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    • 22. 发明授权
    • Fabrication method for pattern-formed structure
    • 图案形成结构的制作方法
    • US09017929B2
    • 2015-04-28
    • US11855244
    • 2007-09-14
    • Makoto AbeMasaaki KuriharaKazuaki Baba
    • Makoto AbeMasaaki KuriharaKazuaki Baba
    • G03F7/207B29D11/00B82Y10/00B82Y40/00G03F7/00G03F7/20
    • G03F7/2037B29D11/00365B82Y10/00B82Y40/00G03F7/0002G03F7/2053G03F7/2059G03F7/70383
    • An object of the present invention is to provide a fabrication method for pattern-formed structure having a smooth three-dimensional structure through a fewer processes. To achieve the object, the present invention provides a fabrication method for pattern-formed structure comprising: a dot modulation pattern forming process of binarizing a shape of a targeted three-dimensional structure to form a dot modulation pattern, a writing process of using the dot modulation pattern to write directly by a writer on a photosensitive resin layer formed on a substrate, and a developing process of developing the photosensitive resin layer after the writing to form a resin layer with three-dimensional structure, wherein the writing process is performed by a writing energy supplying method in which writing energy is supplied to the photosensitive resin layer by an area larger than a minimum dot area in the dot modulation pattern.
    • 本发明的目的是提供一种通过较少的工艺具有平滑三维结构的图案形成结构的制造方法。 为了实现该目的,本发明提供了一种用于图案形成结构的制造方法,包括:将二维化目标三维结构的形状二值化以形成点调制图案的点调制图案形成处理,使用点 由写入器直接写在形成在基板上的感光树脂层上的调制图案以及在写入之后使感光性树脂层显影以形成具有三维结构的树脂层的显影过程,其中写入处理由 写入能量供给方法,其中写入能量通过点调制图案中的最小点区域大于该感光性树脂层。
    • 24. 发明授权
    • Organic domain/inorganic domain complex materials and use thereof
    • 有机域/无机域复合材料及其用途
    • US07244797B2
    • 2007-07-17
    • US10467485
    • 2002-02-08
    • Masaaki KuriharaHiroyoshi Matsuyama
    • Masaaki KuriharaHiroyoshi Matsuyama
    • C08F30/04
    • C08G77/58A01N25/10A01N33/12A01N41/04A01N43/40A01N55/00A01N59/00A01N59/06A01N59/16A01N59/20C08G77/42C08G2270/00C09D7/65C09D183/14
    • Disclosed are an organic domain/inorganic domain hybrid material comprising an organic domain comprising at least one water-soluble organic polymer having anionic and/or cationic functional groups, and an inorganic domain, the organic and inorganic domains being chemically bonded to each other through the functional groups, the inorganic domain comprising inorganic bridges, each independently comprising at least one Si atom, at least two O atoms and at least one divalent metal atom, wherein the Si atom and the O atoms together form at least one siloxane linkage arranged longitudinally of the inorganic bridge, wherein each divalent metal atom is ionically bonded to the O atoms of the siloxane linkages positioned adjacent to the divalent metal atoms, wherein, when at least a part of the organic domain is comprised of at least one organic polymer having an anionic functional group and optionally a cationic functional group, the organic domain/inorganic domain weight ratio is less than 1.0; and the use thereof as a hydrophilicity reagent and an antibacterial/antifungal reagent.
    • 公开了一种有机域/无机域杂化材料,其包含含有至少一种具有阴离子和/或阳离子官能团的水溶性有机聚合物的有机结构域和无机区域,有机和无机区域通过 官能团,无机域包括无机桥,各自独立地包含至少一个Si原子,至少两个O原子和至少一个二价金属原子,其中Si原子和O原子一起形成至少一个硅氧烷键, 无机桥,其中每个二价金属原子离子键合到与二价金属原子相邻的硅氧烷键的O原子,其中当至少一部分有机结构域由至少一种具有阴离子的有机聚合物 官能团和任选的阳离子官能团,有机结构域/无机畴重量比小于1.0 ; 以及作为亲水性试剂和抗菌/抗真菌试剂的用途。
    • 26. 发明授权
    • Patterning method with micro-contact printing and its printed product
    • 微接触印刷及其印刷产品的图案化方法
    • US06868786B2
    • 2005-03-22
    • US10738367
    • 2003-12-12
    • Masamichi FujihiraUichi AkibaHiroki OkuiShintaro FujiiMasaaki Kurihara
    • Masamichi FujihiraUichi AkibaHiroki OkuiShintaro FujiiMasaaki Kurihara
    • G03F7/00B41F1/18
    • B82Y10/00B82Y40/00G03F7/0002Y10T428/31663
    • A patterning method for micro-contact printing involves the steps of: applying a resin on a master having projected patterns, hardening the resin and thereafter removing the hardened resin from the master to make a stamp of the resin; applying a molecular ink including hydrophobic molecules dispersed in a solvent on the stamp; forming micro-contact printed patterns of the hydrophobic molecular layer on a substrate by means of the stamp on which the molecular ink is applied; dipping the substrate with micro-contact printed patterns in a hydrophilic molecule solution dispersed in a solvent to give chemical modification to the areas of the surface of the substrate around the micro-contact printed patterns, the solution including hydrophilic molecules having a chain length shorter than the chain length of hydrophobic molecules included in the molecular ink is used as the hydrophilic molecule solution. According to the method, printed products having micro-contact printed patterns of a molecular level are obtained with a contrast between the micro-contact printed patterns and the area of the surface of the substrate around the micro-contact printed patterns.
    • 用于微接触印刷的图案化方法包括以下步骤:将树脂施加在具有突出图案的母版上,硬化树脂,然后从母版中除去硬化树脂以制成树脂的印模; 将包含分散在溶剂中的疏水性分子的分子油墨施加到印模上; 通过施加分子油墨的印模在基材上形成疏水分子层的微接触印刷图案; 将具有微接触印刷图案的基底浸渍在分散在溶剂中的亲水性分子溶液中,以对微接触印刷图案周围的基底表面的区域进行化学改性,该溶液包括链长短于 包含在分子油墨中的疏水性分子的链长用作亲水性分子溶液。 根据该方法,通过微接触印刷图案与微接触印刷图案周围的基板表面的面积之间的对比度获得具有分子水平的微接触印刷图案的印刷产品。