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21. 发明授权

US08968877B2 Barrier materials for mirror assemblies 有权
标题翻译：镜组件阻挡材料
公开(公告)号：US08968877B2
公开(公告)日：2015-03-03
申请号：US13397208
申请日：2012-02-15
申请人： Sudip Mukhopadhyay , David Nalewajek , Desaraju Varaprasad , Awdhoot Vasant Kerkar
发明人： Sudip Mukhopadhyay , David Nalewajek , Desaraju Varaprasad , Awdhoot Vasant Kerkar
IPC分类号： B05D1/02 , B05D3/02 , C09D127/12 , F24J2/10 , G02B5/08 , G02B1/10
CPC分类号： G02B1/14 , B05D1/02 , B05D3/02 , C09D127/12 , F24S2023/86 , G02B1/105 , G02B5/0808 , Y10T428/26 , Y10T428/269 , Y10T428/3154
摘要： Provided herein is a reflective optical construction containing a fluoropolymer barrier layer, wherein the fluoropolymer is selected from the group consisting of homopolymers and copolymers of at least one tetrafluoropropene or pentafluoropropene, preferably 2,3,3,3-tetrafluoropropene. Also disclosed is a method of forming a reflective optical construction including (a) applying a barrier layer comprising one or more fluoropolymers selected from the group consisting of homopolymers and copolymers of at least one tetrafluoropropene or pentafluoropropene, and (b) curing.
摘要翻译：本文提供了含有氟聚合物阻挡层的反射光学结构，其中氟聚合物选自由至少一种四氟丙烯或五氟丙烯，优选2,3,3,3-四氟丙烯的均聚物和共聚物组成的组。还公开了一种形成反射光学结构的方法，其包括（a）施加包含一种或多种选自至少一种四氟丙烯或五氟丙烯的均聚物和共聚物的含氟聚合物的阻隔层和（b）固化。

22. 发明授权

US08820079B2 Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids 有权
标题翻译：氯代和溴代氟代烯烃化合物可用作有机有机酸循环工作液
公开(公告)号：US08820079B2
公开(公告)日：2014-09-02
申请号：US12630647
申请日：2009-12-03
申请人： Gary Zyhowski , Ryan J. Hulse , Haridasan K. Nair , David Nalewajek , Rajiv R. Singh
发明人： Gary Zyhowski , Ryan J. Hulse , Haridasan K. Nair , David Nalewajek , Rajiv R. Singh
IPC分类号： F01K25/08 , C09K5/04 , F25B25/00
CPC分类号： C09K5/048 , C07B2200/09 , C07C21/18 , C09K5/045 , C09K2205/126 , F01K25/06 , F01K25/08
摘要： Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R1, R2, R3, and R4 are each independently selected from the group consisting of: H, F, Cl, Br, and C1-C6 alkyl, at least C6 aryl, at least C3 cycloalkyl, and C6-C15 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.
摘要翻译：本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H ，F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷基芳基，其中式（I）含有至少一个 F和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。工作流体在兰金循环系统中有用，可有效地将工业过程产生的废热（如燃料电池的发电）转化为机械能或进一步电力。本发明的工作流体也可用于采用其它热能转换过程和循环的设备中。

23. 发明授权

US08529684B2 Carrier solvent for fingerprint formulations 失效
标题翻译：用于指纹配方的载体溶剂
公开(公告)号：US08529684B2
公开(公告)日：2013-09-10
申请号：US13587433
申请日：2012-08-16
申请人： David Nalewajek , Cheryl L. Cantlon , Andrew J. Poss , Rajiv Ratna Singh , Ian Shankland
发明人： David Nalewajek , Cheryl L. Cantlon , Andrew J. Poss , Rajiv Ratna Singh , Ian Shankland
IPC分类号： C09D11/00 , A61B5/117
CPC分类号： A61B5/1172
摘要： A method and composition for transforming a latent physiological biometric into a visible physiological biometric are provided, the method comprising: providing a latent biometric disposed on a surface of an article, wherein said biometric comprises at least one eccrine-derived compound; contacting said latent biometric with a developing solution, wherein said developing solution comprises at least one imaging reagent selected from ninhydrin and 1,8-diazafluoren-9-one and a carrier solvent comprising at least one C3-C4 hydrofluorocarbon; and reacting said imaging reagent with said eccrine-derived compound to produce a visible physiological biometric.
摘要翻译：提供了一种用于将潜在生理学生物转化为可见生理生物学的方法和组合物，所述方法包括：提供设置在制品表面上的潜伏生物测定，其中所述生物测定包含至少一种衍生化合物; 使所述潜在生物测定与显影溶液接触，其中所述显影溶液包含至少一种选自茚三酮和1,8-二氮杂芴-9-酮的成像试剂和包含至少一种C 3 -C 4氢氟烃的载体溶剂; 并使所述成像试剂与所述外分泌衍生的化合物反应以产生可见的生理学生物学特征。

24. 发明申请

US20120015863A1 CLEANING COMPOSITIONS AND METHODS 有权
标题翻译：清洁组合物和方法
公开(公告)号：US20120015863A1
公开(公告)日：2012-01-19
申请号：US13140176
申请日：2009-12-17
申请人： Rajat Basu , Gary Zyhowski , Kane Cook , David Nalewajek
发明人： Rajat Basu , Gary Zyhowski , Kane Cook , David Nalewajek
IPC分类号： D06M13/477 , C11D3/43 , C09K3/00 , C11D17/00 , D06B9/06 , F26B7/00
CPC分类号： C11D3/43 , C11D1/004 , C11D1/006 , C11D7/5018 , C23G5/02809 , C23G5/02825 , D06L1/04 , D06M13/453 , D06M23/10 , D06M2200/01
摘要： The invention provides solvent and cleaning compositions comprising an ionic surfactant, which preferably has a fluorinated portion thereof, and a solvent selected from hydrofluoro- and/or hydrochlorofluoro-olefins. Additionally, the invention provides drying, dry cleaning, and soil repellency compositions containing a hydrofluoro- or hydrochlorofluoro-olefin and said surfactant. Additionally, the invention provides drying compositions containing a hydrofluoro-olefin or hydrochlorofluoro-olefin and an alcohol such as methanol, ethanol or isopropanol.
摘要翻译：本发明提供溶剂和清洁组合物，其包含优选具有其氟化部分的离子表面活性剂和选自氢氟酸和/或氢氯氟烯烃的溶剂。此外，本发明提供了含有氢氟或氢氯氟烯烃和所述表面活性剂的干燥，干洗和疏水组合物。此外，本发明提供含有氢氟烯烃或氢氯氟代烯烃和醇如甲醇，乙醇或异丙醇的干燥组合物。

25. 发明申请

US20110288349A1 PROCESS FOR THE PRODUCTION OF FLUORINATED ALKENES 有权
标题翻译：生产氟化碱的方法
公开(公告)号：US20110288349A1
公开(公告)日：2011-11-24
申请号：US13110992
申请日：2011-05-19
申请人： Andrew Joseph Poss , David Nalewajek , Michael Van Der Puy , Haridasan K. Nair
发明人： Andrew Joseph Poss , David Nalewajek , Michael Van Der Puy , Haridasan K. Nair
IPC分类号： C07C17/278
CPC分类号： C07C21/18 , C07C17/206 , C07C17/25 , C07C17/278 , C07C17/354 , Y02P20/582 , C07C19/08 , C07C21/22 , C07C19/10
摘要： The present invention provides a method for the preparation of suitable chlorofluorocarbon and hydrochlorofluorocarbon materials or chlorofluorocarbon and hydrochlorofluorocarbon alkene and alkyne intermediates which serve as useful feedstock for fluorination and reduction to cis-1,1,1,4,4,4-hexafluoro-2-butene. Also presented is a continuous process for the production of cis-1,1,1,4,4,4-hexafluoro-2-butene from the alkene and alkyne intermediates.
摘要翻译：本发明提供了制备合适的氯氟烃和氢氯氟烃材料或氯氟烃和氢氯氟烃烯烃和炔烃中间体的方法，其用作氟化和还原成顺式-1,1,1,4,4,4-六氟-2 丁烯。还提出了从烯烃和炔烃中间体生产顺式-1,1,1,4,4,4-六氟-2-丁烯的连续方法。

26. 发明申请

US20110288346A1 PROCESS FOR CIS 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE 有权
标题翻译： CIS 1,1,1,4,4,4-HEXAFLOROR-2-BUTENE的方法
公开(公告)号：US20110288346A1
公开(公告)日：2011-11-24
申请号：US13110979
申请日：2011-05-19
申请人： Andrew Joseph Poss , David Nalewajek , Haridasan K. Nair , Michael Van Der Puy
发明人： Andrew Joseph Poss , David Nalewajek , Haridasan K. Nair , Michael Van Der Puy
IPC分类号： C07C17/354
CPC分类号： C07C17/278 , C07C17/04 , C07C17/206 , C07C17/23 , C07C17/25 , C07C17/354 , C07C19/10 , C07C21/22 , C07C21/18
摘要： Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluoropropene comprising the steps of (a) reacting CCl4 with a compound having the formula CF3CX═CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF3CXClCXHCCl3; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF3CXHCXHCF3; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF3C≡CCF3; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula:
摘要翻译：公开了一种制备顺式-1,1,1,4,4,4-六氟丙烯的方法，包括以下步骤：（a）使CCl4与具有式CF 3 C X = C X H的化合物反应，其中每个X独立地为卤素或氢，形成式CF3CXClCXHCCl3的化合物; （b）氟化步骤（a）中形成的化合物以形成具有式CF 3 C XHCXHCF 3的化合物; （c）通过选自脱卤化氢，脱卤和两种反应的反应转化步骤（b）中形成的化合物，以形成具有式CF 3C≡CCF3的化合物; 和（d）用氢气将步骤（c）中形成的化合物催化还原以形成具有下式的化合物：

27. 发明授权

US07605117B2 Methods of replacing refrigerant 有权
标题翻译：更换制冷剂的方法
公开(公告)号：US07605117B2
公开(公告)日：2009-10-20
申请号：US11109190
申请日：2005-04-18
申请人： David P. Wilson , Hang T. Pham , Rajiv R. Singh , Raymond H. Thomas , David Nalewajek
发明人： David P. Wilson , Hang T. Pham , Rajiv R. Singh , Raymond H. Thomas , David Nalewajek
IPC分类号： C11D7/50
CPC分类号： C09K3/30 , C08J9/144 , C08J2207/04 , C09K5/045 , C09K2205/126 , C09K2205/22 , C10M171/008 , C10M2207/042 , C10N2220/302 , C11D7/5063 , F25B9/006
摘要： Provided are azeotrope-like compositions comprising tetrafluoropropene and pentafluoropropene and uses thereof, including use in refrigerant compositions, blowing agent compositions, foamable compositions, foams, sterilant compositions, sprayable compositions, and systems and methods using same.
摘要翻译：提供包含四氟丙烯和五氟丙烯的类共沸组合物及其用途，包括用于制冷剂组合物，发泡剂组合物，可发泡组合物，泡沫，灭菌剂组合物，可喷雾组合物，以及使用它们的系统和方法。

28. 发明授权

US07049386B2 Compositions and methods for thermosetting molecules in organic compositions 失效
标题翻译：有机组合物中热固性分子的组成和方法
公开(公告)号：US07049386B2
公开(公告)日：2006-05-23
申请号：US10176335
申请日：2002-06-19
申请人： Kreisler S. Lau , Feng Quan Liu , Boris A. Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
发明人： Kreisler S. Lau , Feng Quan Liu , Boris A. Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
IPC分类号： C08G63/78
CPC分类号： C08G61/02 , C08G61/12 , C08G65/40 , C08G2650/60
摘要： In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arlyene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
摘要翻译：在制造低介电常数聚合物的方法中，提供了一种热固性单体，其中该热固性单体具有笼形化合物或芳基核心结构，以及共价结合笼形化合物或核心结构的多个臂。在随后的步骤中，将热固性单体引入聚合物中以形成低介电常数聚合物，其中掺入聚合物中包含位于至少一个臂中的三键的化学反应。沉积的笼状化合物和核心结构包括金刚烷，金刚烷，硅，苯基和亚噻吩基，而优选的臂包括芳烯，支链亚芳基和亚芳基醚。热固性单体可以有利地用于在电子器件中产生低k介电材料，并且聚合物的介电常数可以通过改变臂的整个长度来控制。

29. 发明授权

US06713590B2 Low dielectric constant materials with polymeric networks 失效
标题翻译：低介电常数材料与聚合网络
公开(公告)号：US06713590B2
公开(公告)日：2004-03-30
申请号：US10004584
申请日：2001-12-03
申请人： Kreisler S. Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
发明人： Kreisler S. Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
IPC分类号： C08G802
CPC分类号： C08G69/48 , C08G61/02 , C08G61/12 , C08G65/4012 , C08G2650/20 , C08G2650/60 , C08L2312/00
摘要： A low dielectric constant material has a polymeric network that is fabricated from a first and a second component. The first component comprises a polymeric strand, and the second component comprises a molecule having a central portion with at least three arms extending from the central portion, wherein each of the arms includes a backbone with a reactive group. The first component and the second component form the polymeric network in a reaction that involves at least one of the reactive groups when the first and second components are thermally activated. Contemplated low dielectric constant materials are advantageously employed in the fabrication of electronic devices, and particularly contemplated devices include integrated circuits.
摘要翻译：低介电常数材料具有由第一和第二组分制成的聚合物网络。第一组分包含聚合物链，并且第二组分包含具有至少三个从中心部分延伸的臂的中心部分的分子，其中每个臂包括具有反应性基团的主链。当第一和第二组分被热活化时，第一组分和第二组分在涉及至少一个反应性基团的反应中形成聚合物网络。考虑的低介电常数材料有利地用于制造电子器件，并且特别预期的器件包括集成电路。

30. 发明授权

US06579667B2 Radiation curable fluorinated vinyl ethers derived from hexafluoropropene 失效
标题翻译：衍生自六氟丙烯的可辐射固化氟化乙烯基醚
公开(公告)号：US06579667B2
公开(公告)日：2003-06-17
申请号：US10264380
申请日：2002-10-04
申请人： Haridasan K. Nair , David Nalewajek , David E. Bradley
发明人： Haridasan K. Nair , David Nalewajek , David E. Bradley
IPC分类号： G03F7028
CPC分类号： C07C43/17 , C07C43/172 , C07C43/176 , C07C2601/14 , C08F16/26 , C09D11/101 , G02B6/1221 , G02B6/13
摘要： Processes for producing optical devices by the steps of: (a) applying a layer of a photocurable composition onto a substrate; (b) imagewise exposing the photocurable composition to actinic radiation to form exposed and non-exposed areas on the substrate; and (c) removing the imagewise non-exposed areas while leaving the imagewise exposed areas on the substrate; wherein the photocurable composition includes: a curable component having at least one compound of the formula: R—O—X—O—CH═CH2 wherein R is R1—CFH—CF2— or R1—CF═CF—, in which R1 is selected from unsubstituted and substituted aliphatic radicals, unsubstituted and substituted cyclic aliphatic radicals, unsubstituted and substituted aromatic radicals, unsubstituted and substituted araliphatic radicals and unsubstituted and substituted heterocyclic radicals; and X is selected from unsubstituted and substituted aliphatic radicals, unsubstituted and substituted cyclic aliphatic radicals, unsubstituted and substituted aromatic radicals, unsubstituted and substituted araliphatic radicals and unsubstituted and substituted heterocyclic radicals; and a photoinitiator compound so that the composition is photocurable.
摘要翻译：通过以下步骤制造光学器件的方法：（a）将光可固化组合物层施加到基底上;（b）将光固化组合物成像曝光于光化辐射，以在基底上形成暴露和未曝光的区域; 并且（c）在将成像曝光区域留在基片上的同时去除成像非曝光区域;其中所述可光固化组合物包括：具有至少一种下式化合物的可固化组分：其中R为R 1 -CFH-CF 2 - 或R 1 -CF = CF-，其中R1选自未取代和取代的脂族基团，未取代和取代的环状脂族基团，未取代和取代的芳族基团，未取代和取代的芳脂族基团和未取代和取代的杂环基团; X选自未取代和取代的脂族基团，未取代和取代的环状脂族基团，未取代和取代的芳族基团，未取代和取代的芳脂族基团和未取代和取代的杂环基团; 和光引发剂化合物，使得组合物是光固化的。

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