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21. 发明授权

US5866290A Toner and developer compositions 失效
公开(公告)号：US5866290A
公开(公告)日：1999-02-02
申请号：US905040
申请日：1997-08-01
申请人： Guerino G. Sacripante , Robert D. Bayley , Carol A. Fox , Thomas R. Hoffend , Bernard Grushkin
发明人： Guerino G. Sacripante , Robert D. Bayley , Carol A. Fox , Thomas R. Hoffend , Bernard Grushkin
IPC分类号： C08G63/20 , G03G9/087 , G03G9/09
CPC分类号： G03G9/08788 , C08G63/20 , G03G9/08755 , G03G9/08793 , G03G9/0904 , Y10S430/105
摘要： A toner composition comprised of a polyester resin with hydrophobic end groups, colorant, optional wax, optional charge additive, and optional surface additives.

22. 发明授权

US5536615A Liquid developers and toner aggregation processes 失效
标题翻译：液体显影剂和调色剂聚集过程
公开(公告)号：US5536615A
公开(公告)日：1996-07-16
申请号：US498206
申请日：1995-07-05
申请人： Michael A. Hopper , Raj D. Patel , Grazyna E. Kmiecik-Lawrynowicz , Peter G. Odell , Bernard Grushkin , George A. Gibson
发明人： Michael A. Hopper , Raj D. Patel , Grazyna E. Kmiecik-Lawrynowicz , Peter G. Odell , Bernard Grushkin , George A. Gibson
IPC分类号： G03G9/08 , G03G9/12 , G03G9/135 , G03G9/13
CPC分类号： G03G9/12 , G03G9/0804 , G03G9/0819 , G03G9/1355
摘要： A process for the preparation of liquid developers comprising:(i) preparing a pigment dispersion, which dispersion is comprised of a pigment, and an ionic surfactant;(ii) shearing said pigment dispersion with a latex or emulsion blend comprised of a nonionic surfactant, resin, and a counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and optionally adding further anionic, or nonionic surfactant to stabilize the aggregates obtained in (iii);(iii) heating the above resulting sheared aqueous blend below about the glass transition temperature (Tg) of the resin to form toner size aggregates with a narrow particle size distribution;(iv) heating said bound aggregates above about the Tg of the resin to form toner size particles in an aqueous medium and which particles possess a narrow particle size distribution; and(v) separating from the aqueous medium toner particles of resin and pigment, and dispersing said toner particles in a carrier fluid.
摘要翻译：一种用于制备液体显影剂的方法，包括：（i）制备颜料分散体，该分散体由颜料和离子表面活性剂组成; （ii）用包含非离子表面活性剂，树脂和抗衡离子表面活性剂的胶乳或乳液共混物剪切所述颜料分散体，所述非离子表面活性剂，树脂和所述离子表面活性剂的电荷极性与所述离子表面活性剂具有相反的电荷极性，（iii）中得到的聚集体; （iii）将上述所得的剪切含水混合物加热到低于树脂的玻璃化转变温度（Tg）的温度以形成具有窄粒度分布的调色剂尺寸聚集体; （iv）将所述结合的聚集体加热到树脂的Tg附近，以在水性介质中形成调色剂颗粒，并且该颗粒具有窄的粒度分布; 和（v）从水性介质中分离树脂和颜料的调色剂颗粒，并将所述调色剂颗粒分散在载体流体中。

23. 发明授权

US5496676A Toner aggregation processes 失效
标题翻译：调色剂聚合过程
公开(公告)号：US5496676A
公开(公告)日：1996-03-05
申请号：US411196
申请日：1995-03-27
申请人： Melvin D. Croucher , Raj D. Patel , Grazyna E. Kmiecik-Lawrynowicz , Michael A. Hopper , Bernard Grushkin
发明人： Melvin D. Croucher , Raj D. Patel , Grazyna E. Kmiecik-Lawrynowicz , Michael A. Hopper , Bernard Grushkin
IPC分类号： G03G9/08 , G03G9/087
CPC分类号： G03G9/0815 , G03G9/0804
摘要： A process comprising:(i) preparing a pigment dispersion comprised of pigment, ionic surfactant, and optional charge control agent;(ii) mixing at least two resins in the form of latexes, each latex comprising a resin, ionic and nonionic surfactants and optionally a charge control agent, and wherein the ionic surfactant has a countercharge to the ionic surfactant of (i) to obtain a latex blend;(iii) shearing said pigment dispersion with the latex blend of (ii) comprised of resins, counterionic surfactant with a charge polarity of opposite sign to that of said ionic surfactant and a nonionic surfactant;(iv) heating the above sheared blends of (iii) below about the glass transition temperature (Tg) of the resin, to form electrostatically bound toner size aggregates with a narrow particle size distribution; and(v) subsequently adding further anionic surfactant solution to minimize further growth of the bound aggregates (vi);(vi) heating said bound aggregates above about the glass transition temperature Tg of the resin to form stable toner particles; and optionally(vii) separating and drying the toner.
摘要翻译：一种方法，包括：（i）制备由颜料，离子表面活性剂和任选的电荷控制剂组成的颜料分散体; （ii）混合至少两种胶乳形式的树脂，每种胶乳包含树脂，离子和非离子表面活性剂以及任选的电荷控制剂，并且其中所述离子表面活性剂与（i）的离子表面活性剂相反，以获得胶乳混合物（iii）用（ii）由树脂构成的胶乳混合物剪切所述颜料分散体，具有与所述离子表面活性剂相反的电荷极性的反离子表面活性剂和非离子表面活性剂; （iv）将上述（iii）的剪切混合物加热到约树脂的玻璃化转变温度（Tg）以下以形成具有窄粒度分布的静电结合的调色剂尺寸聚集体; 和（v）随后加入另外的阴离子表面活性剂溶液以使结合的聚集体（vi）的进一步生长最小化。（vi）将所述结合的聚集体加热到高于树脂的玻璃化转变温度Tg以形成稳定的调色剂颗粒; 和（vii）分离和干燥调色剂。

24. 发明授权

US5486443A Magnetic toner compositions with silica, strontium titanate and polyvinylidene fluoride 失效
标题翻译：具有二氧化硅，钛酸锶和聚偏二氟乙烯的磁性调色剂组合物
公开(公告)号：US5486443A
公开(公告)日：1996-01-23
申请号：US331444
申请日：1994-10-31
申请人： Michael L. Grande , Bernard Grushkin , Eugene F. Young , Douglas A. Lundy , Joseph R. E. Matalevich
发明人： Michael L. Grande , Bernard Grushkin , Eugene F. Young , Douglas A. Lundy , Joseph R. E. Matalevich
IPC分类号： G03G9/083 , G03G9/08 , G03G9/087 , G03G9/09 , G03G9/097
CPC分类号： G03G9/09766 , G03G9/0904 , G03G9/0914 , G03G9/09708 , G03G9/09725 , G03G9/08782
摘要： A toner comprised of resin particles, magnetite, carbon black, rhodamine charge additive, wax, and a surface mixture of silica, strontium titanate and polyvinylidene fluoride.
摘要翻译：由树脂颗粒，磁铁矿，炭黑，罗丹明电荷添加剂，蜡和二氧化硅，钛酸锶和聚偏二氟乙烯的表面混合物组成的调色剂。

25. 发明授权

US5482805A Magnetic toner compositions with aluminum oxide, strontium titanate and polyvinylidene fluoride 失效
标题翻译：具有氧化铝，钛酸锶和聚偏二氟乙烯的磁性调色剂组合物
公开(公告)号：US5482805A
公开(公告)日：1996-01-09
申请号：US331441
申请日：1994-10-31
申请人： Michael L. Grande , Bernard Grushkin , Eugene F. Young , Douglas A. Lundy , Joseph R. E. Matalevich
发明人： Michael L. Grande , Bernard Grushkin , Eugene F. Young , Douglas A. Lundy , Joseph R. E. Matalevich
IPC分类号： G03G9/083 , G03G9/087 , G03G9/09 , G03G9/097
CPC分类号： G03G9/097 , G03G9/083 , G03G9/0872 , G03G9/0904 , G03G9/0914
摘要： A toner comprised of resin particles, magnetite, carbon black, rhodamine charge additive, wax, and a surface mixture of aluminum oxide, strontium titanate and polyvinylidene fluoride.
摘要翻译：由树脂颗粒，磁铁矿，炭黑，罗丹明电荷添加剂，蜡和氧化铝，钛酸锶和聚偏二氟乙烯的表面混合物组成的调色剂。

26. 发明授权

US5061964A Developer unit using magnetic toner particles 失效
标题翻译：显影单元使用磁性调色剂颗粒
公开(公告)号：US5061964A
公开(公告)日：1991-10-29
申请号：US556500
申请日：1990-07-20
申请人： Jan Bares , John S. Berkes , Bernard Grushkin
发明人： Jan Bares , John S. Berkes , Bernard Grushkin
IPC分类号： G03G15/06 , G03G15/08 , G03G15/09
CPC分类号： G03G15/0907
摘要： An apparatus in which developer material comprising carrier granules and magnetic toner particles is transported closely adjacent to a latent image. The developer roller transporting the developer material is electrically biased. The electrical bias has a wave form that removes a substantially uniform distribution of magnetic toner particle sizes from the carrier granules and develops the latent image therewith.
摘要翻译：其中包含载体颗粒和磁性调色剂颗粒的显影剂材料紧密地传送到潜像附近的装置。传送显影剂材料的显影辊被电偏置。电偏压具有波形，其从载体颗粒中除去磁性调色剂颗粒的基本上均匀的分布并且与其形成潜像。

27. 发明授权

US4032339A Photosensitive composition containing vanadyl phthalocyanine for photoelectrophoretic imaging systems 失效
标题翻译：含有VANADYL PHTHOCOCANANINE用于光电成像系统的光敏组合物
公开(公告)号：US4032339A
公开(公告)日：1977-06-28
申请号：US689713
申请日：1976-05-24
申请人： Bernard Grushkin , Edward Forest , Leonard M. Carreira
发明人： Bernard Grushkin , Edward Forest , Leonard M. Carreira
IPC分类号： C09B47/08 , G03G5/06 , G03G5/07 , G03G17/04
CPC分类号： G03G5/071 , G03G17/04 , G03G5/0696 , G03G5/07
摘要： Photosensitive composition for use in photoelectrophoretic imaging system. The particulate component of this composition includes vanadyl phthalocyanine pigment particles which have been treated with a polymer having structural units of the formula ##STR1## WHEREIN Z is a pendant group of the formula ##STR2## X is a substituent substantially incapable of withdrawing electrons from the electron rich pyridinyl moiety;M is a whole number from 0 to 3; andN is a whole number in excess of 25.The intimate association of at least some of the polymer with at least some of the vanadyl phthalocyanine pigment is believed to effectively attenuate photoinjection of holes from the phthalocyanine pigment into the surrounding materials thereby both reducing the D.sub.min of the phthalocyanine pigment; and, to improve color separation of reproductions prepared by processes employing a subtractive color system.

28. 发明授权

US3965049A One-step synthesis of aromatic organic diselenides 失效
标题翻译：一步合成芳香族有机二硒化物
公开(公告)号：US3965049A
公开(公告)日：1976-06-22
申请号：US471376
申请日：1974-05-20
申请人： Bernard Grushkin , Michael N. Salzman
发明人： Bernard Grushkin , Michael N. Salzman
IPC分类号： C07C391/02 , C08G79/00 , C09B43/00 , G03G5/06 , G03G5/07 , C07D293/00 , C07D345/00
CPC分类号： C07C391/02 , C08G79/00 , C09B43/00 , G03G5/062 , G03G5/07 , C07C2103/24 , C07C2103/50
摘要： Disclosed is a novel method for the preparation of aromatic organic diselenide compounds. The method involves reacting an alkali metal diselenide with certain halogenated aromatic compounds in dimethylformamide to form the corresponding aromatic diselenide. The use of dimethylformamide enables one to prepare certain aromatic diselenide compounds containing two replaceable halogen atoms in a one-step process.
摘要翻译：公开了一种制备芳族有机二硒化合物的新方法。该方法包括在二甲基甲酰胺中使碱金属二硒化物与某些卤代芳族化合物反应形成相应的芳族二硒化物。使用二甲基甲酰胺使得能够在一步法中制备含有两个可替换卤素原子的某些芳族二硒化合物。

29. 发明授权

US06503677B1 Emulsion aggregation toner particles coated with negatively chargeable and positively chargeable additives and method of making same 有权
标题翻译：涂有带负电荷和可带正电荷的添加剂的乳液聚集调色剂颗粒及其制备方法
公开(公告)号：US06503677B1
公开(公告)日：2003-01-07
申请号：US09901085
申请日：2001-07-10
申请人： Edward J. Gutman , Bernard Grushkin , John G. Ruhland
发明人： Edward J. Gutman , Bernard Grushkin , John G. Ruhland
IPC分类号： G03G9097
CPC分类号： G03G9/09791 , G03G9/08755 , G03G9/097 , G03G9/09708 , G03G9/09716 , G03G9/09766 , G03G9/09775
摘要： An emulsion aggregation toner particularly adapted for use in hybrid scavengeless development includes toner particles of polymer binder, colorant and a surface additive package containing at least one additive negatively chargeable to a carrier and at least one additive positively chargeable to the carrier. The toner is able to exhibit high stable triboelectric charging ability, and substantially eliminates charge through and slow admix in a developer employing the toner.
摘要翻译：特别适用于杂交无花开发发展的乳液聚集调色剂包括聚合物粘合剂，着色剂的调色剂颗粒和包含至少一种负载于载体的添加剂的表面添加剂组合物和至少一种能够负载于载体的添加剂。调色剂能够表现出高稳定的摩擦带电能力，并且基本上消除了使用调色剂的显影剂中的电荷和缓慢混合。

30. 发明授权

US5914209A Single development toner for improved MICR 失效
标题翻译：单一显影调色剂，用于改善MICR
公开(公告)号：US5914209A
公开(公告)日：1999-06-22
申请号：US702533
申请日：1991-05-20
申请人： Bernard Grushkin
发明人： Bernard Grushkin
IPC分类号： G03G9/083 , G03G9/087 , G03G9/097
CPC分类号： G03G9/0837 , G03G9/0833 , G03G9/0835 , G03G9/0839 , G03G9/08782 , G03G9/09725
摘要： The use of a mixture of hard and soft magnetites as well as a lubricating wax in the formulation of single component developers is disclosed. The mixture allows for sufficient high remenance for MICR applications without high levels of magnetite loadings that can adversely affect the toner rheological properties and at the same time reduce sorter image abrasion.
摘要翻译：公开了在单组分显影剂的制剂中使用硬和软磁体的混合物以及润滑蜡。该混合物允许对MICR应用具有足够高的剩余量，而不会导致不利于影响调色剂流变性能的高水平磁铁矿负载，同时减少分选机图像磨损。

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