01J29/7038 , B01J29/047 , B01J35/002 , C01B39/06 , C01B39/48 , C07C2/66 , C07C6/123 , C07C29/36 , C07C37/08 , C07C37/11 , C07C37/14 , C07C37/20 , C07C41/06 , C07C57/30 , C07C263/20 , C07C2529/70 , Y02P20/52 , C07C265/14 , C07C39/06 , C07C43/046 , C07C33/20 , C07C39/04 , C07C39/16
摘要： This disclosure relates to a crystalline MCM-22 family molecular sieve composition having, in its as-synthesized form, an X-ray diffraction pattern including a peak at d-spacing maximum of 12.33±0.23 Angstroms, a distinguishable peak at a d-spacing maximum between 12.57 to about 14.17 Angstroms and a non-discrete peak at a d-spacing maximum between 8.8 to 11. Angstroms, wherein the peak intensity of the d-spacing maximum between 12.57 to about 14.17 Angstroms is less than 90% of the peak intensity of the d-spacing maximum at 12.33±0.23 Angstroms. This disclosure also relates to methods of making the crystalline MCM-22 family molecular sieve composition.
摘要翻译：本公开涉及一种结晶MCM-22族分子筛组合物，其以其合成形式具有包括在d间距最大值为12.33±0.23埃处的峰的X射线衍射图，d-间隔处的可区分峰最大值在12.57至约14.17埃之间，并且在8.8至11之间的d间距最大值处的非离散峰。其中，在12.57至约14.17埃之间的d间距最大值的峰值强度小于峰值的90％ d间距最大强度为12.33±0.23埃。本公开还涉及制备结晶MCM-22族分子筛组合物的方法。

26. 发明申请

US20080253959A1 Synthesis crystalline molecular sieves 审中-公开
标题翻译：合成结晶分子筛
公开(公告)号：US20080253959A1
公开(公告)日：2008-10-16
申请号：US11731870
申请日：2007-03-30
申请人： Ivy D. Johnson , Glenn R. Sweeten , Robert A. Crane
发明人： Ivy D. Johnson , Glenn R. Sweeten , Robert A. Crane
IPC分类号： C01B33/20 , C01B39/00
CPC分类号： C01B37/00 , C01B39/00
摘要： In a process for synthesizing a crystalline molecular sieve, an aqueous synthesis mixture is produced capable of forming the crystalline molecular sieve. Crystallization of the synthesis mixture is induced so as to form crystals of said molecular sieve in the synthesis mixture and, when crystallization is complete, the molecular sieve crystals are allowed or caused to separate from the remainder of the synthesis mixture to produce a solid phase comprising said molecular sieve crystals and a supernatant liquid phase. The supernatant liquid phase is then decanted from the solid phase to recover the molecular sieve crystals and the crystals are dried without initially being subjected to washing or filtration.
摘要翻译：在合成结晶分子筛的方法中，制备能够形成结晶分子筛的水性合成混合物。诱导合成混合物的结晶，以便在合成混合物中形成所述分子筛的晶体，并且当结晶完成时，使分子筛结晶与合成混合物的其余部分分离以产生包含所述分子筛晶体和上清液相。然后从固相中倾析出上清液相，回收分子筛晶体，并将晶体干燥，最初不进行洗涤或过滤。

27. 发明授权

US5260501A Catalytic oligomerization process using modified mesoporous crystalline material 失效
标题翻译：使用改性介孔结晶材料的催化低聚方法
公开(公告)号：US5260501A
公开(公告)日：1993-11-09
申请号：US920944
申请日：1992-07-28
申请人： Nazeer A. Bhore , Ivy D. Johnson , Kathleen M. Keville , Quang N. Le , Grant H. Yokomizo
发明人： Nazeer A. Bhore , Ivy D. Johnson , Kathleen M. Keville , Quang N. Le , Grant H. Yokomizo
IPC分类号： C07C2/10 , C07C2/12
CPC分类号： B01J29/044 , C07C2/10 , C07C2/12 , C07C2529/70
摘要： A novel oligomerization catalyst and process for upgrading olefins employing new synthetic catalyst of ultra-large pore crystalline material. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units; and the porous crystalline material is impregnated with at least one oligomerization promoting metal, such as Groups VIIIA metals, preferably nickel.The new process is provided for catalytic oligomerization of olefin feedstock which comprises contacting the feedstock under catalytic conversion conditions with the metal-modified acid metallosilicate solid catalyst having the structure of MCM-41 with hexagonal honeycomb lattice structure consisting essentially of uniform pores in the range of about 20 to 100 Angstroms. The oligomerization reaction is very selective, especially when conducted at temperature of 60.degree. to 120.degree. C. Low severity reaction permits excellent conversion of lower olefins at pressure of about 100-13,000 kPa range and moderate space velocity.
摘要翻译：一种新型低聚催化剂和使用新型超大孔结晶材料合成催化剂改质烯烃的方法。新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克，可以用大于约100的d100值进行指数的六方电子衍射图 18埃单位和具有至少约13埃单位的最大垂直横截面的均匀尺寸孔的六边形排列; 并且多孔结晶材料用至少一种低聚促进金属浸渍，例如第VIIIA族金属，优选镍。提供了用于烯烃原料的催化低聚的新方法，其包括在催化转化条件下使原料与具有MCM-41结构的金属改性的酸式金属硅酸盐固体催化剂接触，六方蜂窝晶格结构基本上由均匀的孔组成，约20至100埃。低聚反应是非常有选择性的，特别是在60℃至120℃的温度下进行。低强度反应允许在约100-13000kPa范围和适度的空间速度的压力下对低级烯烃进行极好的转化。

28. 发明授权

US5237121A Highly selective N-olefin isomerization process using microcrystalline ZSM-22 失效
标题翻译：使用微晶ZSM-22的高选择性N-烯烃异构化方法
公开(公告)号：US5237121A
公开(公告)日：1993-08-17
申请号：US925442
申请日：1992-08-11
申请人： Iraj Rahmim , Albin Huss, Jr. , Daria N. Lissy , Donald J. Klocke , Ivy D. Johnson
发明人： Iraj Rahmim , Albin Huss, Jr. , Daria N. Lissy , Donald J. Klocke , Ivy D. Johnson
IPC分类号： C07C5/27
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
摘要翻译：公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化成异烯烃的方法，其中线性烯烃例如正丁烯与包含ZSM-22的催化剂接触，ZSM-22的晶体尺寸最大尺寸不大于0.5微米。该方法在异构化条件下进行以产生相应碳数的异烯烃，例如异丁烯。即使在相对较低的温度下也能获得高的全部异烯烃收率。

29. 发明授权

US5156828A Method for manufacturing synthetic mesoporous crystalline material 失效
标题翻译：制造合成介孔结晶材料的方法
公开(公告)号：US5156828A
公开(公告)日：1992-10-20
申请号：US732516
申请日：1991-07-18
申请人： Thomas F. Degnan , Ivy D. Johnson , Kathleen M. Keville
发明人： Thomas F. Degnan , Ivy D. Johnson , Kathleen M. Keville
IPC分类号： B01J29/04 , B01J29/70 , C01B37/00 , C01B37/02 , C01B39/00
CPC分类号： C01B37/02 , B01J29/04 , B01J29/70 , C01B37/00 , C01B39/00 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要： This invention relates to a method for synthesizing an ultra-large pore crystalline material and the use of such crystalline material as a sorbent and in catalytic conversion of organic and inorganic compounds. The synthesis method includes hydrothermally treating the as-synthesized crystalline material in the presence or absence of a binder. In a preferred embodiment, the crystalline material contains organic directing agent and is composited in an alumina binder. The crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units.
摘要翻译：本发明涉及一种用于合成超大孔结晶材料的方法以及这种结晶材料作为吸附剂的用途以及催化转化有机和无机化合物。合成方法包括在存在或不存在粘合剂的情况下水解处理合成的结晶材料。在优选的实施方案中，结晶材料含有有机导向剂并且在氧化铝粘合剂中复合。结晶物质表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克/ 100克，六方形电子衍射图可用d100值大于约18 埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。

30. 发明授权

US5112589A Method for synthesizing mesoporous crystalline material using acid 失效
标题翻译：使用酸合成介孔结晶材料的方法
公开(公告)号：US5112589A
公开(公告)日：1992-05-12
申请号：US720286
申请日：1991-06-25
申请人： Ivy D. Johnson , John P. McWilliams
发明人： Ivy D. Johnson , John P. McWilliams
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： B01J29/0308 , B01D53/8628 , B01J20/02 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42 , Y10S423/30
摘要： A method for synthesizing an ultra-large pore crystalline material which can be used as a sorbent or catalyst component for conversion of organic and inorganic compound is improved through the addition of a strong acid to the reaction mixture.
摘要翻译：通过向反应混合物中加入强酸，可以提高合成可用作转化有机和无机化合物的吸附剂或催化剂组分的超大孔结晶材料的方法。

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