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    • 30. 发明申请
    • HIGH PERFORMANCE SILICON ELECTRODES HAVING IMPROVED INTERFACIAL ADHESION BETWEEN BINDER AND SILICON
    • 高性能硅电极具有改善的界面粘结性和粘结性
    • US20150228980A1
    • 2015-08-13
    • US14178541
    • 2014-02-12
    • GM GLOBAL TECHNOLOGY OPERATIONS LLC
    • Xiaosong Huang
    • H01M4/60H01M4/1399H01M4/62H01M4/48H01M4/04
    • H01M4/622H01M4/0404H01M4/134H01M4/1395H01M4/386Y02E60/122Y02P70/54
    • Methods for making a negative electrode material for use in an electrochemical cell, like a lithium ion battery, are provided. The electroactive material comprises silicon. The electroactive material comprises a functionalized surface having a grafted reactive group (e.g., an epoxide group, an amino group, a carboxyl group, and the like). The functionalized surface is admixed and reacted with a polymeric binder (e.g., polyalkylene oxide (PAO), polyvinylidene difluoride (PVDF), polymethylmethacrylate (PMMA), polyimide (PI), and the like that also has at least one reactive functional group) and optionally electrically conductive particles. A porous solid electrode material is thus formed. Negative electrodes are also provided, which provide significant performance benefits and reduce the issues associated with capacity fade, diminished electrochemical cell performance, cracking, and short lifespan associated with conventional silicon anode materials.
    • 提供了制造用于电化学电池的负极材料的方法,如锂离子电池。 电活性材料包括硅。 电活性材料包括具有接枝反应性基团(例如环氧基,氨基,羧基等)的官能化表面。 将官能化表面与也具有至少一个反应性官能团的聚合物粘合剂(例如聚环氧烷(PAO),聚偏二氟乙烯(PVDF),聚甲基丙烯酸甲酯(PMMA),聚酰亚胺(PI)等)混合并反应, 任选的导电颗粒。 由此形成多孔固体电极材料。 还提供负电极,其提供显着的性能优点并减少与常规硅阳极材料相关的容量衰减,电化学电池性能降低,开裂和短寿命相关的问题。