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21. 发明授权

US3991164A Process for the dearsenication of polyphosphoric acid 失效
标题翻译：多磷酸脱砷的方法
公开(公告)号：US3991164A
公开(公告)日：1976-11-09
申请号：US514450
申请日：1974-10-15
申请人： Wolfgang Scheibitz , Hasso Spott , Gero Heymer
发明人： Wolfgang Scheibitz , Hasso Spott , Gero Heymer
IPC分类号： C01B25/24 , C01B21/16
CPC分类号： C01B25/24
摘要： Polyphosphoric acid is dearsenicated by placing the polyphosphoric acid in a reactor; adding a phosphorus oxo-compound containing phosphorus in the monovalent or trivalent electropositive oxidation stage; heating the resulting mixture to effect disproportionation of the phosphorus oxo-compound; and removing the resulting off-gas having arsenic therein.
摘要翻译：多磷酸通过将多磷酸置于反应器中来进行脱砷; 在一价或三价正电氧化阶段加入含磷磷氧化合物; 加热所得混合物以实现磷氧化合物的歧化; 并除去其中具有砷的所得废气。

22. 发明授权

US4596703A Process for purifying wet-processed phosphoric acid 失效
标题翻译：净化湿法磷酸的方法
公开(公告)号：US4596703A
公开(公告)日：1986-06-24
申请号：US557111
申请日：1983-12-01
申请人： Reinhard Gradi , Gero Heymer , Gunther Schimmel
发明人： Reinhard Gradi , Gero Heymer , Gunther Schimmel
IPC分类号： C01B25/234 , C01B25/46 , C01B25/16 , C01B15/16 , C01B25/26
CPC分类号： C01B25/461 , C01B25/462
摘要： The disclosure relates to a process for purifying crude, concentrated wet-processed phosphoric acid. To this end, the disclosure provides:(a) for the organic solvent to be mixed with the starting product in a ratio by volume of more than 4:1 to effect the extraction in a single process step--from the crude wet-processed phosphoric acid--of a quantity of phosphoric acid necessary for 40 to 70 weight % of the P.sub.2 O.sub.5 used to go into the organic phase, and for the resulting aqueous phosphoric acid raffinate to contain at most 28-32 weight % P.sub.2 O.sub.5, and for the organic phosphoric acid solution to be separated from the phosphoric acid raffinate;(b) for the separated organic phosphoric acid solution to be scrubbed with a quantity of scrubbing solution corresponding at most to 5% of the volume of the phosphoric acid solution; for the scrubbing solution to be recycled into stage (a), and for purified phosphoric acid and phosphate salt solution, respectively, to be recovered in known manner from the scrubbed phosphoric acid solution; and(c) for the aqueous phosphoric acid raffinate produced in stage (a), if desired after prior removal of residual solvent therefrom, to be directly utilized or subjected to known purifying treatment.
摘要翻译：本公开涉及纯化粗浓缩湿法磷酸的方法。为此，本公开内容提供：（a）使有机溶剂与起始产物以体积比大于4:1的比例混合以在单一工艺步骤中进行萃取，从粗制湿法磷酸酸为一定量的磷酸，用于进入有机相中的40〜70重量％的P2O5，所得到的磷酸提取液含有最多28-32重量％的P2O5，对于有机磷酸酸性溶液与磷酸提余液分离; （b）对于待洗涤的分离的有机磷酸溶液，其量为相当于磷酸溶液体积的至多5％的洗涤溶液; 将洗涤溶液再循环到阶段（a）中，分别用纯化的磷酸和磷酸盐溶液从已洗涤的磷酸溶液中以已知方式回收; 和（c）如果需要，在步骤（a）中制备的磷酸残液水溶液中，在预先除去残余溶剂之后，直接使用或进行已知的纯化处理。

23. 发明授权

US4346065A Process for the manufacture of finely dispersed sparingly soluble salts of oxyacids of phosphorus 失效
标题翻译：用于制造磷的含氧酸的微细分散的微溶盐的方法
公开(公告)号：US4346065A
公开(公告)日：1982-08-24
申请号：US222079
申请日：1981-01-02
申请人： Alexander Maurer , Renate Adrian , Gero Heymer
发明人： Alexander Maurer , Renate Adrian , Gero Heymer
IPC分类号： C01B25/16 , C01B25/163 , C01B25/26 , C01B25/32 , C01B25/34 , C01B25/37 , C01B25/42 , C09D5/08 , C01B15/16 , C04B11/22
CPC分类号： C01B25/322 , C01B25/16 , C01B25/163 , C01B25/265 , C01B25/34 , C01B25/37 , C01B25/377 , C01B25/42 , C09D5/084
摘要： The invention relates to a process for making a finely dispersed, sparingly soluble salt of an oxyacid of phosphorus, having a maximum particle size of 20 .mu.m, by reacting a compound of a divalent metal with the oxyacid of phosphorus or an alkali metal or ammonium salt thereof. More particularly, finely dispersed salt consisting to an extent of at least 90% of particles with a size between 0.05 and 7 .mu.m is made. To this end, an at least 5% by weight aqueous solution or suspension of a compound of a divalent metal selected from the group Mg, Ca, Sr, Ba, Mn, Zn, Cu, Cd, Pb, Sn, Co and Ni is reacted, while maintaining a pH range of between 3 and 9 and while stirring, with an at least 2 mol % solution of at least one trivalent metal selected from the group Al, Fe and Cr in the oxyacid of phosphorus and, optionally, with an aqueous solution of an alkali metal or ammonium salt of the oxyacid of phosphorus, and the precipitated salt is separated off and dried.
摘要翻译：本发明涉及通过使二价金属的化合物与磷或碱金属或铵的含氧酸反应来制造磷的含氧酸的微细分散，微溶的最大粒度为20μm的盐的方法的盐。更具体地说，制备了至少90％粒度在0.05和7μm之间的颗粒的程度的精细分散的盐。为此，选自Mg，Ca，Sr，Ba，Mn，Zn，Cu，Cd，Pb，Sn，Co和Ni中的二价金属的化合物的至少5重量％的水溶液或悬浮液是反应，同时保持pH范围在3和9之间并在搅拌的同时，使用至少2mol％的选自Al，Fe和Cr中的至少一种选自Al，Fe和Cr的三价金属的溶液在磷的含氧酸中，并且任选地与将磷酸的含氧酸的碱金属或铵盐的水溶液分离出来并干燥。

24. 发明授权

US4279878A Process for freeing phosphoric acid from organic contaminants 失效
标题翻译：从有机污染物中释放磷酸的方法
公开(公告)号：US4279878A
公开(公告)日：1981-07-21
申请号：US131234
申请日：1980-03-17
申请人： Alexander Maurer , Klaus Schrodter , Gero Heymer
发明人： Alexander Maurer , Klaus Schrodter , Gero Heymer
IPC分类号： C01B25/237 , B01J23/00 , C01B25/235 , C01B25/16
CPC分类号： C01B25/235
摘要： The invention relates to a process for freeing aqueous phosphoric acid solutions from organic contaminants. To this end, the solutions are admixed and reacted with hydrogen peroxide in the presence of a catalyst consisting of a noble metal or metal oxide being inert with respect to phosphoric acid or of a mixture of said noble metal and metal oxide.
摘要翻译：本发明涉及从有机污染物中释放磷酸水溶液的方法。为此，在由相对于磷酸或所述贵金属和金属氧化物的混合物呈惰性的贵金属或金属氧化物组成的催化剂存在下，将溶液混合并与过氧化氢反应。

25. 发明授权

US4156697A Production of alkylphosphines 失效
标题翻译：生产烷基膦
公开(公告)号：US4156697A
公开(公告)日：1979-05-29
申请号：US823140
申请日：1977-08-09
申请人： Klaus Hestermann , Hartfrid Vollmer , Gero Heymer , Ernst-Gunther Schlosser
发明人： Klaus Hestermann , Hartfrid Vollmer , Gero Heymer , Ernst-Gunther Schlosser
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines of the general formula:R.sub.n PH.sub.3-n (I)are made. To this end hydrogen phosphide, a primary or a secondary phosphine is reacted with an alkylamine of the general formula:R.sub.n NH.sub.3-n (II)in a molar ratio of 0.1 to 10 mols of the alkylamine of formula II per mol of hydrogen phosphide or primary or secondary phosphine. The reaction is effected at a 150.degree. to 400.degree. C., at atmospheric pressure or a superatmospheric pressure up to 1 atmosphere gauge, and in contact with a catalyst comprising active carbon, copper (II) chromite, or one or more metals of Group Ib or VIII of the Periodic System of the elements. The starting materials are passed through a reaction zone at a rate which permits a contact time between them and the catalyst of 0.1 to 400 seconds.
摘要翻译：具有以下通式的烷基膦：

26. 发明授权

US4150058A Production of alkyl phosphines 失效
标题翻译：烷基膦的生产
公开(公告)号：US4150058A
公开(公告)日：1979-04-17
申请号：US904027
申请日：1978-05-08
申请人： Klaus Hestermann , Gero Heymer
发明人： Klaus Hestermann , Gero Heymer
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines are made. To this end, phosphorus in vapor form is reacted with steam and an alkyl amine at elevated temperature in contact with a carbon catalyst placed in a reactor, the reactants being used individually or in admixture with one another.
摘要翻译：制备烷基膦。为此，蒸气形式的磷与蒸汽和烷基胺在升高的温度下与放置在反应器中的碳催化剂接触，反应物单独使用或彼此混合使用。

27. 发明授权

US4128620A Production of phosphine 失效
标题翻译：生产磷化氢
公开(公告)号：US4128620A
公开(公告)日：1978-12-05
申请号：US830160
申请日：1977-09-02
申请人： Jurgen Stenzel , Gero Heymer
发明人： Jurgen Stenzel , Gero Heymer
IPC分类号： C01B25/06 , C01B25/37 , C01B25/00
CPC分类号： C01B25/37 , C01B25/06
摘要： Production of phosphine. The phosphine is produced by reducing, in a first step, anhydrous zinc phosphate to zinc phosphide by treatment with carbon at a temperature higher than 1000.degree. C, and, in a second step, reacting the zinc phosphide formed in the first step with phosphoric acid. The resulting gaseous phosphine is collected, and the resulting zinc phosphate, which is obtained as a difficultly soluble precipitate, is dried, dehydrated and recycled to the first step.
摘要翻译：生产磷化氢。通过在高于1000℃的温度下用碳处理将第一步中的无水磷酸锌还原为磷化锌，并且在第二步骤中，使第一步中形成的磷化锌与磷酸。收集所得的气态膦，将得到的作为难溶性沉淀物得到的磷酸锌干燥，脱水并再循环至第一步。

28. 发明授权

US4091078A Production of phosphine 失效
标题翻译：生产磷化氢
公开(公告)号：US4091078A
公开(公告)日：1978-05-23
申请号：US736556
申请日：1976-10-28
申请人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
发明人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
IPC分类号： C01B25/06 , C01B25/00
CPC分类号： C01B25/06
摘要： Phosphine is produced from elementary yellow phosphorus and an aqueous alkali metal hydroxide solution in the presence of an alcohol. The phosphine is more particularly made by using an alcohol having from 5 to 10 carbon atoms and a dissolving power for yellow phosphorus of more than 5 g/l; suspending the phosphorus with agitation in the said alcohol in a reaction zone; reacting the resulting suspension with the alkali metal hydroxide solution at temperatures lower than the boiling point of the alcohol; and collecting the resulting issuing gaseous phosphine.
摘要翻译：在醇的存在下，由元素黄磷和碱金属氢氧化物水溶液生产磷化氢。膦更特别地通过使用具有5至10个碳原子的醇和大于5g / l的黄磷的溶解力来制备; 在反应区内搅拌将磷悬浮在所述醇中; 在低于醇的沸点的温度下使得到的悬浮液与碱金属氢氧化物溶液反应; 并收集产生的发出的气态膦。

29. 发明授权

US4073810A Production of organophosphines 失效
标题翻译：生产有机膦
公开(公告)号：US4073810A
公开(公告)日：1978-02-14
申请号：US549172
申请日：1975-02-12
申请人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
发明人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
IPC分类号： B01J21/00 , C07B61/00 , C07F9/50 , C07F9/53 , C07F9/54
CPC分类号： C07F9/5086 , C07F9/54
摘要： Production of organophosphines of the general formula R.sub.n PH.sub.3-n, in which R stands for identical or different, substituted or unsubstituted alkyl, cycloalkyl or aralkyl groups having from 1 to 18 carbon atoms, preferably from 1 to 4 carbon atoms, more preferably from 1 to 2 carbon atoms, and n stands for a whole number within the range 1 and 3. The compounds are more particularly produced by continuously reacting hydrocarbon halides of the general formula RX, in which R has the meaning given hereinabove and X stands for halogen, especially for chlorine or bromine, with hydrogen phosphide, and primary or secondary organophosphines at temperatures within the range 100.degree. and 600.degree. C. and under pressures of up to 20 atmospheres in contact with a catalyst being placed in a reactor. Gaseous matter issuing from the reactor is cooled and the resulting organophosphonium halides (R.sub.n PH.sub.4-n)X are hydrolyzed in conventional manner to the corresponding organophosphines.
摘要翻译：制备通式RnPH3-n的有机膦，其中R代表相同或不同的取代或未取代的具有1至18个碳原子，优选1至4个碳原子的烷基，环烷基或芳烷基，更优选1至 2个碳原子，n表示1和3范围内的整数。化合物更特别地通过连续反应通式RX的卤代烃，其中R具有上文给出的含义，X代表卤素，特别是对于氯或溴，与磷化氢以及初级或次级有机膦在100℃和600℃的温度范围内以及在与置于反应器中的催化剂接触的情况下在高达20个大气压的压力下进行。将从反应器排出的气态物质冷却，并将所得的有机鏻卤化物（RnPH4-n）X以常规方式水解成相应的有机膦。

30. 发明授权

US4042324A Process for inhibiting the corrosions and deposition of boiler scale in water-conveying systems 失效
标题翻译：防止锅炉水垢在水输送系统中的腐蚀和沉积的过程
公开(公告)号：US4042324A
公开(公告)日：1977-08-16
申请号：US654885
申请日：1976-02-03
申请人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
发明人： Theodor Auel , Hannsjorg Ulrich , Horst-Dieter Wasel-Nielen , Gero Heymer
IPC分类号： C02F5/14 , C07F9/38 , C23F11/167 , C02B5/06 , C23F11/16
CPC分类号： C23F11/1676 , C02F5/14 , C07F9/3808 , C23F11/167
摘要： Corrosion and deposition of boiler scale in water-conveying systems are inhibited. To this end the water is admixed with at least one carboxy-alkane compound of phosphorus of the general formula: ##STR1## in which each of the substituents R.sup.1, R.sup.2, R.sup.3, and R.sup.4 stands for hydrogen or an alkyl group having from 1 to 4 carbon atoms, R.sup.5 stands for hydrogen, an OH-group or an alkyl group having from 1 to 3 carbon atoms, and n stands for 0 or 1, or with at least one water-soluble salt thereof.
摘要翻译：锅炉秤在输水系统中的腐蚀和沉积受到抑制。为此，将水与至少一种以下通式的磷的羧基烷烃化合物混合：其中每个取代基R 1，R 2，R 3和R 4代表氢或具有1至 4个碳原子，R5代表氢，OH-基团或具有1至3个碳原子的烷基，n代表0或1，或其至少一种水溶性盐。

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